Hybrid Materials for Energy Storage and Conversion

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Materials for Energy Applications".

Deadline for manuscript submissions: 10 June 2025 | Viewed by 2200

Special Issue Editors


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Guest Editor
School of Mechanical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea
Interests: photocatalysts; photoelectrochemical water splitting; graphitic carbon nitride; kinetics; nickel; electrochemical impedance spectroscopy; photoelectrodes; photoelectrochemical activity
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Guest Editor
Department of Physics, Sri Ramaswamy Memorial Institute of Science and Technology, Ramapuram, Chennai 600089, India
Interests: thin-film solar cell; dye degradation; photocatalysts; photoelectrochemical water splitting; photoelectrodes; photoelectrochemical activity

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Guest Editor
Department of Physics, Marri Laxman Reddy Institute of Technology and Management, Dundigal, Hyderabad Telangana 500043, India
Interests: band engineering; surface modification; composite materials; electrode materials; supercapacitors

Special Issue Information

Dear Colleagues,

Currently, the eco-friendly production and storage of energy play a vital role in protecting the environment and controlling climatic conditions, which oxide-based hybrid nanostructures show great potential for.  Hence, through this Special Issue, the role of hybrid structures in the production and storage of energy can be elucidated by focusing on various affecting factors, like synthesis techniques, Fermi-level and band engineering, hybrid defects, optical capability, kinetics, electrolyte pH, temperature, and interface migrations.

Dr. I. Neelakanta Reddy
Dr. Moorthy Dhanasekar
Dr. Mallikarjuna Koduru
Guest Editors

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Keywords

  • hybrid structure
  • materials engineering
  • pH
  • electrochemical 
  • energy storage

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Published Papers (2 papers)

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Research

14 pages, 4227 KiB  
Article
Boosted Electrochemical Activity with SnO2 Nanostructures Anchored on α-Fe2O3 for Improved Charge Transfer and Current Density
by Itheereddi Neelakanta Reddy, Bhargav Akkinepally, Jaesool Shim and Cheolho Bai
Crystals 2024, 14(8), 734; https://doi.org/10.3390/cryst14080734 - 18 Aug 2024
Viewed by 830
Abstract
This study presents a straightforward and cost-effective method to enhance the photoelectrochemical (PEC) water-splitting performance of α-Fe2O3 (F), SnO2 (S), and α-Fe2O3 decorated with SnO2 quantum dots (FS) photoanodes in a NaOH electrolyte. The FS [...] Read more.
This study presents a straightforward and cost-effective method to enhance the photoelectrochemical (PEC) water-splitting performance of α-Fe2O3 (F), SnO2 (S), and α-Fe2O3 decorated with SnO2 quantum dots (FS) photoanodes in a NaOH electrolyte. The FS electrode demonstrated a notable improvement in PEC efficiency within the electrolyte. In particular, the generated charges of the FS anode in the NaOH electrolyte reached approximately 12.01 mA cm−2 under illumination, indicating that the developed heterostructures effectively enhanced kinetics, leading to improved separation of induced carrier pairs. This active carrier-pair separation mechanism contributed considerably to the increased PEC activity in the 0.1 M NaOH electrolyte. The reduction in the bandgap of FS increased its absorption capability in visible light, which further enhanced the current density. Furthermore, the reduction in electrolyte resistance (9.71 Ω), internal resistance (20.19 Ω), charge transfer resistance (3.21 kΩ), Tafel slope (45.5 mV dec-1), limiting current density (−2.09 mA cm−2), and exchange current density (−3.68 mA cm−2) under illumination at the interface enhanced the charge density of FS. Further, a strong interaction among photoanode nanostructures significantly enhances PEC activity by improving efficient charge separation and transport, reducing recombination rates, and enabling quicker movement of charge carriers to the electrode/electrolyte interface. Thus, this study provides an effective approach to increasing the PEC activity of heterostructures. Full article
(This article belongs to the Special Issue Hybrid Materials for Energy Storage and Conversion)
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12 pages, 2750 KiB  
Article
Mechanically Mixed Thermally Expanded Graphite/Cobalt(II) Perrhenate—Co(ReO4)2—As Electrodes in Hybrid Symmetric Supercapacitors
by Mateusz Ciszewski, Karolina Pianowska, Joanna Malarz, Katarzyna Leszczyńska-Sejda and Lukasz Hawelek
Crystals 2024, 14(7), 627; https://doi.org/10.3390/cryst14070627 - 8 Jul 2024
Viewed by 790
Abstract
A mechanically homogenized composite of expanded graphite and cobalt(II) perrhenate has been described. Cobalt(II) perrhenate was obtained in a reaction of perrhenic acid with cobalt(II) nitrate. A simple mortar homogenization method was used to enhance the intercalation of cobalt species within the carbon [...] Read more.
A mechanically homogenized composite of expanded graphite and cobalt(II) perrhenate has been described. Cobalt(II) perrhenate was obtained in a reaction of perrhenic acid with cobalt(II) nitrate. A simple mortar homogenization method was used to enhance the intercalation of cobalt species within the carbon matrix. The specific capacitance of the composite was enhanced by 50% (to 78 F/g) in comparison to bare expanded graphite (52 F/g). The electrochemical characteristics were significantly improved, including better cyclability (7% capacitance loss), a lower resistance of the electrode material, and a lower iR drop, with respect to expanded graphite without cobalt(II) perrhenate active species. Expanded graphite, with its unique specific surface area and pore size diameter, was proved to be a potential and cheap carbon support. Full article
(This article belongs to the Special Issue Hybrid Materials for Energy Storage and Conversion)
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