Tribochemistry and Interfaces

A special issue of Lubricants (ISSN 2075-4442).

Deadline for manuscript submissions: closed (20 December 2019) | Viewed by 9583

Special Issue Editor


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Laboratory of Tribology and System Dynamics, Ecole Centrale de Lyon, University Lyon, ENISE, ENTPE, CNRS UMR5513, 69134 Ecully, France

Special Issue Information

Dear Colleagues,

An interface can be defined as a transition between different phases of matter. In a tribological contact, interfaces have the specificity to be under motion, making studies very complicated. Furthermore, interfaces can be of different types depending on the considered tribosystems: solid/solid, solid/gas/solid or solid/liquid/solid. Moreover, under certain conditions, chemical reactions could occur within these interfaces and generate a new compound called a tribofilm due to a tribochemical process. This tribofilm, with a thickness of only few nanometers in some cases, is able to control both wear and friction in the contact. The understanding of tribochemical phenomena is an actual key scientific challenge that this Special Issue proposes to address.

It is important to highlight that several parameters influence tribochemical processes: i) the chemical types of molecules present in the liquid or gas environment of the contact; ii) the nature and morphology of the solid surfaces involved in the contact; and iii) the contact conditions. To study such processes, friction tests and post-mortem characterization (topography, physico-chemical composition, mechanical properties, structure, etc.) are commonly performed. Advanced surface analytical tools, in-situ experimental techniques and computational chemistry tools have recently provided new input for the understanding of such phenomena.

This Special Issue aims to publish the latest developments in the field of tribochemistry. Research articles dedicated to any kind of tribochemical phenomena under dry or fluid lubrication and involving different types of lubricant additives, coatings, gas, etc., will be of great interest to this Special Issue. Tailoring surfaces to optimize tribochemical reactivity is also considered an interesting aspect. Advanced in-situ tribometry studies, recent developments of tribofilm characterization techniques, and modeling studies are also highly welcome.

Assoc. Prof. Dr. Clotilde Minfray


Guest Editor

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Keywords

  • Tribochemistry
  • Lubricant additives
  • Dry lubrication
  • Coatings
  • In-situ tribometry
  • Advanced physico-chemical surface characterization techniques
  • Modeling

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Published Papers (2 papers)

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Research

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15 pages, 6497 KiB  
Article
Tribochemical Interaction of Multicomponent Aluminum Alloys During Sliding Friction with Steel
by Pavel Podrabinnik, Iosif Gershman, Alexander Mironov, Ekaterina Kuznetsova and Pavel Peretyagin
Lubricants 2020, 8(3), 24; https://doi.org/10.3390/lubricants8030024 - 2 Mar 2020
Cited by 9 | Viewed by 3142
Abstract
In this work, aluminum multicomponent alloys were studied after friction with steel in a mixed lubrication regime. The resulting secondary structures on the friction surface were investigated by scanning electron microscopy (SEM), energy dispersive analysis (EDX), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction [...] Read more.
In this work, aluminum multicomponent alloys were studied after friction with steel in a mixed lubrication regime. The resulting secondary structures on the friction surface were investigated by scanning electron microscopy (SEM), energy dispersive analysis (EDX), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction analysis (XRD). In addition to the mass transfer of steel counterbody particles, phase transformations and new chemical compounds formed as a result of interaction with the lubricant were revealed. The release of elements, mainly magnesium and to a lesser extent zinc, from a solid solution of aluminum alloy was also observed, which indicates the occurrence of a non-spontaneous reaction with a negative entropy production. Full article
(This article belongs to the Special Issue Tribochemistry and Interfaces)
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Review

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25 pages, 1646 KiB  
Review
The Effect of Addition of Nanoparticles, Especially ZrO2-Based, on Tribological Behavior of Lubricants
by Adam Rylski and Krzysztof Siczek
Lubricants 2020, 8(3), 23; https://doi.org/10.3390/lubricants8030023 - 2 Mar 2020
Cited by 36 | Viewed by 6068
Abstract
The aim of the paper was to discuss different effects, such as, among others, agglomeration of selected nanoparticles, particularly those from zirconia, on the tribological behavior of lubricants. The explanation of the difference between the concepts of ‘aggregation’ and ‘agglomeration’ for ZrO2 [...] Read more.
The aim of the paper was to discuss different effects, such as, among others, agglomeration of selected nanoparticles, particularly those from zirconia, on the tribological behavior of lubricants. The explanation of the difference between the concepts of ‘aggregation’ and ‘agglomeration’ for ZrO2 nanoparticles is included. The factors that influence such an agglomeration are considered. Classification and thickeners of grease, the role of additives therein, and characteristics of the lithium grease with and without ZrO2 additive are discussed in the paper. The role of nanoparticles, including those from ZrO2 utilized as additives to lubricants, particularly to the lithium grease, is also discussed. The methods of preparation of ZrO2 nanoparticles are described in the paper. The agglomeration of ZrO2 nanoparticles and methods to prevent it and the lubrication mechanism of the lithium nanogrease and its tribological evaluation are also discussed. Sample preparation and a ball-on disc tester for investigating of spinning friction are described. The effect of ZrO2 nanoparticles agglomeration on the frictional properties of the lithium grease is shown. The addition of 1 wt.% ZrO2 nanoparticles to pure lithium grease can decrease the friction coefficient to 50%. On the other hand, the agglomeration of ZrO2 nanoparticles in the lithium grease can increase twice the friction coefficient relative to that for the pure grease. Full article
(This article belongs to the Special Issue Tribochemistry and Interfaces)
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