Designing a Stable Alloy Interlayer on Li Metal Anodes for Fast Charging of All-Solid-State Li Metal Batteries
Abstract
:1. Introduction
2. Materials and Methods
2.1. Sputter Deposition of Tin on Li Metal Surface
2.2. Plasma Cleaning of Sn-Coated Li Metal Anodes
2.3. Deposition of a Polymer/Ceramic Layer on Sn-Coated Li Metal Anodes
2.4. Preparation of LiFePO4 Electrodes
2.5. Preparation of the Solid Polymer Electrolyte
2.6. Assembling of Pouch Cells and Electrochemical Tests
2.7. Characterizations
3. Results and Discussion
3.1. Formation of an Alloy Layer on Li Surface during Deposition of Sn
3.2. Evolution of the Deposited Layer during Battery Assembly and Cycling
3.2.1. LFP/SPE/Li Battery Stack after Assembling
3.2.2. LFP/SPE/Li Battery Stack after One C/40 Charge
3.2.3. LFP/SPE/Li Battery Stack after Long-Cycling at 1C in Charge
3.3. Overcoating of a Polymer/Ceramic Layer on the Surface of the Li–Sn Foil
3.4. Effect of Plasma Cleaning of Sn Surface
4. Conclusions
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- The process must be easily transposable at the industrial level, fast, clean, reproducible, cheap (Sn metal), and performed in a well-controlled environment.
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- Ultra-thin Li metal anode can also be modified with this technique.
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- The layer must be dense and thin to not impact the energy density of the electrochemical system.
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- The in-situ generation of a 3D Li-rich alloy favors the fast Li+ ion transfer at the SPE/Sn interface [40].
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- The chemical and electrochemical stabilities of the artificial layer permit to cycle the battery at high C-rates for several hundreds of cycles.
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- The higher electrochemical potential of the alloy layer in comparison to Li metal reduces the reactivity with the electrolyte [41].
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- Post-modifications can be applied on the alloy layer to respond to various applications (e.g., reduce the SPE thickness by deposing a thin ceramic-rich polymer layer, overcoating of a SPE, deposition of a non-electronic-conductive layer, etc.).
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- The electrodeposition of Li+ ions must occur uniformly underneath the artificial layer and on the Li metal side.
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Thickness of Sn Deposited (nm) | Thickness of LixSny Layer Measured (nm) | Condition of Assembling/Cycling | Expansion (%) |
---|---|---|---|
400 | 1.4–1.5 | No assembling | Up to 380 |
600 | 1.8 | No assembling | 300 |
600 | 1.8 | After cell assembling | 300 |
600 | 2.0 | After one charge at C/40 | 330 |
600 | 2.3 | After 225 cycles at 1C–C/2 | 380 |
- | - | - | 380 1 |
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Delaporte, N.; Perea, A.; Collin-Martin, S.; Léonard, M.; Matton, J.; Demers, H.; Clément, D.; Gariépy, V.; Zhu, W. Designing a Stable Alloy Interlayer on Li Metal Anodes for Fast Charging of All-Solid-State Li Metal Batteries. Batteries 2024, 10, 253. https://doi.org/10.3390/batteries10070253
Delaporte N, Perea A, Collin-Martin S, Léonard M, Matton J, Demers H, Clément D, Gariépy V, Zhu W. Designing a Stable Alloy Interlayer on Li Metal Anodes for Fast Charging of All-Solid-State Li Metal Batteries. Batteries. 2024; 10(7):253. https://doi.org/10.3390/batteries10070253
Chicago/Turabian StyleDelaporte, Nicolas, Alexis Perea, Steve Collin-Martin, Mireille Léonard, Julie Matton, Hendrix Demers, Daniel Clément, Vincent Gariépy, and Wen Zhu. 2024. "Designing a Stable Alloy Interlayer on Li Metal Anodes for Fast Charging of All-Solid-State Li Metal Batteries" Batteries 10, no. 7: 253. https://doi.org/10.3390/batteries10070253
APA StyleDelaporte, N., Perea, A., Collin-Martin, S., Léonard, M., Matton, J., Demers, H., Clément, D., Gariépy, V., & Zhu, W. (2024). Designing a Stable Alloy Interlayer on Li Metal Anodes for Fast Charging of All-Solid-State Li Metal Batteries. Batteries, 10(7), 253. https://doi.org/10.3390/batteries10070253