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Volume 70
Issue 2
10.3797/scipharm.aut-02-17
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Article

The Behaviour of Arylidene Barbituric Acid and Cyclohexadione Derivatives Towards Tris(dimethy1amino)phosphin

by
Mohame N. R.
1,*,
El-Saidi M. M. T.
1,
Abdel Aziz S . A.
2 and
Zayed M. F.
1
1
National Research Center, Cairo, Egypt
2
Agriculture Research Center, Cairo, Egypt
*
Author to whom correspondence should be addressed.
Sci. Pharm. 2002, 70(2), 147-163; https://doi.org/10.3797/scipharm.aut-02-17
Submission received: 6 November 2001 / Revised: 11 February 2002 / Accepted: 11 February 2002 / Published: 18 May 2002
Versions Notes

Abstract

Tris(dimethy1amino)phosphine 1 reacted with phenylarylidene barbituric acids 4 to yield the triaminophosphonium dipolar ion adduct 7. 2-Arylidene-1,3- cyclohexanedione 5 and 2-Arylidene-5,5-dimethylcyclohaxane1-,3 -diones 6 reacted with phosphine 1 to produce the dioxyxanthenes 10 and 12, respectively. Structural assignments are based on analytical, chemical, and spectroscopic evidences. A mechanism is proposed to explain the formation of these compounds. The biological acitivity of the new synthesized compounds against Aphis Craccivora, a serious pest infecting many crops in Egypt, was studied.
Keywords: Tris(dimethy1amino)phosphine 1,  Barbituric acids 4, Cyclohexanediones 5 & 6, Phosphonium dipolar ions 7, Dioxyxanthenes 10 & 12, Aphis Craccivora Tris(dimethy1amino)phosphine 1,  Barbituric acids 4, Cyclohexanediones 5 & 6, Phosphonium dipolar ions 7, Dioxyxanthenes 10 & 12, Aphis Craccivora

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MDPI and ACS Style

N. R., M.; M. M. T., E.-S.; S . A., A.A.; M. F., Z. The Behaviour of Arylidene Barbituric Acid and Cyclohexadione Derivatives Towards Tris(dimethy1amino)phosphin. Sci. Pharm. 2002, 70, 147-163. https://doi.org/10.3797/scipharm.aut-02-17

AMA Style

N. R. M, M. M. T. E-S, S . A. AA, M. F. Z. The Behaviour of Arylidene Barbituric Acid and Cyclohexadione Derivatives Towards Tris(dimethy1amino)phosphin. Scientia Pharmaceutica. 2002; 70(2):147-163. https://doi.org/10.3797/scipharm.aut-02-17

Chicago/Turabian Style

N. R., Mohame, El-Saidi M. M. T., Abdel Aziz S . A., and Zayed M. F. 2002. "The Behaviour of Arylidene Barbituric Acid and Cyclohexadione Derivatives Towards Tris(dimethy1amino)phosphin" Scientia Pharmaceutica 70, no. 2: 147-163. https://doi.org/10.3797/scipharm.aut-02-17

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