Tetrahydroxidohexaoxidopentaborate(1-) Salts of C6-Linked Substituted Diimidazolium and Dipyrrolidinium Cations: Synthesis, Characterization and XRD Studies
Abstract
:1. Introduction
2. Results and Discussion
2.1. General and Synthetic Procedures
2.2. Spectroscopic and Thermal Analyses
2.3. Crystallographic Studies
3. Experimental
3.1. General
3.2. X-ray Crystallography
3.3. Synthesis of Dication C6-Linked Bispentaborate Salts
3.3.1. Preparation of 1,1′-(1,6-Hexanediyl)bis(3-methyl-1H-imidazol-3-ium)bispentaborate [CH3(C3H3N2)(CH2)6(C3H3N2)CH3][B5O6(OH)4]2 (1)
3.3.2. Preparation of 1,1′-(1,6-Hexanediyl)bis(3-ethyl-1H-imidazol-3-ium)bispentaborate [C2H5(C3H3N2)(CH2)6(C3H3N2)C2H5][B5O6(OH)4]2·3H2O (2)
3.3.3. Preparation of 1,1′-[1,4-Phenylenebis(methylene)]bis(2-methyl-1H-imidazol-3-ium)bispentaborate [CH3(C3H3N2)CH2(C6H4)CH2(C3H3N2)CH3][B5O6(OH)4]2 (3)
3.3.4. Preparation of 1,1′-(1,6-Hexanediyl)bis(1-methylpyrrolidin-1-ium)bispentaborate [CH3(C4H8N)(CH2)6(C4H8N)CH3][B5O6(OH)4]2 (4)
3.3.5. Preparation of 1,1′-(1,6-Hexanediyl)bis(1-ethylpyrrolidin-1-ium)bispentaborate [C2H5(C4H8N)(CH2)6(C4H8N)C2H5][B5O6(OH)4]2 (5)
3.3.6. Preparation of 1,1′-(1,6-Hexanediyl)bis(1-butylpyrrolidin-1-ium) bispentaborate [C4H9(C4H8N)(CH2)6(C4H8N)C4H9][B5O6(OH)4]2·4B(OH)3 (6)
3.3.7. Preparation of 1,1′-(1,6-Hexanediyl)bis(1-allylpyrrolidin-1-ium)bispentaborate [C3H5(C4H8N)(CH2)6(C4H8N)C3H5][B5O6(OH)4]2 (7)
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Al-Dulayymi, A.R.; Beckett, M.A.; Braganca, R.; Coles, S.J.; Horton, P.N.; Rixon, T.A. Tetrahydroxidohexaoxidopentaborate(1-) Salts of C6-Linked Substituted Diimidazolium and Dipyrrolidinium Cations: Synthesis, Characterization and XRD Studies. Inorganics 2024, 12, 220. https://doi.org/10.3390/inorganics12080220
Al-Dulayymi AR, Beckett MA, Braganca R, Coles SJ, Horton PN, Rixon TA. Tetrahydroxidohexaoxidopentaborate(1-) Salts of C6-Linked Substituted Diimidazolium and Dipyrrolidinium Cations: Synthesis, Characterization and XRD Studies. Inorganics. 2024; 12(8):220. https://doi.org/10.3390/inorganics12080220
Chicago/Turabian StyleAl-Dulayymi, Ahmad R., Michael A. Beckett, Radek Braganca, Simon J. Coles, Peter N. Horton, and Thomas A. Rixon. 2024. "Tetrahydroxidohexaoxidopentaborate(1-) Salts of C6-Linked Substituted Diimidazolium and Dipyrrolidinium Cations: Synthesis, Characterization and XRD Studies" Inorganics 12, no. 8: 220. https://doi.org/10.3390/inorganics12080220