Lubricant Additives and Ash: Do We Know Enough?

A special issue of Lubricants (ISSN 2075-4442).

Deadline for manuscript submissions: 30 November 2024 | Viewed by 3179

Special Issue Editors


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Guest Editor
1. Kymanetics, Inc., Boston, MA, USA
2. Mechanical Engineering Department, University of Hawaii, Honolulu, HI 96822, USA
3. Massachusetts Institute of Technology, Cambridge, MA 02139, USA
Interests: catalysis; lubricants and additives; ash; emissions control systems; X-ray analytical techniques; focused ion beam milling; ceramics; CFD; kinetic modeling

E-Mail Website
Guest Editor
Department of Mechanical Engineering, Massachusetts Institute of Technology, 77 Mass. Avenue, Cambridge, MA 02139, USA
Interests: lubricant additives; wear; emission control systems; used oil analysis; soot; automotive catalysts; fuels

Special Issue Information

Dear Colleagues,

Friction, the resistance to motion, is ubiquitously present at the interface of surfaces in contact and is often a destructive force that causes significant wear and hardware durability issues. Understanding friction and its mitigation requires significant effort from industry and academia across many disciplines. It is estimated that roughly 10-30% of energy produced in internal combustion engines (dependent on many factors) is required to overcome friction and can be alleviated by low-viscosity lubricants and additive designs, combustion and engine designs, and materials and surface engineering strategies. Lubricant additives provide many vital functions to current lubricants, including (but not limited to) viscosity modifiers, friction modifiers, pour point depressants, anti-wear, detergents, dispersants, oxidation inhibitors/antioxidants, antifoam, corrosion inhibitors, extreme-pressure additives, and demulsifiers/emulsifiers. Additives aid by enhancing desirable or suppressing undesirable base oil properties or by adding new properties, and they are consumed via decomposition, adsorption, and separation. Novel additive chemistries (low-ash/ashless additives, ionic liquids, etc.), additive mixture packages, and supplemental additives continue to be developed to achieve further reductions in friction for specific automotive applications, advanced combustion strategies, lower-viscosity lubricants, etc. 

Some additives (especially those which contain inorganic species) form incombustible ash which can be harmful to catalysts in emissions control systems and may degrade particle filters by causing clogs, chemical interactions, and various other mechanisms. The most common forms of ash are inorganic compounds (such as CaSO4, MgSO4, Zn3(PO4)2, etc.) which are derived from detergents and anti-wear additives, with particle sizes ranging from tens of nm to hundreds of µm, and they can become hydrated in some environments. Ash formation is influenced by many factors, including the specific lubricant additive package, oil consumption mechanisms, the engine application type (i.e., diesel, HCCI, GDI, etc.), exhaust properties (i.e., temperature, soot, humidity, etc.), particle filter operation strategies, and many others. Ash formation may reduce vehicle fuel economy and result in various after-treatment issues which require filters/catalysts to be cleaned or replaced. 

This Special Issue aims to add knowledge to the rhetorical question of ‘do we know enough?’ in the areas of automotive lubricant additives and ash. The Guest Editors seek original research papers and review articles relevant to emerging solutions and advancements in the understanding of automotive lubricant additives and lubricant-derived ash. 

Dr. Carl Justin Kamp
Dr. Sujay Dilip Bagi
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Lubricants is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • wear
  • lubricant
  • ash
  • anti-wear additive
  • detergents
  • over-based additives
  • ionic liquid lubricants
  • low-ash
  • ashless
  • catalyst poisoning

Published Papers (2 papers)

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Research

12 pages, 17511 KiB  
Article
Investigating Friction and Antiwear Characteristics of Organic and Synthetic Oils Using h-BN Nanoparticle Additives: A Tribological Study
by Umida Ziyamukhamedova, Shah Wasil, Sanjay Kumar, Rakesh Sehgal, M. F. Wani, Chandra Shekhar Singh, Nodirjon Tursunov and Himanshu Shekhar Gupta
Lubricants 2024, 12(1), 27; https://doi.org/10.3390/lubricants12010027 - 22 Jan 2024
Cited by 1 | Viewed by 1595
Abstract
Friction and wear are two major elements that influence the life of a variety of equipment. According to estimates, as much as 30% of the energy used is dissipated as friction. However, this figure can be reduced by developing materials that enhance surfaces [...] Read more.
Friction and wear are two major elements that influence the life of a variety of equipment. According to estimates, as much as 30% of the energy used is dissipated as friction. However, this figure can be reduced by developing materials that enhance surfaces and apply lubricants appropriately. This study aims to analyze the impact of hexagonal boron nitride (h-BN) nanoparticles on the rheological and antiwear characteristics of four distinct oil varieties, namely Society of Automotive Engineers SAE-20W50, soybean, Polyalphaolefin PAO-4, and olive oils. The results of the tribological tests demonstrated a noteworthy enhancement in antiwear characteristics with the addition of 0.2 wt.% of h-BN nanolubricant. Among all nanolubricants, the maximum reduction in coefficient of friction (COF) and wear scar diameter was observed at 0.2 wt.% of h-BN in SAE-20W50 oil. Compared to the base oils, the wear scar diameter decreased by 17.93%, 8.80%, 22.65%, and 24.04% for (soybean oil and 0.2 wt.% of h-BN), (SAE20W50 and 0.2 wt.% of h-BN), (PAO4 and 0.2 wt.% of h-BN), and (olive oil and 0.2 wt.% of h-BN), respectively. Rheological test results indicated that with the addition of h-BN nanoparticles, the viscosity of the base oils significantly increased. The maximum viscosity was observed at 40 °C for SAE20W50 base nanolubricants, according to the rheological measurements. Full article
(This article belongs to the Special Issue Lubricant Additives and Ash: Do We Know Enough?)
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19 pages, 18801 KiB  
Article
Tribological Investigation of the Effect of Nanosized Transition Metal Oxides on a Base Oil Containing Overbased Calcium Sulfonate
by Álmos Dávid Tóth, Hajnalka Hargitai and Ádám István Szabó
Lubricants 2023, 11(8), 337; https://doi.org/10.3390/lubricants11080337 - 8 Aug 2023
Cited by 1 | Viewed by 1130
Abstract
In this study, copper(II) oxide, titanium dioxide and yttrium(III) oxide nanoparticles were added to Group III-type base oil formulated with overbased calcium sulfonate. The nanosized oxides were treated with ethyl oleate surface modification. The tribological properties of the homogenized oil samples were tested [...] Read more.
In this study, copper(II) oxide, titanium dioxide and yttrium(III) oxide nanoparticles were added to Group III-type base oil formulated with overbased calcium sulfonate. The nanosized oxides were treated with ethyl oleate surface modification. The tribological properties of the homogenized oil samples were tested on a linear oscillating tribometer. Friction was continuously monitored during the tribological tests. A surface analysis was performed on the worn samples: the amount of wear was determined using a digital optical and confocal microscope. The type of wear was examined with a scanning electron microscope, while the additives adhered to the surface were examined with energy-dispersive X-ray spectroscopy. From the results of the measurements, it can be concluded that the surface-modified nanoparticles worked well with the overbased calcium sulfonate and significantly reduced both wear and friction. In the present tribology system, the optimal concentration of all three oxide ceramic nanoadditives is 0.4 wt%. By using oxide nanoparticles, friction can be reduced by up to 15% and the wear volume by up to 77%. Overbased calcium sulfonate and oxide ceramic nanoparticles together form a lower friction anti-wear boundary layer on the worn surfaces. The results of the tests represent another step toward the applicability of these nanoparticles in commercial engine lubricants. It is advisable to further investigate the possibility of formulating nanoparticles into the oil. Full article
(This article belongs to the Special Issue Lubricant Additives and Ash: Do We Know Enough?)
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Planned Papers

The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.

1. Azam, S.; Park, S.-S.; Investigating the Effect of CeO2 Nanoparticle Concentration on Tribological and Thermal Properties of Lubricating Oil. Lubricants 2023
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