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Article

High-Temperature Wide Thermal Hysteresis of an Iron(II) Dinuclear Double Helicate

by
Shiori Hora
1 and
Hiroaki Hagiwara
2,*
1
Graduate School of Education, Gifu University, Yanagido 1-1, Gifu 501-1193, Japan
2
Department of Chemistry, Faculty of Education, Gifu University, Yanagido 1-1, Gifu 501-1193, Japan
*
Author to whom correspondence should be addressed.
Inorganics 2017, 5(3), 49; https://doi.org/10.3390/inorganics5030049
Submission received: 28 June 2017 / Revised: 25 July 2017 / Accepted: 25 July 2017 / Published: 28 July 2017
(This article belongs to the Special Issue Spin-Crossover Complexes)
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Abstract

:
Two new dinuclear iron(II) complexes (1·PF6 and 1·AsF6) of the general formula [FeII2(L2C3)2](X)4·nH2O·mMeCN (X = PF6, n = m = 1.5 for 1·PF6 and X = AsF6, n = 3, m = 1 for 1·AsF6) have been prepared and structurally characterized, where L2C3 is a bis-1,2,3-triazolimine type Schiff-base ligand, 1,1′-[propane-1,3-diylbis(1H-1,2,3-triazole-1,4-diyl)]bis{N-[2-(pyridin-2-yl)ethyl]methanimine}. Single crystal X-ray structure analyses revealed that 1·PF6 and 1·AsF6 are isostructural. The complex-cation [FeII2(L2C3)2]4+ of both has the same dinuclear double helicate architecture, in which each iron(II) center has an N6 octahedral coordination environment. Neighboring helicates are connected by intermolecular π–π interactions to give a chiral one-dimensional (1D) structure, and cationic 1D chains with the opposite chirality exist in the crystal lattice to give a heterochiral crystal. Magnetic and differential scanning calorimetry (DSC) studies were performed only for 1·AsF6, since the thermal stability in a high-temperature spin crossover (SCO) region of 1·PF6 is poorer than that of 1·AsF6. 1·AsF6 shows an unsymmetrical hysteretic SCO between the low-spin–low-spin (LS–LS) and high-spin–high-spin (HS–HS) states at above room temperature. The critical temperatures of warming (Tc↑) and cooling (Tc↓) modes in the abrupt spin transition area are 485 and 401 K, respectively, indicating the occurrence of 84 K-wide thermal hysteresis in the first thermal cycle.

Graphical Abstract

1. Introduction

The interconversion between a high-spin (HS) and a low-spin (LS) state, the so-called “spin crossover” (SCO), is one of the most attractive phenomena in the field of molecular bistability [1,2,3]. This phenomenon is observed in 3d4–3d7 transition metal complexes with various coordination geometries (e.g., octahedral, square-pyramidal, trigonal-bipyramidal, tetrahedral, etc.) [1,4,5,6,7], and is triggered by an external stimulus such as temperature, pressure, light irradiation, or a magnetic field [1,2,3]. While SCO originates from an individual metal center, a spin transition profile, for example, abruptness and multi-steps with or without hysteresis, is provided from the cooperative effect between SCO metal sites through intra- or intermolecular pathways [1,2,3]. There is a need for SCO materials which are capable of abrupt and complete HS–LS interconversion at around room temperature (RT) with wide thermal hysteresis width (ΔT) for potential applications in molecular memories, switches, and display devices. As such, various cooperative SCO compounds have been produced with supramolecular assembly via intermolecular hydrogen bonding [8,9,10] and π–π stacking [11,12,13], or coordination polymeric architecture by using bridging ligands [14,15,16,17,18]. Multinuclear clusters have also been widely studied in the hope of developing multistable compounds with more accessible spin states towards denser information storage, or hybrid SCO materials with multifunctional properties (e.g., SCO with charge transfer, magnetic coupling, luminescence, etc.) arising from the combination of the SCO metal center and other metal centers [2,19,20,21,22,23,24]. In particular, dinuclear species have received much attention since they are a simple model for revealing intra- and intermolecular interactions for enhancing cooperativity [25,26,27,28,29,30,31,32,33,34]. From a more practical point of view, the importance of studying the reproducible nature and scan rate dependence of the hysteresis loop and high-temperature SCO with sufficient thermal stability has recently been pointed out in order to define the limiting characteristics of SCO materials [33,35,36,37,38,39].
Recently, we have focused on SCO molecules with 1-R-1H-1,2,3-triazole-containing Schiff-base (1-R-1H-1,2,3-triazolimine; R = Me and Ph) ligands since the ligand system can easily modify its structure with the choice of a substituent R of a precursor, 1-R-1H-1,2,3-triazole-4-carbaldehyde, and another amino precursor by simple click reaction [40,41,42], Schiff-base reaction [43] and replacement of R using the method reported by L’abbé and coworkers [44,45]. The iron(II) complexes with multidentate 1-R-1H-1,2,3-triazolimine ligand show a variety of SCO properties such as gradual, abrupt, and two-step transition with (or without) hysteresis in a wide temperature range (around RT, below RT and above RT over ca. 100 °C) [34,46,47]. In one of these studies, we reported the SCO iron(II) dinuclear double helicate for the first time [34]. This compound, with the formula [FeII2(L2C2)2](PF6)4·5H2O·MeCN, has two bis-tridentate type ligand strands (L2C2) in which two 1,2,3-triazolimine moieties of the ligand strand are bridged by an ethylene chain (Scheme 1), and shows an anomalous two-step SCO with 11 K-wide hysteresis in a second step centered at 432 K, which is the highest hysteretic transition temperature in the dinuclear SCO system reported so far [26,27,28,29,33,48].
From the fascinating structure and function of the [FeII2(L2C2)2]4+ system, our own interest in the system has increasingly concerned the effect of the bridging alkyl chain length. We report here the synthesis, thermal stability, and structure of the corresponding propylene-bridged iron(II) dinuclear double helicate complexes [FeII2(L2C3)2](PF6)4·1.5H2O·1.5MeCN (1·PF6) and [FeII2(L2C3)2](AsF6)4·3H2O·MeCN (1·AsF6), where L2C3 = 1,1′-[propane-1,3-diylbis(1H-1,2,3-triazole-1,4-diyl)]bis{N-[2-(pyridin-2-yl)ethyl]methanimine} (Scheme 1), and the high-temperature hysteretic SCO of 1·AsF6.

2. Results and Discussion

2.1. Synthesis and Characterization of [FeII2(L2C3)2](PF6)4·1.5H2O·1.5MeCN (1·PF6) and [FeII2(L2C3)2](AsF6)4·3H2O·MeCN (1·AsF6)

The ligand L2C3 was prepared stoichiometric by the 1:2 condensation reaction of 1,1′-(propane-1,3-diyl)bis(1H-1,2,3-triazole-4-carbaldehyde) (4) and 2-(2-aminoethyl)pyridine. 4 was synthesized starting from 1-phenyl-1H-1,2,3-triazole-4-carbaldehyde and 1,3-diaminopropane (Scheme 2) based on the previously reported procedure of a related ethylene-bridged compound [34]. The dinuclear 1·PF6 and 1·AsF6 were prepared by mixing the ligand L2C3, FeIICl2∙4H2O, and KX (X = PF6 and AsF6 for 1·PF6 and 1·AsF6, respectively) with a 1:1:2 molar ratio in MeOH/H2O mixed solution, which was then recrystallized from the MeCN/MeOH mixed solution. All the synthetic procedures were performed in air and both complexes were obtained as dark-red block crystals. The infrared spectra of both showed a characteristic band at ca. 1609 cm−1, corresponding to the C=N stretching vibration of the Schiff-base ligand [34,49]. In addition, characteristic bands at ca. 844 and 701 cm−1 were observed, corresponding to the counter anions, PF6− and AsF6− for 1·PF6 and 1·AsF6, respectively [34,49,50]. The formula of both complexes was confirmed by elemental analyses and thermogravimetric analyses. Thermogravimetry and differential thermal analysis (TG/DTA) curves of both are shown in Figure 1. As shown in Figure 1a, when the powdered sample of 1·PF6 was heated from 30 °C (303 K) at a rate of 10 °C·min−1, the sample weight decreased gradually and a weight loss of 4.3% at 224 °C (497 K) was observed, which corresponds to the calculated weight percentages of 0.5H2O and 1.5MeCN molecules per [FeII2(L2C3)2](PF6)4·1.5H2O·1.5MeCN (1·PF6) (4.2%). Above this temperature, the weight loss became abrupt, and then the weight loss of the remaining one H2O molecule (1.1%) was observed at 242 °C (515 K). In this region, a sharp thermal anomaly in DTA appeared (Tmax = 232 °C (505 K)). Finally, above 242 °C (515 K), the weight loss became more and more abrupt, indicating the decomposition of 1·PF6. In the same way, as shown in Figure 1b, when the powdered sample of 1·AsF6 was heated from 30 °C (303 K) at a rate of 10 °C·min−1, the sample weight decreased gradually and the total weight loss was 5.0% at 215 °C (488 K) in agreement with the calculated weight percentage of 3H2O and one MeCN molecule per [FeII2(L2C3)2](AsF6)4·3H2O·MeCN (1·AsF6) (5.1%). On further increasing the temperature from 215 °C (488 K), the desolvated sample of 1·AsF6 was stable up to ca. 263 °C (536 K), and began to decompose above this temperature. Although a sharp thermal anomaly in DTA was also observed at Tmax = 212 °C (485 K) in 1·AsF6, this peak was far from the decomposition temperature (ca. 263 °C), which is obviously different from that of 1·PF6. To access the reason for exhibiting a sharp thermal anomaly in DTA around 485–505 K, thermochromic properties of both compounds were also investigated (Figure 2). Although the orange-brown color of powdered samples of 1·PF6 becomes slightly lighter from 300 K to ca. 483 K, possibly due to the partial SCO, further elevation of the temperature to 493 K induces rapid black coloration, suggesting the decomposition of the compound (Figure 2a). This thermochromic tendency and TG/DTA results suggest that the decomposition temperature overlaps the spin transition temperature in 1·PF6. On the other hand, powdered samples of 1·AsF6 showed a clearly distinguishable thermochromism from orange-brown at 300 K to orange-yellow at ca. 498 K, suggesting the occurrence of SCO (Figure 2b). Then, further increasing the temperature to 503 K induces slight yellowish coloration, and ca. 5 min. later, a black coloration related to decomposition proceeds. This color change of 1·AsF6 in a step-by-step-manner is comparable to the clear distinction between sharp thermal anomaly at Tmax = 485 K and decomposition temperature observed in TG/DTA curves. Consequently, we decided to investigate SCO properties only for 1·AsF6 which is more stable than 1·PF6 in a high-temperature SCO region.

2.2. Crystal Structure of 1·PF6 and 1·AsF6

The crystal structure of 1·PF6 and 1·AsF6 was determined at 120 K (low-spin–low-spin (LS–LS) state). As shown in Table 1, both complexes crystallize in the same monoclinic space group type C2/c (number 15) with Z = 4 and are isostructural. The structure consists of a [FeII2(L2C3)2]4+ complex-cation, two disordered monovalent counterions (PF6− and AsF6− for 1·PF6 and 1·AsF6, respectively), and H2O and MeCN molecules as lattice solvents. In the crystal lattice, both solvent molecules are in the one solvent site in a severely disordered manner in both compounds. Thus, these regions, including solvent molecules, are treated with the PLATON SQUEEZE program [51] (see Experimental Section 3.3 including the details about analyses of disordered counter anions and solvent molecules).
Figure 3 shows the molecular structure of the complex-cation [FeII2(L2C3)2]4+ of 1·AsF6 at 120 K. As shown in Table 2, the structural feature of the complex-cation of 1·PF6 is similar to that of 1·AsF6. Thus, we only discuss the structure of 1·AsF6 below. The complex-cation has a dinuclear double-helical architecture, in which each ligand L2C3 bound as a bis-tridentate ligand to two different iron centers, and conversely, the FeII centers are N6-coordinated pseudo-octahedral coordination environments bound to two different ligand strands. The intra-helical metal–metal distance is 10.894(3) Å, which is much longer than that of the related ethylene-bridged helicate [FeII2(L2C2)2]4+ (7.855(3) Å) [34] due to the elongation of the alkyl chain from two to three C atoms. Each metal site is chiral, with either a Δ or a Λ configuration, and the complex-cation depicted in Figure 3 has a homochiral Λ–Λ pair. In the crystal, complex-cations with the Δ–Δ and Λ–Λ pairs coexist to form a racemic crystal since the complex crystallizes in a centrosymmetric space group, C2/c. The Fe–N coordination bond distances (1.954(3)–2.007(3) and 1.945(3)–2.007(3) Å for Fe1–N and Fe2–N, respectively) indicate that both centers are in the LS FeII state. While the average Fe–N bond distance and octahedral volume of LS–LS [FeII2(L2C3)2]4+ are similar to those of LS–LS [FeII2(L2C2)2]4+, the Θ [52] and continuous shape measures (CShMs) relative to the regular octahedron with the center as the reference shape [53] of LS–LS [FeII2(L2C3)2]4+ are lower than those of LS–LS [FeII2(L2C2)2]4+, indicating that the FeII centers of LS–LS [FeII2(L2C3)2]4+ have a more regular octahedral geometry than those of LS–LS [FeII2(L2C2)2]4+ with the one minor exception of the Σ [54] of LS–LS [FeII2(L2C2)2]4+, which is slightly lower than that of LS–LS [FeII2(L2C3)2]4+ (average Fe–N bond distance, Σ, Θ, CShMs and octahedral volume of the LS–LS [FeII2(L2C2)2]4+ for [FeII2(L2C2)2](PF6)4·5H2O·MeCN [34] are 1.971 Å, 42.5°, 133.7°, 0.696 and 10.096 Å3, respectively).
The assembly structure of 1·AsF6 is shown in Figure 4. As shown in Figure 4a, a cationic one-dimensional (1D) structure is formed along the b-axis by slightly inclined intermolecular π–π interactions between all pyridyl rings of neighboring complex-cations with Cg1···Cg2 ii = 4.123(3) Å.
(Cg1 = centroid of the N1–C1–C2–C3–C4–C5 ring, Cg2 = centroid of the N6–C12–C13–C14–C15–C16 ring; symmetry operation: (ii) x, −1 + y, z; Table 3). In the light of chiral assembly, homochiral complex-cations are linked together in the π–stacked 1D structure to give a homochiral 1D chain (Δ–Δ···Δ–Δ···Δ–Δ··· or Λ–Λ···Λ–Λ···Λ–Λ···). Figure 4b shows the stacking observed between adjacent cationic 1D chains viewed along the ac plane. One-dimensional chains of opposite chirality are alternately arrayed along the c-axis to give a heterochiral crystal. Each cationic 1D chain is separated by AsF6− ions and solvent molecules occupying the space between the 1D chains in a strongly disordered manner even at 120 K. Although the assembly structure of 1·PF6 is almost same as that of 1·AsF6, these 1D-based structures are remarkably different from the two-dimensional (2D) assembly of the related ethylene-bridged helicate [FeII2(L2C2)2](PF6)4·5H2O·MeCN by intermolecular π–π and CH/π interactions [34].

2.3. Magnetic Property of 1·AsF6

The magnetic susceptibilities for polycrystalline samples of 1·AsF6 were measured upon heating from 300 to 498 K and subsequent cooling to 300 K at a sweep rate of 0.5 K·min−1 under an applied magnetic field of 1 T using a superconducting quantum interference device (SQUID) magnetometer with a special heating setup. The χMT vs. T plots are shown in Figure 5, where χM is the molar magnetic susceptibility per Fe and T is the absolute temperature. As shown in Figure 5, 1·AsF6 showed an unsymmetrical hysteretic SCO above room temperature. The initial χMT value is 0.3 cm3·K·mol−1 at 300 K, which is consistent with the theoretical value for a LS–LS FeII system. On raising the temperature from 300 K, the χMT value increases gradually to reach ca. 2.1 cm3·K·mol−1 at 478 K, and then increases abruptly to reach ca. 6.3 cm3·K·mol−1 at 498 K, which is consistent with the theoretical value for a high-spin–high-spin (HS–HS) FeII system (χMT = 6.0 cm3·K·mol−1). On lowering the temperature from 498 K, the χMT value decreases gradually, reaching ca. 4.3 cm3·K·mol−1 at 409 K, and then decreases abruptly to reach ca. 1.5·cm3·K mol−1 at 379 K. Then, the χMT value further decreases gradually to reach ca. 0.5 cm3·K·mol−1 at 300 K. The critical temperatures of the warming (Tc↑) and cooling (Tc↓) modes in the abrupt spin transition area are 485 and 401 K, respectively, indicating the occurrence of ΔT = 84 K, which is the widest thermal hysteresis loop in the dinuclear system reported so far [26,27,28,29,33,34,48]. It is also noteworthy that the Tc↑ of 1·AsF6 is considerably higher than that of the related ethylene-bridged helicate [FeII2(L2C2)2](PF6)4·5H2O·MeCN (Tc↑ = 437 K) [34] by about 48 K.

2.4. Reproducibility of Hysteretic SCO of 1·AsF6

To reveal the desolvation effect and reproducibility of hysteretic SCO of 1·AsF6, temperature-dependent magnetic susceptibilities were also measured over three consecutive cycles. As shown in Figure 6a, although 1·AsF6 shows a more gradual spin transition in the second cycle than in the first cycle, probably due to the in situ solvent liberation in the first heating, an asymmetric wide hysteresis loop is then still observed. Further thermal cycling (third cycle) causes the spin transition pattern to have a much more gradual and partial SCO fashion, which does not occur in the related ethylene-bridged helicate [FeII2(L2C2)2](PF6)4·5H2O·MeCN [34]. Comparing powder X-ray diffraction (PXRD) patterns of as-synthesized 1·AsF6 and after first thermal cycle of SQUID measurement confirms that there is no structural phase transition associated with the desolvation, because the peak patterns of the sample are not changed, although the peak positions increase slightly possibly due to the removal of solvent molecules and concomitant lattice contraction (Figure 6b). However, an intensity decrease and peak broadening are observed after three thermal cycles of SQUID measurement, presumably due to a loss of crystallinity and/or partial decomposition.
These properties were also confirmed by differential scanning calorimetry (DSC) experiments of four consecutive thermal cycles at a sweep rate of 10 K·min−1, in the temperature range of 222–502 K (Figure 7). As shown in Figure 7, from the first cycle in heating and following cooling modes, a thermal hysteresis of ca. 85 K was detected (Tmax↑ and Tmax↓ are 498 and 413 K, respectively) and the hysteresis width is consistent with the ΔT value observed by the magnetic measurement. As the thermal cycling is repeated, the shape of DSC peaks becomes broader and smaller, and the position of the peak shifts to a lower temperature in both the heating and cooling modes of the second cycle due to the solvent loss in the first heating (Tmax↑ and Tmax↓ are 487 and 401 K, respectively, in the second cycle). However, further thermal cycling from the second cycle induces the peak shift to the opposite directions, in which the temperature variation in cooling modes is larger than that in heating modes (Tmax↑ and Tmax↓ are 490 and 392 K, respectively, in the third cycle, and 492 and 384 K, respectively, in the fourth cycle). In addition, peak broadening and reduction also continue in the third and fourth cycles. As a whole, thermal hysteresis of 1·AsF6 is retained for at least four cycles, although the spin transition becomes gradual and incomplete with shifting the transition temperature due to the solvent liberation in the first cycle and a loss of crystallinity and/or partial decomposition upon further thermal cycling.

3. Materials and Methods

3.1. Synthesis of FeII Complexes

3.1.1. General

All reagents and solvents were purchased from commercial sources and used for the syntheses without further purification. The 1-Phenyl-1H-1,2,3-triazole-4-carbaldehyde was prepared according to methods in the literature [47]. The synthetic procedure of 1,1′-(propane-1,3-diyl)bis(1H-1,2,3-triazole-4-carbaldehyde) (4) was constructed by modifying the reported procedures [34]. All the synthetic procedures were carried out in air.

3.1.2. Preparation of 1,1′-(propane-1,3-diyl)bis(1H-1,2,3-triazole-4-carbaldehyde) (4)

To a warm pale yellow solution of 1-phenyl-1H-1,2,3-triazole-4-carbaldehyde (3.464 g, 20 mmol) in MeOH (30 mL), 1,3-diaminopropane (0.741 g, 10 mmol) in MeOH (1 mL) was added. The resulting solution was stirred for 1 h at 60 °C, and was then cooled in a fridge. The precipitated white powders were collected by suction filtration, washed with Et2O (10 mL × 3), and dried in vacuo. White solid of N,N’-(propane-1,3-diyl)bis[1-(1-phenyl-1H-1,2,3-triazol-4-yl)methanimine] (2). Yield: 3.005 g (78%). Mp 127–128 °C (from MeOH), 1H NMR (600 MHz; DMSO-d6; TMS): δ 9.24 (s, 2H), 8.55 (s, 2H), 8.00–7.98 (m, 4H), 7.63–7.60 (m, 4H), 7.53–7.51 (m, 2H), 3.72 (t, J = 6.5 Hz, 4H), 2.05–2.00 (m, 2H). Anal. Calcd. for 2·0.2H2O = C21H20.4N8O0.2: C, 65.00; H, 5.30; N, 28.88%. Found: C, 65.05; H, 5.19; N, 29.01%.
A suspension of 2 (2.898 g, 7.5 mmol) in 1-PrOH (25 mL) was heated at 80 °C for 16 h, turning into a pale yellow solution, and the resulting solution was then cooled in a fridge. The precipitated white powders were collected by suction filtration, washed with Et2O (10 mL), and dried in vacuo. White solid of 1,1′-[propane-1,3-diylbis(1H-1,2,3-triazole-1,4-diyl)]bis(N-phenylmethanimine) (3). Yield: 2.260 g (78%). m.p. 192–193 °C (from 1-PrOH), 1H NMR (600 MHz; DMSO-d6; TMS): δ 8.78 (s, 2H), 8.67 (s, 2H), 7.43–7.41 (m, 4H), 7.28–7.25 (m, 6H), 4.52 (t, J = 6.9 Hz, 4H), 2.59–2.55 (m, 2H). Anal. Calcd. for 3·0.35H2O = C21H20.7N8O0.35: C, 64.55; H, 5.34; N, 28.68%. Found: C, 64.15; H, 5.20; N, 29.06%.
Hydrochloric acid (36%) (1.671 g, 16.5 mmol) in H2O (28 mL) was added to white powders of 3 (2.125 g, 5.5 mmol), and the mixture was stirred for 2 h at room temperature. After turning the mixture into a yellowish-white suspension, the residual white solids of 4 were collected by suction filtration, washed with H2O (10 mL) and then Et2O (10 mL), and dried in vacuo. Yield: 1.103 g (86%). m.p. 124–125 °C (from H2O), 1H NMR (600 MHz; DMSO-d6; TMS): δ 10.03 (s, 2H), 8.89 (s, 2H), 4.52 (t, J = 6.9 Hz, 4H), 2.55–2.51 (m, 2H). Anal. Calcd. for C9H10N6O2: C, 46.15; H, 4.30; N, 35.88%. Found: C, 45.87; H, 4.19; N, 35.56%.

3.1.3. Synthesis of the Bis-Tridentate Ligand L2C3 = 1,1′-[propane-1,3-diylbis(1H-1,2,3-triazole-1,4-diyl)]bis{N-[2-(pyridin-2-yl)ethyl]methanimine}

The ligand L2C3 was prepared by mixing 4 and 2-(2-aminoethyl)pyridine with 1:2 molar ratio in MeOH. The ligand solution thus prepared was used for the synthesis of FeII complexes without further purification and isolation.

3.1.4. Preparation of [FeII2(L2C3)2](PF6)4·1.5H2O·1.5MeCN (1·PF6)

2-(2-Aminoethyl)pyridine (0.122 g, 1 mmol) in MeOH (1 mL) was added to a solution of 4 (0.118 g, 0.5 mmol) in MeOH (20 mL), and the resulting mixture was stirred at ambient temperature for 1 h. A pale yellow solution of the ligand (0.5 mmol) thus prepared was treated first with a solution of FeIICl2∙4H2O (0.099 g, 0.5 mmol) in MeOH (1 mL), turning into a dark orange-red solution, and then with KPF6 (0.184 g, 1 mmol) in 4 mL of a mixed solution of MeOH and H2O (1/1 by volume). The resulting mixture was stirred at ambient temperature for 1 h, during which time the precipitated orange-brown crude product was collected by suction filtration. The collected precipitate was dissolved in MeCN (4 mL) and then filtered. Dark-red block crystals were obtained by slow diffusion of MeOH (8 mL) into the filtrate (liquid–liquid diffusion) for a day. Yield: 0.154 g (37%). Anal. Calcd. for [FeII2(L2C3)2](PF6)4·1.5MeCN·1.5MeOH = C49H59.5N21.5O1.5P4F24Fe2: C, 35.34; H, 3.60; N, 18.08%. Found: C, 35.48; H, 3.37; N, 18.06%. IR (KBr): νC=N 1609 cm−1, νP–F(PF6−) 844 cm−1.

3.1.5. Preparation of [FeII2(L2C3)2](AsF6)4·3H2O·MeCN (1·AsF6)

2-(2-Aminoethyl)pyridine (0.122 g, 1 mmol) in MeOH (2 mL) was added to a solution of 4 (0.118 g, 0.5 mmol) in MeOH (20 mL), and the resulting mixture was stirred at ambient temperature for 1 h. A pale yellow solution of the ligand (0.5 mmol) thus prepared was treated first with a solution of FeIICl2∙4H2O (0.099 g, 0.5 mmol) in MeOH (2 mL), turning into a dark orange-red solution, and then with KAsF6 (0.228 g, 1 mmol) in 4 mL of a mixed solution of MeOH and H2O (1/1 by volume). The resulting mixture was stirred at ambient temperature for 30 min, during which time the precipitated red-orange crude product was collected by suction filtration. The collected precipitate was dissolved in MeCN (3 mL) and then filtered. Dark-red block crystals were obtained by slow diffusion of MeOH (7 mL) into the filtrate (liquid–liquid diffusion) for a day. Yield: 0.155 g (33%). Anal. Calcd. for [FeII2(L2C3)2](AsF6)4·3H2O·MeCN = C48H61N21O3As4F24Fe2: C, 31.21; H, 3.33; N, 15.92%. Found: C, 31.46; H, 3.04; N, 16.25%. IR (KBr): νC=N 1609 cm−1, νAs–F(AsF6−) 701 cm−1.

3.2. Physical Measurements

Elemental C, H, and N analyses were performed on a J-Science Lab (Kyoto, Japan) MICRO CORDER JM-10. IR spectra were recorded at room temperature using a JASCO (Tokyo, Japan) FT/IR 460Plus spectrophotometer or a PerkinElmer (Waltham, MA, USA) Spectrum100 FT-IR spectrometer with the samples prepared as KBr disks. 1H NMR spectra were recorded on a JEOL (Tokyo, Japan) ECA-600 spectrometer. The melting point was measured through a Yanaco (Kyoto, Japan) MP-S3 micro melting point meter and was uncorrected. Thermogravimetric data were collected on a TG/DTA6300 (SII Nano Technology Inc., Chiba, Japan) instrument in the temperature range of 30–318 °C (303–591 K) for 1·PF6 and 30–381 °C (303–654 K) for 1·AsF6 at a rate of 10 K·min−1 under a nitrogen atmosphere. DSC measurements for 1·AsF6 were performed with a DSC6200 (SII Nano Technology Inc., Chiba, Japan) over the temperature range of 222–502 K, at a sweep rate of 10 K·min−1 under a nitrogen atmosphere using aluminum hermetic pans with an empty pan as reference. Magnetic susceptibilities of 1·AsF6 were measured in the temperature range of 300–498 K at a sweep rate of 0.5 K·min−1 under an applied magnetic field of 1 T using a Quantum Design (San Diego, CA, USA) MPMS-7 SQUID magnetometer with a special heating setup of a sample space oven option. The sample was wrapped in an aluminum foil and was then inserted into a quartz glass tube with a small amount of glass wool filler. Corrections for diamagnetism of the sample were made using Pascal’s constants [55] and a background correction for the sample holder was applied. PXRD patterns were recorded at room temperature on a portion of polycrystalline powders placed on a non-reflecting silicon plate, using a Rigaku (Tokyo, Japan) MiniFlex600 diffractometer with Cu Kα radiation (λ = 1.5418 Å) operated at 0.4 kW power (40 kV, 10 mA). Images of grinding samples were recorded under an optical microscope SMZ800N (Nikon, Tokyo, Japan). The sample temperature was controlled by using a Linkam (Tadworth, UK) THMS 600 heating and freezing stage.

3.3. Crystallographic Data Collection and Structure Analyses

X-ray diffraction data of 1·PF6 and 1·AsF6 were collected by a Rigaku (Tokyo, Japan) AFC7R Mercury CCD diffractometer using graphite monochromated Mo Kα radiation (λ = 0.71075 Å) operated at 5 kW power (50 kV, 100 mA). A single crystal was mounted on a MiTeGen (Ithaca, NY, USA) MicroMount (200 μm) with liquid paraffin, then rapidly frozen in a nitrogen-gas stream at 120 K to avoid the loss of crystal solvents and the diffraction data were collected at 120 K. The temperature of the crystal was maintained by means of a Rigaku cooling device to within an accuracy of ±2 K. The data were corrected for Lorentz, polarization, and absorption effects. The structures were solved by the direct method [56] and refined on F2 data using the full-matrix least-squares algorithm using SHELXL-2014 [57]. Non-hydrogen atoms were refined anisotropically. The structure of 1·PF6 contains two disordered PF6− ions. Both PF6− ions were disordered over two positions and the occupancy factors for the possible two positions of F atoms (F1A–F6A:F1B–F6B = 0.518(15):0.482(15) for P(1)F6− and F7A–F12A:F7B–F12B = 0.635(16):0.365(16) for P(2)F6−) were refined using the tools available from the SHELXL-2014 program package. In the refinement of these disordered PF6− ions, the SADI command for all P–F bonds and F···F distances and the RIGU command for all P and F atoms were also applied. In addition, diffraction quality of the crystal of 1·PF6 was not sufficient to model highly disordered solvent molecules. The PLATON SQUEEZE program (290617, A.L. Spek, Utrecht, NL-UT, The Netherlands) [51] was used to treat regions with disordered solvent molecules which could not be sensibly modelled in terms of atomic sites. Available void volume was 892 Å3. Then, 196 electrons per unit cell were located and these were assigned to 1.5 H2O and 1.5 MeCN molecules per complex (196/4 = 49 e per complex; 1.5 H2O (15) + 1.5 MeCN (33) = 48 electrons). In the same way, the structure of 1·AsF6 contains two disordered AsF6− ions and severely disordered solvent molecules. In 1·AsF6, both AsF6− ions were disordered over three positions and the occupancy factors for the possible three positions of F atoms (F1A–F6A:F1B–F6B:F1C–F6C = 0.434(3):0.291(3):0.275(3) for As(1)F6− and F7A–F12A:F7B–F12B:F7C–F12C = 0.513(3):0.219(3):0.268(3) for As(2)F6−) were refined using the SUMP command to keep the sum of three occupancy factors of each ion as 1.0. In the refinement of these disordered AsF6− ions, the SADI command for all As–F bonds and F···F distances, the RIGU command for all As and F atoms, and the EADP command for F5A, F5B, F5C and F6A, F6B, F6C were also applied. The PLATON SQUEEZE program was also used to treat regions with disordered solvent molecules in the structure of 1·AsF6. Available void volume was 926 Å3, and 220 electrons per unit cell were located. These were assigned to 3 H2O and 1 MeCN molecules per complex (220/4 = 55 e per complex; 3 H2O (30) + 1 MeCN (22) = 52 electrons). All H atoms were placed in geometrically calculated positions, with the distances of C–H = 0.95 (aromatic) and 0.99 (CH2) Å, and refined as riding atoms, with Uiso(H) = 1.2 Ueq(C). All calculations were performed by using the Yadokari-XG software package [58]. The CShMs of the FeII centers relative to the ideal octahedron were calculated by SHAPE 2.1 [53]. The octahedral volumes of the FeII centers were calculated by OLEX2 [59]. CCDC 1544125–1544126 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html or from the CCDC (12 Union Road, Cambridge CB2 1EZ, UK; Fax: +44 1223 336033; E-mail: [email protected]).

4. Conclusions

In conclusion, the present work reveals the effects of the extension of the bridging alkyl chain length (from C2 to C3) on the structure and SCO properties of the iron(II) dinuclear double helicate [FeII2(L2R)2](X)4·solvent, with the concomitant effects of the coexistent counter anions and lattice solvents. While propylene-bridged dinuclear complexes [FeII2(L2C3)2](PF6)4·1.5H2O·1.5MeCN (1·PF6) and [FeII2(L2C3)2](AsF6)4·3H2O·MeCN (1·AsF6) are isostructural, the thermal stability of 1·PF6 is lower than that of 1·AsF6 in a high-temperature SCO region. 1·AsF6 shows an unsymmetrical hysteretic SCO between the LS–LS and HS–HS states at above room temperature with ΔT = 84 K (Tc↑ = 485 K and Tc↓ = 401 K in the abrupt spin transition area) in the first thermal cycle, which is the widest hysteresis loop in the dinuclear system reported so far. In addition, the Tc↑ of 1·AsF6 is considerably higher than that of the related ethylene-bridged compound, by about 48 K. This high-temperature wide thermal hysteresis may be related to the 1D assembly structure composed of inter-helicate π–π interactions, which is obviously different from the 2D assembly of the related ethylene-bridged compound. Although the desolvation of 1·AsF6 does not directly affect the assembly structure, consecutive thermal cycles cause a loss of crystallinity and/or partial decomposition, and subsequent modification of the hysteretic SCO loop to a more gradual and partial fashion. As a consequence, the extension of the bridging alkyl chain length (from C2 to C3) and subsequent elongation of the dinuclear cation makes the 2D supramolecular assembly one-dimensional, and enhances the width of the hysteresis loop. Simultaneous raising of the Tc↑ may also cause the overlapping between spin transition temperature and decomposition temperature, which is related to the thermal durability upon SCO.

Supplementary Materials

The following are available online at www.mdpi.com/2304-6740/5/3/49/s1. Cif and cif-checked files.

Acknowledgments

This work was partly funded by the Gifu University for the promotion of the research of young scientists. Part of this work was conducted at the Institute for Molecular Science, supported by the Nanotechnology Platform Program (Molecule and Material Synthesis) of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan. The authors would like to thank Professor O. Sakurada (Gifu University, Japan) for his assistance in collecting PXRD data.

Author Contributions

The experimental work was performed mainly by Shiori Hora with assistance from Hiroaki Hagiwara. Hiroaki Hagiwara supervised the experiments. Both authors analyzed the data and contributed to the preparation of the manuscript.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Gütlich, P.; Goodwin, H.A. (Eds.) Spin Crossover in Transition Metal Compounds I-III; Topics in Current Chemistry; Springer: Berlin, Germany, 2004; Volume 233–235. [Google Scholar]
  2. Halcrow, M.A. (Ed.) Spin-Crossover Materials–Properties and Applications; John Wiley & Sons: Chichester, UK, 2013. [Google Scholar]
  3. Gütlich, P.; Gaspar, A.B.; Garcia, Y. Spin state switching in iron coordination compounds. Beilstein J. Org. Chem. 2013, 9, 342–391. [Google Scholar] [CrossRef] [PubMed]
  4. Jenkins, D.M.; Peters, J.C. Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d7 Ion. J. Am. Chem. Soc. 2003, 125, 11162–11163. [Google Scholar] [CrossRef] [PubMed]
  5. Li, J.; Lord, R.L.; Noll, B.C.; Baik, M.-H.; Schulz, C.E.; Scheidt, W.R. Cyanide: A Strong-Field Ligand for Ferrohemes and Hemoproteins? Angew. Chem. Int. Ed. 2008, 47, 10144–10146. [Google Scholar]
  6. Scepaniak, J.J.; Harris, T.D.; Vogel, C.S.; Sutter, J.; Meyer, K.; Smith, J.M. Spin Crossover in a Four-Coordinate Iron(II) Complex. J. Am. Chem. Soc. 2011, 133, 3824–3827. [Google Scholar] [PubMed]
  7. Mossin, S.; Tran, B.L.; Adhikari, D.; Pink, M.; Heinemann, F.W.; Sutter, J.; Szilagyi, R.K.; Meyer, K.; Mindiola, D.J. A Mononuclear Fe(III) Single Molecule Magnet with a 3/2↔5/2 Spin Crossover. J. Am. Chem. Soc. 2012, 134, 13651–13661. [Google Scholar] [PubMed]
  8. Weber, B.; Bauer, W.; Obel, J. An Iron(II) Spin-Crossover Complex with a 70 K Wide Thermal Hysteresis Loop. Angew. Chem. Int. Ed. 2008, 47, 10098–10101. [Google Scholar] [CrossRef] [PubMed]
  9. Weber, B.; Bauer, W.; Pfaffender, T.; Dîrtu, M.M.; Naik, A.D.; Rotaru, A.; Garcia, Y. Influence of Hydrogen Bonding on the Hysteresis Width in Iron(II) Spin-Crossover Complexes. Eur. J. Inorg. Chem. 2011, 2011, 3193–3206. [Google Scholar]
  10. Zhao, X.-H.; Zhang, S.-L.; Shao, D.; Wang, X.-Y. Spin Crossover in [Fe(2-Picolylamine)3]2+ Adjusted by Organosulfonate Anions. Inorg. Chem. 2015, 54, 7857–7867. [Google Scholar] [CrossRef] [PubMed]
  11. Hayami, S.; Gu, Z.-Z.; Yoshiki, H.; Fujishima, A.; Sato, O. Iron (III) spin-crossover compounds with a wide apparent thermal hysteresis around room temperature. J. Am. Chem. Soc. 2001, 123, 11644–11650. [Google Scholar] [PubMed]
  12. Schäfer, B.; Rajnák, C.; Šalitroš, I.; Fuhr, O.; Klar, D.; Schmitz-Antoniak, C.; Weschke, E.; Wende, H.; Ruben, M. Room temperature switching of a neutral molecular iron(II) complex. Chem. Commun. 2013, 49, 10986–10988. [Google Scholar] [CrossRef] [PubMed]
  13. Iasco, O.; Rivière, E.; Guillot, R.; Cointe, M.B.-L.; Meunier, J.-F.; Bousseksou, A.; Boillot, M.-L. FeII(pap-5NO2)2 and FeII(qsal-5NO2)2 Schiff-Base Spin-Crossover Complexes: A Rare Example with Photomagnetism and Room-Temperature Bistability. Inorg. Chem. 2015, 54, 1791–1799. [Google Scholar] [CrossRef] [PubMed]
  14. Kröber, J.; Codjovi, E.; Kahn, O.; Grolière, F.; Jay, C. A Spin Transition System with a Thermal Hysteresis at Room Temperature. J. Am. Chem. Soc. 1993, 115, 9810–9811. [Google Scholar] [CrossRef]
  15. Kahn, O.; Martinez, C.J. Spin-Transition Polymers: From Molecular Materials toward Memory Devices. Science 1998, 279, 44–48. [Google Scholar] [CrossRef]
  16. Muñoz-Lara, F.J.; Gaspar, A.B.; Aravena, D.; Ruiz, D.; Muñoz, M.C.; Ohba, M.; Ohtani, R.; Kitagawa, S.; Real, J.A. Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers. Chem. Commun. 2012, 48, 4686–4688. [Google Scholar] [CrossRef] [PubMed]
  17. Lochenie, C.; Bauer, W.; Railliet, A.P.; Schlamp, S.; Garcia, Y.; Weber, B. Large Thermal Hysteresis for Iron(II) Spin Crossover Complexes with N-(Pyrid-4-yl)isonicotinamide. Inorg. Chem. 2014, 53, 11563–11572. [Google Scholar] [CrossRef] [PubMed]
  18. Dîrtu, M.M.; Naik, A.D.; Rotaru, A.; Spinu, L.; Poelman, D.; Garcia, Y. FeII Spin Transition Materials Including an Amino–Ester 1,2,4-Triazole Derivative, Operating at, below, and above Room Temperature. Inorg. Chem. 2016, 55, 4278–4295. [Google Scholar] [CrossRef] [PubMed]
  19. Murray, K.S. Advances in Polynuclear Iron(II), Iron(III) and Cobalt(II) Spin-Crossover Compounds. Eur. J. Inorg. Chem. 2008, 3101–3121. [Google Scholar] [CrossRef]
  20. Nihei, M.; Sekine, Y.; Suganami, N.; Nakazawa, K.; Nakao, A.; Nakao, H.; Murakami, Y.; Oshio, H. Controlled Intramolecular Electron Transfers in Cyanide-Bridged Molecular Squares by Chemical Modifications and External Stimuli. J. Am. Chem. Soc. 2011, 133, 3592–3600. [Google Scholar] [CrossRef] [PubMed]
  21. Hietsoi, O.; Dunk, P.W.; Stout, H.D.; Arroyave, A.; Kovnir, K.; Irons, R.E.; Kassenova, N.; Erkasov, R.; Achim, C.; Shatruk, M. Spin Crossover in Tetranuclear Fe(II) Complexes, {[(tpma)Fe(μ-CN)]4}X4 (X = ClO4−, BF4−). Inorg. Chem. 2014, 53, 13070–13077. [Google Scholar] [CrossRef] [PubMed]
  22. Matsumoto, T.; Newton, G.N.; Shiga, T.; Hayami, S.; Matsui, Y.; Okamoto, H.; Kumai, R.; Murakami, Y.; Oshio, H. Programmable spin-state switching in a mixed-valence spin-crossover iron grid. Nat. Commun. 2014, 5, 3865. [Google Scholar] [CrossRef] [PubMed]
  23. Wu, S.-Q.; Wang, Y.-T.; Cui, A.-L.; Kou, H.-Z. Toward Higher Nuclearity: Tetranuclear Cobalt(II) Metallogrid Exhibiting Spin Crossover. Inorg. Chem. 2014, 53, 2613–2618. [Google Scholar] [CrossRef] [PubMed]
  24. Steinert, M.; Schneider, B.; Dechert, S.; Demeshko, S.; Meyer, F. Spin-State Versatility in a Series of Fe4 [2 × 2] Grid Complexes: Effects of Counteranions, Lattice Solvent, and Intramolecular Cooperativity. Inorg. Chem. 2016, 55, 2363–2373. [Google Scholar] [CrossRef] [PubMed]
  25. Charbonnière, L.J.; Williams, A.F.; Piguet, C.; Bernardinelli, G.; Rivara-Minten, E. Structural, Magnetic, and Electrochemical Properties of Dinuclear Triple Helices: Comparison with Their Mononuclear Analogues. Chem. Eur. J. 1998, 4, 485–493. [Google Scholar] [CrossRef]
  26. Ksenofontov, V.; Gaspar, A.B.; Niel, V.; Reiman, S.; Real, J.A.; Gütlich, P. On the Nature of the Plateau in Two-Step Dinuclear Spin-Crossover Complexes. Chem. Eur. J. 2004, 10, 1291–1298. [Google Scholar] [CrossRef] [PubMed]
  27. Weber, B.; Kaps, E.S.; Obel, J.; Achterhold, K.; Parak, F.G. Synthesis and Characterization of a Dinuclear Iron(II) Spin Crossover Complex with Wide Hysteresis. Inorg. Chem. 2008, 47, 10779–10787. [Google Scholar] [CrossRef] [PubMed]
  28. Min, K.S.; Swierczek, K.; DiPasquale, A.G.; Rheingold, A.L.; Reiff, W.M.; Arif, A.M.; Miller, J.S. A dinuclear iron(II) complex, [(TPyA)FeII(THBQ2−)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2− = 2,3,5,6-tetrahydroxy-1,4-benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange. Chem. Commun. 2008, 317–319. [Google Scholar] [CrossRef]
  29. Sunatsuki, Y.; Kawamoto, R.; Fujita, K.; Maruyama, H.; Suzuki, T.; Ishida, H.; Kojima, M.; Iijima, S.; Matsumoto, N. Structures and Spin States of Bis(tridentate)-Type Mononuclear and Triple Helicate Dinuclear Iron(II) Complexes of Imidazole-4-carbaldehyde azine. Inorg. Chem. 2009, 48, 8784–8795. [Google Scholar] [CrossRef] [PubMed]
  30. Sunatsuki, Y.; Kawamoto, R.; Fujita, K.; Maruyama, H.; Suzuki, T.; Ishida, H.; Kojima, M.; Iijima, S.; Matsumoto, N. Structures and spin states of mono- and dinuclear iron(II) complexes of imidazole-4-carbaldehyde azine and its derivatives. Coord. Chem. Rev. 2010, 254, 1871–1881. [Google Scholar] [CrossRef]
  31. Archer, R.J.; Hawes, C.S.; Jameson, G.N.L.; Mckee, V.; Moubaraki, B.; Chilton, N.F.; Murray, K.S.; Schmitt, W.; Kruger, P.E. Partial spin crossover behaviour in a dinuclear iron(II) triple helicate. Dalton Trans. 2011, 40, 12368–12373. [Google Scholar] [CrossRef] [PubMed]
  32. Schneider, C.J.; Cashion, J.D.; Chilton, N.F.; Etrillard, C.; Fuentealba, M.; Howard, J.A.K.; Létard, J.-F.; Milsmann, C.; Moubaraki, B.; Sparkes, H.A.; et al. Spin Crossover in a 3,5-Bis(2-pyridyl)-1,2,4-triazolate-Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2-(μ-L1)2]—Powder versus Single Crystal Study. Eur. J. Inorg. Chem. 2013, 2013, 850–864. [Google Scholar] [CrossRef]
  33. Kulmaczewski, R.; Olguín, J.; Kitchen, J.A.; Feltham, H.L.C.; Jameson, G.N.L.; Tallon, J.L.; Brooker, S. Remarkable Scan Rate Dependence for a Highly Constrained Dinuclear Iron(II) Spin Crossover Complex with a Wide Thermal Hysteresis Loop. J. Am. Chem. Soc. 2014, 136, 878–881. [Google Scholar] [CrossRef] [PubMed]
  34. Hagiwara, H.; Tanaka, T.; Hora, S. Synthesis, structure, and spin crossover above room temperature of a mononuclear and related dinuclear double helicate iron(II) complexes. Dalton Trans. 2016, 45, 17132–17140. [Google Scholar] [CrossRef] [PubMed]
  35. Halcrow, M.A. Spin-crossover Compounds with Wide Thermal Hysteresis. Chem. Lett. 2014, 43, 1178–1188. [Google Scholar] [CrossRef]
  36. Brooker, S. Spin crossover with thermal hysteresis: Practicalities and lessons learnt. Chem. Soc. Rev. 2015, 44, 2880–2892. [Google Scholar] [CrossRef] [PubMed]
  37. Fujinami, T.; Nishi, K.; Hamada, D.; Murakami, K.; Matsumoto, N.; Iijima, S.; Kojima, M.; Sunatsuki, Y. Scan Rate Dependent Spin Crossover Iron(II) Complex with Two Different Relaxations and Thermal Hysteresis fac-[FeII(HLn-Pr)3]Cl·PF6 (HLn-Pr = 2-Methylimidazol-4-yl-methylideneamino-n-propyl). Inorg. Chem. 2015, 54, 7291–7300. [Google Scholar] [CrossRef] [PubMed]
  38. Bao, X.; Guo, P.-H.; Liu, W.; Tucek, J.; Zhang, W.-X.; Leng, J.-D.; Chen, X.-M.; Gural’skiy, I.; Salmon, L.; Bousseksou, A.; et al. Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks. Chem. Sci. 2012, 3, 1629–1633. [Google Scholar] [CrossRef]
  39. Liu, W.; Bao, X.; Li, J.-Y.; Qin, Y.-L.; Chen, Y.-C.; Ni, Z.-P.; Tong, M.-L. High-Temperature Spin Crossover in Two Solvent-Free Coordination Polymers with Unusual High Thermal Stability. Inorg. Chem. 2015, 54, 3006–3011. [Google Scholar] [CrossRef] [PubMed]
  40. Rostovtsev, V.V.; Green, L.G.; Fokin, V.V.; Sharpless, K.B. A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes. Angew. Chem. Int. Ed. 2002, 41, 2596–2599. [Google Scholar] [CrossRef]
  41. Tornøe, C.W.; Christensen, C.; Meldal, M. Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides. J. Org. Chem. 2002, 67, 3057–3064. [Google Scholar] [CrossRef] [PubMed]
  42. Pathigoolla, A.; Pola, R.P.; Sureshan, K.M. A versatile solvent-free azide–alkyne click reaction catalyzed by in situ generated copper nanoparticles. Appl. Catal. A: Gen. 2013, 453, 151–158. [Google Scholar] [CrossRef]
  43. Schiff, H. Mittheilungen aus dem Universitätslaboratorium in Pisa: Eine neue Reihe organischer Basen. Justus Liebigs Ann. Chem. 1864, 131, 118–119. [Google Scholar] [CrossRef]
  44. L’abbé, G.; Bruynseels, M. Replacement of aryl by alkyl in 1-substituted 1H-1,2,3-triazole-4-carbaldehydes. J. Chem. Soc. Perkin Trans. 1 1990, 1492–1493. [Google Scholar] [CrossRef]
  45. L’abbé, G.; Bruynseels, M.; Delbeke, P.; Toppet, S. Molecular rearrangements of 4-iminomethyl-1,2,3-triazoles. Replacement of 1-aryl substituents in 1H-1,2,3-triazole-4-carbaldehydes. J. Heterocycl. Chem. 1990, 27, 2021–2027. [Google Scholar] [CrossRef]
  46. Hagiwara, H.; Minoura, R.; Okada, S.; Sunatsuki, Y. Synthesis, Structure, and Magnetic Property of a New Mononuclear Iron (II) Spin Crossover Complex with a Tripodal Ligand Containing Three 1, 2, 3-Triazole Groups. Chem. Lett. 2014, 43, 950–952. [Google Scholar] [CrossRef]
  47. Hagiwara, H.; Okada, S. A polymorphism-dependent T1/2 shift of 100 K in a hysteretic spin-crossover complex related to differences in intermolecular weak CH···X hydrogen bonds (X = S vs. S and N). Chem. Commun. 2016, 52, 815–818. [Google Scholar] [CrossRef] [PubMed]
  48. Schneider, C.J.; Moubaraki, B.; Cashion, J.D.; Turner, D.R.; Leita, B.A.; Batten, S.R.; Murray, K.S. Spin crossover in di-, tri- and tetranuclear, mixed-ligand tris(pyrazolyl)methane iron(II) complexes. Dalton Trans. 2011, 40, 6939–6951. [Google Scholar] [CrossRef] [PubMed]
  49. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 6th ed.; John Wiley & Sons: Hoboken, NJ, USA, 2009. [Google Scholar]
  50. Yamada, M.; Hagiwara, H.; Torigoe, H.; Matsumoto, N.; Kojima, M.; Dahan, F.; Tuchagues, J.-P.; Re, N.; Iijima, S. A Variety of Spin-Crossover Behaviors Depending on the Counter Anion: Two-Dimensional Complexes Constructed by NH···Cl− Hydrogen Bonds, [FeIIH3LMe]Cl·X (X = PF6−, AsF6−, SbF6−, CF3SO3−; H3LMe = Tris[2-{[(2-methylimidazol-4-yl)methylidene]amino}ethyl]amine). Chem. Eur. J. 2006, 12, 4536–4549. [Google Scholar] [CrossRef] [PubMed]
  51. Spek, A.L. PLATON SQUEEZE: A tool for the calculation of the disordered solvent contribution to the calculated structure factors. Acta Crystallogr. Sect. C Struct. Chem. 2015, 71, 9–18. [Google Scholar] [CrossRef] [PubMed]
  52. Marchivie, M.; Guionneau, P.; Létard, J.-F.; Chasseau, D. Photo-induced spin-transition: The role of the iron(II) environment distortion. Acta Crystallogr. Sect. B 2005, 61, 25–28. [Google Scholar] [CrossRef] [PubMed]
  53. Llunell, M.; Casanova, D.; Cirera, J.; Alemany, P.; Alvarez, S. SHAPE2.1. Program for Calculating Continuous Shape Measures of Polyhedral Structures; Universitat de Barcelona: Barcelona, Spain, 2013. [Google Scholar]
  54. Guionneau, P.; Marchivie, M.; Bravic, G.; Létard, J.-F.; Chasseau, D. Structural aspects of spin crossover. Examples of the [FeIILn(NCS)2] complexes. Top. Curr. Chem. 2004, 234, 97–128. [Google Scholar]
  55. Kahn, O. Molecular Magnetism; VCH: Weinheim, Germany, 1993. [Google Scholar]
  56. Burla, M.C.; Caliandro, R.; Carrozzini, B.; Cascarano, G.L.; Cuocci, C.; Giacovazzo, C.; Mallamo, M.; Mazzone, A.; Polidori, G. Crystal structure determination and refinement via SIR2014. J. Appl. Cryst. 2015, 48, 306–309. [Google Scholar] [CrossRef]
  57. Sheldrick, G.M. Crystal structure refinement with SHELXL. Acta Cryst. 2015, C71, 3–8. [Google Scholar]
  58. Kabuto, C.; Akine, S.; Nemoto, T.; Kwon, E. Release of Software (Yadokari-XG 2009) for Crystal Structure Analyses. J. Cryst. Soc. Jpn. 2009, 51, 218–224. [Google Scholar] [CrossRef]
  59. Dolomanov, O.V.; Bourhis, L.J.; Gildea, R.J.; Howard, J.A.K.; Puschmann, H. OLEX2: A complete structure solution, refinement and analysis program. J. Appl. Cryst. 2009, 42, 339–341. [Google Scholar] [CrossRef]
Inorganics 05 00049 sch001 550
Scheme 1. Synthesis of the dinuclear double helicate complex-cation [FeII2(L2R)2]4+ (R = C2 = ethylene [34], R = C3 = propylene (this work)).
Scheme 1. Synthesis of the dinuclear double helicate complex-cation [FeII2(L2R)2]4+ (R = C2 = ethylene [34], R = C3 = propylene (this work)).
Inorganics 05 00049 sch001
Inorganics 05 00049 sch002 550
Scheme 2. Synthetic scheme of the ligand L2C2. Reagents and conditions: (1) 1,3-diaminopropane, MeOH, 1 h, 60 °C; 78%; (2) 1-PrOH, 16 h, 80 °C; 78%; (3) HCl (aq), 2 h, room temperature (RT); 86%; (4) 2-(2-aminoethyl)pyridine (2 equiv), MeOH, 1 h, RT.
Scheme 2. Synthetic scheme of the ligand L2C2. Reagents and conditions: (1) 1,3-diaminopropane, MeOH, 1 h, 60 °C; 78%; (2) 1-PrOH, 16 h, 80 °C; 78%; (3) HCl (aq), 2 h, room temperature (RT); 86%; (4) 2-(2-aminoethyl)pyridine (2 equiv), MeOH, 1 h, RT.
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Figure 1. Thermogravimetry and differential thermal analysis (TG/DTA) curves of 1·PF6 (a) and 1·AsF6 (b).
Figure 1. Thermogravimetry and differential thermal analysis (TG/DTA) curves of 1·PF6 (a) and 1·AsF6 (b).
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Figure 2. Temperature-dependent optical microscope images of grinding samples of 1·PF6 (a) and 1·AsF6 (b) deposited on a heating stage. Unless otherwise noted, after increasing the sample temperature at each target point, the sample was held for 5 min, and then an image was taken at each temperature.
Figure 2. Temperature-dependent optical microscope images of grinding samples of 1·PF6 (a) and 1·AsF6 (b) deposited on a heating stage. Unless otherwise noted, after increasing the sample temperature at each target point, the sample was held for 5 min, and then an image was taken at each temperature.
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Figure 3. ORTEP drawing of the dinuclear double helicate complex-cation [FeII2(L2C3)2]4+ of 1·AsF6 at 120 K with the atom numbering scheme except for carbon atoms, where the thermal ellipsoids are drawn with a 50% probability level. H atoms have been omitted for clarity. Symmetry operation: (i) –x, y, 3/2 − z.
Figure 3. ORTEP drawing of the dinuclear double helicate complex-cation [FeII2(L2C3)2]4+ of 1·AsF6 at 120 K with the atom numbering scheme except for carbon atoms, where the thermal ellipsoids are drawn with a 50% probability level. H atoms have been omitted for clarity. Symmetry operation: (i) –x, y, 3/2 − z.
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Figure 4. (a) Intermolecular interactions of 1·AsF6 at 120 K. Adjacent complex-cations [FeII2(L2C3)2]4+ with the same chirality are connected by intermolecular π–π interactions (green dotted line) to form the homochiral 1D chain structure along the b-axis. Symmetry operations: (i) −x, y, 3/2 − z; (ii) x, −1 + y, z; (iii) −x, −1 + y, 3/2 − z; (b) Packing diagram of 1·AsF6 at 120 K viewed along the ac plane. Δ–Δ-[FeII2(L2C3)2]4+ and Λ–Λ-[FeII2(L2C3)2]4+ enantiomers are represented by green and red colors, respectively. Cationic 1D chains with the opposite chirality running along the b-axis exist in a crystal lattice to give a heterochiral crystal. Each cationic chain is separated by the space-occupying two disordered AsF6− ions (blue and orange; only the major component is indicated) and solvent molecules such as 3H2O and one MeCN molecule (not indicated), which could not be sensibly modeled due to the strong disorder and regions including these solvent molecules being treated with the PLATON SQUEEZE program. H atoms have been omitted for clarity.
Figure 4. (a) Intermolecular interactions of 1·AsF6 at 120 K. Adjacent complex-cations [FeII2(L2C3)2]4+ with the same chirality are connected by intermolecular π–π interactions (green dotted line) to form the homochiral 1D chain structure along the b-axis. Symmetry operations: (i) −x, y, 3/2 − z; (ii) x, −1 + y, z; (iii) −x, −1 + y, 3/2 − z; (b) Packing diagram of 1·AsF6 at 120 K viewed along the ac plane. Δ–Δ-[FeII2(L2C3)2]4+ and Λ–Λ-[FeII2(L2C3)2]4+ enantiomers are represented by green and red colors, respectively. Cationic 1D chains with the opposite chirality running along the b-axis exist in a crystal lattice to give a heterochiral crystal. Each cationic chain is separated by the space-occupying two disordered AsF6− ions (blue and orange; only the major component is indicated) and solvent molecules such as 3H2O and one MeCN molecule (not indicated), which could not be sensibly modeled due to the strong disorder and regions including these solvent molecules being treated with the PLATON SQUEEZE program. H atoms have been omitted for clarity.
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Figure 5. The magnetic behavior of 1·AsF6 in the form of the χMT vs. T plots. 1·AsF6 was warmed from 300 to 498 K (filled triangles; red), and then cooled from 498 to 300 K (filled inverted triangles; blue) at a sweep rate of 0.5 K·min−1.
Figure 5. The magnetic behavior of 1·AsF6 in the form of the χMT vs. T plots. 1·AsF6 was warmed from 300 to 498 K (filled triangles; red), and then cooled from 498 to 300 K (filled inverted triangles; blue) at a sweep rate of 0.5 K·min−1.
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Figure 6. (a) Temperature dependence of the χMT product of 1·AsF6 in the heating (empty triangles) and cooling (empty inverted triangles) modes over three successive thermal cycles at a sweep rate of 0.5 K·min−1. Orange: first cycle; magenta: second cycle; olive: third cycle; (b) Powder X-ray diffraction (PXRD) patterns of 1·AsF6 at RT in different states. Black: simulated from the SQUEEZE-applied single crystal X-ray data at 120 K; red: as-synthesized 1·AsF6; orange: 1·AsF6 after the first thermal cycle of superconducting quantum interference device (SQUID) measurement; olive: 1·AsF6 after a third thermal cycle of SQUID measurement.
Figure 6. (a) Temperature dependence of the χMT product of 1·AsF6 in the heating (empty triangles) and cooling (empty inverted triangles) modes over three successive thermal cycles at a sweep rate of 0.5 K·min−1. Orange: first cycle; magenta: second cycle; olive: third cycle; (b) Powder X-ray diffraction (PXRD) patterns of 1·AsF6 at RT in different states. Black: simulated from the SQUEEZE-applied single crystal X-ray data at 120 K; red: as-synthesized 1·AsF6; orange: 1·AsF6 after the first thermal cycle of superconducting quantum interference device (SQUID) measurement; olive: 1·AsF6 after a third thermal cycle of SQUID measurement.
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Figure 7. Differential scanning calorimetry (DSC) curves of 1·AsF6 in the heating mode (a) and cooling mode (b) recorded over four successive thermal cycles at a sweep rate of 10 K·min−1, in the temperature range of 222–502 K. Orange: first cycle; magenta: second cycle; olive: third cycle; navy blue: fourth cycle.
Figure 7. Differential scanning calorimetry (DSC) curves of 1·AsF6 in the heating mode (a) and cooling mode (b) recorded over four successive thermal cycles at a sweep rate of 10 K·min−1, in the temperature range of 222–502 K. Orange: first cycle; magenta: second cycle; olive: third cycle; navy blue: fourth cycle.
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Table
Table 1. X-ray crystallographic data for 1·PF6 and 1·AsF6 at 120 K.
Table 1. X-ray crystallographic data for 1·PF6 and 1·AsF6 at 120 K.
[FeII2L2C32](PF6)4 1.5H2O·1.5MeCN (1·PF6) a[FeII2L2C32](AsF6)4·3H2O·MeCN (1·AsF6) a
FormulaC49H59.5N21.5O1.5P4F24Fe2C48H61N21O3As4F24Fe2
Formula weight1665.261847.55
Crystal systemmonoclinicmonoclinic
Space groupC2/c (No. 15)C2/c (No.15)
a/Å19.049(6)19.410(3)
b/Å19.056(5)19.034(3)
c/Å20.600(9)20.772(5)
β/deg.115.832(3)115.723(2)
V/Å36731(4)6914(2)
Z44
dcalcd./g·cm−31.6431.775
μ (Mo Kα)/mm−10.6492.441
R1 b (I > 2sigma(I))0.08790.0520
wR2 c (I > 2sigma(I))0.21410.1167
R1 b (all data)0.10540.0626
wR2 c (all data)0.22860.1236
u c0.07910.0425
v c27.413316.3374
S1.1421.112
CCDC number15441251544126
a The PLATON SQUEEZE program [51] was used to treat regions with highly disordered solvent molecules which could not be sensibly modeled in terms of atomic sites; b R1 = Σ||Fo| − |Fc||/Σ|Fo|; c wR2 = [Σw(|Fo|2 − |Fc|2)2/Σw|Fo2|2]1/2, w = 1/[σ2(|Fo|2) + (uP)2 + vP] where P = (|Fo|2 + 2|Fc|2)/3.
Table
Table 2. Coordination bond lengths, angles, and structural parameters for 1·PF6 and 1·AsF6 at 120 K. CShMs: continuous shape measures.
Table 2. Coordination bond lengths, angles, and structural parameters for 1·PF6 and 1·AsF6 at 120 K. CShMs: continuous shape measures.
Fe1 Site1·PF61·AsF6Fe2 Site1·PF61·AsF6
Fe1–N Bond Lengths (Å)Fe2–N Bond Lengths (Å)
Fe1–N11.998(4)2.007(3)Fe2–N62.033(4)2.007(3)
Fe1–N21.990(4)1.970(4)Fe2–N71.911(4)1.962(3)
Fe1–N31.931(4)1.954(3)Fe2–N81.957(4)1.945(3)
Fe1–N1 i1.998(4)2.007(3)Fe2–N6 i2.034(4)2.007(3)
Fe1–N2 i1.990(5)1.970(4)Fe2–N7 i1.911(4)1.962(3)
Fe1–N3 i1.931(4)1.954(3)Fe2–N8 i1.957(4)1.945(3)
Average Fe1–N1.9731.977Average Fe2–N1.9671.971
N–Fe1–N Bond Angles (°)N–Fe2–N Bond Angles (°)
N1–Fe1–N289.1(2)91.35(15)N6–Fe2–N793.38(17)92.63(12)
N1–Fe1–N3171.26(19)170.93(14)N6–Fe2–N8172.89(15)172.40(12)
N1–Fe1–N1 i91.4(2)92.67(18)N6–Fe2–N6 i93.9(2)92.05(17)
N1–Fe1–N2 i98.00(19)95.70(14)N6–Fe2–N7 i95.50(16)96.18(12)
N1–Fe1–N3 i92.58(16)91.47(12)N6–Fe2–N8 i89.72(17)91.84(12)
N2–Fe1–N382.65(18)80.20(13)N7–Fe2–N880.17(17)80.47(12)
N2–Fe1–N1 i98.00(19)95.69(15)N7–Fe2–N6 i95.50(16)96.17(12)
N2–Fe1–N2 i169.9(3)169.79(18)N7–Fe2–N7 i167.0(3)167.32(16)
N2–Fe1–N3 i89.86(17)92.27(13)N7–Fe2–N8 i90.38(16)90.16(12)
N3–Fe1–N1 i92.58(16)91.47(12)N8–Fe2–N6 i89.72(17)91.84(12)
N3–Fe1–N2 i89.85(17)92.27(13)N8–Fe2–N7 i90.38(16)90.16(12)
N3-Fe1–N3 i84.6(2)85.61(17)N8–Fe2–N8 i87.3(3)85.07(17)
N1 i–Fe1–N2 i89.1(2)91.36(15)N6 i–Fe2–N7 i93.38(17)92.63(12)
N1 i–Fe1–N3 i171.26(19)170.93(14)N6 i–Fe2–N8 i172.89(15)172.41(12)
N2 i–Fe1–N3 i82.65(18)80.20(14)N7 i–Fe2–N8 i80.17(17)80.47(12)
Σ (°) [54]44.848.2 45.347.7
Θ (°) [52]113.9120.1 106.9108.1
CShMs c [53]0.5940.616 0.6360.590
Octahedral volume (Å3)10.13210.183 10.02910.098
Symmetry operation: (i) −x, y, 3/2 – z; c The reference shape is the regular octahedron with center.
Table
Table 3. Intermolecular contacts (Å) of π–π interaction for 1·PF6 and 1·AsF6 at 120 K.
Table 3. Intermolecular contacts (Å) of π–π interaction for 1·PF6 and 1·AsF6 at 120 K.
1·PF61·AsF6
Cg1 a···Cg2 b,ii4.139(4)4.123(3)
C3···C14 ii3.582(13)3.610(9)
C3···C15 ii3.403(12)3.423(8)
C4···C14 ii3.432(11)3.421(7)
C4···C15 ii3.711(11)3.703(6)
a Cg1 = centroid of the N1–C1–C2–C3–C4–C5 ring; b Cg2 = centroid of the N6–C12–C13–C14–C15–C16 ring. Symmetry operation: (ii) x, 1 + y, z for 1·PF6 and x, −1 + y, z for 1·AsF6.

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Hora, S.; Hagiwara, H. High-Temperature Wide Thermal Hysteresis of an Iron(II) Dinuclear Double Helicate. Inorganics 2017, 5, 49. https://doi.org/10.3390/inorganics5030049

AMA Style

Hora S, Hagiwara H. High-Temperature Wide Thermal Hysteresis of an Iron(II) Dinuclear Double Helicate. Inorganics. 2017; 5(3):49. https://doi.org/10.3390/inorganics5030049

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Hora, Shiori, and Hiroaki Hagiwara. 2017. "High-Temperature Wide Thermal Hysteresis of an Iron(II) Dinuclear Double Helicate" Inorganics 5, no. 3: 49. https://doi.org/10.3390/inorganics5030049

APA Style

Hora, S., & Hagiwara, H. (2017). High-Temperature Wide Thermal Hysteresis of an Iron(II) Dinuclear Double Helicate. Inorganics, 5(3), 49. https://doi.org/10.3390/inorganics5030049

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