Two Perovskite Modifications of BiFe0.6Mn0.4O3 Prepared by High-Pressure and Post-Synthesis Annealing at Ambient Pressure
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
4. Conclusions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Atom | WP | x/a | y/b | z/c | Biso (Å2) |
---|---|---|---|---|---|
Bi1 | 8d | 0.2169(5) | 0.00935(9) | 0.62476(16) | 1.18(5) |
Bi2 | 4c | 0.2135(7) | 0.25 | 0.6251(2) | 1.37(7) |
Bi3 | 4c | 0.7729(7) | 0.25 | 0.3635(2) | 1.55(7) |
FeMn1 | 8d | 0.2397(12) | 0.1227(6) | 0.8779(7) | 1.06(11) |
FeMn2 | 8d | 0.2615(11) | 0.6249(5) | 0.8770(6) | 0.54(10) |
O1 | 8d | 0.809(4) | −0.0026(12) | 0.6556(18) | 0.24(16) |
O2 | 4c | 0.641(6) | 0.25 | 0.653(3) | =B(O1) |
O3 | 4c | 0.177(7) | 0.25 | 0.425(3) | =B(O1) |
O4 | 8d | 0.099(4) | 0.1267(17) | 0.7217(19) | =B(O1) |
O5 | 8d | −0.003(4) | 0.3942(15) | −0.0260(21) | =B(O1) |
O6 | 8d | 0.041(4) | 0.6458(14) | 0.7424(23) | =B(O1) |
O7 | 8d | 0.019(5) | 0.3989(13) | 0.516(3) | =B(O1) |
Atom | WP | x/a | y/b | z/c | Biso (Å2) |
---|---|---|---|---|---|
Bi1 | 4g | 0.2431(3) | 0.3807(3) | 0 | 2.15(6) |
Bi2 | 4h | 0.2061(3) | 0.3676(2) | 0.5 | 0.32(3) |
FeMn | 8i | 0.2552(6) | 0.1239(14) | 0.2487(13) | 0.80(5) |
O1 | 4g | 0.241(4) | 0.162(3) | 0 | 1.8(9) |
O2 | 4h | 0.338(5) | 0.093(3) | 0.5 | 1.2(7) |
O3 | 8i | 0.078(4) | 0.2649(16) | 0.275(3) | 1.7(5) |
O4 | 4f | 0 | 0.5 | 0.188(3) | 1.3(7) |
O5 | 4e | 0 | 0 | 0.202(4) | 2.4(8) |
Atom | WP | x/a | y/b | z/c | Biso (Å2) |
---|---|---|---|---|---|
Bi1 | 4g | 0.2383(4) | 0.3786(5) | 0 | 3.31(13) |
Bi2 | 4h | 0.2141(5) | 0.3700(4) | 0.5 | 1.91(9) |
FeMn | 8i | 0.2524(9) | 0.1246(25) | 0.2499(17) | 1.56(6) |
O1 | 4g | 0.257(5) | 0.170(5) | 0 | 2.3 (3) |
O2 | 4h | 0.304(6) | 0.091(5) | 0.5 | =B(O1) |
O3 | 8i | 0.075(4) | 0.2678(19) | 0.271(4) | =B(O1) |
O4 | 4f | 0 | 0.5 | 0.185(4) | =B(O1) |
O5 | 4e | 0 | 0 | 0.206(4) | =B(O1) |
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Belik, A.A. Two Perovskite Modifications of BiFe0.6Mn0.4O3 Prepared by High-Pressure and Post-Synthesis Annealing at Ambient Pressure. Inorganics 2024, 12, 226. https://doi.org/10.3390/inorganics12080226
Belik AA. Two Perovskite Modifications of BiFe0.6Mn0.4O3 Prepared by High-Pressure and Post-Synthesis Annealing at Ambient Pressure. Inorganics. 2024; 12(8):226. https://doi.org/10.3390/inorganics12080226
Chicago/Turabian StyleBelik, Alexei A. 2024. "Two Perovskite Modifications of BiFe0.6Mn0.4O3 Prepared by High-Pressure and Post-Synthesis Annealing at Ambient Pressure" Inorganics 12, no. 8: 226. https://doi.org/10.3390/inorganics12080226