Facile Fabrication of Magnetic Poly(Vinyl Alcohol)/Activated Carbon Composite Gel for Adsorptive Removal of Dyes
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Characterization
2.3. Preparation of mPVA/AC CG
2.4. Adsorption Experiments
2.5. Reusability Evaluation
3. Results and Discussions
3.1. Preparation and Characterization of mPVA/AC CG
3.2. Adsorption Performance of mPVA/AC CG
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Dye | Chemical Structure | λmax (nm) | Molecular Weight (g mol−1) |
---|---|---|---|
MB | | 662 | 319.85 |
MO | | 463 | 327.33 |
Pseudo-First-Order | Pseudo-Second-Order | ||||||
---|---|---|---|---|---|---|---|
ln(Qe − Qt) = lnQe − k1t | t/Qt = 1/k2Q2e + t/Qe | ||||||
Qe-exp (mg/g) | Qe-cal (mg/g) | k1 (min−1) | R2 | Qe-cal (mg/g) | k2 (mg−1 min−1) | R2 | |
MB | 24.34 ± 0.62 | 29.02 ± 0.15 | 0.028 ± 0.003 | 0.972 | 25.80 ± 0.94 | 0.0017 ± 0.0001 | 0.999 |
MO | 20.55 ± 0.39 | 16.65 ± 0.13 | 0.012 ± 0.002 | 0.990 | 22.05 ± 0.75 | 0.0016 ± 0.0001 | 0.994 |
Isotherm Model | Parameter | MB | MO |
---|---|---|---|
Langmuir: Ce/Qe = Ce/Qm + 1/KLQm | Qm (mg/g) | 173.91 ± 1.6 | 146.63 ± 1.3 |
KL (L/mg) | 0.018 ± 0.002 | 0.004 ± 0.001 | |
R2 | 0.992 | 0.990 | |
Freundlich: lnQe = lnKF + bFlnCe | KF (mg/g) | 12.93 ± 0.21 | 3.065 ± 0.038 |
bF | 0.370 ± 0.031 | 0.511 ± 0.022 | |
R2 | 0.947 | 0.989 |
Dye | Adsorbent | Qmax (mg/g) | Reference |
---|---|---|---|
MB | Magnetic GO | 64.23 | 33 |
MB | Magnetic carbon nanotube | 15.74 | 34 |
MB | Magnetic rectorite/Fe3O4 composites | 60.24 | 35 |
MB | Magentic γ-Fe2O3@GL | 69.93–91.74 | 36 |
MB | Magnetic GO-Fe3O4 hybrid | 167.3 | 37 |
MB | mPVA/AC CG | 173.91 | This study |
MO | Magnetic lignin-based carbon nanoparticles | 113.00 | 38 |
MO | Magnetic LDH@Fe3O4/PVA composites | 19.59 | 39 |
MO | Chitosan modified magnetic kaolin | 349.70 | 40 |
MO | mPVA/AC CG | 146.63 | This study |
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Wen, T.; Huang, B.; Zhou, L. Facile Fabrication of Magnetic Poly(Vinyl Alcohol)/Activated Carbon Composite Gel for Adsorptive Removal of Dyes. J. Compos. Sci. 2022, 6, 55. https://doi.org/10.3390/jcs6020055
Wen T, Huang B, Zhou L. Facile Fabrication of Magnetic Poly(Vinyl Alcohol)/Activated Carbon Composite Gel for Adsorptive Removal of Dyes. Journal of Composites Science. 2022; 6(2):55. https://doi.org/10.3390/jcs6020055
Chicago/Turabian StyleWen, Tao, Baotao Huang, and Li Zhou. 2022. "Facile Fabrication of Magnetic Poly(Vinyl Alcohol)/Activated Carbon Composite Gel for Adsorptive Removal of Dyes" Journal of Composites Science 6, no. 2: 55. https://doi.org/10.3390/jcs6020055