3.1. Simulation Results
Figure 2a presents the temperature variation curves at node 337,259, located in the middle of the specimen, for scanning speeds of 20 mm/s and laser powers of 600 W, 800 W, 1000 W, 1200 W, and 1400 W. From the temperature changes depicted in the figure, it is evident that, at a constant laser scanning speed, the maximum temperature on the shield machine’s main bearing raceway surface increases with rising laser power. The duration within the high-temperature range also slightly increases, along with the heating and cooling rates. When the laser scanning speed is 20 mm/s and the laser power is 1400 W, the maximum temperature on the shield machine’s main bearing raceway surface reaches 1626.9 °C, which exceeds the melting temperature, 1400 °C, of 42CrMo steel [
15]. This indicates that, under a constant laser scanning speed, the surface temperature of the specimen increases with rising laser power until it surpasses the melting point. Additionally, the area of the specimen’s surface where the temperature exceeds the Ac
1 (lower transformation temperature) and Ac
3 (upper transformation temperature) gradually expands, leading to an increase in both the width of the phase transformation hardening zone and the depth of the hardened layer. However, it is crucial to note that, near the critical point of laser power, slight surface melting of the material may occur, which should be avoided on the surface of the bearing raceway.
The temperature change rate at node 337,259 under different laser powers is depicted in
Figure 2b. It can be observed that, at a constant laser scanning speed, higher laser power results in a faster temperature change rate. A higher temperature change rate promotes rapid cooling of the material, which accelerates the formation of austenite and its subsequent transformation into martensite. This leads to the development of finer grains and a greater quantity of martensite, thereby enhancing the material’s hardness and strength. Conversely, if the temperature change rate is too slow, it may result in larger grain growth and an uneven microstructure, reducing the effectiveness of the hardening process. Additionally, a faster temperature change rate can minimize material deformation during phase transformation hardening, leading to improved dimensional control and shape retention. However, it is important to note that rapid cooling may also induce higher residual stresses. Therefore, controlling the temperature change rate is crucial for optimizing the effectiveness of laser phase transformation hardening.
Figure 3 illustrates the maximum temperature on the surface, along with the hardened layer depth and hardness, under various laser powers. The numerical simulation employed a two-dimensional Gaussian plane heat source, which is unsuitable for scenarios involving surface melting. As a result, the simulation data for the 1400 W power level exhibit significant discrepancies when compared to actual conditions. Consequently, the simulation results for this power group are marked in red and deemed unreliable. At a laser power of 800 W, the maximum temperature on the shield machine’s main bearing raceway surface reaches 997.2 °C, which corresponds to the Ac
3 temperature of 42CrMo steel. In this condition, within a 1.9 mm diameter surrounding the center of the laser spot, the temperature surpasses the Ac
3 point, indicating extensive austenitization in this region. However, the measured width of the hardened layer is only 3.27 mm, with a depth of 0.48 mm, which is insufficient to meet the requirements for effective laser phase transformation hardening. When the laser power is reduced to 600 W, the maximum temperature on the surface of the specimen drops to 736 °C, which is close to the Ac
1 temperature of the material. As a result, no martensitic transformation occurs on the surface, and a hardened layer formed by phase transformation is not achieved.
Figure 4a,b present the temperature variations in different specimens at scanning speeds of 10, 20, 30, 40, and 50 mm/s under a constant laser power of 1200 W. As the scanning speed increases, the peak surface temperature of the specimen decreases, along with a reduction in the duration of the high-temperature zone, while both the heating and cooling rates rise. This is primarily because, at constant power, increasing the scanning speed reduces the duration of laser exposure on any given surface area of the specimen, thereby decreasing the total laser energy absorbed by the surface and lowering the peak temperature. However, as the scanning speed increases, the laser energy is delivered to the surface more rapidly, leading to higher rates of temperature change. Additionally, as the temperature decreases, the thermal conductivity of the material increases within the simulated temperature range, further contributing to the increased heating and cooling rates at higher scanning speeds. Under constant power, a faster scanning speed reduces the heat input into the substrate, thereby limiting the area in which the material surface can reach austenitizing temperatures, resulting in narrower and shallower hardened layers.
For the 1200 W group, where the peak surface temperature remained below the melting point but produced a relatively deep hardened layer, the surface phase volume fraction change curves for each phase were collected and plotted, as shown in
Figure 5. Sampling was conducted on cell 449,068, near node 337,259. From 0 to 0.77 s, the heat source had not yet reached this point, and the microstructure of the base metal remained unchanged, containing only the initial phase. At 0.84 s, the temperature exceeded the lower transformation temperature, Ac
1, leading to a rapid decline in the volume fraction of the initial phase as the temperature rose. Concurrently, the austenite volume fraction increased sharply until 0.91 s, at which point the initial phase had completely transformed into austenite. At 0.98 s, the temperature peaked at 1431.3 °C, with the austenite volume fraction reaching its maximum of 99.9%. Thereafter, as the temperature decreased to around 350 °C at 1.64 s, the austenite volume fraction began to rapidly decrease while the martensite volume fraction increased continuously. By the end of the simulation, at 150 s, the austenite volume fraction had diminished to 4.9%, while the martensite volume fraction had risen to 94.9%. At this stage, the temperature had dropped to 48.2 °C, and the microstructure of the cell predominantly consisted of martensite, with small amounts of retained austenite and trace quantities of residual ferrite and bainite. Laser phase hardening increases the heating rate, the austenite phase transformation is completed in a very short time in the high temperature region with a large degree of superheat, and the cooling rate is much faster than the critical cooling rate of the martensitic phase transformation. The Austenite nucleation rate is very high, with austenite grain refinement. At the same time, the rapid cooling after instantaneous heating means that it is too late for the ultrafine austenite grains to grow, as well as being too late for the carbon atoms to diffuse. With the transformation of austenite to martensite (and if the cooling rate is sufficient to exceed the critical cooling rate of the transformation to martensite), the martensite is very fine. Due to the extremely fast cooling rate, the carbon atoms do not have time to diffuse, resulting in a very high carbon content in the martensite, while the residual austenite also obtains a very high dislocation density.
At the same laser energy density, variations in process parameters result in different widths and depths of the hardened layer. For an energy density of 8.33 J/mm
2, the study simulated the effects of different process parameters on surface temperature and the formation of the hardened layer. Four sets of process parameters, all under the same laser energy density, are presented in
Table 3. In these scenarios, increasing the laser power is coupled with an increase in laser scanning speed.
The graphs in
Figure 6a,b present simulation results for four different process parameters under the same laser energy density. From the temperature variations at node 337,259 across these four sets of parameters, it can be observed that, although the laser energy density on the surface of the test piece remains constant, the peak temperature at node 337,259 increases with higher laser power and scanning speed. This suggests that maintaining the same laser energy density does not guarantee a uniform temperature distribution on the workpiece surface; instead, this is influenced by factors such as laser power and scanning speed. Therefore, when determining the process parameters for laser phase transformation hardening, it is crucial to consider not only the laser energy density but also laser power and scanning speed, to achieve the desired temperature distribution and hardening effect.
Faster scanning speeds result in the rapid transfer of laser energy to the material surface, leading to variations in temperature gradients. When the scanning speed reaches 40 mm/s, noticeable fluctuations in the temperature gradient occur, as evidenced by the wave-like ripples on the hardened surface layer shown in
Figure 7a. These ripples appear when the laser scanning speed is too high. Conversely, when the scanning speed is too slow, the laser beam dwells on the specimen surface for an extended period, causing the surface temperature to rise excessively. This can lead to micro-melting, severe burning, or unwanted structural changes. Therefore, to enhance processing efficiency while maintaining a consistent beam size, it is essential to increase the laser power in conjunction with higher scanning speeds. This ensures sufficient heating to raise the specimen surface temperature above the Ac
3 point, thereby balancing the heating duration and temperature gradients to achieve the desired hardening effect.
The width and depth of the hardened layer under four different process parameters are presented in
Figure 7b. It can be observed that both the width and depth of the hardened layer correlate positively with the highest surface temperature of the specimen. As the surface temperature and temperature change rate increase, the width and depth of the hardened layer also show a significant increase. However, when the laser power reaches a certain threshold, such as in the fourth group with 1600 W and a scanning speed of 32 mm/s, the highest surface temperature exceeds the material’s melting point. In such cases, the measurements for the width and depth of the hardened layer become unreliable. Consequently, the data for this group are highlighted in red and are not considered valid.
In general, at lower power levels and scanning speeds, the laser remains for longer over the same area, allowing the self-cooling effect of the substrate to control the cooling process during laser phase transformation hardening. This prolonged exposure results in a slower surface temperature change rate, which can lead to the formation of martensite in the microstructure due to carbon diffusion, thereby reducing the surface hardness. Conversely, increasing laser power and scanning speed boosts energy input and the cooling rate per unit time, thereby enhancing the phase transformation hardening effect and improving material hardness. However, rapid heating and cooling processes may introduce significant thermal stresses into the material, potentially compromising its stability and performance. Therefore, careful control of these parameters is crucial to achieve the optimal hardening effect.
3.4. Analysis of Metallographic Structure
The metallographic structure of the hardened layer near the surface center of sample 3, captured using an optical microscope, is shown in
Figure 10a. The predominant structures in this region are lath-shaped and needle-shaped martensite. The bright white structures observed between the martensite, lacking a fixed form, are identified as residual austenite. The metallographic morphology at various depths of the sample, obtained under the same process parameters and captured using a scanning electron microscope (SEM), is presented in
Figure 10b–d. When the laser beam directly irradiates the material’s surface, the surface temperature increases rapidly due to the absorption of laser energy, causing localized heating. This heat is then conducted towards the interior of the material due to its thermal conductivity. However, since the laser’s penetration depth is limited, the temperature inside the material remains relatively low. At the same time, the surface cooling rate is relatively slow, due to a slower heat exchange with the surrounding environment, while the interior cools faster because of more efficient thermal conduction. These temperature gradients and uneven cooling rates influence the phase transformations and crystal structure of the material, leading to the formation of complex metallographic structures throughout the hardened layer.
As shown in
Figure 10b, the surface temperature of the material is higher, and the cooling rate is slower compared to regions closer to the base material. This prolonged austenitization leads to the formation of coarse martensite structures after cooling, along with a small amount of residual austenite.
Figure 10c illustrates the central region of the hardened layer, which, being closer to the base material, experiences faster heating and cooling rates. In this region, austenite transforms into refined martensite structures before significant growth occurs, resulting in finer martensite compared to the surface.
Figure 10d represents the transition zone, which is farther from the surface and undergoes more rapid heat absorption and cooling. The thermal equilibrium temperature in this zone is near the lower critical point, resulting in a mixed structure of base material, martensite, and residual austenite.
3.5. Microhardness Analysis
Sections of samples 3 and 9 were selected for hardness testing, starting from the surface toward the substrate at the center of the single-pass laser phase transformation-hardened samples. The Vickers hardness measured along the depth direction is shown in
Figure 11a. In sample 3, the hardness at the center region closest to the surface reaches 793.2 HV
0.2, while the highest hardness within this section is 883.4 HV
0.2. The microhardness along the depth from the surface toward the substrate shows a slight increase followed by a decrease, with the hardness at 1 mm depth from the surface measuring 243.4 HV
0.2, which is indicative of the substrate. In contrast, sample 9 exhibits slightly higher surface and subsurface hardness compared to sample 3, with surface hardness reaching 811.8 HV
0.2 and a hardness of 880.7 HV
0.2 at a depth of 0.1 mm. The microhardness profile in sample 9 also shows an initial increase followed by a gradual decrease. However, within the hardened layer, the decline in hardness is more gradual, with a pronounced drop occurring at the boundary between the hardened layer and the substrate. This sudden decrease in hardness can be attributed to the high hardness of martensite in the hardened layer, while the substrate, having undergone less heat exposure, experiences minimal or no martensite formation during the laser processing, leading to an abrupt transition in hardness. As highlighted in the previous microstructural analysis, the surface exhibits slightly coarse martensite, while the subsurface and central regions of the hardened layer predominantly consist of fine martensite. The presence of fine martensite introduces more interfaces and dislocations in the material, which impede dislocation movement, thereby increasing the material’s strength and hardness. Consequently, the hardness trend from the surface into the depth shows a slight rise before gradually decreasing. In cross-sectional comparisons, sample 9 shows marginally higher hardness in the surface and subsurface layers, which can be attributed to the increased laser power and scanning speed. These adjustments enhance energy input and cooling rates per unit time, thereby raising the surface hardness. However, this also impacts the uniformity of the phase transformation hardening process, leading to fluctuations in internal hardness. In contrast, sample 3 demonstrates more stable hardness variations, with a better average hardness and greater hardened layer depth.
The average of the highest three surface hardness points was used as the benchmark for maximum hardness. A value of 75% of this benchmark is considered the threshold for defining the effective hardened layer. The average hardness within this effective hardened layer is recorded as the sample’s surface average hardness.
Figure 11b presents a line graph illustrating the surface hardness measurements and their distribution, measured from the centerline of the hardened zone toward both sides for samples 3 and 9. For sample 3, the highest surface hardness reaches 782 HV
0.2, with an average hardness of 744.9 HV
0.2, and the effective hardened width is approximately 5.4 mm. Sample 9 exhibits a slightly higher surface hardness of 792 HV
0.2, with an average hardness of 745.2 HV
0.2, and an effective hardened width of around 5.1 mm. Although sample 9 shows a marginally higher surface average hardness, the difference is not significant. Sample 3, however, has a wider effective hardened layer and a more uniform surface hardness distribution. Based on the comparison of these two laser surface phase transformation hardening experiments, it can be concluded that sample 3 demonstrates better overall performance.