1. Introduction
Magnesium (Mg) alloys are composed of magnesium based on the addition of other elements, normally added elements such as Al, Zn, and Mn [
1]. As one of the most widely used metallic materials in contemporary industry, Mg alloys are regarded as the green industrial materials of the 21st century [
2,
3]. The density of Mg alloy is low, only two-thirds that of Al, making it the lightest engineering material available [
4]. Mg alloys have good heat dissipation, high specific strength, high specific stiffness, a high modulus of elasticity, good damping properties, and cutting properties [
5]. It also exhibits excellent physical and chemical properties such as good biocompatibility, good recyclability, high hydrogen storage capacity, and a high theoretical specific capacity of the battery [
6,
7]. Owing to their excellent physical and chemical properties, Mg alloys are used in the aerospace, automotive, electronics, biomedical, and energy industries [
8,
9]. Nonetheless, the low hardness, poor wear resistance, and weak corrosion resistance of Mg alloys limit their further promotion [
10,
11,
12].
For the improvement of the surface properties of Mg alloys, laser cladding technology is widely applied. Asghar et al. [
13] successfully fabricated Ni60 coatings on LA43M Mg alloys by using the ultra-high-speed laser cladding technique and obtained superior surface mechanical properties. Sundaraselvan et al. [
14] used laser melting technology to surface modify the AZ61 Mg alloy with nano-Al
2O
3 and investigated the strengthening effect of nanoceramic particles. Studies have shown that laser cladding of alloy coatings can effectively address surface property defects in Mg alloys [
15,
16,
17,
18]. The binary alloys are often similar in composition to the matrix material, possess good physical and chemical compatibility with the matrix, and bond firmly after fusion coating [
19,
20,
21,
22]. Dziadoń et al. [
23] investigated the microstructure of the surface layer of Mg laser alloyed with Al-Si. The differences in the microstructure of surface layers corresponded to the differences in their wear resistance and corrosion resistance. Zhang et al. [
24] prepared an Al-Si coating on the surface of a Mg-6Zn-1Ca alloy using laser cladding in order to improve the surface properties of Mg alloys. The results revealed that the coating mainly consisted of α-Mg, Mg
2Si dendrites, Mg
17Al
12, and Al
3Mg
2 phases. The microhardness of the coating (310 HV) was approximately five times higher than that of the substrate (54 HV). Wang [
25] et al. designed three melting solutions by using pulsed direct current (P-DC) cold arc on the surface of AZ61 Mg alloy, namely Al-Si alloy (AlSi
5), Al-Mn alloy (AlMn), and Al-Mg alloy (AlMg
5). The Al-Si alloy coating had the lowest wear rate, approximately 13.9% of that of the matrix. Laser cladding Al-Si alloy coatings significantly improves the surface properties of the Mg alloys. Additionally, the microstructure formed by adding Y
2O
3 has pronounced effects on the friction and wear characteristics of the coating [
26,
27,
28]. There is quite limited research into the improvement of Mg alloy surface coatings by means of Y
2O
3. Moreover, the relevant research mainly focuses on the improvement of coating performance by low rare earth oxide addition, and some research only takes it as one of the variables [
29,
30]. Therefore, studying the addition of rare earth oxides as the only variable and in the higher range is quite beneficial.
The AZ91 series of Mg alloys has the advantages of high yield, mature technology, and promising development. In this paper, the AZ91HP Mg alloy, which has better performance in the AZ91 series, was chosen as the substrate. The surface properties were improved by preparing Al-Si alloy coatings with Y2O3 through laser cladding technology. The research focused on the effect of various Y2O3 contents on the microstructure, Vickers hardness, and wear resistance of the cladding. The findings provide an experimental foundation and theoretical guidance for further improvement of the microstructure and wear properties of Mg alloys.
3. Results and Discussion
Figure 1 shows the macroscopic surface morphology of the coatings with various Y
2O
3 contents. As seen in
Figure 1, the coatings exhibit a metallic lustre. The surface of the five specimens shows no oxidation blackening, which indicates that the protective gas flow rate was controlled within a reasonable range. The relatively flatter coating can be clearly observed in
Figure 1b–e. This indicates that the addition of Y
2O
3 increases the absorption of the laser, which results in a more uniform heating of the coating. Some porosities can be observed in
Figure 1a,b,e. The poor fluidity of the melt pool leads to the formation of cavities, whereas the addition of Y
2O
3 can significantly improve the fluidity of the melt pool [
29,
30,
31]. The coatings in
Figure 1a,b have poor melt pool fluidity caused by the absence of Y
2O
3 or low Y
2O
3 content, resulting in the appearance of porosities. The coatings in
Figure 1c,d have no porosity owing to the moderate addition of Y
2O
3, which improves the fluidity of the coating and allows the gases generated during the laser cladding process to escape before the melt pool solidifies. While some porosities are generated again in
Figure 1e caused by the addition of excessive amounts of Y
2O
3, resulting in the blocking of the melt pool flow and impeding the discharge of gas.
Figure 2 presents the XRD results of the laser cladding coatings with various Y
2O
3 contents. As shown, the coatings containing Y
2O
3 mainly consist of Mg
17Al
12, Mg
2Al
3, Mg
2Si, Al
4MgY, and α-Mg, while the Al
4MgY phase is absent in coatings without Y
2O
3 addition. The original phases in the AZ91HP Mg alloy are Mg
17Al
12 and α-Mg. Due to the effect of the high-energy laser beam, the Mg alloy fully reacts with the coating material to produce a variety of intermetallic compounds as well as Al
4MgY rare earth compounds. The diffraction peaks of the coating are concentrated between 35° and 40° with the high peaks being all Mg-containing phases, indicating that Mg diffuses into the coating through the melt pool and reacts fully with the coating elements to produce a variety of phase structures. Furthermore, the addition of Y
2O
3 resulted in a significant alteration in the phase diffraction intensity of the coating, as shown by the fact that a high peak at 36° appears in the coating without Y
2O
3, while a trend of decreasing and then increasing a peak at 36° occurs with increasing Y
2O
3 content. Similarly, a peak of 39° occurs in the coating without Y
2O
3, while the peak shows an increasing trend as the Y
2O
3 content increases from 2.5 to 10.0 wt.%.
Figure 3 illustrates the cross-sectional microstructure of the coating with various Y
2O
3 contents. The coating consists of four parts, from top to bottom: the cladding zone (CZ), the bonding zone (BZ), the heat-affected zone (HAZ), and the substrate. The strip between the coating and the substrate is wavy. The reason for this is that the different melting points of the native α-Mg in the Mg alloy and the dissociated eutectic tissue at the grain boundaries, leads to a different amount of melting at different locations on the surface of the substrate. Thus, the surface of the substrate appears as a local melting depression area, which makes the solidified substrate and coating bonding interface wavy. This further confirms that the coating shows a good metallurgical bond with the substrate.
Figure 4 shows the results of the line scan of the coating cross-sections with various Y
2O
3 contents. Using the internal direction of the coating as the positive horizontal axis and the elemental content as the vertical axis, it can be seen that the elemental content of Mg gradually increases and rises steeply at the interface between the substrate and the coating, reaching a maximum in the substrate, while the elemental content of Al shows a decreasing trend, reaching a minimum in the substrate. The most abundant element in the coating is Mg, which reveals that the substrate surface layer melts instantly under the action of the laser to form a molten pool. It is conducive to a good bond between the coating material and the substrate, but this also results in the problem of an excessive dilution rate. From
Figure 4a–d, the Mg element content in the coating gradually decreases as the Y
2O
3 content increases until the Y
2O
3 content is 7.5 wt.%, at which point the minimum amount of elemental Mg is reached and the lowest dilution rate is achieved. This is because Y
2O
3 has a very high melting point. Incorporating it into the coating increases the latent heat of melting the alloy powder, lowers the liquid phase temperature in the melt pool, raises the solid phase temperature, and reduces the time for solidification, which allows less time for the elements to diffuse [
32,
33]. This allows more of the coating elements to remain in the melt pool and inhibits the massive influx of Mg elements into the coating, thus enhancing the surface properties. In addition, the high melting point Y
2O
3 does not melt rapidly at the first stage of melt pool formation; instead, it is dispersed in different parts of the melt pool to absorb energy, slowing down the increase in melt pool temperature, reducing the movement of Mg atoms, and slowing down element diffusion. As the Y
2O
3 content continues to increase, the Mg element content in the coating begins to rise, as shown in
Figure 4e, indicating that the addition of excessive Y
2O
3 will increase the dilution rate of the coating. This is attributed to the presence of the higher melting point Y
2O
3 in the melt pool over a large area, which impedes the convection between the Mg alloy and the Al-Si alloy in the molten state and reduces the convective heat exchange efficiency in the melt pool. This prolongs the existence of the melt pool and increases the opportunity for chemical element diffusion, which allows a large number of Mg atoms to enter the coating and the dilution rate to rise. The Mg content of the coatings with Y
2O
3 is lower than that of the coatings without Y
2O
3, which means that the addition of Y
2O
3 in the right amount can reduce the dilution rate of the coatings.
Figure 5 shows the microstructure of the coating with a Y
2O
3 content of 2.5 wt.%. The coating consists mainly of dendritic crystals (1), a punctate phase (2), a matrix phase (3), and an acicular phase (4). Dendrites are generated because the grains within the coating are rough interfacial structures at the time of crystallization and the temperature gradient is negative, with a large but unstable supercooling at the front of the solid-liquid interface. The crystallization proceeds in that direction when the supercooling at the rest of the interface spikes, thus making it more favorable for the tip to grow in that direction. The tip also grows laterally, but not as fast as the front of the tip due to the latent heat of crystallization, resulting in the tip growing rapidly into elongated grains called primary dendrites. The secondary dendrites are those that grow in other directions due to fluctuations in the surrounding supercooling. The latent heat of crystallization causes the subcooling to decrease below a critical level, so the free energy generated during crystallization is lower than the surface free energy, allowing secondary dendrites to not continue to grow and form dendrite-like grains.
The point scan of the points in
Figure 5 using EDS gave the chemical element composition as shown in
Table 3. The ratio of Mg atoms to Si atoms at point 1 is approximately 2:1, which is close to the atomic ratio of the Mg
2Si phase, so the phase is judged to be the Mg
2Si hard phase. The ratio of Al, Mg, and Y atoms at point 2 is approximately 4:1:1, so this is the Al
4MgY phase. The ratio of Mg atoms to Al atoms at point 3 is approximately 3:2, which is close to the atomic ratio of Mg
17Al
12, indicating that this phase is Mg
17Al
12. The ratio of Mg atoms to Al atoms at point 4 is approximately 2:3, indicating that this phase is Mg
2Al
3.
Figure 6 illustrates the evolution of the microstructure for the 2.5 wt.% Y
2O
3 coating at different depths. A clear change in grain morphology from the top to the bottom of the coating can be observed.
Figure 6a reveals the top of the coating, where the grains are relatively sparse but fine. This is because the surface layer is exposed to direct laser light, resulting in the burnout of some elements, so there is a relatively loose microstructure. There are many channels for heat dissipation from the top of the coating, which means that free energy drops more quickly in the upper part of the melt pool, making the conversion of the surface liquid phase into a solid phase more dynamic. The rapid drop in temperature causes the top layer to have a lower actual crystallization temperature, resulting in a larger degree of subcooling. This leads to a refinement of the grain size, so the top layer has finer grains.
Figure 6b shows the microstructure of the upper-middle part of the coating. The microstructure is much denser and has the finest grain size, exhibiting the best overall coating quality. There is no significant elemental burning as in the surface layer, and some of the slag and impurities from the laser coating float up to this area, which provides nuclei for crystallization and thus increases the nucleation rate to refine the grains.
Figure 6c shows the lower-middle of the coating. The grains in
Figure 6c are significantly coarser than in the upper part. This is because the microstructure has limited heat dissipation channels during crystallization, and there is a loss of laser energy density transfer resulting in a low melt pool temperature, which reduces subcooling and coarsens the grains.
Figure 6d depicts the bottom of the coating. The microstructure in this area has the coarsest grains. This area has the worst heat dissipation and is affected by the latent heat of crystallization in the upper layers, which causes poor fluidity and low nucleation rates, producing grains that are coarse.
Figure 7 illustrates the microstructure of the coatings with different Y
2O
3 contents. As shown, the coating without Y
2O
3 has the coarsest grains, while the coating microstructure is significantly refined after the addition of Y
2O
3. The coating microstructure gradually becomes finer with the increase of Y
2O
3 content in a certain range, and the coating microstructure is finest when the content of Y
2O
3 is 7.5 wt.%. This is attributed to the denser Y
2O
3, which tends to enrich at the front end of the solid-liquid interface, thus increasing the component subcooling of the coating. As the Y
2O
3 content increases, the subcooling is greater, which refines the grain size. Additionally, the increased Y
2O
3 content improves the absorption rate of the coating material by the laser, which makes the coating more uniformly heated, resulting in a denser and more homogeneous microstructure. The addition of Y
2O
3 also increases the nucleation rate during melt pool crystallization. The high melting point of Y
2O
3 acts as a heterogeneous impurity, offering ready-made nuclei for crystallization, which increases the number of nuclei and thus refines the microstructure [
27]. When the Y
2O
3 content exceeds 7.5 wt.%, the grain coating becomes coarser, but it still outperforms the coating without Y
2O
3, as shown in
Figure 7e. This is because the excess Y
2O
3 is difficult to melt in the melt pool, which impedes convective heat exchange in the melt pool and reduces the degree of subcooling during crystallization, resulting in a reduction in grain refinement. Moreover, when Y
2O
3 acts as a heterogeneous mass to provide nucleation, excessive content results in its massive enrichment. This reduces the available nucleation substrate, and heterogeneous nucleation ceases once the nucleation substrate is completely encapsulated by the crystal nucleus, resulting in a decrease in the nucleation rate and a reduction in the number of grains.
The hardness curves of the coatings with different Y
2O
3 contents are presented in
Figure 8. The curves are roughly divided into three parts: the surface of the melt layer; the melt zone; the heat-affected zone. The hardness of the coatings prepared by laser cladding technology (226.3–285.0 HV) is much higher than that of the substrate (80.0 HV). This is owing to the presence of phases such as Mg
2Si, Mg
2Al
3, and Al
4MgY in the coating, which have a finer grain structure, a higher hardness, and are distributed in various parts of the coating, impeding dislocation movement and greatly enhancing the hardness of the coating. The coating also exhibits a significant refinement of the microstructure, which leads to a fine crystal strengthening effect, resulting in a much higher hardness than the substrate. The hardness of each coating follows a trend of increasing, then leveling off, and finally decreasing to the substrate hardness, with the maximum hardness occurring in the melt zone of the coating. This is because the direct irradiation of the laser causes burnout of the most superficial elements, which results in a thinning of the surface microstructure and a reduction in hardness. With the increase in Y
2O
3 content, the average hardness of each coating in order is 226.3 HV, 266.0 HV, 273.8 HV, 285.0 HV, and 234.8 HV. The hardness of the coating is seen to increase and then decrease as the content of Y
2O
3 increases, reaching a maximum value (285.0 HV) at 7.5 wt.% Y
2O
3. The addition of Y
2O
3 increases the subcooling of the crystals, which improves the nucleation rate and limits the growth of the grains, thus increasing the degree of grain refinement with increasing content. Furthermore, the decomposition of Y
2O
3 in the melt pool produces rare earth compounds. The compounds possess the effect of purifying the melt pool, which results in a denser and more homogeneous melt pool, increasing the hardness. The average hardness of the coating starts to decrease as the Y
2O
3 content continues to increase but remains higher than the average hardness of the coating without the Y
2O
3. An excessive amount of Y
2O
3 (over 7.5 wt.%) increases the overall melting point of the coating, decreases the subcooling, and reduces the nucleation rate, causing coarsening of the grains and a decrease in hardness.
The wear volume of the coating with various Y
2O
3 contents is presented in
Figure 9. As shown, the wear volume of the coating is significantly lower than that of the substrate. The presence of the hard phase in the coating changes the contact between the coating and the grinding ball, decreasing the contact area and reducing the tendency to adhere. The coating microstructure is significantly refined, which strengthens the coating properties and increases the hardness and wear resistance of the coating. The wear resistance was further improved by the addition of Y
2O
3 to the coating. As the Y
2O
3 content increases, the wear volume of the coating first decreases and then increases, but both are smaller than the wear volume of the substrate. The minimum value (0.4584 mm
3) is reached when the Y
2O
3 content is 7.5 wt.%, which is only 26.68% of the wear volume of the substrate. The addition of Y
2O
3 refines the grain size and makes the coating more evenly distributed, increasing the surface hardness and enhancing wear resistance. With the continued increase in Y
2O
3 content, however, the wear volume of the coating with a Y
2O
3 content of 10 wt.% increases compared to the wear volume of the coating at 7 wt.%. Excess Y
2O
3 reduces the fluidity of the melt pool, hinders the heat dissipation of the melt pool, and decreases the degree of subcooling, resulting in larger grains and an uneven microstructure distribution. This microstructure presents lower surface coating hardness and poorer wear resistance.
Figure 10 shows the wear morphology of the 10 wt.% Y
2O
3 coating. Clear furrows can be seen in
Figure 10a, and the partial enlargement of the wear morphology is given in
Figure 10b. From
Figure 10, one can observe clear signs of spalling. The coating suffered from abrasive and adhesive wear during the experiment. There is the relative movement between the grinding ball and the hard phase exposed to the coating surface by friction, which results in abrasive wear. This form of wear causes a large number of furrows on the wear surface. In addition, the reciprocating motion of the friction test generates heat that softens the coating, which causes bonding at the point of contact between the coating and the grinding ball. This results in adhesive wear, which causes extensive spalling of the wear surface.