Dissolution and Precipitation Dynamics at the Mineral–Fluid Interface

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Environmental Mineralogy and Biogeochemistry".

Deadline for manuscript submissions: 31 January 2025 | Viewed by 1116

Special Issue Editors


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Guest Editor
Department of Mineralogy and Petrology, Faculty of Geosciences, University Complutense of Madrid, C/Jose António Novais 12, 28040 Madrid, Spain
Interests: experimental mineralogy; fluid–mineral interactions; mineral replacement reactions; crystal growth

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Guest Editor
Department of Mineralogy and Crystallography, Faculty of Geological Sciences, University Complutense of Madrid, C/José Antonio Novais 2, 28040 Madrid, Spain
Interests: environmental chemistry and remediation; biomineralization and crystal growth

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Guest Editor
Department of Geology and Geoenvironment, National and Kapodistrian University of Athens, 15784 Athens, Greece
Interests: mineral surface science and nanogeoscience; microporous/nanoporous minerals and rocks; environmental mineralogy and geochemistry; biomineralogy and medical geology; mineral atmospheric particles; marine mineralogy and geochemistry
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Special Issue Information

Dear Colleagues,

Mineral reactivity is a major factor controlling the natural fluxes of matter and energy in the Geosphere. In fact, all large-scale geological phenomena are underpinned by physical-chemical reactions involving mineral compounds and fluids, throughout a wide spectrum of pressure and temperature conditions, and at different time scales. From the paragenetic pathways followed by subsolidus metamorphic reactions, to the low temperature progressive development of lateritic soils; from the large-scale hydrothermalism affecting oceanic plates at tectonic spreading centers, to the precipitation of salts by evaporation of seawater in coastal sabkhas; the key to understand complex geological processes often rests in mineral stability/reactivity features. Beyond the realm of the Geosphere, and especially at the interface between the latter and the Biosphere, mineral-fluid-organism/organic substance interactions are central to the dynamics of the Earth's Critical Zone, especially those involving the chemical interplay between silicates and soil organics. Under a more applied perspective, the study of mineral-fluid interactions is of great importance to the characterization and prediction of the mobility of hazardous elements and compounds in the environment. Concerning environmental remediation, specific coupled mineral dissolution-precipitation reactions, and/or surface sorption mechanisms, are frequently efficient methods for correcting aqueous concentrations of targeted pollutants.  Finally, all biomineralization processes, regardless of the type of organism and physiological context, are strongly dependent on the thermodynamic and kinetic forcing factors of dissolution, nucleation, and growth of critical biomineral systems, such as calcium phosphates, carbonates, or oxalates. 

The present Special Issue invites submissions of original research related to the study of mineral-fluid interactions, especially those concerning mineral dissolution/precipitation features, in various contexts (geoscientific, experimental mineralogy, environmental management-remediation, material sciences, biomineralization, etc.).

Dr. André Pinto
Dr. Nuria Sánchez-Pastor
Dr. Athanasios Godelitsas
Guest Editors

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Keywords

  • mineral dissolution–precipitation
  • mineral surface reactivity
  • sorption mechanisms
  • mineral replacement
  • environmental remediation
  • biomineralization

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Published Papers (1 paper)

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Research

13 pages, 3858 KiB  
Article
The Controlling Effect of CaCO3 Supersaturation over Zn Carbonate Assemblages: Co-Crystallization in Silica Hydrogel
by André Jorge Pinto, Nuria Sánchez-Pastor and Angeles Fernández-González
Minerals 2024, 14(12), 1274; https://doi.org/10.3390/min14121274 - 15 Dec 2024
Viewed by 601
Abstract
Weathering products of sphalerite-bearing ores play an important role in controlling the fate of Zn in the environment. In this framework, the relative stability of Zn carbonates is of special relevance for the common case of ore weathering by carbonated groundwater in the [...] Read more.
Weathering products of sphalerite-bearing ores play an important role in controlling the fate of Zn in the environment. In this framework, the relative stability of Zn carbonates is of special relevance for the common case of ore weathering by carbonated groundwater in the presence of calcium carbonates. We investigated the experimental (co)nucleation and growth of Zn and Ca carbonates at 25 °C in finite double diffusion silica hydrogel media with the purpose of deciphering the system’s reactive pathway and unraveling the major governing factors behind the obtained mineral assemblages. The crystallized solids were carefully extracted two months post-nucleation and studied with micro-Raman spectroscopy, micro X-ray diffraction (XRD), scanning electron microscopy, and electron microprobe (EMP) methods. The obtained results indicate that the grown Zn-bearing phases corresponded to smithsonite and/or Zn hydroxyl carbonate, while CaCO3 polymorphs aragonite and calcite were also crystallized. Moreover, the observed mineral textural relationships reflected the interplay between supersaturation with respect to CaCO3/pCO2 and the grown Zn-bearing carbonate. Experiments conducted in more supersaturated conditions with respect to CaCO3 polymorphs (higher pCO2) favored the precipitation of smithsonite, while the opposite was true for the obtained Zn hydroxyl carbonate phase. The gathered Raman, XRD, and EMP data indicate that the latter phase corresponded to a non-stoichiometric, poorly crystalline solid. Full article
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