Comparative Extraction of Aluminum Group Metals Using Acetic Acid Derivatives with Three Different-Sized Frameworks for Coordination
Abstract
:1. Introduction
2. Experimental
2.1. Reagents
2.1.1. 1,1,1-Tris(carboxymethoxymethyl)-9-decene (2)
2.1.2. 10-Undecenoxyacetic acid (5)
2.2. Distribution Study
3. Results and Discussion
3.1. Extraction Rate
3.2. Structural Effect
3.3. Slope Analysis and Extraction Reactions
3.4. Spectroscopic Studies on the Ga3+- and In3+-Loaded Reagents
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Calix[4]arene (Cone) | “Trident” Molecule | Trihydroxytriphenylmethane | |
---|---|---|---|
Modified group | Active phenols | Non-reactive alchohols | Active phenols |
Coordination site (Site size) | small at lower rim (2.0 Å at distal position) | Small and narrow (1.7 Å between O to O) | Small and narrow (less than 2.0 Å) |
Inversion (Fixing) | Probable (controllable) | None (already 3-D controlled) | None |
Rigidity | Rigid | Relatively rigid | Rigid |
Polyfunctionality | e.g., Tetradentate | e.g., Tridentate | e.g., Tridentate |
Symmetry | e.g., C2, C4 symmetry | e.g., C3 symmetry | e.g., C3 symmetry |
Spectroscopic transparency | UV absorptive | UV Transparent | UV absorptive |
Lipophilicity | Poor | Poor | High |
Extractant | Half pH Values, pH1/2 | ∆pH1/2 | ∆pH1/2 | |||||
---|---|---|---|---|---|---|---|---|
Al | Ga | In | Al | Ga | In | Al-Ga | Ga-In | |
1 | 3.58 | 2.92 | 2.60 | 0.29 | 0.30 | 0.52 | 0.66 | 0.32 |
4 | 3.87 | 3.22 | 3.12 | 0.65 | 0.10 | |||
2 | 2.41 | 1.89 | 1.85 | >1.49 | 1.34 | 1.23 | 0.52 | 0.04 |
5 | >3.90 | 3.23 | 3.08 | >0.67 | 0.15 | |||
3 | 3.63 | 3.14 | 2.89 | >0.22 | 0.64 | 0.86 | 0.49 | 0.25 |
6 | >3.85 | 3.78 | 3.75 | >0.07 | 0.03 |
Extractant | Extraction Equilibrium Constants, Kex1 and Kex2 | Separation Factors, ß | |||
---|---|---|---|---|---|
Al | Ga | In | Ga/Al | In/Ga | |
1 | 3.64 × 10−9 | 3.48 × 10−7 | 3.17 × 10−6 | 95.6 | 9.11 |
2 | 1.18 × 10−5 | 4.28 × 10−4 | 5.64 × 10−4 | 36.3 | 1.32 |
3 | 2.58 × 10−9 | 7.60 × 10−8 | 4.28 × 10−7 | 29.5 | 5.63 |
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Ohto, K.; Fuchiwaki, N.; Furugou, H.; Morisada, S.; Kawakita, H.; Wenzel, M.; Weigand, J.J. Comparative Extraction of Aluminum Group Metals Using Acetic Acid Derivatives with Three Different-Sized Frameworks for Coordination. Separations 2021, 8, 211. https://doi.org/10.3390/separations8110211
Ohto K, Fuchiwaki N, Furugou H, Morisada S, Kawakita H, Wenzel M, Weigand JJ. Comparative Extraction of Aluminum Group Metals Using Acetic Acid Derivatives with Three Different-Sized Frameworks for Coordination. Separations. 2021; 8(11):211. https://doi.org/10.3390/separations8110211
Chicago/Turabian StyleOhto, Keisuke, Nako Fuchiwaki, Hiroaki Furugou, Shintaro Morisada, Hidetaka Kawakita, Marco Wenzel, and Jan J. Weigand. 2021. "Comparative Extraction of Aluminum Group Metals Using Acetic Acid Derivatives with Three Different-Sized Frameworks for Coordination" Separations 8, no. 11: 211. https://doi.org/10.3390/separations8110211