Validation of Forward Voltage Method to Estimate Cracks of the Solder Joints in High Power LED
Round 1
Reviewer 1 Report
Reviewer Feedback
Title:
A method based on forward voltage to estimate solder joint reliability in high power LED.
The reviewer is a bit concerned on the aim and objectives of this research. Are the authors proposing:
- “A method based on forward voltage to estimate presence of crack and fatigue life of solder joints in high power LED”? Then the title should read that, and validation of the model carried out and presented. The solder joint reliability and presence of crack in a solder joint have been used interchangeably in this research.
- “Predicting fatigue failure of solder joints in high power LED. Then the title should read that, and the objectives of the manuscript reworked to reflect that.
General:
The research presented in this manuscript is very important and needed by researchers in this field. However, the design of the research needs to be more effective for the results and findings to be more convincing.
The academic and technical writing style of the manuscript can be improved.
I do not think the climatic chamber used in this experiment is appropriate. There appears to be room for error. Also is the thermal cycle.
The experiment needs to be more systematically designed for improved results and research quality.
Abstract:
Are there evidence that LEDs have longer life than the other technologies?
Line 6: “Malfunction” may be better called “presence of crack”.
The abstract needs significant improvement. It has not stated significant results, findings, and brief conclusions. The structure and contents of the abstract need improvement. They will benefit from a clear aim and objectives of the research.
Introduction:
Lines 28 to 31:
Authors need to be specific on what they are investigating.
Lines 53 to 56:
“In this paper it is proposed to define the failure criteria of the solder joint by the Vf increasing”. This implies that the VF increasing method is already validated. Thus, the current title will not be standing.
“In this paper we present the aging test carried out”. It seems it is accelerated thermal cycle test (ATCT) that is carried out. There should be a distintion between aging and ATCT.
“Propose the development of an experimental method to measure the Vf and to determine the probability of failure estimating the lifetime of the considered LEDs”. With the current manuscript title, the authors ought to have done these in validating the proposed Vf methods. The non-accurate validation could have accounted for the high percentage LEDs with lifetime greater than 20 years.
2.0 Materials and Methods
2.1 Experimental protocol:
Line 102:
Please check for typographical error.
“Totally, 1900 thermal cycles are performed and the test, at every 100 cycles, is suspended to carry 107 out the measurement of Vf”. Will the suspension not introduce stress relaxation and thus error in the magnitude of stress and damage accumulated in the solder joints?
2.2. Thermal Cycling test
Is the adopted and used TCT the standard for electronics and LED testing? Just concerned about the ramp rate - knowing the effect of ramp rate of solder joints qualification.
Line114 to 115:
“This test accelerates the aging of LEDs allowing to estimate the lifetime in a reduced time compared to the real conditions”. This sentence can be revised for its intended purpose. Many sentences are like this. What the test accelerated is more of the damage of the solder joints. The authors should always bear in mind the difference between the “solder joints in the LED” and the “LED” itself.
A picture of the climatic chamber will help the research community understand the level of sophistication of the equipment involved. Is the transfer done mechanical? Then there would be a room for significant error. The solder joints may experience shock and/or impact loading during the transfer. This would have become additional load not accounted for in the research.
Five seconds (5 s) transfer time amount to huge ramp rate. Is this the correct ramp rate?
- Oscilloscope Test
Line 129: Check for typo.
2.5. Metallographic section
Line 164 to 166:
“In order to validate the Vf increase as a method of estimating the reliability of the solder joint, the metallographic sections of unbroken LEDs, are compared with the metallographic sections of failed LEDs”. The Vf has been used in this investigation to predict the presence of crack and not reliability of solder joint. Reliability has not been used very well in this manuscript.
- Results
Fig 5 does not seem to represent normal observed failure rate or the bathtub curve. Were the solder joints of the LED pre-qualified and the standard faultless assembles selected for the thermal test? Otherwise, the ought to be infant mortality arising from faulty assemblies.
I do not think that Fig 8 presents much information and reasonable conclusions could be drawn from it.
Conclusions:
Lines 255 to 256: “The results obtained from the experimental protocol showed that 96% of the considered LEDs have a lifetime greater than 20 years”. I do not think this result approximates what is obtainable in real life. An LED lasting more than 20 years – do the authors think this is realisation in real world? If not, them the method is faulty, and the experiment have room for error.
Author Response
Responds to the reviewer’s comments:
Dear Reviewer:
Thank you for your comments concerning our paper. Those comments are all valuable and very helpful for revising and improving our paper, as well as the important guiding significance to our research. We have studied comments carefully and have made correction. Revised portion are marked in yellow in the paper. The responds to the reviewer’s comments are below:
Title:
A method based on forward voltage to estimate solder joint reliability in high power LED.
The reviewer is a bit concerned on the aim and objectives of this research. Are the authors proposing:
- “A method based on forward voltage to estimate presence of crack and fatigue life of solder joints in high power LED”? Then the title should read that, and validation of the model carried out and presented. The solder joint reliability and presence of crack in a solder joint have been used interchangeably in this research.
- “Predicting fatigue failure of solder joints in high power LED. Then the title should read that, and the objectives of the manuscript reworked to reflect that.
Response: We have modified the title and we have explained better the aim of our paper.
General:
The research presented in this manuscript is very important and needed by researchers in this field. However, the design of the research needs to be more effective for the results and findings to be more convincing.
The academic and technical writing style of the manuscript can be improved.
I do not think the climatic chamber used in this experiment is appropriate. There appears to be room for error. Also is the thermal cycle.
The experiment needs to be more systematically designed for improved results and research quality.
Response: We have completely rewritten many parts to better describe the work done and improve the overall quality of the article. We also expanded the results section and added the discussion section.
Abstract:
Are there evidence that LEDs have longer life than the other technologies?
Line 6: “Malfunction” may be better called “presence of crack”.
The abstract needs significant improvement. It has not stated significant results, findings, and brief conclusions. The structure and contents of the abstract need improvement. They will benefit from a clear aim and objectives of the research.
Response: We have completely modified the abstract trying to better target the work.
Introduction:
Lines 28 to 31:
Authors need to be specific on what they are investigating.
Lines 53 to 56:
“In this paper it is proposed to define the failure criteria of the solder joint by the Vf increasing”. This implies that the VF increasing method is already validated. Thus, the current title will not be standing.
“In this paper we present the aging test carried out”. It seems it is accelerated thermal cycle test (ATCT) that is carried out. There should be a distintion between aging and ATCT.
“Propose the development of an experimental method to measure the Vf and to determine the probability of failure estimating the lifetime of the considered LEDs”. With the current manuscript title, the authors ought to have done these in validating the proposed Vf methods. The non-accurate validation could have accounted for the high percentage LEDs with lifetime greater than 20 years.
Response: We have fully modified the introduction section trying to use more appropriate terms and to better explain all the concepts used. Additional references have also been added to justify some choices.
Materials and Methods
2.1 Experimental protocol:
Line 102:
Please check for typographical error.
Response: Thanks for the report, we have corrected typographical error.
“Totally, 1900 thermal cycles are performed and the test, at every 100 cycles, is suspended to carry 107 out the measurement of Vf”. Will the suspension not introduce stress relaxation and thus error in the magnitude of stress and damage accumulated in the solder joints?
Response: The suspensions are necessary to acquire the measures of Vf. In literature it is used suspensions during thermal cycling test as shown in reference [20].
2.2. Thermal Cycling test
Is the adopted and used TCT the standard for electronics and LED testing? Just concerned about the ramp rate - knowing the effect of ramp rate of solder joints qualification.
Response: We have adopted the TCT following the standard IPC-9701A.
Line114 to 115:
“This test accelerates the aging of LEDs allowing to estimate the lifetime in a reduced time compared to the real conditions”. This sentence can be revised for its intended purpose. Many sentences are like this. What the test accelerated is more of the damage of the solder joints. The authors should always bear in mind the difference between the “solder joints in the LED” and the “LED” itself.
Response: We have modified sentence lines 122- 124 and revised the use of the terms to avoid confusion.
A picture of the climatic chamber will help the research community understand the level of sophistication of the equipment involved. Is the transfer done mechanical? Then there would be a room for significant error. The solder joints may experience shock and/or impact loading during the transfer. This would have become additional load not accounted for in the research.
Five seconds (5 s) transfer time amount to huge ramp rate. Is this the correct ramp rate?
Response: We have added a picture of the climatic chamber. The transfer between one chamber to another is mechanical. The climatic chamber used in this study is certified. We assume it works well therefore impact loading is not considered. The transfer time is 5 s and it cannot be set despite we know that is a huge ramp rate.
- Oscilloscope Test
Line 129: Check for typo.
Response: Thanks for the report, we have fixed it.
2.5. Metallographic section
Line 164 to 166:
“In order to validate the Vf increase as a method of estimating the reliability of the solder joint, the metallographic sections of unbroken LEDs, are compared with the metallographic sections of failed LEDs”. The Vf has been used in this investigation to predict the presence of crack and not reliability of solder joint. Reliability has not been used very well in this manuscript.
Response: We thank the reviewer for this comment. We have modified the sentence and we have checked the use of reliability in the manuscript.
- Results
Fig 5 does not seem to represent normal observed failure rate or the bathtub curve. Were the solder joints of the LED pre-qualified and the standard faultless assembles selected for the thermal test? Otherwise, the ought to be infant mortality arising from faulty assemblies.
Response: The solder joints of the LED have subjected a functional test before thermal test. In any case, all the assembled circuits worked correctly.
I do not think that Fig 8 presents much information and reasonable conclusions could be drawn from it.
Response: We have modified Figure 8 and we have pointed out voids and cracks with red circles.
Conclusions:
Lines 255 to 256: “The results obtained from the experimental protocol showed that 96% of the considered LEDs have a lifetime greater than 20 years”. I do not think this result approximates what is obtainable in real life. An LED lasting more than 20 years – do the authors think this is realisation in real world? If not, them the method is faulty, and the experiment have room for error.
Response: We have modified the conclusion section. Results refer to the lifetime of the solder joint of LED, we have tried to better explain the use of the terms also in the other sections.
Author Response File: 
Author Response.pdf
Reviewer 2 Report
Comments
At the beginning I would like to appreciate the contribution of the authors' work on laboratory tests. However, I have a few comments in particular regarding the analysis of the obtained results and the conclusions.
- The "Introduction" section is quite short in terms of the existing number of publications on the topic covered by the article. In my opinion, the Authors have not performed an in-depth review of the available literature.
- In the introduction, the authors wrote: „In this paper it is proposed to define the failure criteria of the solder joint by the Vf increasing.” In the article, unfortunately, I did not find any clearly defined criteria. If the method is to be useful, the Authors should define the criteria for the LED failure.
- The authors wrote that they use Matlab programming environment for data analysis and presentation. Taking into account the capabilities of MATLAB program, the quality of Figure 3 could be better. I don't know if this poor quality is due to the resolution of the figure or conversion to pdf file.
- In Figure 5 the authors presented "Exponential trend of failed LEDs". The points obtained from the measurements are not marked in the figure. How this curve has been determined? Did the authors use the "Curve Fitting Toolbox"? If the authors have curve fitting, they could include an analytical formula describing the curve and R2. On the figure the Authors have placed "(a)", which suggests that it is a figure marked with this symbol. Didn't the Authors include figure "b"?
- Despite a detailed description of experimental setup and measurement methods, the authors did not sufficiently describe the methods of data analysis. An example is Figure 6. How the probability of failure curve was determined
- Figure 7 shows "Weibull Distribution". How did the authors determine the parameters of this distribution? Have the conformity tests been carried out, if so, which ones?
- Table 1 contains the results of lifetime calculations. The authors have included only one calculated parameter "Lifetime" in the table. Is it not possible to expand the table and include other values needed from the "Lifetime" calculation e.g. AF. This will increase the usefulness of the article and allow the reader to verify the presented calculations
- The conclusions are written in very general terms and lack the discussion part required by the Guide for Authors.
- Please also check the correct formatting of references
Comments for author File: Comments.pdf
Author Response
Responds to the reviewer’s comments:
Dear Reviewer:
Thank you for your comments concerning our paper. Those comments are all valuable and very helpful for revising and improving our paper, as well as the important guiding significance to our research. We have studied comments carefully and have made correction. Revised portion are marked in yellow in the paper. The responds to the reviewer’s comments are below:
At the beginning I would like to appreciate the contribution of the authors' work on laboratory tests. However, I have a few comments in particular regarding the analysis of the obtained results and the conclusions.
Point 1: The "Introduction" section is quite short in terms of the existing number of publications on the topic covered by the article. In my opinion, the Authors have not performed an in-depth review of the available literature.
Response 1: We thank the reviewer for this advice. A deeper analysis of the existing literature was made, we have added and analyzed other articles.
Point 2: In the introduction, the authors wrote: „In this paper it is proposed to define the failure criteria of the solder joint by the Vf increasing.” In the article, unfortunately, I did not find any clearly defined criteria. If the method is to be useful, the Authors should define the criteria for the LED failure.
Response 2: I have explained the failure criterion proposed on lines 64 and 113-116. In the results section we have shown that this criterion is correct for determining the presence of cracks in the solder joint.
Point3: The authors wrote that they use Matlab programming environment for data analysis and presentation. Taking into account the capabilities of MATLAB program, the quality of Figure 3 could be better. I don't know if this poor quality is due to the resolution of the figure or conversion to pdf file.
Response 3: Quality of figure 3 has been improved.
Point 4: In Figure 5 the authors presented "Exponential trend of failed LEDs". The points obtained from the measurements are not marked in the figure. How this curve has been determined? Did the authors use the "Curve Fitting Toolbox"? If the authors have curve fitting, they could include an analytical formula describing the curve and R2. On the figure the Authors have placed "(a)", which suggests that it is a figure marked with this symbol. Didn't the Authors include figure "b"?
Response 4: We thank the reviewer for allowing us to improve the data analysis. We have modified Figure 5 and we have added measurement points. The curve was determined using "Curve fitting toolbox". We have included the analytical formula and R2 value to the results analysis. Thanks for reporting the typos (a), we have modified it.
Point 5: Despite a detailed description of experimental setup and measurement methods, the authors did not sufficiently describe the methods of data analysis. An example is Figure 6. How the probability of failure curve was determined.
Response 5: We have made a more detailed description of the data analysis method. We have included the formulas used to derive the reliability and probability of failure as show in lines 201-202 The curve of Figure 6 has been determined using "Curve fitting Toolbox". The analytical formula and R2 value have been added as show in line 207.
Point 6: Figure 7 shows "Weibull Distribution". How did the authors determine the parameters of this distribution? Have the conformity tests been carried out, if so, which ones?
Response 6: We have obtained the Weibull graph and parameters using the Matlab “Distribution Fitter Toolbox” which approximates the data set using the Weibull distribution and the probability plot. We used Weibull only as a method of representation and not as an analysis method. The conformity test has not been carried out.
Point 7: Table 1 contains the results of lifetime calculations. The authors have included only one calculated parameter "Lifetime" in the table. Is it not possible to expand the table and include other values needed from the "Lifetime" calculation e.g. AF. This will increase the usefulness of the article and allow the reader to verify the presented calculations
Response 7: We really thank the reviewer for allowing us to improve results. We have included other parameters in Table 1. We have added the total number of failed SJLs at each cycle, the AF value and the percentage values of the Vf increase.
Point 8: The conclusions are written in very general terms and lack the discussion part required by the Guide for Authors.
Response 8: We have added the discussion section and we rewrote the conclusions section trying to better specify the contents.
Point 9: Please also check the correct formatting of references
Response 9: We have fully checked and corrected formatting of the references.
Author Response File: Author Response.pdf
Reviewer 3 Report
In this paper, author presents a simple and non-destructuve methodology to determine the solder joint fatigue and the presence of craks in LEDs. A detailed work is performed but some points must be resolved in a revision process.
Comments:
-It is inelegant to use words contracted in an official scientific manuscript. There are several throughout the text, as “can’t, haven’t, doesn’t…..,please correct them.
-In the paper the authors comment that Osram Spa defines the 2% increase in the Vf as a failure criterion. If the criterion of the work is to evaluate the failures of the LEDs with the Vf, what is the novelty of this work besides validating that method?
- In section 2: t in the first sentences he authors describe what is the motivation and what they are going to do in the work. I think it is a motivation and it is not appropriate to include it in this section. What is new about the experimental system and the methodology employed for author make such a broad and detailed description?
- Authors have to incorporated a description of de Figures in the Figure caption.
-Some units are contracted and others are not ....as for example in paragraph 2.2. ...10 minute, 5 s....they should homogenize the way of expressing the units.
- There are many figures for the amount of information provided, Figure 1 and Figure 2 can be unified into one.
-Figure 4 is not necessary. It should be eliminated.
-Figure 5 and Figure 6 can be also unified into one. Specifically in Figure 5 thet explain the exponential growth of the curve. They should analyze the exponential growth with a fitting informing about the exponencial coefficients. With respect to the Figure 6, where authors present the probabily of failure, they should perform a siminar analysis than in the curve of Figure 5. This curve shows an exponential growth also but with different characteristics. They should be analyze the exponential growth with numbers and compare with the probability where apparently the growth is larger to the trend of failed LEDs.
-Can they analyze the trend of the lifetime in Table 1….the lifetime growth is linear, exponential? Please, analyze the lifetime behavior with the number of the cycles and the failed LEDs.
-In Figure 8, where they show the X-ray analysis the failed LEDs, it is not possible to appreciate the presence of voids …..they should improve the quality of the images o change them by other ones where the Reader can distinguish the defects (voids).
-Figure 9 and 10 should be combined into one.
-Remove the text related to future developments in last section.
-Define the acronym LED in the abstract.
Author Response
Responds to the reviewer’s comments:
Dear Reviewer:
Thank you for your comments concerning our paper. Those comments are all valuable and very helpful for revising and improving our paper, as well as the important guiding significance to our research. We have studied comments carefully and have made correction. Revised portion are marked in yellow in the paper. The responds to the reviewer’s comments are below:
In this paper, author presents a simple and non-destructuve methodology to determine the solder joint fatigue and the presence of craks in LEDs. A detailed work is performed but some points must be resolved in a revision process.
Point 1: It is inelegant to use words contracted in an official scientific manuscript. There are several throughout the text, as “can’t, haven’t, doesn’t…..,please correct them.
Response 1: Thanks for reporting. We have fully corrected them.
Point 2: In the paper the authors comment that Osram Spa defines the 2% increase in the Vf as a failure criterion. If the criterion of the work is to evaluate the failures of the LEDs with the Vf, what is the novelty of this work besides validating that method?
Response 2: As our best knowledge in the literature the validation of this type of method does not exist. Osram Spa has declared this failure criterion without validating it. The results of our paper check the validity of this criterion to detect the presence of cracks in the solder joint considering a statistically significant number of cases.
Point 3: In section 2: t in the first sentences he authors describe what is the motivation and what they are going to do in the work. I think it is a motivation and it is not appropriate to include it in this section. What is new about the experimental system and the methodology employed for author make such a broad and detailed description?
Response 3: We thank the reviewer for this comment. We have eliminated the motivation for the work presented in section 2. The experimental protocol and the method have been discussed in detail to allow understanding the choices made and to permit a correct reproducibility.
Point 4: Authors have to incorporated a description of de Figures in the Figure caption.
Response 4: We have incorporated a complete description of the Figures in the Figure caption
Point 5: Some units are contracted and others are not ....as for example in paragraph 2.2. ...10 minute, 5 s....they should homogenize the way of expressing the units.
Response 5: The way of expressing the units has been homogenize as show in lines 127-130 and 215.
Point6: There are many figures for the amount of information provided, Figure 1 and Figure 2 can be unified into one.
Response 6: We have unified Figure 1 and Figure 2 into one.
Point 7: Figure 4 is not necessary. It should be eliminated.
Response 7: We have eliminated Figure 4.
Point 8: Figure 5 and Figure 6 can be also unified into one. Specifically in Figure 5 thet explain the exponential growth of the curve. They should analyze the exponential growth with a fitting informing about the exponencial coefficients. With respect to the Figure 6, where authors present the probabily of failure, they should perform a siminar analysis than in the curve of Figure 5. This curve shows an exponential growth also but with different characteristics. They should be analyze the exponential growth with numbers and compare with the probability where apparently the growth is larger to the trend of failed LEDs.
Response 8: We really thank the reviewer for allowing us to improve the data analysis. We have modified Figure 5 and we have added measurement points. We have determined curves in Figures 5 and 6 with "Curve Fitting Toolbox" and we have added the analytical formula of the function. The two curves have a different growth because Figure 5 expresses the trend of failures at each cycle while Figure 6 presents the total probability of failure at each cycle.
Point 9: Can they analyze the trend of the lifetime in Table 1….the lifetime growth is linear, exponential? Please, analyze the lifetime behavior with the number of the cycles and the failed LEDs.
Response 9: We thank the reviewer for allowing us to get better discussion of the results. We have analyzed the lifetime behavior in the discussion section.
Point 10: In Figure 8, where they show the X-ray analysis the failed LEDs, it is not possible to appreciate the presence of voids …..they should improve the quality of the images o change them by other ones where the Reader can distinguish the defects (voids).
Response 10: We have improved the quality of the images and we have pointed out the voids and cracks defects with red circles.
Point 11: Figure 9 and 10 should be combined into one.
Response 11: We have combined Figures 9 and 10 into one.
Point 12: Remove the text related to future developments in last section.
Response 12: We have eliminated text related to future developments.
Point 13: Define the acronym LED in the abstract
Response 13: We have defined the acronym LED in the abstract.
Author Response File: Author Response.pdf
Round 2
Reviewer 1 Report
The revised manuscript presents improved aim and objectives of the investigation. The abstract and conclusions are significantly improved – though there is still room for improvement. It is difficult to track the responses to the questions/concerns earlier presented as the authors did not vividly present their responses in a separate document.
The level of English language use in writing the article can still be improved significantly. Some of the sentences are hanging and not really a complete sentence.
Other than that, the manuscript may be accepted for publication.
Author Response
Responds to the reviewer’s comments:
The revised manuscript presents improved aim and objectives of the investigation. The abstract and conclusions are significantly improved – though there is still room for improvement. It is difficult to track the responses to the questions/concerns earlier presented as the authors did not vividly present their responses in a separate document.
The level of English language use in writing the article can still be improved significantly. Some of the sentences are hanging and not really a complete sentence.
Other than that, the manuscript may be accepted for publication.
Response: Thank you for the remark about the improve of the English level. A more careful reading of the whole document was carried out by the authors with the help of an English native speaker. Corrections have been highlighted in yellow in the text.
Author Response File: Author Response.pdf
Reviewer 2 Report
Dear Authors
Thank you for responses. I accept the responses, but I have two comments.
1. Table 1 is not formatted according to the Guide for Authors. The AF variable should be written in
italics.
2. Matlab offers the possibility to carry out a conformity test, e.g. using the one-sampled and
two-sampled Kolmogorow-Smirnow test - Matlab function: "kstest" and "kstest2". This function
can be used to obtain other parameters that are indicative of the quality of the Weibull
distribution match. It is easy to do and I don't understand why the Authors didn't make the
conformity test. I am providing a link to the function description page:
https://uk.mathworks.com/help/stats/kstest.html
Comments for author File: Comments.pdf
Author Response
Responds to the reviewer’s comments:
Dear Authors
Thank you for responses. I accept the responses, but I have two comments.
- Table 1 is not formatted according to the Guide for Authors. The AF variable should be written in
italics.
Response 1: Thanks so much for the comment. We have checked the correct formatting of the Table 1 and we have modified the AF variable in italics.
- Matlab offers the possibility to carry out a conformity test, e.g. using the one-sampled and
two-sampled Kolmogorow-Smirnow test - Matlab function: "kstest" and "kstest2". This function
can be used to obtain other parameters that are indicative of the quality of the Weibull
distribution match. It is easy to do and I don't understand why the Authors didn't make the
conformity test. I am providing a link to the function description page:
https://uk.mathworks.com/help/stats/kstest.html
Response 2: We really thank the reviewer for the advice. We have done the conformity test using the Matlab function “lillietest” as adviced in case of Weibull distribution by the suggested web page.
The sampled population complies with the Weibull distribution and presents a p-value = 0.38.
Author Response File: Author Response.pdf
Reviewer 3 Report
Manuscript can be accepted in the current format. However, the authors should be are requested to check all the wording very carefully and correct any typographical or English errors. For example on line 22 of the introduction "LEDs they", on line 37 "the voids’ effect", on line 49 "cracks’ detection", or line 266 in conclusions "4,1%".
Author Response
Responds to the reviewer’s comments:
Manuscript can be accepted in the current format. However, the authors should be are requested to check all the wording very carefully and correct any typographical or English errors. For example on line 22 of the introduction "LEDs they", on line 37 "the voids’ effect", on line 49 "cracks’ detection", or line 266 in conclusions "4,1%".
Response: Thank you for the remark about the incorrect use of some words and typos. A more careful reading of the whole document was carried out by the authors with the help of an English native speaker. The errors highlighted by the reviewer and many others corrections have been highlighted in yellow in the text.
Author Response File: Author Response.pdf
