1. Introduction
Electromagnetic rail launch technology is a kind of launch technology that uses armature to accelerate a load to ultra-high speed in milliseconds, driven by the Lorentz force in a strong magnetic field. It has outstanding advantages such as high controllability, fast response, and high kinetic energy [
1]. It can solve many unfavorable factors such as low launch efficiency, low energy levels, and poor control performance shared by traditional mechanical and chemical energy launches. It can be applied to rocket and satellite launches, aircraft launches, and high-speed electromagnetic train driving, and it has very broad application prospects.
The working conditions of electromagnetic rail launch systems show characteristics of extreme complexity. The pulse high current is MA-level, the working time is ms-level, the contact pressure of the armature rail is 100 Mpa-level, and the relative speed of the armature rail can reach 2.5 km/s. On the one hand, under the impact of pulsed high current, the transition phenomenon easily occurs between the armature and rail, and the sliding arc in the chamber causes a stronger energy arc, which causes serious ablation of the armature metal material; on the other hand, the heat generated by the arc vaporizes the surface of the armature instantaneously, and a large amount of aluminum vapor causes a more intense arc discharge, resulting in melting splashing and evaporation erosion of the material, which seriously restricts the long-term service stability of the electromagnetic energy equipment under extreme conditions [
2]. This puts forward higher requirements for the ablation resistance of the armature material [
3]. Therefore, it is of great significance and engineering value to study the surface modification methods of armature materials in extremely complex environments to improve the reliability of electromagnetic rail launch and accelerate its engineering application.
Addressing the problem of the damage suppression of armature and rail materials, Bolin Cai [
4] proposed that armature erosion can be suppressed by highly temperature-resistant, highly conductive thermal materials without affecting launch efficiency. At present, various kinds of carbon materials, metals, and ceramics are widely used as surface modification reinforcements [
5].
At present, graphene-reinforced polymers are widely used as a means of increasing the strength of a material while maintaining its plasticity [
6,
7]. Numerous studies have reported that the mechanical, thermal, and electrical properties of materials can be improved by adding graphene nanoparticles to the aluminum matrix [
8,
9,
10]. However, graphene has a small volume but a large specific surface area, which means that it easily agglomerates in the process of ball milling and mixing, resulting in poor bonding between the graphene and the metal matrix. Additionally, graphene is highly susceptible to oxidation at high temperatures in an aerobic environment, so it is not suitable as a surface modification material for electromagnetic gun aluminum alloy armature. Junwei Ye and other researchers [
11,
12,
13] first proposed the concept of high-entropy alloys. According to the characteristics and functions of each metal element, a high-entropy alloy coating with “cocktail” performance is formed according to different ratios, which can greatly improve the surface performance of the armature material. Hsu [
14] prepared NiCo
0.6Fe
0.2Cr
1.5SiAlTi
0.2 HEA coatings with plasma cladding equipment and found that a large amount of Cr
3Si phase was formed in the coating, and the hardness and wear resistance were greatly increased when aging at 800 °C and 1100 °C. Cai [
15] prepared NiCrCoTiVAl alloys on a Ti-6Al-4V substrate through laser cladding, and the phase structure remained unchanged after being held at 900 °C for 8 h. The results showed that the coating was stable below 1005 °C. However, the composition design of high-entropy alloy coatings lacks systematic theoretical support, and the relationship between elements and alloys is still unclear. Most of them consist of “cocktail-style” blending [
16], and high-entropy alloys are multi-principal element alloys. This paper is devoted to the study of single-principal element reinforced composites with aluminum as the main element.
The American Standard Test Method (ASTM) defines cermets as heterogeneous materials composed of one metal or alloy with one or more ceramics, in which the volume of metal accounts for 15%–85% [
17,
18]. The metal–ceramic composite material has the comprehensive advantages of both metal and ceramic. The ceramic material has high hardness, strong wear resistance, and good thermal conductivity. However, due to its brittleness, it is not easy to process due to its sensitivity to stress and cracks. The preparation of metal–ceramic composite coatings can solve the above problems to a certain extent [
19]. Currently, ceramic particle-reinforced aluminium-matrix composites are prepared by a powder metallurgy and in-situ autogenous method, in which the manufacturing process of the powder metallurgy method is relatively complex and costly, and, after adding a large number of ceramic particles, the plasticity of the material is significantly reduced, which leads to poor formability in secondary processing. The in-situ synthesis method has the advantages of small particle size, regular shape, high stiffness, and clean interface [
20,
21,
22], and has become an important preparation method for high-performance particle-reinforced aluminum-matrix composites. The in-situ synthesized reinforced particles in aluminum-matrix composites mainly include TiB
2, TiC, Al
2O
3, ZrB
2, TiN, and TiAl
3 [
23,
24,
25,
26,
27]. Among them, TiC particles have advantages such as a high melting point and high hardness, which are widely chosen as a hard ceramic reinforcement. Pradeep [
28] prepared Al-10 wt% TiC and Al-5 wt% TiC composites by in-situ synthesis. Zhang [
29], Jiang [
30], Zhuang [
31], and Wang [
32] formed TiC aluminum-matrix composites for an Al-Cu alloy, 5052 aluminum alloy, 6061 aluminum alloy, and 7075 aluminum alloy, respectively. Studies have shown that a small amount of in-situ TiC can improve the tensile strength, hardness, and ablation resistance of the composites. When the content of in-situ TiC is high, a large number of agglomerates will be formed at the grain boundary, reducing the bonding strength between the matrix and the reinforcement, and the strength and plasticity decrease simultaneously but the high hardness agglomerates cause the overall hardness of the composite to increase linearly. In this study, without changing the existing structure and main materials of the armature, only the arc root motion and residence area of the armature surface were modified and designed. Therefore, the TiC particle-reinforced aluminum-matrix composite coating was prepared on the surface of the armature, which was expected to improve the ablation resistance of the armature.
Based on molecular dynamics simulation, this study constructed a pure aluminum alloy model and TiC particle-reinforced aluminum-matrix composite coating–pure aluminum alloy composite model. Then, the arc impact simulation of each model was carried out. The anti-ablation performance of the material was analyzed by the depth of arc bombardment, the number of evaporated atoms, and the mass loss of the model. The evolution of the microstructure of the material was revealed by the degree of atomic shear strain and DXA analysis to study the anti-ablation mechanism of TiC particle-reinforced aluminum-matrix composites.
3. Results and Discussion
Under high-temperature and high-speed arc impact, the material undergoes melting, gasification, splashing, and other ablation processes. In order to evaluate the ablation protection effect of the TiC particle-reinforced coating on the matrix material, the depth of arc erosion, the mass loss during the ablation process, and the number of gasification atoms were used as the microscopic characterization of the ablation degree. The damage degree of the surface and subsurface of the material and the surface temperature of the material after arc impact were analyzed to explore the effect of TiC particle doping on the ablation resistance of aluminum alloy from the micro-molecular level and reveal the anti-ablation mechanism of TiC particle-reinforced aluminum-matrix composites.
3.1. Arc Erosion Depth Analysis
The impact and erosion of the arc lead to changes in the surface morphology and composition of the material [
40]. During the arc burning period, the temperature of the material rises sharply, and, when it rises to the melting point, a flowing molten pool is generated, and even splashing occurs; when it rises to the boiling point, the molten pool evaporates into metal vapor, resulting in evaporation loss. After the arc is extinguished, the gas and liquid materials condense into solids, accompanied by material transfer. The depth of arc erosion can reflect the micro-deterioration of the material during the dynamic process of arc erosion. After the arc impact, the distance between the deepest invaded aluminum atom and the upper surface of the material is regarded as the maximum erosion depth of the arc. The average distance between all the invaded aluminum atoms and the upper surface of the material is the average erosion depth of the arc, as shown in
Table 4. By comparing the above two parameters, the arc impact ablation resistance of the pure Al and TiC/Al-Al systems was evaluated.
Table 4 shows that the maximum arc erosion depth of the TiC/Al-Al system was about 43% lower than that of the pure Al system, and the average arc erosion depth was about 61% lower than that of the pure Al system. This shows that the TiC particle-reinforced aluminum-matrix composite coating helped to reduce the penetration depth of the arc in the armature, thereby improving the ablation resistance of the armature. The reasons for this are mainly divided into the following three points: First, because TiC and Al have the same crystal structure and similar lattice constants, the mismatch between atoms was within a reasonable range and the wettability with the matrix was good. This allowed TiC particles to be dispersed in the matrix in a more homogeneous form, with the effect of diffuse strengthening. Second, the melting point of TiC is high. When the temperature rise caused by arc impact was higher than the melting point of Al, TiC could still exist in the form of particles. During solidification, it was promoted by Al dendrites and enriched at grain boundaries, promoting the heterogeneous nucleation of crystals, inhibiting grain growth, effectively refining grains, and improving material strength. Thirdly, because the hardness of TiC particles is much higher than that of the Al matrix, when the material was impacted by the arc, the load was transferred from the metal matrix to the ceramic particle reinforcement, and the tensile strength of the material was enhanced.
Figure 3 shows the structural changes of the pure Al and TiC/Al-Al systems after arc shock. It can be seen that after the material was subjected to arc bombardment, the surface atoms splashed and the internal atoms deformed, deviating from the normal arrangement of the crystal structure. Compared with the pure Al system, the deformation atom range of the TiC/Al-Al system was smaller, and most of the bombarded aluminum atoms were blocked above the TiC particle doping area.
In order to analyze the microstructural changes caused by the arc impact more intuitively, the atomic shear strain cloud diagram of the pure Al and TiC/Al-Al systems after arc bombardment and after cooling to room temperature was calculated by OVITO, and only the atoms with strain greater than 0.1 Å in the model were retained. From
Figure 4, it can be seen that after the arc impact, compared with the pure Al system, the strain atomic range of the TiC/Al-Al system was smaller and the strain degree was lower. It can be seen from
Figure 5 that after the system was cooled to room temperature, the strain range of both systems was expanded. This is because the arc impact process generated energy transfer. The arc carrying high energy first transferred energy to the atoms on the surface of the material and then the energy continued to be transmitted downward in the form of a shock wave, causing the atoms inside the material to strain. Compared with the pure Al system, the deformation atom range of the TiC/Al-Al system was significantly reduced, and the strain degree was significantly reduced. The atomic shear strain cloud diagram of the pure Al system was nearly tetragonal, indicating that the shock wave propagated more evenly downward in the system until it decayed to 0. The strain cloud diagram of the TiC/Al-Al system was inverted conical because the addition of TiC particles made the matrix grains finer, and the fine grain reinforcement resulted in a more dispersed and faster decay of impact stresses in the coated armature. This is because the TiC particles were closely combined with the matrix. The additional load was transferred from the metal matrix to the reinforcement particles through the interface between the matrix and the reinforcement so that the matrix and the particle reinforcement bore the additional load together, thus resisting the deformation caused by the impact stress.
3.2. Analysis of Material Mass Loss and the Number of Gasification Atoms
The electromagnetic rail launch process is accompanied by the generation and development of the arc. Under the action of ultra-high arc heat, the aluminum alloy armature rapidly melts or even vaporizes, and a large amount of aluminum vapor causes more intense arc discharge. In this study, the armature material was enhanced and modified to reduce the steam content of the aluminum alloy material due to ablation, thereby inhibiting the development of the arc. Therefore, it was necessary to analyze the degree of gasification and mass loss of the material under arc ablation. In order to quantify the ablation reduction effect of the TiC particle-reinforced aluminum alloy coating on the matrix, the normalized mass of the pure Al system and TiC/Al-Al system was calculated as shown in
Figure 6. The normalized mass is the ratio of the remaining material mass to the initial mass of the material after the arc bombardment is completed and the system is stable.
The mass loss trends of the two systems were similar, and both decreased first and then reached dynamic equilibrium. The mass loss rate of the uncoated aluminum matrix after ablation was about 18% and the mass loss rate of the TiC/Al-Al composite was about 9%, which was lower than that of the pure aluminum alloy armature, indicating that the addition of TiC particles to modify the material was helpful to enhance the ablation resistance of the armature. From a microscopic point of view, since the reinforcing phase TiC was distributed around the matrix grains and the structure of the TiC particles was stable, the melting point could reach more than 3200 °C. When the aluminum matrix expanded outward by heating, it was hindered by TiC, so the thermal stability of the composite was improved. During the ablation process, due to the low evaporation latent heat of the aluminum, the aluminum atoms first vaporized and were exuded from the ceramic composite material, which played the role of ‘sweating cooling’ and protected the ceramic skeleton.
Figure 7 shows the morphology change of TiC particles in the composite during arc ablation, in which Al atoms are deleted. It can be seen that under the action of high temperature, the ceramic skeleton grains grew, the phenomenon of large grains annexing small grains occurred, and obvious roundness occurred, which was conducive to further improving the strength of the ceramic skeleton and increasing the ablation resistance. Therefore, during the ablation process, the ability of the composite skeleton to resist heat flow erosion gradually increased, thereby improving its ablation resistance.
A vacuum layer was set in the 110 Å–160 Å region above the material, and the variation of the number of atoms vaporized into the vacuum layer in the pure Al system and TiC/Al-Al system was counted, as shown in
Figure 8. There was no atomic gasification of the pure Al system into the vacuum layer within 0–50 ps of arc ablation. This is because the temperature of the material had not reached the boiling point at the beginning of arc ablation, and the lowest vacuum layer was 30 Å away from the surface of the material. It takes a certain amount of time for gasification atoms to rise to a vacuum layer. In the TiC/Al-Al system, there were gasification atoms in the vacuum layer until 70 ps. With the progress of ablation, the number of atoms in the vacuum layer of the pure Al system increased rapidly and reached dynamic equilibrium at 120 ps. The number of atoms evaporating into the vacuum layer in the TiC/Al-Al system increased slowly and began to reach dynamic equilibrium at about 110 ps. This indicates that the use of TiC particle-reinforced aluminum-matrix composites to coat the aluminum alloy armature effectively reduced the amount of metal vapor generated, thereby reducing the arc energy and inhibiting its rapid growth. In addition, the change trend of the number of gasification atoms and the change trend of the normalized mass of the material could be mutually verified, which also verified the correctness of the model.
3.3. Material Surface Temperature Analysis
In the process of electromagnetic rail launch, the armature temperature will rise sharply, resulting in material melting and gasification, which is a very critical factor in the arc triggering mechanism. Therefore, it was necessary to analyze the change in material surface temperature caused by arc impact. The atoms in the matrix model from the top surface to the bottom 25 Å were set as the temperature measurement layer to study the temperature variation of the pure Al system and TiC/Al-Al system effected by the arc impact.
Figure 9 shows the variation in the temperature of the pyrometry layer of the two systems over time under a bombardment speed of 15 km/s. The peak temperature of the pyrometry layer of the TiC/Al-Al system was 2815 K, which was 22% higher than that of 2309 K of the pure Al system.
Figure 10 is the X-Y two-dimensional temperature cloud diagram of the surface of the two types of materials at the end of the arc bombardment. Because the arc bombardment position set by this model was the material center, and the arc action time was extremely short, the heat had not yet been transmitted to a large number of surroundings, so the material center temperature was higher. The surface temperature of the TiC/Al-Al system was higher than that of the pure Al system, and the high temperature range was smaller than that of the pure Al system. It can be seen that the addition of TiC particles reduced the thermal conductivity of the aluminum alloy armature.
In the composites, the low thermal conductivity of TiC (21 W/m·K) and the material lattice distortion induced by the incorporation of ceramic particles reduced the thermal conductivity of the aluminum alloy armature. The lattice distortion of the aluminum alloy matrix caused by the ceramic particles reduced the thermal conductivity of the aluminum alloy matrix. The thermal conduction mechanism of metal mainly includes two parts [
41]: electronic thermal conduction and lattice thermal conduction. First, hot electrons diffuse in the temperature field. As the temperature increases, free electrons accelerate and diffuse around, and cold electrons exchange energy through collision, thereby conducting heat. The second is lattice vibration. Lattice vibration is small at low temperatures, the number of phonons is small, and the average free path is long, so lattice thermal conductivity is strong. At high temperatures, the average free path of phonons will be significantly reduced and the thermal conductivity of the lattice will also be greatly reduced or even negligible. In addition, the increase in temperature also promotes the movement of free electrons, shortens the average free path, and weakens the ability of electrons to conduct heat. Therefore, the thermal conductivity of aluminum-matrix composites also decreases with increasing temperature. The solute atoms, precipitated phases, and lattice defects including dislocations, grain boundaries, and twins in the aluminum matrix will scatter free electrons to weaken its thermal conductivity. Therefore, the enhanced particle morphology and the dislocations and lattice distortions induced by ceramic particles will have a greater impact on the thermal conductivity of the matrix. However, compared with the huge scattering effect of solute atoms on free electrons in copper alloys, ceramic particles have little effect on thermal conductivity [
42,
43]. Therefore, the use of ceramic particles to enhance aluminum-matrix composites can improve the strength of the aluminum matrix while reducing the weakening of its thermal conductivity. It is a more effective strengthening method. In addition, the reduction of the thermal conductivity of the composite coating can delay the transfer of arc heat to the substrate.
3.4. Surface Morphology Analysis
The change in material surface morphology caused by arc impact can reflect the mechanical properties and ablation resistance of materials.
Figure 11 and
Figure 12 show the change in the surface morphology of the pure Al system and TiC/Al-Al system over time under arc impact.
Figure 11a and
Figure 12a are the surface morphology of the two systems at the end of the arc impact. It can be seen that under high-energy arc impact, the surface material of the substrate began to be heated, and the material beyond the melting point underwent phase transformation stripping and was gradually removed.
Figure 11b–d and
Figure 12b–d show the change in the surface morphology of the pure Al system and TiC/Al-Al system in the time from the end of arc impact to cooling to room temperature. Firstly, the ablation pit expanded along the depth direction. This is because the material was subjected to arc impact for a short time, the energy density of the material center was high, and the heat transfer to the depth direction was more intense than the radial direction, so the material was eroded more obviously along the depth direction. As the heat transfer process continued, the area outside the center absorbed enough heat and began to melt and vaporize, and the pit expanded along the radial direction. Due to the temperature gradient in the radial heat transfer process, the molten material produced a surface tension gradient, and the partially molten material moved upward from the pit to the surface, that is, the Marangoni effect occurred, forming a bulge on the ablated surface and forming a recast layer after cooling. Compared with the pure Al system, the surface morphology of the TiC/Al-Al system was more irregular, the impact crater was more flat, and the trend of radial development was more obvious. This is because TiC particle-reinforced aluminum-matrix composites have the effect of load transfer strengthening and micromechanical strengthening, which is beneficial for the improvement of material strength.
To quantitatively characterize the surface damage degree of the material, the surface atomic coordinates of the material were extracted and the RMS deformation degree at each moment was calculated. The results are shown in
Figure 13. At 20 ps, 40 ps, 60 ps, 80 ps, and 110 ps, the surface RMS deformation of the TiC/Al-Al system was 23%, 14%, 46%, 59%, and 49% smaller than that of the pure Al system, and the TiC/Al-Al system could reach a stable state faster after the impact. This is due to the fact that the hard TiC particles were dispersed in the composites and acted as pinning agents in the matrix, which increased the resistance to dislocation and grain boundary movement, resulting in the improved mechanical properties of the material.
3.5. Subsurface Damage Analysis
Arc impact will not only cause damage to the surface of a material but also subsurface damage below the surface. Subsurface damage not only affects the integrity of the function of the material itself but may also eventually lead to the failure of the material, and its degree of damage can be expressed by the dislocation density in statistical molecular dynamics simulation. The ratio of the total length of the dislocation line to the volume of the material is the dislocation density, and, since the volume size of the model was constant in this study, the trend of the dislocation length was consistent with the trend of the dislocation density. The Dislocation Extraction Analysis (DXA) module in OVITO 3.7.9 software was used to calculate and output the dislocation length in combination with its internal Python interface, as shown in
Figure 14.
Figure 14 shows the length of the total dislocation line in the two systems. It can be seen from the figure that there were almost no dislocations in the two systems before the arc impact. After the arc impact, due to the existence of the second-phase hard particle in the TiC/Al-Al system, the dislocation pinning effect brought by it caused the dislocation to be unable to cut through and only able to bypass, so the total length of the dislocation line in the system increased greatly. In the process of the system gradually returning to stability, the dislocation line length of the pure Al system was larger. This is because the TiC-reinforced aluminum-matrix composite coating had a certain protective effect on the Al matrix, which made the damage to the TiC/Al-Al system lesser. In order to analyze the reason, the dislocation evolution process inside the two systems was extracted, as shown in
Figure 15 and
Figure 16. In the figures, OTHER- and FCC-type atoms are deleted, and only dislocation and HCP-type atoms are retained.
It can be observed that at 20 ps, the pits in the TiC/Al-Al system had a clear trend of radial development, while the pits in the pure Al system extended more obviously in the longitudinal direction. This phenomenon was more intuitive at 60 ps. The dislocation line and HCP-type atoms in the pure Al system almost touched the bottom of the material. While, in the TiC/Al composite system, the defects of the material caused by arc impact ablation were lighter, and it was due to the dislocation pinning effect of the TiC particles. At 80 ps, the pure Al system had not yet reached a stable state, and there were many defects at the bottom of the material, while the TiC/Al composite system had almost reached a stable state. The reason is that under the action of arc impact, small holes were generated at the material interface and cracks were transmitted and developed near the interface. There was a stress field near the interface due to lattice distortion. When the dislocation passed through, it was necessary to perform more work to tear the interface, so the yield strength of the TiC/Al composites was significantly upgraded.
3.6. Total Consequence and Discussion
In this section, the simulation process of arc impact is analyzed and the strengthening mechanism of the TiC particles in the aluminum matrix is explored. The simulation results show that compared with the pure Al system, the arc erosion depth of the TiC/Al-Al system was significantly reduced, the degree of internal atomic strain was reduced, and the material mass loss caused by the impact ablation of the arc was also reduced. In addition, the surface and subsurface damage of the armature coated with the modified layer was lower than that of the pure Al alloy armature. Combining the simulation results with theoretical analysis, the following conclusions are drawn: the strengthening mechanism of TiC particle-reinforced aluminum-matrix composites includes fine grain strengthening, dispersion strengthening, and dislocation strengthening and covering TiC particle-reinforced aluminum-matrix composite coatings on the surface of the aluminum matrix is helpful to reduce the impact ablation effect of arc on the armature.