Recent Advances in Oil Structuring

A special issue of Gels (ISSN 2310-2861). This special issue belongs to the section "Gel Applications".

Deadline for manuscript submissions: closed (30 June 2024) | Viewed by 11925

Special Issue Editors


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Guest Editor
Department of Management and Product Quality, Faculty of Chemical Engineering and Commodity Science, Kazimierz Pulaski University of Technology and Humanities, 26-600 Radom, Poland
Interests: modification of fats; oleogels; emulsions; enzymatic interesterification; structuring substances

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Guest Editor
Institute of Food Sciences, Department of Food Technology and Assessment, Division of Fat and Oils and Food Concentrates Technology, Warsaw University of Life Sciences-SGGW (WULS-SGGW), Nowoursynowska St. 159c, 02-776 Warsaw, Poland
Interests: new directions for the use of food industry waste products; food packaging; oleo gelation; structuring substances; fats
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Special Issue Information

Dear Colleagues,

Nowadays, there are increasing demands regarding the quality of fats. Fats obtained directly from plant and animal raw materials do not always meet the expectations of technologists, nutritionists or consumers. For this reason, they are subjected to numerous modifications that make it possible to obtain a product with the desired features and properties and that also meet consumers’ expectations with regard to sensory properties. New fat products are characterized by specific parameters, i.e., adequate plasticity, melting point, composition, oxidative stability, or improved sensory characteristics. Modifications may also contribute to the use of less attractive fats, such as waste fats. Thanks to the use of these types of processes, fats are of a higher quality, have a longer shelf life and often meet the expectations set by consumers.

The most common processes enabling fat modification are: fractionation, blending, hydrogenation interesterification and oleogelation. Nowadays, much interest is placed on the methods that are compatible with sustainable development. One such method is enzymatic interesterification. This method makes it possible to obtain more and more advanced products thanks to the specificity of lipases, which are used as catalysts in the reaction. Oleogelation, on the other hand, is a method which enables the structuring of oil, e.g., vegetable oil, by adding structure-forming substances, thanks to which the new fat changes physical characteristics and can be applied in new ways in industry. Gelation techniques have been used for oil structuring reasons, allowing for the development of diverse oleogel or organogel systems, with a multitude of colloidal architectures (e.g., crystalline networks, self-assembled conformations or polymeric complexes).

Both of these methods provide a new structured fat alternative for the hydrogenation process. Taking into account nutritional properties, the fats obtained by these methods are free of trans isomers.

Prof. Dr. Malgorzata Kowalska
Prof. Dr. Anna Żbikowska
Guest Editors

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Keywords

  • oleogelation
  • enzymatic interesterification
  • structuring substances
  • lipases
  • nutritional properties modification of fats

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Published Papers (4 papers)

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Research

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17 pages, 1060 KiB  
Article
Candelilla Wax and Glycerol Monostearate-Based Oleogels as Animal Fat Substitutes in Bologna Sausages
by Anda Elena Tanislav, Anca Alexandra Cornea, Eugen Dan Radu, Dorin Țibulcă, Vlad Mureșan and Elena Mudura
Gels 2024, 10(6), 399; https://doi.org/10.3390/gels10060399 - 13 Jun 2024
Cited by 1 | Viewed by 1372
Abstract
The aim of this study was to produce Bologna sausages rich in unsaturated fatty acids and to evaluate this replacement on the structural characteristics. For the purpose of a comparative analysis, three different types of sausages were produced, distinct only in the type [...] Read more.
The aim of this study was to produce Bologna sausages rich in unsaturated fatty acids and to evaluate this replacement on the structural characteristics. For the purpose of a comparative analysis, three different types of sausages were produced, distinct only in the type of fat used: I. sausages obtained with pork backfat (PBF), II. sausages produced with oleogel formed from refined sunflower oil and glycerol monostearate (GM_OG), and III. with candelilla wax oleogel (CW_OG). The meat composition was also analyzed to better understand the process in the dynamics and the finished products were analyzed both uncooked and cooked. The enhanced oil-binding capacity of oleogels suggests their potential value as substitutes for saturated fats (>99%). In terms of meat composition textural analysis, the highest hardness value was registered for PBF_C of 25.23 N, followed by a CW_OG_C of 13.08 N and a GM_OG_C of 12.27 N. However, adhesiveness, cohesiveness, springiness index, and gumminess showed similar values between samples. Reformulation of products with oleogels as a fat source abundant in mono- and polyunsaturated fatty acids resulted in uncooked products exhibiting reduced hardness values of 49.01 N (CW_OG_US) and 40.51 N (GM_OG_US), compared to 65.03 N (PBF_US). Color results of the cross-section color can indicate the potential for consumer acceptance due to the reduced color differences between the conventional and oleogel samples. Full article
(This article belongs to the Special Issue Recent Advances in Oil Structuring)
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15 pages, 773 KiB  
Article
Exploring the Antimicrobial Potential and Stability of Black Soldier Fly (Hermentia illucens) Larvae Fat for Enhanced Food Shelf-Life
by Aelita Zabulionė, Alvija Šalaševičienė, Natalja Makštutienė and Antanas Šarkinas
Gels 2023, 9(10), 793; https://doi.org/10.3390/gels9100793 - 2 Oct 2023
Cited by 2 | Viewed by 2384
Abstract
The larvae of the Black Soldier Fly (BSF, Hermetia illucens) have been introduced as one of the tools to create a circular economy model, which will be used in areas such as waste management and the treatment of industrial by-products to produce [...] Read more.
The larvae of the Black Soldier Fly (BSF, Hermetia illucens) have been introduced as one of the tools to create a circular economy model, which will be used in areas such as waste management and the treatment of industrial by-products to produce high-added-value food grade ingredients. The main aim of this research was to investigate the fat composition and antimicrobial activity against food pathogens and spoilers of Black Soldier Fly larvae. The research revealed that the Black Soldier Fly larvae fats are predominantly lauric fatty (40.93%), which are followed by palmitic, oleic, myristic, linolenic and palmitoleic fatty acids, accounting for 19.11, 17.34, 6.49, 8.79 and 3.89% of the fatty acid content, respectively. The investigation of the fats showed stability through a one-year monitoring period with no indication of chemical or microbiological spoilage. Different fat fractions were tested for antimicrobial activity, which showed efficiency against Candida albicans (the inhibition zone varied from 10.5 to 12.5 mm), Bacillus subtilis (from 12.5 to 16.5 mm), Staphylococcus aureus (12.5 mm) and Escherichia coli (10.0 mm). The inhibitory effect on Candida albicans was confirmed by shelf-life studies using larvae fat-based oleogel in a model food matrix. GraphPad Prism (ver. 8.0.1) was used for the statistical data processing. This research revealed the potential of Black Soldier Fly larvae fat as a very stable ingredient with promising antibacterial properties that can extend the product shelf-life in food matrixes even when used in relatively small amounts. Full article
(This article belongs to the Special Issue Recent Advances in Oil Structuring)
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Review

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25 pages, 1036 KiB  
Review
Oleogels as a Promising Alternative to Animal Fat in Saturated Fat-Reduced Meat Products: A Review
by Md. Jannatul Ferdaus, Bishal Barman, Niaz Mahmud and Roberta Claro da Silva
Gels 2024, 10(2), 92; https://doi.org/10.3390/gels10020092 - 25 Jan 2024
Cited by 1 | Viewed by 3237
Abstract
The surge in chronic diseases is closely linked to heightened levels of saturated and trans fatty acids in processed foods, particularly meat products. Addressing this concern, various strategies have been employed to alleviate the impact of these detrimental fats. Among these, oleogels have [...] Read more.
The surge in chronic diseases is closely linked to heightened levels of saturated and trans fatty acids in processed foods, particularly meat products. Addressing this concern, various strategies have been employed to alleviate the impact of these detrimental fats. Among these, oleogels have emerged as a novel and promising approach in the food industry. As restructured fat systems, oleogels offer a unique opportunity to enhance the nutritional profile of meat products while providing distinct health and environmental advantages. This comprehensive review explores the transformative role of oleogels as innovative substitutes for traditional animal fats in a variety of meat products. Utilizing materials such as hydroxypropyl methylcellulose (HPMC), sterols, beeswax, γ-oryzanol, β-sitosterol, and others, oleogels have been investigated in diverse studies. The examination encompasses their impact on the textural, nutritional, and oxidative dimensions of meat patties, pork patties, pork liver pâtés, beef heart patties, and meat batters. An in-depth exploration is undertaken into the influence of various elements, including the type of oil, gelling agents, and processing methods, on the stability and physicochemical attributes of oleogels. Additionally, the paper scrutinizes the potential effects of oleogels on sensory attributes, texture, and the shelf life of meat products. In conclusion, this collective body of research emphasizes the versatility and efficacy of oleogels as viable replacements for traditional animal fats across a spectrum of meat products. The documented improvements in nutritional quality, oxidative stability, and sensory attributes pave the way for the development of healthier and more sustainable formulations in the meat industry. Full article
(This article belongs to the Special Issue Recent Advances in Oil Structuring)
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18 pages, 1458 KiB  
Review
Trends in Fat Modifications Enabling Alternative Partially Hydrogenated Fat Products Proposed for Advanced Application
by Anna Zbikowska, Sylwia Onacik-Gür, Małgorzata Kowalska, Katarzyna Zbikowska and Melánia Feszterová
Gels 2023, 9(6), 453; https://doi.org/10.3390/gels9060453 - 1 Jun 2023
Cited by 8 | Viewed by 4145
Abstract
The natural properties of oils and fats do not always allow for their direct use in industry (e.g., for food, cosmetics, and pharmaceuticals). Furthermore, such raw materials are often too expensive. Nowadays, the requirements for the quality and safety of fat products are [...] Read more.
The natural properties of oils and fats do not always allow for their direct use in industry (e.g., for food, cosmetics, and pharmaceuticals). Furthermore, such raw materials are often too expensive. Nowadays, the requirements for the quality and safety of fat products are increasing. For this reason, oils and fats are subjected to various modifications that make it possible to obtain a product with the desired characteristics and good quality that meets the needs of product buyers and technologists. The modification techniques of oils and fats change their physical (e.g., raise the melting point) and chemical properties (e.g., fatty acid composition). Conventional fat modification methods (hydrogenation, fractionation, and chemical interesterification) do not always meet the expectations of consumers, nutritionists, and technologists. In particular, Hydrogenation, while it allows us to obtain delicious products from the point of view of technology, is criticised for nutritional reasons. During the partial hydrogenation process, trans-isomers (TFA), dangerous for health, are formed. One of the modifications that meets current environmental requirements and trends in product safety and sustainable production is the enzymatic interesterification of fats. The unquestionable advantages of this process are the wide spectrum of possibilities for designing the product and its functional properties. After the interesterification process, the biologically active fatty acids in the fatty raw materials remain intact. However, this method is associated with high production costs. Oleogelation is a novel method of structuring liquid oils with small oil-gelling substances (even 1%). Based on the type of oleogelator, the methods of preparation can differ. Most oleogels of low molecular weight (waxes, monoglycerides, and sterols) and ethyl cellulose are prepared by dispersion in heated oil, while oleogels of high molecular weight require dehydration of the emulsion system or solvent exchange. This technique does not change the chemical composition of the oils, which allows them to keep their nutritional value. The properties of oleogels can be designed according to technological needs. Therefore, oleogelation is a future-proof solution that can reduce the consumption of TFA and saturated fatty acids while enriching the diet with unsaturated fatty acids. Oleogels can be named “fats of the future” as a new and healthy alternative for partially hydrogenated fats in foods. Full article
(This article belongs to the Special Issue Recent Advances in Oil Structuring)
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