Electrochemical Study of Stainless Steel Anchor Bolt Corrosion Initiation in Corrosive Underground Water
Abstract
:1. Introduction
2. Materials and Experiments
2.1. Materials
2.2. Experiments
3. Results and Discussion
3.1. Open-Circuit Potential
3.2. Electrochemical Impedance Spectroscopy
3.3. Semiconducting Properties of the Passive Film
3.4. Potentiodynamic Polarization
3.5. The Corrosion Initiation of Stainless Steel in Underground Water
4. Conclusions
- The open-circuit potential and charge transfer resistance increase, while the double-layer capacitance, donor density and passive current density decrease as the SO42− concentration, HCO3− concentration or pH value of the underground water increase.
- The corrosion of 201 low-nickel stainless steel is inhibited by SO42−, HCO3− and OH− in underground water.
- The inhibitive effect of SO42− and HCO3− is significant at low concentration (for SO42−, it is less than 22 g/L, and for HCO3−, it is less than 2.8 g/L), while the excessive addition of SO42− and HCO3− only showed a little improvement on the corrosion resistance of 201 low-nickel stainless steel.
- The passivity and corrosion resistance of low-nickel stainless steel is substantially improved in alkaline underground waters.
- Anion concentrations was magnified in simulated underground waters in the present study. Corrosion behavior of 201 low-nickel stainless steel in underground waters with lower concentration of anions, and the relationship between corrosion rates in the simulated solution and that in actual groundwater environment should be investigated in the future study.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Solution | A1 | A2 | A3 | A4 | A5 | B1 | B2 | B3 | B4 | B5 | C1 | C2 | C3 |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Cl− (g/L) | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 | 12.00 |
SO42− (g/L) | 2.75 | 5.50 | 11.00 | 22.00 | 44.00 | 11.00 | 11.00 | 11.00 | 11.00 | 11.00 | 11.00 | 11.00 | 11.00 |
HCO3− (g/L) | 1.40 | 1.40 | 1.40 | 1.40 | 1.40 | 0.35 | 0.70 | 1.40 | 2.80 | 5.60 | 1.40 | 1.40 | 1.40 |
pH | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 5.0 | 7.0 | 9.0 |
Solution | A1 | A2 | A3 | A4 | A5 | B1 | B2 | B3 | B4 | B5 | C1 | C2 | C3 |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Rs (Ω cm2) | 22.4 | 16.4 | 18.2 | 18.0 | 9.52 | 15.9 | 17.3 | 18.2 | 16.3 | 14.7 | 16.9 | 18.2 | 11.2 |
Rct (×105 Ω cm2) | 1.3 | 1.7 | 2.3 | 3.3 | 4.2 | 2.1 | 2.1 | 2.3 | 3.1 | 3.3 | 0.65 | 2.3 | 5.4 |
Q (×10−5 Ω−1 Sn cm2) | 6.2 | 6.0 | 5.9 | 5.0 | 4.9 | 5.8 | 5.0 | 5.9 | 4.9 | 4.0 | 9.6 | 5.9 | 6.3 |
Solution | A1 | A2 | A3 | A4 | A5 | B1 | B2 | B3 | B4 | B5 | C1 | C2 | C3 |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
ND (×1020 cm−3) | 3.22 | 2.44 | 1.85 | 1.50 | 1.33 | 4.48 | 2.84 | 1.85 | 1.95 | 1.23 | 4.94 | 1.85 | 1.10 |
Solution | A1 | A2 | A3 | A4 | A5 | B1 | B2 | B3 | B4 | B5 | C1 | C2 | C3 |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
ipass (×10−6 A cm−2) | 58.8 | 2.92 | 2.38 | 1.97 | 1.69 | 4.58 | 3.69 | 2.38 | 1.12 | 0.950 | 46.4 | 2.38 | 4.80 |
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Ma, F.; Zeng, Q.; Lu, X.; Wu, T.; Lu, X.; Zhang, T.; Feng, X. Electrochemical Study of Stainless Steel Anchor Bolt Corrosion Initiation in Corrosive Underground Water. Processes 2021, 9, 1553. https://doi.org/10.3390/pr9091553
Ma F, Zeng Q, Lu X, Wu T, Lu X, Zhang T, Feng X. Electrochemical Study of Stainless Steel Anchor Bolt Corrosion Initiation in Corrosive Underground Water. Processes. 2021; 9(9):1553. https://doi.org/10.3390/pr9091553
Chicago/Turabian StyleMa, Fangping, Qing Zeng, Xiangyu Lu, Tong Wu, Xiao Lu, Tianyi Zhang, and Xingguo Feng. 2021. "Electrochemical Study of Stainless Steel Anchor Bolt Corrosion Initiation in Corrosive Underground Water" Processes 9, no. 9: 1553. https://doi.org/10.3390/pr9091553