A Hybrid Solar–Thermoelectric System Incorporating Molten Salt for Sustainable Energy Storage Solutions
Abstract
:1. Introduction
- Assess the utilization of the current state of solar energy in the UAE by evaluating the existing solar power projects, especially photovoltaic (PV) systems and concentrated solar power (CSP) systems. Also, analyze the efficiency and cost-effectiveness of these technologies used in the UAE.
- Integrate Molten Salt Energy Storage (MSES) with solar power systems and study the recent technological achievements in molten salt as a heat storage system in trough solar systems and then explore the feasibility of this integration and its benefits in the UAE’s renewable energy systems.
- Optimize thermal energy storage systems for increasing power generation by optimizing the thermal energy’s charging and discharging processes.
- Evaluate the environmental and economic impacts and benefits such as greenhouse gas emissions and improve energy sustainability and efficiency.
2. Literature Review
3. Design Methodology
- Aluminum frame: The design of solar systems is an essential aspect for boosting the efficiency and affordability of solar applications [24]. One key component of these systems is the structure that holds the mirrors, tank, and the whole design. Numerous academic investigations have highlighted the benefits of using durable and lightweight materials in solar systems. These studies have revealed that the careful selection of the frame material can enhance thermal performance, reduce installation complexity, which can lead to reductions in installation costs, and enhance overall system reliability [31]. For our design, we selected aluminum to be the frame material. AL is considered an ideal choice for this design because of its superior characteristics, such as its high strength-to-weight ratio and resistance to corrosion; these characteristics ensure its durability in all environments [32].
- Parabolic trough system: The design of this system is built based on the idea of the novel design developed by [21] as illustrated in Figure 1. The idea of this design was to have two mirrors: the solar radiation reflected from mirror 1 toward its focal point. This point (F) is in front of mirror 2 that is responsible for reflecting the lights back to the front focal point of mirror 2, where the receiver is placed.
- 3.
- Copper tank: Another core subsystem in our design is the tank of molten salts. This tank, shown in Figure 3, is composed of a copper interior and a glass-covered upper portion. When the solar radiation is reflected by the third mirror directly to this tank, it transfers the heat to the molten salt inside. The copper material provides excellent heat conductivity, and the thermal conductivity is constant with a value of 385, while the glass cover allows for solar radiation to penetrate while helping to retain heat. The vacuum between the copper and the glass is created to minimize heat loss, improving the tank’s ability to store heat efficiently. In the literature, there are several materials used in heat storage tanks in addition to copper such as nickel-based alloys, silicon carbide and alumina, stainless steel 316L, and carbon steel. These options are evaluated based on its availability, cost, thermal conductivity, resistance to corrosion, and thermal stability. Copper material is found to be the best for our design.
- 4.
- Molten salts: The molten salt acts as a heat transfer fluid, storing and transferring the thermal energy collected by the parabolic trough system. The selection of the molten salt will depend on several factors to ensure optimal performance and safety, such as the following [23]:
- Thermal stability, where the molten salt with higher decomposition temperature is more efficient in transferring and storing heat.
- Thermal conductivity, where molten salts with higher thermal conductivity are preferable to ensure that the heat is transferred and stored quickly and efficiently.
- Specific heat capacity, to enhance the storing efficiency; high specific heat means that more thermal energy can be stored per unit mass.
- Corrosion resistance: selecting salts that exhibit low corrosivity is crucial to prevent damage to storage tanks and thermal stability.
- Viscosity: Molten salts with low viscosity are preferable.
- Cost and Availability: Molten salt should be available and affordable.
- Non-Toxicity and Safety: The selected molten salt should be non-toxic and environmentally friendly in the case of leaks or spills; this ensures safety for operators and the environment.
- 5.
- Thermoelectric generator (TEG) and heat sinks: In our design, we combine the use of molten salts with other systems, such as TEGs, to enhance the efficiency and effectiveness of thermal energy storage solutions and generate electricity rapidly. The number and size of TEG modules will depend on the desired power output and the temperature gradient available. The used TEG is TEG1-12611-8.0, which has the following specifications: the hot side temperature is 300 °C, the cold side temperature is 30 °C, the open circuit voltage is 9.5 V, where the matched load resistance is 1.8 ohms, the matched load output voltage is 4.8 V, and the matched load output current is 2.7 A, the matched load output power is 13.0 W, the heat flow across the module is 325 W, the heat flow density is 10.4 W, the AC resistance (ohms) measured under 27 °C at 1000 HZ is 0.7~1.0, its dimensions are 56 mm × 56 mm, and the TEM leg height of TEG1-12611-8.0 is 1.7 mm. Based on these specifications, it appears that the TEG1-12611-8.0 module has a high temperature difference between the hot and cold sides, resulting in a significant heat flow across the module. This, in turn, generates electrical power through the Seebeck effect. The heat flow across the module is approximately 325 W, and the heat flow density is approximately 10.4 W. This indicates that the module can handle a substantial amount of heat and convert it into electrical power. Additionally, the AC resistance of the module is measured under specific conditions. The measured AC resistance at 27 °C and 1000 Hz falls within the range of 0.7 to 1.0 ohms. This resistance value is important for determining the electrical performance and efficiency of the module. These modules work best in the temperature range of 220 to 300 °C. The capability to operate at higher-temperature ranges and deliver superior performance in these conditions makes the TEG1-12611-8.0 module a reliable choice for thermoelectric power generation. These specifications make this type of TEG the best choice to use in our design. With respect to the heat sinks, the heat sink is used to maintain the temperature difference necessary for TEGs to generate electricity efficiently.
- 6.
- Fan: We can use a fan to aid the heat sink with generating the high-temperature difference; therefore, TEGs will operate with more efficiency.
- 7.
- Tracking system: A single-axis tracker can be used to track the solar radiation during the day. This type of tracking system ensures the balance between solar radiation capture, cost, and complexity [33]. The UAE’s location (latitude ~24° N) makes the application of the proposed design in the research of [33] very useful since the sun’s path is relatively consistent throughout the year. Also, their proposed design aligns with this study’s objectives of scalability and the ability to apply this technology in off-grid areas. The specifications of the recommended tracker system that match this study are summarized in Table 1.
4. Data Analysis and Results
- Solar Energy Collection and Mirror Area:
- Thermal Energy Required at the Collector:
- The total energy required at the collector (Q collector):
- Trough Calculations:
- Parabolic Trough Opening ():
- Parabolic Trough Length (L):
- To calculate the focal length () and the collector opening at focal length ():
- Thermal Energy Storage in Molten Salt
- Molten salt tank:
- Thermoelectric Generator (TEG) Performance
- Overall system efficiency
- represents the radiative, conductive, and convective losses. Using the glass envelope and the vacuum-insulated copper tank can reduce these losses. This is an estimated value and needs to be validated by an experiment. This value can be improved by using low E-glass and anti-reflective coatings on the envelope.
- combining the mirror reflectivity (95%) and tank absorptance (95%): These values are assumed to be based on the manufacturing tolerances, and they are common in most of the solar systems but need to be verified. The copper material and the vacuum with a semicylindrical shape of a tank ensure the high value of absorbance. The reflectivity of mirrors can be increased by using the proposed tracking system and by using the anti-reflective coatings on the mirror.
- : This value is considered as mentioned in the technical characteristics of the used TEG. In the current design, the use of a heat sink and fan can reduce the temperature of the cold side of the TEG; this will maximize the and efficiency. To increase the temperature of the hot side, ref. [42] studied the effect of using liquid-saturated porous medium in enhancing the heat transfer from TEGs and improving the TEG’s performance. The used TEG is the same TEG we use in this study. The results of their experiments showed a significant improvement in efficiency, especially when they used the copper particles; the performance improved by 149%. Following this approach in our design may enhance the efficiency of TEGs since it is the same TEG used in this study, and the molten salt tank is made of copper. We can attach a layer of copper foam to the outer surface of the copper tank and mount the TEG directly using a thermal interface material onto the porous medium that is saturated with the molten salt that acts as a heat transfer medium for the TEG in our design. Although this study promises a significant increase in performance, an experimental study should be utilized to validate the design.
5. Economic Assessment and Comparative Analysis
5.1. Initial Investment Costs
- Parabolic Trough Mirrors:
- Copper Tank: With a mass of 86.45 kg, the estimated cost = USD 12/kg (UAE 2025 market estimate), totaling USD 1037.40 (86.45 × USD 12).
- Glass Tube: Glass mass = 24.63 kg. The estimated cost = USD 1–2/kg [44], totaling USD 24.63–49.26 (24.63 × USD 1 to 24.63 × USD 2).
- Vacuum and Assembly: A vacuum layer enhances insulation, estimated at USD 50–100 for small-scale fabrication, consistent with CSP component cost breakdowns [45].
- Molten Salt: 352.27 kg at an estimated USD 0.626/kg, totaling USD 220.50 (352.27 × USD 0.626).
- Total Tank Cost: Ranges between USD 1332.53 and 1407.16 (USD 1037.40 + 24.63 + 50 + 220.50 to USD 1037.40 + 49.26 + 100 + 220.50).
- Heat sinks and fan add an estimated USD 50–100, summing to USD 330–660.
- Aluminum Frame: 15 kg at an estimated USD 2.24/kg (UAE 2025 market estimate), totaling USD 33.60 (15 × USD 2.24/kg; [32]).
- Single-Axis Tracker: Estimated USD 150–300 [33].
- Miscellaneous (Wiring, Assembly): Estimated USD 50–100.
- Total Initial Cost: Falls in the ranges of USD 2102.63–2913.76 and USD 256.50 + 1332.53 + 280 + 33.60 + 150 + 50 to USD 513 + 1407.16 + 560 + 33.60 + 300 + 100.
5.2. Lifetime Costs
- TEG Replacement: Assumed negligible over 25 years due to solid-state reliability, as evidenced by Voyager 1’s TEG operating over 41 years [47]. TEGs (300 °C hot side, 30 °C cold side) operate within specifications, and their solid-state design eliminates mechanical failure. The UAE climate may slightly reduce system lifespan, but 25 years is feasible with proper heat sink appropriate maintenance and upkeep.
- Operation and Maintenance (O&M): Estimated USD 10–20/year for 25 years, using a discount value at 8.14% [26], Table 2), then the present value annuity factor is calculated as PV = C × [(1 − (1 + 0.0814)^(−25))/0.0814], where C = USD 10–20). The resulting O&M cost is estimated to be in the range of USD 108.62–217.
- Total Lifetime Cost: Estimated to range between USD 2211.25 and 3130.24 (USD 2102.63 + 108.62 to USD 2913.76 + 217.24).
5.3. Levelized Cost of Electricity (LCOE)
- Lifetime energy output: 18,851.25 kWh (754.05 kWh/year × 25 years).
- LCOE = Total Lifetime Cost/lifetime energy:
- Minimum with USD 2211.25 lifetime cost: USD 2211.25/18,851.25 = USD 0.117/kWh.
- Maximum with USD 3130.24 lifetime cost: USD 3130.24/18,851.25 = USD 0.166/kWh.
- Range: USD 0.117–0.166/kWh.
5.4. Levelized Cost of Storage (LCOS)
- Storage cost: USD 1332.53–1407.16 (tank only).
- Lifetime stored energy: 18,851.25 kWh (all energy passes through storage).
- LCOS = Storage cost/lifetime stored energy:
- Minimum: USD 1332.53/18,851.25 = USD 0.071/kWh.
- Maximum: USD 1407.16/18,851.25 = USD 0.075/kWh.
- Range: USD 0.071–0.075/kWh.
5.5. Comparative Analysis with Alternative Systems
- PV with Battery System
- -
- Initial Cost:
- 400 W PV panel: Based on wholesale and retail pricing in the UAE, USD 158–330. This aligns with the UAE’s competitive solar market, driven by initiatives like Shams Dubai and low labor costs.
- 12 V 200 Ah LiFePO4 battery: Based on wholesale and retail pricing in the UAE, USD 500–800. This aligns with the UAE’s competitive solar market, driven by initiatives like Shams Dubai and low labor costs.
- Controller and wiring: USD 120–250 (estimated).
- Total: USD 778–1380 (USD 158 + 500 + 120 to USD 330 + 800 + 250).
- -
- Lifetime Cost:
- Battery degradation: 2.5% annually, requiring replacements at years 10 and 20.
- Total: USD 1220.62–2131.64 (USD 778 + 229 + 105 + 108.62 to USD 1380 + 366.40 + 168 + 217.24; estimated).
- -
- LCOE:
- Adjusted lifetime energy (with degradation): 16,348 kWh.
- Minimum: USD 1220.62/16,348 = 0.075/kWh.
- Maximum: USD 2131.64/16,348 = 0.130/kWh.
- Range: USD 0.075–0.130/kWh (estimated).
- -
- LCOS: USD 0.027–0.042/kWh (USD 500–800/18,851.25; estimated).
- Standard Parabolic Trough System
- -
- Initial Cost:
- Mirrors (5.13 m2): USD 256.50–513 ([26]; estimated).
- Two-tank molten salt system (450 kg, estimated for 33 kWh/day thermal):
- Copper (139.46 kg): Volume = 2 × π × [(0.242 m)2 − (0.24 m)2] × 2.565 m = 0.0156 m3, mass = 0.0156 × 8940 = 139.46 kg [32], cost = USD 1673.52 (139.46 × USD 12; estimated).
- Glass (40 kg): Volume = 2 × π × [(0.252 m)2 − (0.249 m)2] × 2.565 m = 0.016 m3, mass = 0.016 × 2500 = 40 kg, cost = USD 40–80 (40 × USD 1–2; [44]; estimated).
- Vacuum and assembly: USD 100–200 (two tanks; [45]; estimated).
- Molten salt (450 kg): USD 281.70 (450 × USD 0.626; estimated).
- Total: USD 2095.22–2235.22 (USD 1673.52 + 40 + 100 + 281.70 to USD 1673.52 + 80 + 200 + 281.70; estimated).
- Receiver and turbine: USD 500–1000 ([45]; estimated).
- Tracker and misc: USD 200–400 ([33]; estimated).
- Total: USD 3051.72–4148.22 (USD 256.50 + 2095.22 + 500 + 200 to USD 513 + 2235.22 + 1000 + 400; estimated).
- -
- Lifetime Cost:
- -
- LCOE:
- Lifetime energy: 18,851.25 kWh.
- Minimum: USD 3160.34/18,851.25 = USD 0.168/kWh.
- Maximum: USD 4365.46/18,851.25 = USD 0.232/kWh.
- Range: USD 0.168–0.232/kWh (estimated).
- -
- LCOS: USD 0.111–0.119/kWh (USD 2095.22–2235.22/18,851.25; estimated).
6. Design Evaluation and Alignment with the UAE’s Policy
7. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Parameter | Value | Unit |
---|---|---|
Tracker Type | Single-Axis | - |
Rotation Axis | North–South | - |
Tracking Accuracy | ±0.5° | - |
Drive Mechanism | Motorized or Manual | - |
Control System | Solar Sensor or Timer | - |
Maintenance Requirements | Low | - |
Parameter | Symbol | Value | Unit |
---|---|---|---|
Daily Energy Requirement | 2.067 | kWh/day | |
Thermal Energy at TEGs | 25.84 | kWh/day | |
Optical Efficiency | 90.25% | - | |
Thermal Efficiency | 90% | - | |
Mirror Area | 5.13 | m2 | |
Molten Salt Mass | 352.27 | kg | |
TEG Output Power | 26 | W | |
Number of TEGs | - | 14 | - |
System Efficiency | 6.5% | - | |
Parabolic Trough Opening | 2.0 | m | |
Parabolic Trough Length | 2.565 | m | |
Collector Opening Area | 5.13 | m2 | |
Rim Angle | 80° | - | |
Collector Opening at Focal Length | 0.419 | m | |
Focal Length | 0.596 | m |
System | Initial Cost (USD) | Lifetime Cost (USD) | LCOE (USD/kWh) | LCOS (USD/kWh) | Comments and Trade-Offs |
---|---|---|---|---|---|
Hybrid (Proposed) | 2102.63–2913.76 | 2211.25–3130.24 | 0.117–0.166 | 0.071–0.075 | Offers 24/7 power and high reliability; higher initial cost offset by no fuel or replacement expenses. Trade-off: Higher upfront investment for continuous power vs. cheaper daytime-only alternatives. |
PV+ Battery | 778–1380 | 1220.62–2131.64 | 0.075–0.130 | 0.027–0.042 | Lowest cost but limited by battery lifespan and degradation; suits intermittent use with lower upfront investment. Trade-off: Cheaper initially but recurring battery costs reduce long-term savings. |
Standard Trough | 3051.72–4148.22 | 3160.34–4365.46 | 0.168–0.232 | 0.111–0.119 | Higher cost due to turbine and dual-tank complexity; reliable for 24/7 power but less efficient at small scale. Trade-off: Robust power delivery at a premium cost vs. simpler, less-expensive options. |
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Mistarihi, M.Z.; Magableh, G.M.; Abu Dalu, S.M. A Hybrid Solar–Thermoelectric System Incorporating Molten Salt for Sustainable Energy Storage Solutions. Technologies 2025, 13, 104. https://doi.org/10.3390/technologies13030104
Mistarihi MZ, Magableh GM, Abu Dalu SM. A Hybrid Solar–Thermoelectric System Incorporating Molten Salt for Sustainable Energy Storage Solutions. Technologies. 2025; 13(3):104. https://doi.org/10.3390/technologies13030104
Chicago/Turabian StyleMistarihi, Mahmoud Z., Ghazi M. Magableh, and Saba M. Abu Dalu. 2025. "A Hybrid Solar–Thermoelectric System Incorporating Molten Salt for Sustainable Energy Storage Solutions" Technologies 13, no. 3: 104. https://doi.org/10.3390/technologies13030104
APA StyleMistarihi, M. Z., Magableh, G. M., & Abu Dalu, S. M. (2025). A Hybrid Solar–Thermoelectric System Incorporating Molten Salt for Sustainable Energy Storage Solutions. Technologies, 13(3), 104. https://doi.org/10.3390/technologies13030104