Next Article in Journal
Time-Course Transcriptome Analysis Reveals Global Gene Expression Profiling and Dynamic Developmental Signatures across Complete Life Cycle of Bombyx mori
Previous Article in Journal
Interterminal Truck Routing Optimization Using Cooperative Multiagent Deep Reinforcement Learning
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Processes
Volume 9
Issue 10
10.3390/pr9101729
processes-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles thumb_up
...
Endorse textsms
...
Comment
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Review

Photocatalysis for Heavy Metal Treatment: A Review

by
Xinyu Gao
and
Xiangchao Meng
*
Department of Chemical Engineering, Ocean University of China, Qingdao 266100, China
*
Author to whom correspondence should be addressed.
Processes 2021, 9(10), 1729; https://doi.org/10.3390/pr9101729
Submission received: 19 August 2021 / Revised: 18 September 2021 / Accepted: 20 September 2021 / Published: 27 September 2021
(This article belongs to the Section Environmental and Green Processes)
Browse Figures
Versions Notes

Abstract

:
Environmental and human health are threatened by anthropogenic heavy metal discharge into watersheds. Traditional processes have many limitations, such as low efficiency, high cost, and by-products. Photocatalysis, an emerging advanced catalytic oxidation technology, uses light energy as the only source of energy. It is a clean new technology that can be widely used in the treatment of organic pollutants in water. Given the excellent adaptability of photocatalysis in environmental remediation, it can be used for the treatment of heavy metals. In this comprehensive review, the existing reported works in relevant areas are summarized and discussed. Moreover, recommendations for future work are provided.

Graphical Abstract

1. Introduction

Heavy metals are defined as metals with relatively high densities (metals where the density is usually greater than 5 g/cm3), high atomic weights, and high atomic numbers. Heavy metals pose a great threat to the ecosystem, which, in turn, affects human health. The presence of heavy metals, such as mercury, lead, copper, nickel, cadmium, or arsenic, can accumulate in the human body, causing organ failure or cancer and can severely endanger human health. In addition to direct health effects, the heavy metal pollution in in water bodies and the atmosphere can also lead to the poisoning of animals and plants, resulting in reduced crop yields, a shortage of food and water sources, ecological balance, and biodiversity damage. This would further induce large economic losses and disturb geographical and ecological balance because they are difficult to transform or degrade into harmless substances [1,2]. The common uses and health effects of several heavy metal elements are summarized in Table 1. Therefore, the proper disposal of heavy metal pollutants is imperative.
Photocatalysis is a popular technology among these new advanced oxidation technologies and exhibits promise in various areas [3,4,5,6,7]. Figure 1 illustrates a schematic diagram of the basic principle of the photocatalytic process. Generally, photocatalysts have semiconductor structures. When the semiconductor material is irradiated by light, electrons (e−) located in the valence band may jump to CB and may leave a positively charged hole (h+) on the VB if the energy of a photon in the incident light is greater than or equal to the bandgap energy between the semiconductor valence band (VB) and the conduction band (CB). This pair of h+ and e− can, respectively migrate to the surface of the semiconductor to undergo a series of oxidation and reduction reactions, which are embodied in the conversion of different valence states in the treatment of heavy metals [8,9,10]. In the photocatalysis process, the most essential limiting factors are the high energy requirements of the incident light caused by the wide bandgap and the easy recombination of photogenerated carriers (e− and h+). TiO2, the most typical photocatalyst, has received the most extensive research. However, its wide bandgap only responds to UV light [11,12,13]. Hence, more photocatalysts with suitable and efficient bandgaps have been developed and used, such as Bi-based catalysts [14], C3N4 [15], and ZnO [16]. At present, there have been many active reports on photocatalysis in organic wastewater treatment [17], water splitting for hydrogen and oxygen production [18], and nitrogen fixation [19]. Since photocatalysis does not require additional energy input besides light, the active species that are produced have good redox capabilities and do not produce additional pollution [20]. It is highly feasible to use it for redox in water treatment.

2. Traditional Heavy Metal Treatment

Typical industrial methods employed in wastewater treatment, such as adsorption, chemical precipitation, ion exchange, ozonation, biological methods, and electrochemical methods activated by carbon, can hardly reduce the metal concentration in water to within the regulatory standards effectively [23]. This is because there is a considerable number of heavy metals in water that are complexed with organic chelating agents that come from textile, nuclear, and electroplating sources. With copper as an example, the adsorption efficiency is 49.3% of the original under competitive chelation with EDTA [24]. Figure 2 presents a schematic diagram of the most typical electrochemical water treatment tank. Its complete removal requires the assistance of other technologies, though it can effectively oxidize and reduce heavy metals. Moreover, the requirements of electrochemical treatment on equipment parameters and the huge power consumption also cannot be underestimated.
Metals can be precipitated by the addition of coagulants such as alum, lime, alum salts, and other organic polymers. This method is used by almost three-quarters of plating companies. Among them, the most common precipitation methods include sulphide, sodium hydroxide, and carbonate methods. However, the major disadvantage of this process is the large amount of toxic sludge that is produces [26].
Additionally, there are some more processes that can be used to complete heavy metal treatment. Nonetheless, they have their defects, which are summarized in Table 2.
The good redox ability of photocatalytic technology and the performance and adaptability in the treatment of organic pollutants in water [33] enable it to be used for the recovery of heavy metals. Its main advantage is that it does not require energy input other than light energy, which is different from many traditional processes and is beneficial to its continuous operation [34]. In photocatalytic redox, no polluting intermediates are produced. This is another important advantage. This environmentally friendly feature is consistent with the purpose of water treatment [35]. Finally, photoreactions can be adopted to deposit heavy metals that are easily reduced on the surface of the catalyst in the form of solids to achieve the effect of direct separation from the solution [36]. These characteristics of photocatalysis are not available in many traditional heavy metal processing techniques.

3. Photocatalytic Heavy Metal Treatment

As mentioned above, the unique advantages of photocatalysis equip it with great potential in the treatment of heavy metals [11,14,34,37]. Therefore, it has also attracted the attention of many researchers [38,39,40,41,42,43,44,45,46,47,48,49]. Some reported examples of the photocatalytic treatment of heavy metals are provided in Table 3. The specific situations of different heavy metals in photocatalytic treatments are detailed as follows.

3.1. Chromium (Cr)

Chromium is the most studied and most typical metal in heavy metal removal studies. It is a metal with numerous industrial and technological applications in fields such as electroplating, the textile industry, wood preservation, and metallurgy. The production of wastewater containing chromium ions is inevitable with the use of chromium. Cr(VI) ions have been discovered to be more toxic than Cr(III) ions. Compared to Cr(III), which is more thermodynamically stable, long-term exposure to Cr(VI) can damage the nasal septum, cause lung cancer, and result in skin ulcers [75]. Among heavy metal ions, the treatment of Cr(VI) ions is the most studied. Some works have been published on the photocatalytic reduction of Cr(VI) using TiO2-, ZnO-, CdS-, and ZnS-based catalysts [16,50,51,52,53,54,55,56,57,58,59,60,61,62,65].
In 2005, Tuprakay et al. successfully photo-reduced Cr(VI) by using immobilized TiO2 under a UV light intensity of 171 W/m2 in 32 h. The Cr(VI) adsorption followed first-order kinetics, while the reduction exhibited zero-order kinetics [76]. Five years later, Idris et al. observed that the initial concentration of the Cr(VI) present before photoreduction plays a crucial role in determining its removal efficiency. At an equilibrium state, the removal efficiency of Cr(VI) at initial concentrations of 25, 50, 75, 100, 125, and 150 mg/L was revealed to be 100%, 100%, 100%, 100%, 70%, and 70% in 100 min, respectively. A further investigation indicates that the percentage adsorption of Cr(VI) decreased with the increasing initial Cr(VI) concentration. Moreover, this experiment was conducted in sunlight with the use of magnetically separable photocatalyst beads, allowing it to be achieved in less time [77]. The photocatalytic reduction of Cr(VI) is feasible under visible light. Dye-photosensitized TiO2 samples successfully reduced Cr(VI) under visible light.
Di Iorio et al. reported a high efficiency in Cr(VI) reduction by using alizarin red chelated to TiO2. This was slightly dependent on the Cr(VI) concentration and was independent of the photon flux and the irradiation wavelength [78]. At a pH of 2, a rapid reduction of Cr(VI) was observed when visible light was irradiated on TiO2 coated with hydroxyl aluminium tricarboxymonoamide phthalocyanine (AITCPc) in the presence of 4-chlorophenol (4-CP) as a sacrificial donor assisting in preventing the photobleaching of AITCPc [79]. Figure 3a illustrates that the phthalocyanine (Pc) on the surface of TiO2 will excite electrons and holes when photo-sensitized. This is different from the photocatalysis principle of a single material. Moreover, they will migrate to CB and VB for their respective oxidation and reduction reactions. Figure 3b presents the energy band change after the coupling of TiO2 and AITCPc. It can also reflect the migration process of excited electrons on AITCPc to the CB of TiO2. In this way, the coupling effect between different materials can weaken the light utilization efficiency of the entire photocatalytic system, improve the separation efficiency of photogenerated carriers, and enhance the overall reduction ability and efficiency of the entire photocatalytic system to Cr(VI). On the excitation of the dye, an electron was injected into the conduction band to promote Cr(VI) reduction [79,80]. In these photoreduction studies, most of the Cr(VI) ions are reduced to Cr(III) ions, while only a small part is reduced to Cr atoms [60,65].
Cr(VI) + e− → Cr(V)
Cr(V) + e− → Cr(IV)
Cr(IV) + e− → Cr(III)
Cr 2 O 7 2 − + 6 e − + 14 H +   →   2 Cr 3 + + 7   H 2 O   E 0 =   + 1.33   V
The photocatalytic treatment of Cr(VI) is a complete photoreduction process, which is largely affected by the following three factors:
  • A low pH that favors the net reaction in Equation (3); however, neutral or alkaline conditions favor the precipitation and immobilization of Cr(III) as the oxides or hydroxides, contributing to enhancing separation even further [81,82,83].
  • The addition of organic compounds can accelerate the reduction of Cr(VI) by acting as hole or ·OH scavengers [84].
  • Cr(VI) reduction is independent of molecular oxygen, especially at a low pH [65].
In addition to Cr(VI), there are also studies on the removal of Cr(III) ions. Devagi et al. treated wastewater containing three heavy metal ions: Cr(III), Cu(II), and Pb(II), at the same time. They revealed that the adsorption in their system can significantly contribute to the removal of heavy metal ions instead of photoreduction [66].

3.2. Arsenic (As)

As another common heavy metal element, arsenic is highly toxic. This has been demonstrated through the long-term drinking of arsenic-containing water causing various cancers [64]. In addition to the risk of carcinogenesis and acute poisoning, some investigations suggest that chronic arsenic poisoning can impact mental health and the neurobehavior of children, causing long-term and irreversible social harm [85,86]. In an aqueous solution, arsenic mainly exists in the forms of As(III) and As(V). Compared to As(III), As(V) ions are less toxic and are more easily adsorbed and removed [87]. When pH < 9, it mainly exists in the non-ionic form of H3AsO3, which is difficult to remove by simple coagulation precipitation or adsorption because of the neutrality and difficult ionization of H3AsO3 [88,89]. Recently, Zhang et al. effectively achieved the removal of Cr(VI)/As(III) by applying iron(III) cross-linking alginate hydrogel beads (Fe-SA) as photocatalyst under simulated sunlight. The Fe-SA system used Fe(II) and CO2 as intermediates while reducing Cr(VI) and oxidizing As(III) by the photoinduced ligand to metal charge transfer under UV light and adsorbing them (Figure 4). This efficient synergistic system enables the two heavy metals to reach more than 80% in a wide pH range (3–7). In this study, Cr(VI) was reduced to Cr(III) ions, and As(III) was oxidized to As(V) ions. Then, they were adsorbed or settled, allowing them to be removed from the water [61].
Photocatalysis offers a low-cost alternative in treatments to remove arsenic from wastewater. Meichtry et al. impregnated the walls of PET plastic bottles with TiO2, which is the most typical and most commonly used photocatalyst. As(III) solutions of 1000 µg/L at a pH of 7.8 were placed in the bottles and were irradiated by UV light for 6 h; finally, a removal efficiency of 80–86% was recorded for arsenic; this process could be repeated up to three times without any loss of efficiency [90]. The removal efficiency of 94% was recorded in the photooxidation of As from well water samples (taken from Las Hermanas, Santiago del Estero Province, Argentina). This was performed under solar irradiation with the addition of FeCl3 at the end of the experiment. It was discovered to be within the limits of the World Health Organization (WHO).
Simultaneously, there have also been explorations on the reduction and removal of As(V) [62]. Research demonstrates that As(V) can be reduced in the dark by accumulated electrons through the UV irradiation of TiO2 nanoparticles in alcohol. The accumulation of electrons and their participation in the reduction of As(V) was detected as Ti(III) by UV-vis spectrophotometry [91,92].

3.3. Mercury (Hg)

The ingestion of mercury by organisms can cause permanent enzyme inactivation, leaving a devastating effect on metabolic functions [93]. Unlike other heavy metal forms of pollution, mercury is liquid at room temperature. The flow properties of mercury liquid and steam can significantly boost the permeability and scope of pollution. In cases where ions have similar toxicity to other heavy metals, the elemental form of mercury also has strong toxicity and diffusivity. Thus, Hg(0) and Hg(II) have different photocatalytic treatment methods.
Chen et al. revealed that Ag(I), Pb(II), Hg(II), Cr(VI), and Fe(III) can be reduced by photocatalysis after 65 min of irradiation using TiO2 as the photocatalyst, with a removal efficiency of 99.7%, 27.2%, 70%, 79.1%, and 100%, respectively [94]. Kadi et al. employed α-Fe2O3/g-C3N4 to reduce Hg(II) in water under visible light. Within 60 min, 100 mg/L of Hg(II) was completely converted [67]. The photocatalyst adopted in their study exhibited good activity in the photoreduction process and could be used to reduce other heavy metal ions. Regarding mercury ions, simple reduction is not enough for the removal of heavy metal elements. After the mercury ions are reduced to elemental mercury, adsorption may be an indispensable part of this process.
Due to its low water solubility and high volatility, Hg(0) is generally considered more difficult to remove than Hg(II). Several reports have verified that Bi-based photocatalysts show good activity in Hg(0) removal [69,70]. The BiOI/BiOCl microflowers prepared by Sun et al. can effectively photocatalyze oxidation and trap Hg in the gas phase [68]. Different from ordinary heterostructures, the unique multi-level charge transport path of this microflower-like BiOCl/BiOI alternate arrangement structure equips it with better charge transport and photo-generated carrier separation capabilities. The mechanism diagram is illustrated in Figure 5. The experimental results suggest that the Hg removal rate of this microflower BiOCl/BiOI is as high as 72.2%, which is more than four times the efficiency of pure BiOCl and BiOI.
To sum up, it is a more feasible and reasonable treatment to oxidize the elemental state of Hg to Hg(II) and to then remove it in the form of HgO.

3.4. Other Heavy Metals

Moreover, there are many kinds of heavy metal elements that are potentially harmful to the environment. These are not as typical as Cr(VI), nor are they as special as Hg. Considering that simple photoreduction combined with adsorption can effectively treat these heavy metals, they are classified into the same category. Cadmium (Cd), lead (Pb), copper (Cu), zinc (Zn), manganese (Mn), nickel (Ni), and cobalt (Co) are also common heavy metals. They will threaten environmental safety and human health when existing in the form of ions in the solution.
Wahyuni et al. explained that Cr(VI), Cu(II), and Cd(II) can be reduced photo-catalytically, while Pb(II) ions preferably oxidize than reduce because of their negative reduction potential value.
Cu 2 + + 2 e −   →   Cu 0                     E 0 =   + 0.34   V
Cd 2 + + 2 e −   →   Cd 0                       E 0 =   − 0.403   V
Pb 2 +   →   Pb 4 + + 2 e −                     E 0 =   − 0.67   V
In the removal of heavy metals, the influence of pH is a critical factor influencing the sedimentation of ions. According to reports, the optimum pH is 5 in such a system. At this pH, the removal efficiency of 15%, 40%, 45%, and 75% was achieved for Cd(II), Pb(II), Cu(II), and Cr(VI), respectively. At a more alkaline pH (pH 13), Cr(VI) is hardly removed effectively, while the removal rate of Cd(II), Pb(II), and Cu(II) is close to 100%.

4. Discussion and Outlooks

Photocatalytic removal of heavy metals is an essential part of photocatalytic water treatment. At present, the removal of various heavy metal elements using photocatalytic technology has been extensively studied. In this study, the typical works of this research topic are summarized. Although this process has presented advantages, there are still obstacles in its future applications. Possible solutions to existing problems and recommendations for future work are suggested as follows:
  • Low photocatalytic efficiency: At present, the efficiency of the photocatalytic reaction remains low. This is reflected not only in the removal of heavy metals but also in other photocatalytic processes. This situation is expected to be improved as more new materials presenting higher catalytic activity and higher stability efficiency or modification methods (such as doping and morphology control) that can improve the photocatalytic activity and stability of existing materials are proposed.
  • Low light utilization efficiency: Although natural solar energy resources are extremely abundant, the current light energy that can be utilized by photocatalysis is still very low. From one perspective, this is caused by the poor response of the photocatalyst to visible light. From another perspective, it is related to the current photocatalytic system. The former can be improved through the improvement of materials while the latter may require breakthroughs in reactor design.
  • Continuous operation method: It is difficult to remove heavy metals through simple oxidation or reduction. It is a common photocatalytic treatment method to convert difficult-to-treat heavy metal atoms or ions into a form that is easier to adsorb or settle and before removal. Its practical application would lie in the organic combination of the catalytic process and the adsorption/sedimentation process to ensure that the entire process has better overall continuity.
  • No standard platform: Although there is a WHO standard for the removal of heavy metals, this standard has not been widely adopted, especially in photocatalysis research. Moreover, the existing research on the use of light sources and other aspects of the divergence is sufficient. To date, no standard platform can use a unified standard to evaluate the photoactivity of different photocatalysts in different laboratories. The establishment of this standard is necessary and urgent.
  • Technology coupling: With the current efficiency of photocatalysis, it is significantly difficult to complete the task of water treatment on its own. Generally, the combination of different technologies is effective. It may be a good choice to organically combine the photocatalytic system with the existing water treatment technology.
Current research has demonstrated that photocatalytic technology can play a role in the removal of heavy metals. However, there are still many problems in this process, such as low efficiency, difficult separation, and difficult catalyst regeneration. Therefore, this advanced technology requires further development.

Author Contributions

Conceptualization, Literature review, Writing—Original draft preparation (X.G.); Supervision, Writing—Original draft preparation, review and editing, manuscript submission and correspondence (X.M.). All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by Taishan Scholars Foundation of Shandong province (Grant No.: tsqn201909058) and the Fundamental Research Funds for the Central Universities (Grant No.: 202013037).

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

Not applicable.

Conflicts of Interest

There are no conflicts of interest to declare.

References

  1. Litter, M.I. Mechanisms of removal of heavy metals and arsenic from water by TiO2-heterogeneous photocatalysis. Pure Appl. Chem. 2015, 87, 557–567. [Google Scholar] [CrossRef]
  2. Fu, F.; Wang, Q. Removal of heavy metal ions from wastewaters: A review. J. Environ. Manag. 2011, 92, 407–418. [Google Scholar] [CrossRef]
  3. Gao, X.; Yao, Y.; Meng, X. Recent development on BN-based photocatalysis: A review. Mater. Sci. Semicond. Process. 2020, 120, 105256. [Google Scholar] [CrossRef]
  4. Yao, Y.; Gao, X.; Li, Z.; Meng, X. Photocatalytic Reforming for Hydrogen Evolution: A Review. Catalysts 2020, 10, 335. [Google Scholar] [CrossRef] [Green Version]
  5. Yao, Y.; Gao, X.; Meng, X. Recent advances on electrocatalytic and photocatalytic seawater splitting for hydrogen evolution. Int. J. Hydrogen Energy 2021, 46, 9087–9100. [Google Scholar] [CrossRef]
  6. Yao, Y.; Ren, G.; Li, Z.; Bai, H.; Hu, X.; Meng, X. Nitrogen Vacancy-Induced Deposition of Pd Nanoparticles onto g-C3N4 with Greatly Improved Photocatalytic Activity in H2 Evolution. Sol. RRL 2021, 5, 2100145. [Google Scholar] [CrossRef]
  7. Argurio, P.; Fontananova, E.; Molinari, R.; Drioli, E. Photocatalytic membranes in photocatalytic membrane reactors. Processes 2018, 6, 162. [Google Scholar] [CrossRef] [Green Version]
  8. Ullah, H.; Viglašová, E.; Galamboš, M. Visible Light-Driven Photocatalytic Rhodamine B Degradation Using CdS Nanorods. Processes 2021, 9, 263. [Google Scholar] [CrossRef]
  9. Ulyankina, A.; Mitchenko, S.; Smirnova, N. Selective photocatalytic oxidation of 5-HMF in water over electrochemically synthesized TiO2 nanoparticles. Processes 2020, 8, 647. [Google Scholar] [CrossRef]
  10. Wang, C.; Sun, X.; Shan, H.; Zhang, H.; Xi, B. Degradation of Landfill Leachate Using UV-TiO2 Photocatalysis Combination with Aged Waste Reactors. Processes 2021, 9, 946. [Google Scholar] [CrossRef]
  11. Li, Z.; Meng, X.; Zhang, Z. Recent development on MoS2-based photocatalysis: A review. J. Photochem. Photobiol. C Photochem. Rev. 2018, 35, 39–55. [Google Scholar] [CrossRef]
  12. Mukherjee, D.; Barghi, S.; Ray, A.K. Preparation and characterization of the TiO2 immobilized polymeric photocatalyst for degradation of aspirin under UV and solar light. Processes 2014, 2, 12–23. [Google Scholar] [CrossRef] [Green Version]
  13. Mukherjee, D.; Ray, A.K.; Barghi, S. Mechanism of acetyl salicylic acid (aspirin) degradation under solar light in presence of a TiO2-polymeric film photocatalyst. Processes 2016, 4, 13. [Google Scholar] [CrossRef]
  14. Meng, X.; Zhang, Z. Bismuth-based photocatalytic semiconductors: Introduction, challenges and possible approaches. J. Mol. Catal. A Chem. 2016, 423, 533–549. [Google Scholar] [CrossRef]
  15. Safaei, J.; Ullah, H.; Mohamed, N.A.; Mohamad Noh, M.F.; Soh, M.F.; Tahir, A.A.; Ahmad Ludin, N.; Ibrahim, M.A.; Wan Isahak, W.N.R.; Mat Teridi, M.A. Enhanced photoelectrochemical performance of Z-scheme g-C3N4/BiVO4 photocatalyst. Appl. Catal. B Environ. 2018, 234, 296–310. [Google Scholar] [CrossRef]
  16. Liang, H.; Li, T.; Zhang, J.; Zhou, D.; Hu, C.; An, X.; Liu, R.; Liu, H. 3-D hierarchical Ag/ZnO@CF for synergistically removing phenol and Cr(VI): Heterogeneous vs. homogeneous photocatalysis. J. Colloid Interface Sci. 2020, 558, 85–94. [Google Scholar] [CrossRef] [PubMed]
  17. Li, Z.; Zhang, Z.; Wang, L.; Meng, X. Bismuth chromate (Bi2CrO6): A promising semiconductor in photocatalysis. J. Catal. 2020, 382, 40–48. [Google Scholar] [CrossRef]
  18. Zhu, C.; Liu, C.; Fu, Y.; Gao, J.; Huang, H.; Liu, Y.; Kang, Z. Construction of CDs/CdS photocatalysts for stable and efficient hydrogen production in water and seawater. Appl. Catal. B Environ. 2019, 242, 178–185. [Google Scholar] [CrossRef]
  19. Di, J.; Xia, J.; Chisholm, M.F.; Zhong, J.; Chen, C.; Cao, X.; Dong, F.; Chi, Z.; Chen, H.; Weng, Y.X.; et al. Defect-Tailoring Mediated Electron-Hole Separation in Single-Unit-Cell Bi3O4 Br Nanosheets for Boosting Photocatalytic Hydrogen Evolution and Nitrogen Fixation. Adv. Mater. 2019, 31, e1807576. [Google Scholar] [CrossRef]
  20. Li, Z.; Meng, X.; Zhang, Z. Fabrication of surface hydroxyl modified g-C3N4with enhanced photocatalytic oxidation activity. Catal. Sci. Technol. 2019, 9, 3979–3993. [Google Scholar] [CrossRef]
  21. Chowdhury, P.; Elkamel, A.; Ray, A.K. Photocatalytic Processes for the Removal of Toxic Metal Ions. In Heavy Metals in Water: Presence, Removal and Safety; Royal Society of Chemistry: London, UK, 2014; pp. 25–43. [Google Scholar]
  22. WHO Regional Office for Europe. Health Risks of Heavy Metals from Long-Range Transboundary Air Pollution; WHO Regional Office for Europe: Copenhagen, Denmark, 2007; Available online: https://www.euro.who.int/en/publications/abstracts/health-risks-of-heavy-metals-from-long-range-transboundary-air-pollution-2007 (accessed on 19 September 2021).
  23. Subramani, A.; Jacangelo, J.G. Emerging desalination technologies for water treatment: A critical review. Water Res. 2015, 75, 164–187. [Google Scholar] [CrossRef]
  24. Song, L.; Zhao, R.; Yun, D.; Lu, P.; He, J.; Wang, X. Influence of Co (II), Ni (II), tartrate, and ethylenediaminetetraacetic acid on Cu (II) adsorption onto a polyvinylidene fluoride-based chelating membrane. Toxicol. Environ. Chem. 2014, 96, 362–378. [Google Scholar] [CrossRef]
  25. Anglada, Á.; Urtiaga, A.; Ortiz, I. Contributions of electrochemical oxidation to waste-water treatment: Fundamentals and review of applications. J. Chem. Technol. Biotechnol. 2009, 84, 1747–1755. [Google Scholar] [CrossRef]
  26. Ramachandra, T.V.; Ahalya, N.; Kanamadi, R.D. Biosorption: Techniques and mechanisms. CES Tech. Rep. 2005, 110, 1–91. [Google Scholar]
  27. Trivunac, K.; Stevanovic, S. Removal of heavy metal ions from water by complexation-assisted ultrafiltration. Chemosphere 2006, 64, 486–491. [Google Scholar] [CrossRef] [PubMed]
  28. Joshi, N.C. Heavy metals, conventional methods for heavy metal removal, biosorption and the development of low cost adsorbent. Eur. J. Pharm. Med. Res. 2017, 4, 388–393. [Google Scholar]
  29. Bakalár, T.; Búgel, M.; Gajdošová, L. Heavy metal removal using reverse osmosis. Acta Montanistica Slovaca 2009, 14, 250. [Google Scholar]
  30. U.S. Congress, Office of Technology Assessment. Copper: Technology and Competiveness; U.S. Government Printing Office: Washington, DC, USA, 1998. [Google Scholar]
  31. Fiyadh, S.S.; AlSaadi, M.A.; Jaafar, W.Z.; AlOmar, M.K.; Fayaed, S.S.; Mohd, N.S.; Hin, L.S.; El-Shafie, A. Review on heavy metal adsorption processes by carbon nanotubes. J. Clean. Prod. 2019, 230, 783–793. [Google Scholar] [CrossRef]
  32. Pulford, I.D.; Watson, C. Phytoremediation of heavy metal-contaminated land by trees—A review. Environ. Int. 2003, 29, 529–540. [Google Scholar] [CrossRef]
  33. Hasanpour, M.; Hatami, M. Photocatalytic performance of aerogels for organic dyes removal from wastewaters: Review study. J. Mol. Liq. 2020, 309, 113094. [Google Scholar] [CrossRef]
  34. Meng, X.; Zhang, Z.; Li, X. Synergetic photoelectrocatalytic reactors for environmental remediation: A review. J. Photochem. Photobiol. C Photochem. Rev. 2015, 24, 83–101. [Google Scholar] [CrossRef]
  35. Kubota, Y.; Watanabe, K.; Tsuda, O.; Taniguchi, T. Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure. Science 2007, 317, 932. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  36. Xie, W.; Zhang, M.; Liu, D.; Lei, W.; Sun, L.; Wang, X. Photocatalytic TiO2/porous BNNSs composites for simultaneous LR2B and Cr(VI) removal in wool dyeing bath. J. Photochem. Photobiol. A Chem. 2017, 333, 165–173. [Google Scholar] [CrossRef]
  37. Meng, X.; Yun, N.; Zhang, Z. Recent advances in computational photocatalysis: A review. Can. J. Chem. Eng. 2019, 97, 1982–1998. [Google Scholar] [CrossRef]
  38. Lazar, M.; Varghese, S.; Nair, S. Photocatalytic Water Treatment by Titanium Dioxide: Recent Updates. Catalysts 2012, 2, 572–601. [Google Scholar] [CrossRef] [Green Version]
  39. Mozia, S.; Morawski, A.W.; Toyoda, M.; Tsumura, T. Effect of process parameters on photodegradation of Acid Yellow 36 in a hybrid photocatalysis–membrane distillation system. Chem. Eng. J. 2009, 150, 152–159. [Google Scholar] [CrossRef]
  40. Chen, C.; Ma, W.; Zhao, J. Semiconductor-mediated photodegradation of pollutants under visible-light irradiation. Chem. Soc. Rev. 2010, 39, 4206–4219. [Google Scholar] [CrossRef]
  41. Qu, Y.; Duan, X. Progress, challenge and perspective of heterogeneous photocatalysts. Chem. Soc. Rev. 2013, 42, 2568–2580. [Google Scholar] [CrossRef]
  42. Ni, Y.; Wang, W.; Huang, W.; Lu, C.; Xu, Z. Graphene strongly wrapped TiO2 for high-reactive photocatalyst: A new sight for significant application of graphene. J. Colloid Interface Sci. 2014, 428, 162–169. [Google Scholar] [CrossRef]
  43. Chen, G.; Sun, M.; Wei, Q.; Zhang, Y.; Zhu, B.; Du, B. Ag3PO4/graphene-oxide composite with remarkably enhanced visible-light-driven photocatalytic activity toward dyes in water. J. Hazard. Mater. 2013, 244, 86–93. [Google Scholar] [CrossRef]
  44. Su, J.; Zhang, Y.; Xu, S.; Wang, S.; Ding, H.; Pan, S.; Wang, G.; Li, G.; Zhao, H. Highly efficient and recyclable triple-shelled Ag@ Fe3O4@ SiO2@ TiO2 photocatalysts for degradation of organic pollutants and reduction of hexavalent chromium ions. Nanoscale 2014, 6, 5181–5192. [Google Scholar] [CrossRef] [PubMed]
  45. Dong, S.; Feng, J.; Fan, M.; Pi, Y.; Hu, L.; Han, X.; Liu, M.; Sun, J.; Sun, J. Recent developments in heterogeneous photocatalytic water treatment using visible light-responsive photocatalysts: A review. RSC Adv. 2015, 5, 14610–14630. [Google Scholar] [CrossRef]
  46. Casbeer, E.; Sharma, V.K.; Li, X.-Z. Synthesis and photocatalytic activity of ferrites under visible light: A review. Sep. Purif. Technol. 2012, 87, 1–14. [Google Scholar] [CrossRef]
  47. Bahnemann, D. Photocatalytic water treatment: Solar energy applications. Sol. Energy 2004, 77, 445–459. [Google Scholar] [CrossRef]
  48. Chong, M.N.; Jin, B.; Chow, C.W.; Saint, C. Recent developments in photocatalytic water treatment technology: A review. Water Res. 2010, 44, 2997–3027. [Google Scholar] [CrossRef]
  49. Li, F.-F.; Yang, D.-F.; Xia, M.-S.; Wang, Y.; Jiang, Y.-S. Visible-light photocatalytic activity of Sn (2+)-doped TiO (2) and its loading effect on mesoporous montmorillonite. Wuji Cailiao Xuebao J. Inorg. Mater. 2011, 26, 917–922. [Google Scholar] [CrossRef]
  50. Liu, D.; Zhang, M.W.; Xie, W.J.; Sun, L.; Chen, Y.; Lei, W.W. Efficient photocatalytic reduction of aqueous Cr(VI) over porous BNNSs/TiO2 nanocomposites under visible light irradiation. Catal. Sci. Technol. 2016, 6, 8309–8313. [Google Scholar] [CrossRef]
  51. Yang, Y.; Wang, G.; Deng, Q.; Wang, H.; Zhang, Y.; Ng, D.H.L.; Zhao, H. Enhanced photocatalytic activity of hierarchical structure TiO2 hollow spheres with reactive (001) facets for the removal of toxic heavy metal Cr(VI). RSC Adv. 2014, 4, 34577–34583. [Google Scholar] [CrossRef] [Green Version]
  52. Zhang, X.; Song, L.; Zeng, X.; Li, M. Effects of electron donors on the TiO2 photocatalytic reduction of heavy metal ions under visible light. Energy Procedia 2012, 17, 422–428. [Google Scholar] [CrossRef] [Green Version]
  53. Cao, D.; Wang, Q.; Liu, Z.; Zhang, H.; Wang, Y.; Jin, R.; Gao, S. Enhanced the photoelectrocatalytic performance of TiO2 nanotube arrays by the synergistic sensitization of Ag-AgBr nanospheres. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2020, 227, 117674. [Google Scholar] [CrossRef]
  54. Deng, Y.; Xiao, Y.; Zhou, Y.; Zeng, T.; Xing, M.; Zhang, J. A structural engineering-inspired CdS based composite for photocatalytic remediation of organic pollutant and hexavalent chromium. Catal. Today 2019, 335, 101–109. [Google Scholar] [CrossRef]
  55. Chen, F.; Yu, C.; Wei, L.; Fan, Q.; Ma, F.; Zeng, J.; Yi, J.; Yang, K.; Ji, H. Fabrication and characterization of ZnTiO3/Zn2Ti3O8/ZnO ternary photocatalyst for synergetic removal of aqueous organic pollutants and Cr(VI) ions. Sci. Total Environ. 2020, 706, 136026. [Google Scholar] [CrossRef] [PubMed]
  56. Liu, X.; Pan, L.; Lv, T.; Lu, T.; Zhu, G.; Sun, Z.; Sun, C. Microwave-assisted synthesis of ZnO–graphene composite for photocatalytic reduction of Cr(VI). Catal. Sci. Technol. 2011, 1, 1189–1193. [Google Scholar] [CrossRef]
  57. Yang, R.; Zhong, S.; Zhang, L.; Liu, B. PW12/CN@Bi2WO6 composite photocatalyst prepared based on organic-inorganic hybrid system for removing pollutants in water. Sep. Purif. Technol. 2020, 235, 116270. [Google Scholar] [CrossRef]
  58. He, H.; Li, J.; Yu, C.; Luo, Z. Surface decoration of microdisk-like g-C3N4/diatomite with Ag/AgCl nanoparticles for application in Cr(VI) reduction. Sustain. Mater. Technol. 2019, 22, e00127. [Google Scholar] [CrossRef]
  59. Josue, T.G.; Almeida, L.N.B.; Lopes, M.F.; Santos, O.A.A.; Lenzi, G.G. Cr(VI) reduction by photocatalyic process: Nb2O5 an alternative catalyst. J. Environ. Manag. 2020, 268, 110711. [Google Scholar] [CrossRef]
  60. Jiang, W.; Liu, Q.; Tao, Y.; Mu, K.; Wang, Z.; Zhu, Y.; Yue, H.; Liang, B. An environment-friendly strategy for one-step turning Cr(VI) contaminant into a Cr-Loaded catalyst for CO2 utilization. Adv. Sustain. Syst. 2018, 2, 1700165. [Google Scholar] [CrossRef]
  61. Zhang, W.; Liu, F.; Sun, Y.; Zhang, J.; Hao, Z. Simultaneous redox conversion and sequestration of chromate (VI) and arsenite (III) by iron (III)-alginate based photocatalysis. Appl. Catal. B Environ. 2019, 259, 118046. [Google Scholar] [CrossRef]
  62. ZabihiSahebi, A.; Koushkbaghi, S.; Pishnamazi, M.; Askari, A.; Khosravi, R.; Irani, M. Synthesis of cellulose acetate/chitosan/SWCNT/Fe3O4/TiO2 composite nanofibers for the removal of Cr(VI), As(V), methylene blue and congo red from aqueous solutions. Int. J. Biol. Macromol. 2019, 140, 1296–1304. [Google Scholar] [CrossRef]
  63. Hu, J.; Weng, S.; Zheng, Z.; Pei, Z.; Huang, M.; Liu, P. Solvents mediated-synthesis of BiOI photocatalysts with tunable morphologies and their visible-light driven photocatalytic performances in removing of arsenic from water. J. Hazard. Mater. 2014, 264, 293–302. [Google Scholar] [CrossRef]
  64. Dutta, P.K.; Pehkonen, S.O.; Sharma, V.K.; Ray, A.K. Photocatalytic oxidation of arsenic (III): Evidence of hydroxyl radicals. Environ. Sci. Technol. 2005, 39, 1827–1834. [Google Scholar] [CrossRef]
  65. Yan, R.; Luo, D.; Fu, C.; Wang, Y.; Zhang, H.; Wu, P.; Jiang, W. Harmless treatment and selective recovery of acidic Cu (II)-Cr(VI) hybrid wastewater via coupled photo-reduction and ion exchange. Sep. Purif. Technol. 2020, 234, 116130. [Google Scholar] [CrossRef]
  66. Kanakaraju, D.; Rusydah bt Mohamad Shahdad, N.; Lim, Y.-C.; Pace, A. Concurrent removal of Cr(III), Cu (II), and Pb (II) ions from water by multifunctional TiO2/Alg/FeNPs beads. Sustain. Chem. Pharm. 2019, 14, 100176. [Google Scholar] [CrossRef]
  67. Kadi, M.W.; Mohamed, R.M.; Ismail, A.A.; Bahnemann, D.W. Performance of mesoporous α-Fe2O3/g-C3N4 heterojunction for photoreduction of Hg (II) under visible light illumination. Ceram. Int. 2020, 46, 23098–23106. [Google Scholar] [CrossRef]
  68. Sun, X.; Lu, J.; Wu, J.; Guan, D.; Liu, Q.; Yan, N. Enhancing photocatalytic activity on gas-phase heavy metal oxidation with self-assembled BiOI/BiOCl microflowers. J. Colloid Interface Sci. 2019, 546, 32–42. [Google Scholar] [CrossRef] [PubMed]
  69. Xiao, Y.; Tan, S.; Wang, D.; Wu, J.; Jia, T.; Liu, Q.; Qi, Y.; Qi, X.; He, P.; Zhou, M. CeO2/BiOIO3 heterojunction with oxygen vacancies and Ce4+/Ce3+ redox centers synergistically enhanced photocatalytic removal heavy metal. Appl. Surf. Sci. 2020, 530, 147116. [Google Scholar] [CrossRef]
  70. Jia, T.; Xu, K.; Wu, J.; Liu, Q.; Lin, Y.; Gu, M.; Tian, F.; Pan, W.; Wu, J.; Xiao, Y. Constructing 2D BiOIO3/MoS2 Z-scheme heterojunction wrapped by C500 as charge carriers transfer channel: Enhanced photocatalytic activity on gas-phase heavy metal oxidation. J. Colloid Interface Sci. 2020, 562, 429–443. [Google Scholar] [CrossRef] [PubMed]
  71. Elleuch, L.; Messaoud, M.; Djebali, K.; Attafi, M.; Cherni, Y.; Kasmi, M.; Elaoud, A.; Trabelsi, I.; Chatti, A. A new insight into highly contaminated landfill leachate treatment using Kefir grains pre-treatment combined with Ag-doped TiO2 photocatalytic process. J. Hazard. Mater. 2020, 382, 121119. [Google Scholar] [CrossRef] [PubMed]
  72. Thomas, B.; Alexander, L.K. Removal of Pb2+ and Cd2+ toxic heavy metal ions driven by Fermi level modification in NiFe2O4–Pd nano hybrids. J. Solid State Chem. 2020, 288, 121417. [Google Scholar] [CrossRef]
  73. Al-Sherbini, A.A.; Ghannam, H.E.A.; El-Ghanam, G.M.A.; El-Ella, A.A.; Youssef, A.M. Utilization of chitosan/Ag bionanocomposites as eco-friendly photocatalytic reactor for Bactericidal effect and heavy metals removal. Heliyon 2019, 5, e01980. [Google Scholar] [CrossRef] [Green Version]
  74. Ebrahimian, J.; Mohsennia, M.; Khayatkashani, M. Photocatalytic-degradation of organic dye and removal of heavy metal ions using synthesized SnO2 nanoparticles by vitex agnus-castus fruit via a green route. Mater. Lett. 2020, 263, 127255. [Google Scholar] [CrossRef]
  75. McCarron, P.; Harvey, I.; Brogan, R.; Peters, T.J. Self reported health of people in an area contaminated by chromium waste: Interview study. BMJ 2000, 320, 11–15. [Google Scholar] [CrossRef] [Green Version]
  76. Tuprakay, S.; Liengcharernsit, W. Lifetime and regeneration of immobilized titania for photocatalytic removal of aqueous hexavalent chromium. J. Hazard. Mater. 2005, 124, 53–58. [Google Scholar] [CrossRef]
  77. Idris, A.; Hassan, N.; Rashid, R.; Ngomsik, A.-F. Kinetic and regeneration studies of photocatalytic magnetic separable beads for chromium (VI) reduction under sunlight. J. Hazard. Mater. 2011, 186, 629–635. [Google Scholar] [CrossRef]
  78. Iorio, Y.D.; Román, E.S.; Litter, M.I.; Grela, M.A. Photoinduced reactivity of strongly coupled TiO2 ligands under visible irradiation: An examination of an alizarin red@TiO2 nanoparticulate system. J. Phys. Chem. C 2008, 112, 16532–16538. [Google Scholar] [CrossRef]
  79. Litter, M.I.; Quici, N. New advances of heterogeneous photocatalysis for treatment of toxic metals and arsenic. In Nanomaterials for Environmental Protection; Wiley: Hoboken, NJ, USA, 2014; pp. 143–167. [Google Scholar]
  80. Meichtry, J.M.; Rivera, V.; Iorio, Y.D.; Rodríguez, H.B.; Román, E.S.; Grela, M.A.; Litter, M.I. Photoreduction of Cr(VI) using hydroxoaluminiumtricarboxymonoamide phthalocyanine adsorbed on TiO2. Photochem. Photobiol. Sci. 2009, 8, 604–612. [Google Scholar] [CrossRef] [PubMed]
  81. Sahel, K.; Elsellami, L.; Mirali, I.; Dappozze, F.; Bouhent, M.; Guillard, C. Hydrogen peroxide and photocatalysis. Appl. Catal. B Environ. 2016, 188, 106–112. [Google Scholar] [CrossRef]
  82. Nosaka, Y.; Nosaka, A.Y. Generation and Detection of Reactive Oxygen Species in Photocatalysis. Chem. Rev. 2017, 117, 11302–11336. [Google Scholar] [CrossRef] [PubMed]
  83. Lousada, C.M.; Johansson, A.J.; Brinck, T.; Jonsson, M. Mechanism of H2O2 Decomposition on Transition Metal Oxide Surfaces. J. Phys. Chem. C 2012, 116, 9533–9543. [Google Scholar] [CrossRef]
  84. Zhang, J.; Nosaka, Y. Photocatalytic oxidation mechanism of methanol and the other reactants in irradiated TiO2 aqueous suspension investigated by OH radical detection. Appl. Catal. B Environ. 2015, 166–167, 32–36. [Google Scholar] [CrossRef]
  85. Smedley, P.L.; Kinniburgh, D.G. A review of the source, behaviour and distribution of arsenic in natural waters. Appl. Geochem. 2002, 17, 517–568. [Google Scholar] [CrossRef] [Green Version]
  86. Rehman, K.; Fatima, F.; Waheed, I.; Akash, M.S.H. Prevalence of exposure of heavy metals and their impact on health consequences. J. Cell. Biochem. 2018, 119, 157–184. [Google Scholar] [CrossRef]
  87. Guan, X.; Du, J.; Meng, X.; Sun, Y.; Sun, B.; Hu, Q. Application of titanium dioxide in arsenic removal from water: A review. J. Hazard. Mater. 2012, 215–216, 1–16. [Google Scholar] [CrossRef]
  88. Mamindy-Pajany, Y.; Hurel, C.; Marmier, N.; Roméo, M. Arsenic (V) adsorption from aqueous solution onto goethite, hematite, magnetite and zero-valent iron: Effects of pH, concentration and reversibility. Desalination 2011, 281, 93–99. [Google Scholar] [CrossRef]
  89. Mohan, D.; Pittman, C.U. Arsenic removal from water/wastewater using adsorbents—A critical review. J. Hazard. Mater. 2007, 142, 1–53. [Google Scholar] [CrossRef] [PubMed]
  90. Meichtry, J.M.; Lin, H.J.; Luciana, D.; Levy, I.K.; Gautier, E.A.; Blesa, M.A.; Litter, M.I. Low-cost TiO2 photocatalytic technology for water potabilization in plastic bottles for isolated regions photocatalyst fixation. J. Sol. Energy Eng. 2007, 129, 119–126. [Google Scholar] [CrossRef]
  91. Levy, I.K.; Brusa, M.A.; Aguirre, M.E.; Custo, G.; San Román, E.; Litter, M.I.; Grela, M.A. Exploiting electron storage in TiO2 nanoparticles for dark reduction of As(V) by accumulated electrons. Phys. Chem. Chem. Phys. 2013, 15, 10335–10338. [Google Scholar] [CrossRef] [PubMed]
  92. Levy, I.K.; Quici, N.; Custo, G.; Litter, M.I.; Brusa, M.; Aguirre, M.E.; Grela, M.A.; San Román, E. Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles. In Proceedings of the 5th International Congress on Arsenic in the Environment, Buenos Aires, Argentina, 11–16 May 2014; pp. 802–804. [Google Scholar]
  93. Ynalvez, R.; Gutierrez, J.; Gonzalez-Cantu, H. Mini-review: Toxicity of mercury as a consequence of enzyme alteration. Biometals 2016, 29, 781–788. [Google Scholar] [CrossRef]
  94. Chen, D.; Ray, K.A. Removal of toxic metal ions from wastewater by semiconductor photocatalysis. Chem. Eng. Sci. 2001, 56, 1561–1570. [Google Scholar] [CrossRef]
Processes 09 01729 g001 550
Figure 1. Schematic diagram of photocatalytic treatment of heavy metals.
Figure 1. Schematic diagram of photocatalytic treatment of heavy metals.
Processes 09 01729 g001
Processes 09 01729 g002 550
Figure 2. Schematic diagram of electrochemical reactor (Adapted from [25]).
Figure 2. Schematic diagram of electrochemical reactor (Adapted from [25]).
Processes 09 01729 g002
Processes 09 01729 g003 550
Figure 3. (a) Schematic diagram of heterogeneous photocatalytic reduction of Cr(VI) under visible light and (b) energy band of TiO2 modified with AITCPc (Adapted from [79]).
Figure 3. (a) Schematic diagram of heterogeneous photocatalytic reduction of Cr(VI) under visible light and (b) energy band of TiO2 modified with AITCPc (Adapted from [79]).
Processes 09 01729 g003
Processes 09 01729 g004 550
Figure 4. Schematic diagram of photocatalytic simultaneous conversion of Cr(VI) and As(III). (LMCT—ligand to metal charge transfer) (Adapted from [61]).
Figure 4. Schematic diagram of photocatalytic simultaneous conversion of Cr(VI) and As(III). (LMCT—ligand to metal charge transfer) (Adapted from [61]).
Processes 09 01729 g004
Processes 09 01729 g005 550
Figure 5. The mechanism of photocatalytic removal of gas-phase Hg(0) under visible light (Adapted from [68]).
Figure 5. The mechanism of photocatalytic removal of gas-phase Hg(0) under visible light (Adapted from [68]).
Processes 09 01729 g005
Table
Table 1. Health effects of exposure to several heavy metal elements (Adapted from [21]).
Table 1. Health effects of exposure to several heavy metal elements (Adapted from [21]).
Heavy MetalsUse/ExposureHealth EffectsMaximum Contamination Level (WHO *) [22]
Chromium (Cr)Electroplating/Lather tanning/paint industryRespiratory cancers50 ppb
Zinc (Zn)Mining/manufacturingMetal fume fever/restlessness/
Cadmium (Cd)Electroplating/pigment/plastic/polymerization industryBone damage/nephrotoxic effects3 ppb
Mercury (Hg)Pesticides/chlorine-alkali/paint/petrochemical industryDyslexia/neurobehavioral disorders/intellectual retardation/attention deficit hyperactivity disorder1 ppb
Nickel (Ni)Electroplating/mining/paint industryChronic bronchitis/cancers of the lungs and nasal sinus/decreased lung function/
Platinum (Pt)Mining/catalytic converterPlatinosis/allergic reactions/respiratory hypersensitive reaction/
Arsenic (As)Mining/wood preservative/biocidesSkin cancers/liver tumours/acute poisoning/gastrointestinal issues10 ppb
(* WHO—World Health Organization; ppb—parts per billion).
Table
Table 2. Traditional heavy metal processing techniques and their drawbacks.
Table 2. Traditional heavy metal processing techniques and their drawbacks.
TechniquesDrawbacksRef.
Direct adsorptionInefficient in the presence of ligand[24]
Chemical precipitationInefficient in the presence of ligand and potential pollution[26]
OzonationDifficulties in separation and potential contamination[23]
UltrafiltrationSludge generation[27]
Ion-exchangeHigh cost and partial removal of some ions[28]
Reverse osmosisHigh cost[29]
ElectrowinningMany equipment restrictions, large investment and continuous power input demand[30]
Carbon adsorptionHigh cost and low adsorption rates of water-soluble components[31]
PhytoremediationTime-consuming and difficult to regenerate plants[32]
Table
Table 3. Overview of applications of photocatalytic heavy metal treatment.
Table 3. Overview of applications of photocatalytic heavy metal treatment.
PhotocatalystHeavy MetalRedox ProductsLight TypeEfficiencyIrradiation TimeRef.
Porous BNNSs/TiO2Cr(VI)Cr(III)Simulated solar light and visible light99% and 99%70 min and 80 min[50]
TiO2 hollow sphereCr(VI)Cr(III)UV light0.0867 min−180 min[51]
TiO2Cr(VI)Cr(III)Visible light100% (formic acid as electron donor)80 min[52]
TiO2 nanotube arrays/Ag-AgBrCr(VI)Cr(III)Solar light58.63%180 min[53]
CdS/TiO2Cr(VI)Cr(III)Visible light2.14 × 10−2 min−1180 min[54]
ZnTiO3/Zn2Ti3O8/ZnOCr(VI)Cr(III)Full spectrum light47%150 min[55]
ZnO–grapheneCr(VI)Cr(III)UV light98%240 min[56]
Ag/ZnO@CFCr(VI)Cr(III)Full spectrum light71.82%210 min[16]
PW12/CN@Bi2WO6Cr(VI)Cr(III)Visible light98.7%90 min[57]
g-C3N4/diatomite composites/Ag/AgClCr(VI)Cr(III)Visible light7.4 × 10−2 min−145 min[58]
Nb2O5Cr(VI)Cr(III)Full spectrum light90%120 min[59]
ZrO2Cr(VI)Cr(III)/CrUV lightAbout 100%90 min[60]
Iron(III) cross-linking alginate hydrogel beadsCr(VI) and As(III)Cr(III) and As(V)Full spectrum light90% and 100%150 min[61]
Cellulose acetate/chitosan/single walled carbon nanotubes/ferrite/titanium dioxideCr(VI) and As(V)Cr(III) and AsUV light0.0925 and 0.0896 min−160 min[62]
BiOIAs(III)As(V)Natural light1 mg/L to 10 μg/L3 h[63]
TiO2As(III)As(V)UV lightAbout 100%30 min[64]
TiO2-ZrO2Cu(II) and Cr(VI)Cu and Cr(III)/CrUV light96.29 and 99.17%630 min[65]
TiO2/Alg/FeNPsCr(III), Cu(II) and Pb(II)Cr, Cu and PbUV light98.6%, 98.4% and 99.5%120 min[66]
α-Fe2O3/g-C3N4Hg(II)HgVisible light90%60 min[67]
BiOI/BiOClHgHgO/Hg(II)Visible light72.4%50 min[68]
CeO2/BiOIO3HgHgOVisible light86.53%30 min[69]
BiOIO3/MoS2/C500HgHgOUV light78.32%70 min[70]
Ag/TiO2Cd(II), Ni(II), Zn(II), Mn(II) and Cu(II)Cd, Ni, Zn, Mn and CuUV light100, 96, 65.13, 58.22 and 56.20%120 min[71]
NiFe2O4-PdPb(II) and Cd(II)Pb and CdFull spectrum light1.4 × 10−1 and 0.86 × 10−1 min−160 min[72]
Chitosan/AgCu(II), Pb(II) and Cd(II)Cu, Pb and CdNatural sunlight1.10 × 10−4, 1.4 × 10−4 and 1.5 × 10−4 mol dm−3s−1240 min[73]
SnO2 nanoparticlesCo(II)CoUV light94%60 min[74]
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Share and Cite

MDPI and ACS Style

Gao, X.; Meng, X. Photocatalysis for Heavy Metal Treatment: A Review. Processes 2021, 9, 1729. https://doi.org/10.3390/pr9101729

AMA Style

Gao X, Meng X. Photocatalysis for Heavy Metal Treatment: A Review. Processes. 2021; 9(10):1729. https://doi.org/10.3390/pr9101729

Chicago/Turabian Style

Gao, Xinyu, and Xiangchao Meng. 2021. "Photocatalysis for Heavy Metal Treatment: A Review" Processes 9, no. 10: 1729. https://doi.org/10.3390/pr9101729

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop