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Magnetochemistry, Volume 8, Issue 5

2022 May - 12 articles

Cover Story: Several experimental investigations on spin-crossover (SCO) materials conducted by Mössbauer spectroscopy, x-ray diffraction, and Brillouin scattering have shown that the Debye temperature in the low-spin (LS) state is higher than that of the high-spin (HS). These results suggest stronger (resp. weaker) interactions between LS-LS (resp. HS-HS) sites due to the volume contraction accompanying the spin transition from HS to LS. The present theoretical contribution is based on an Ising-like description of this phenomenon accounting for spin-state-dependent interaction parameters, which are denoted as JHS-HS, JHS-LS, and JLS-LS. Usually, this quantity is considered to be constant in HS and LS. We analyze the effects of this approach on the equilibrium temperature as well as on the thermal hysteresis width’s, which is defined as the difference between the switching temperatures Tup and Tdown. View this paper
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Articles (12)

  • Article
  • Open Access
6 Citations
5,109 Views
15 Pages

For single-molecule toroics (SMTs) based on noncollinear Ising spins, intramolecular magnetic dipole–dipole coupling favours a head-to-tail vortex arrangement of the semi-classical magnetic moments associated with a toroidal ground state. Howev...

  • Article
  • Open Access
10 Citations
4,712 Views
13 Pages

During the explosion of energetic materials, electromagnetic interference is generated, which can affect the normal operation of surrounding electronic equipment. Therefore, an electromagnetic radiation measurement device based on a short-wave omnidi...

  • Article
  • Open Access
2 Citations
4,445 Views
8 Pages

Anomalous Hall Effect and Magneto-Optic Kerr Effect in Pt/Co/Pt Heterostructure

  • Yiming Sun,
  • Liangwei Wu,
  • Mengmeng Yang,
  • Mengjia Xia,
  • Wei Gao,
  • Dongxiang Luo,
  • Nengjie Huo and
  • Jingbo Li

Magnetic multilayer with large perpendicular magnetic anisotropy (PMA) has attracted sustained interest owing to its importance to fundamental physics and applications. In this work, the high quality of Pt/Co/Pt heterostructures with large PMA was su...

  • Article
  • Open Access
4 Citations
3,805 Views
9 Pages

Competition of Magnetic Anisotropies in Permalloy Antidot Lattices

  • Jose M. Porro,
  • Aritz Villar,
  • Carolina Redondo,
  • Natalia A. Río-López,
  • Andoni Lasheras,
  • Daniel Salazar,
  • Rafael Morales and
  • Eduardo Fernández-Martín

Antidot lattices made of magnetic thin films are good candidates to be employed in future magnetic recording media. In this manuscript we present a study on the effect of shape and field-induced magnetic anisotropies on the magnetization reversal of...

  • Article
  • Open Access
39 Citations
6,243 Views
16 Pages

High Drug Capacity Doxorubicin-Loaded Iron Oxide Nanocomposites for Cancer Therapy

  • Ekaterina Kovrigina,
  • Alexey Chubarov and
  • Elena Dmitrienko

Magnetic nanoparticles (MNPs) have great potential in the drug delivery area. Iron oxide (Fe3O4) MNPs have demonstrated a promising effect due to their ferrimagnetic properties, large surface area, stability, low cost, easy synthesis, and functionali...

  • Article
  • Open Access
18 Citations
6,574 Views
11 Pages

Water electrolysis is one of the most common methods to produce hydrogen gas with high purity, but its application is limited due to its low energy efficiency. It has been proved that an external magnetic field can reduce energy consumption and incre...

  • Review
  • Open Access
9 Citations
4,457 Views
35 Pages

This review summarizes the data on the stereochemical structure of functionalized azoles (pyrazoles, imidazoles, triazoles, thiazoles, and benzazoles) and related compounds obtained by multipulse and multinuclear 1H, 13C, 15N NMR spectroscopy and qua...

  • Article
  • Open Access
20 Citations
3,371 Views
13 Pages

Structure, Spectra, Morphology, and Magnetic Properties of Nb5+ Ion-Substituted Sr Hexaferrites

  • Wenhao Zhang,
  • Pengwei Li,
  • Yonglun Wang,
  • Jing Guo,
  • Jie Li,
  • Shuo Shan,
  • Saisai Ma and
  • Xing Suo

SrFe12−xNbxO19 (x = 0.00–0.15) was here synthesized by a conventional solid-state reaction method. Thermogravimetry and differential scanning calorimetry curves revealed the sample reactions at four temperature ranges, and the optimal rea...

  • Review
  • Open Access
31 Citations
8,608 Views
72 Pages

Quantum chemical methods for the calculation of indirect NMR spin–spin coupling constants and chemical shifts are always in progress. They never stay the same due to permanently developing computational facilities, which open new perspectives a...

  • Article
  • Open Access
6 Citations
2,885 Views
13 Pages

A Generalized Ising-like Model for Spin Crossover Nanoparticles

  • Catherine Cazelles,
  • Jorge Linares,
  • Pierre-Richard Dahoo and
  • Kamel Boukheddaden

Cooperative spin crossover (SCO) materials exhibit first-order phase transitions in the solid state, between the high-spin (HS) and low-spin (LS) states. Elastic long-range interactions are the basic mechanism for this particular behavior and are des...

  • Article
  • Open Access
3 Citations
2,683 Views
14 Pages

Heterometallic Chain Compounds of Tetrakis(µ-carboxylato)diruthenium and Tetracyanidoaurate

  • Masahiro Mikuriya,
  • Yusuke Tanaka,
  • Daisuke Yoshioka,
  • Motohiro Tsuboi,
  • Hidekazu Tanaka and
  • Makoto Handa

Heterometallic complexes of tetrakis(µ-carboxylato)diruthenium(II,III) with tetracyanidoaurate(III) [Ru2(RCOO)4Au(CN)4]n (R = CH3 (1), C2H5 (2), i-C3H7 (3), and t-C4H9 (4)) were synthesized and characterized by C,H,N-elemental analysis and infr...

  • Article
  • Open Access
7 Citations
4,732 Views
15 Pages

Extending NMR Quantum Computation Systems by Employing Compounds with Several Heavy Metals as Qubits

  • Jéssica Boreli dos Reis Lino,
  • Mateus Aquino Gonçalves,
  • Stephan P. A. Sauer and
  • Teodorico Castro Ramalho

Nuclear magnetic resonance (NMR) is a spectroscopic method that can be applied to several areas. Currently, this technique is also being used as an experimental quantum simulator, where nuclear spins are employed as quantum bits or qubits. The presen...

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Magnetochemistry - ISSN 2312-7481