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Crystals
Special Issues
Emerging Applications of Ferroelectrics in Nanoelectronics and Renewable Energy
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Emerging Applications of Ferroelectrics in Nanoelectronics and Renewable Energy

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Materials for Energy Applications".

Deadline for manuscript submissions: closed (15 October 2024) | Viewed by 3040

Special Issue Editors

Dr. Dawei Zhang

E-Mail Website
Guest Editor
School of Materials Science and Engineering, University of New South Wales, Sydney, NSW 2052, Australia
Interests: multiferroic materials; scanning probe microscopy
Special Issues, Collections and Topics in MDPI journals
Dr. Wenping Geng

E-Mail Website
Guest Editor
Science and Technology on Electronic Test and Measurement Laboratory, North University of China, Taiyuan 030051, China
Interests: ferroelectrics; piezoelectrics; domain wall nanoelectronics
Dr. Ran Su

E-Mail Website
Guest Editor
Hebei Key Laboratory of Photoelectric Control on Surface and Interface, College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, China
Interests: nanoferroelectric materials; piezocatalysis
Special Issues, Collections and Topics in MDPI journals
Dr. Ying Pan

E-Mail Website
Guest Editor
Department of Chemistry, University of Paderborn, 33098 Paderborn, Germany
Interests: electrocatalysis; piezocatalysis; photocatalysis; carbon materials; transition metal-based catalysis‬‬‬‬‬
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Ferroelectric materials, characterized by electrically switchable polarization, have found broad and mature applications in conventional transducers, actuators, and sensors in modern society. Recently, novel ferroelectric materials, made available by advanced synthesis techniques such as freestanding epitaxial thin films, nanometer/sub-nanometer nanoparticles/nanowires, organic ferroelectrics, and 2D van der Waals (vdW) ferroelectrics, have found applications in low-energy electronics and renewable energy. For example, based on the atomic thicknesses and complementary metal-oxide-semiconductor (CMOS) compatibility of 2D vdW ferroelectrics, ferroelectric materials can be used for post-Moore’s law nanoelectronics, including beyond-Boltzmann transistors, nonvolatile memories, and photoelectronic devices. Based on the polymer-like flexibility of ferroelectric nanowires, nanoferroic materials have found new applications in piezocatalysis for water splitting.

It is clear that the future holds great promise for the use of ferroelectric materials in novel applications. This Special Issue aims to showcase the latest advancements in ferroelectric materials and their diverse applications in various fields. We welcome contributions related to the synthesis and characterization of novel ferroelectrics, theoretical studies exploring new physics and functionalities, and nanoelectronic device developments involving vdW ferroelectrics.

Dr. Dawei Zhang
Dr. Wenping Geng
Dr. Ran Su
Dr. Ying Pan
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Crystals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2100 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • ferroelectrics
  • nanoferroelectric materials
  • nanoelectronics
  • catalysis

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Published Papers (3 papers)

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Research

11 pages, 12136 KiB  
Article
Solvent-Dependent Triboelectric Output Performance of Poly(vinylidene fluoride–trifluoroethylene–chlorofluoroethylene) Terpolymer
by Ying Chieh Hu, Hyun Soo Ahn, Joo Hyeong Lee, Kyung Hoon Kim, Jong Hun Kim and Jong Hoon Jung
Crystals 2024, 14(7), 664; https://doi.org/10.3390/cryst14070664 - 19 Jul 2024
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Abstract
The poly (vinylidene fluoride–trifluoroethylene–chlorofluoroethylene) P(VDF-TrFE-CFE) terpolymer has been identified as a promising candidate for the effective conversion of low-frequency mechanical vibrations into electricity. In this study, we provide a comprehensive and systematic investigation of the solvent-dependent mechanical, microstructural, electrical, frictional properties and triboelectric [...] Read more.
The poly (vinylidene fluoride–trifluoroethylene–chlorofluoroethylene) P(VDF-TrFE-CFE) terpolymer has been identified as a promising candidate for the effective conversion of low-frequency mechanical vibrations into electricity. In this study, we provide a comprehensive and systematic investigation of the solvent-dependent mechanical, microstructural, electrical, frictional properties and triboelectric output performance of a relaxor ferroelectric P(VDF-TrFE-CFE) terpolymer. The P(VDF-TrFE-CFE) terpolymer films obtained from high dipole moment solvents have a longer rod-shaped grain than those from low dipole moment solvents. The crystallinity, Young’s modulus and dielectric constant of P(VDF-TrFE-CFE) terpolymer become larger as the dipole moment of solvents increases, while the remnant polarization remains almost the same. The P(VDF-TrFE-CFE) terpolymer film obtained from the highest dipole moment solvent generates almost 1.55 times larger triboelectric charge than that obtained from the lowest moment. We attributed this large difference to the greatly enhanced lateral friction of terpolymer film obtained from high dipole moment solvents. Full article
(This article belongs to the Special Issue Emerging Applications of Ferroelectrics in Nanoelectronics and Renewable Energy)
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11 pages, 4700 KiB  
Article
Ferroelectric Domain Intrinsic Radiation Resistance of Lithium Niobate Ferroelectric Single−Crystal Film
by Jiahe Li, Jinlong He, Liya Niu, Hao Lu, Xiaojun Qiao, Bo Zhong, Mingzhu Xun, Xiujian Chou and Wenping Geng
Crystals 2024, 14(6), 537; https://doi.org/10.3390/cryst14060537 - 7 Jun 2024
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Abstract
The study of the properties of ferroelectric materials against irradiation has a long history. However, anti−irradiation research on the ferroelectric domain has not been carried out. In this paper, the irradiation of switched domain structure is innovatively proposed. The switched domain of 700 [...] Read more.
The study of the properties of ferroelectric materials against irradiation has a long history. However, anti−irradiation research on the ferroelectric domain has not been carried out. In this paper, the irradiation of switched domain structure is innovatively proposed. The switched domain of 700 nm lithium niobate (LiNbO3, LN) thin film remains stable after gamma irradiation from 1 krad to 10 Mrad, which was prepared by piezoresponse force microscopy (PFM). In addition, the changing law of domain wall resistivity is explored through different sample voltages, and it is verified that the irradiated domain wall conductivity is still larger than the domain. This domain wall current (DWC) property can be applied to storage, logic, sensing, and other devices. Based on these, a ferroelectric domain irradiation resistance model is established, which explains the reason at an atomic level. The results open a possibility for exploiting ferroelectric materials as the foundation in the application of space and nuclear fields. Full article
(This article belongs to the Special Issue Emerging Applications of Ferroelectrics in Nanoelectronics and Renewable Energy)
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9 pages, 1931 KiB  
Article
Influence of Stress on the Chiral Polarization and Elastrocaloric Effect in BaTiO3 with 180° Domain Structure
by Yuanyuan Shi and Bo Li
Crystals 2024, 14(6), 511; https://doi.org/10.3390/cryst14060511 - 28 May 2024
Viewed by 636
Abstract
The polarization and elastrocaloric effect of chiral barium titanate (BaTiO3) with an Ising–Bloch-type domain wall under stress was investigated using the Landau–Ginzburg–Devonshire (LGD) theory. It has been shown that tensile stresses increase the magnitude of the Ising polarization component in barium [...] Read more.
The polarization and elastrocaloric effect of chiral barium titanate (BaTiO3) with an Ising–Bloch-type domain wall under stress was investigated using the Landau–Ginzburg–Devonshire (LGD) theory. It has been shown that tensile stresses increase the magnitude of the Ising polarization component in barium titanate, together with a decrease in the domain wall width. Compressive stresses cause a reduction in the Ising polarization component and an increase in the domain width. Under compressive stress, barium titanate exhibits a negative elastrocaloric effect and temperature changes with increasing stress, while BaTiO3 exhibits a positive elastrocaloric effect under tensile stress. Bloch polarization shows angle-dependent polarization under external force, but the temperature change from the elastrocaloric effect is smaller than that of Ising polarization under stress. This work contributes to the understanding of polarization evolution under tension in ferroelectrics with chiral structure. Full article
(This article belongs to the Special Issue Emerging Applications of Ferroelectrics in Nanoelectronics and Renewable Energy)
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