Functionalized Membranes for Sustainable Water and Energy Production

A special issue of Membranes (ISSN 2077-0375). This special issue belongs to the section "Membrane Applications".

Deadline for manuscript submissions: closed (20 March 2021) | Viewed by 2930

Special Issue Editors


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Guest Editor
College of Engineering, The University of Alabama, Tuscaloosa, AL 35487, USA
Interests: membranes; wastewater treatment; desalination
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Department of Chemical and Environmental Engineering, University of Arizona, Tucson, AZ, USA
Interests: membrane processes in environmental applications; water and waste; water treatment; water reuse; desalination process design and intensification

Special Issue Information

Dear colleagues,

Membrane technology is known as one of the most efficient separation techniques regarding energy consumption, reliability, and operational safety. Membrane materials, design, structure, and performance can be enhanced through different chemical, physical, and electrical- surface and substrate functionalization approaches to produce functionalized membranes with enhanced permeability, rejection, and antifouling ability.

This Special Issue will highlight the importance of membrane functionalization techniques, functionalizing materials, and the performance of functionalized membranes for sustainable water and energy production. This Special Issue welcomes both original research and reviews related to functionalized membrane fabrication, characterization, and applications mainly for water treatment, desalination, wastewater treatment, perfluorooctanoic acid derivatives removal, oil–water separation, volatile organic compound removal from aqueous or gas streams, CO2 removal, production, and recovery of high-added products from wastewater.

Prof. Dr. Milad Rabbani Esfahani
Prof. Dr. Andrea Achilli
Guest Editors

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Keywords

  • membrane fabrication
  • surface functionalization
  • grafting
  • layer-by-layer assembly
  • adsorptive membranes
  • nanoparticles
  • carbon-based materials
  • metal organic framework (MOF)

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Published Papers (1 paper)

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Research

14 pages, 2560 KiB  
Article
Estradiol Removal by Adsorptive Coating of a Microfiltration Membrane
by Zahra Niavarani, Daniel Breite, Andrea Prager, Bernd Abel and Agnes Schulze
Membranes 2021, 11(2), 99; https://doi.org/10.3390/membranes11020099 - 30 Jan 2021
Cited by 11 | Viewed by 2425
Abstract
This work demonstrates the enhancement of the adsorption properties of polyethersulfone (PES) microfiltration membranes for 17β-estradiol (E2) from water. This compound represents a highly potent endocrine-disrupting chemical (EDC). The PES membranes were modified with a hydrophilic coating functionalized by amide groups. The modification [...] Read more.
This work demonstrates the enhancement of the adsorption properties of polyethersulfone (PES) microfiltration membranes for 17β-estradiol (E2) from water. This compound represents a highly potent endocrine-disrupting chemical (EDC). The PES membranes were modified with a hydrophilic coating functionalized by amide groups. The modification was performed by the interfacial reaction between hexamethylenediamine (HMD) or piperazine (PIP) as the amine monomer and trimesoyl chloride (TMC) or adipoyl chloride (ADC) as the acid monomer on the surface of the membrane using electron beam irradiation. The modified membranes and the untreated PES membrane were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), water permeance measurements, water contact angle measurements, and adsorption experiments. Furthermore, the effects of simultaneous changes in four modification parameters: amine monomer types (HMD or PIP), acid monomer types (TMC or ADC), irradiation dosage (150 or 200 kGy), and the addition of toluene as a swelling agent, on the E2 adsorption capacity were investigated. The results showed that the adsorption capacities of modified PES membranes toward E2 are >60%, while the unmodified PES membrane had an adsorption capacity up to 30% for E2 under similar experimental conditions, i.e., an enhancement of a factor of 2. Next to the superior adsorption properties, the modified PES membranes maintain high water permeability and no pore blockage was observed. The highlighted results pave the way to develop efficient low-cost, stable, and high-performance adsorber membranes. Full article
(This article belongs to the Special Issue Functionalized Membranes for Sustainable Water and Energy Production)
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