Advanced Nanocomposite Magnets with the L10 Phase

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Nanocomposite Materials".

Deadline for manuscript submissions: 10 September 2024 | Viewed by 535

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National Institute for Materials Physics, 077125 Magurele, Romania
Interests: magnetic nanomaterials; exchange spring and exchange bias; spintronics; THz technologies
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Special Issue Information

Dear Colleagues,

Rare-earth-free permanent magnets with the L10 phase are actively researched for their potential as a future class of magnetic materials capable of operating at higher temperatures and in challenging corrosion environments, such as for renewable energy applications. Among these classes, novel magnets fabricated without rare earth materials show promising potential, being cost-effective with interesting magnetic properties. Sustained efforts are currently being made in the search for new classes of magnets, a search that is motivated by the continuous depletion of RE oxide resources and the need for improved magnetic parameters, especially for high-temperature applications. Indeed, RE-free magnets can operate under extreme conditions such as high temperatures and corrosive media, for instance in wind turbine motors subjected to strong variations in temperature and humidity. Various possible RE-free magnets have been proposed and largely investigated, including compounds derived from the binary systems FePt, MnAl, MnBi, MnGa, and others. Common to all these different systems is the fact that they all may exhibit, under certain conditions, the formation of the tetragonal L10 phase, which has been shown to present large magneto-crystalline anisotropy and high coercivity.

The motivation of this Special Issue is that the research community has already begun searching for magnetic materials based on abundant elements that are less costly and easier to process without a significant degradation in the magnetic performances of current classes of rare earth magnets.

The present Special Issue will address all the challenges encountered in developing novel RE-free nanocomposite magnets, including, but not limited to, the following:

  • The theory and modeling of novel magnetic alloy compositions;
  • Synthesis challenges and microstructure optimization for novel nanocomposite magnets;
  • Magnetic phase coexistence and phase stability with temperature;
  • Hard–soft exchange coupling in multiphase magnetic nanocomposites;
  • The optimization of magnetic performances in RE-free nanocomposite magnets;
  • Magnetic performances under extreme conditions of operation.

Dr. Ovidiu Crisan
Guest Editor

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Keywords

  • RE-free nanocomposite magnets
  • hard-soft exchange coupling
  • magnetic stability
  • structural phase transformation
  • L10 phase

Published Papers (1 paper)

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Research

17 pages, 2591 KiB  
Article
High Magnetic Performance in MnGa Nanocomposite Magnets
by Ovidiu Crisan and Alina Daniela Crisan
Nanomaterials 2024, 14(15), 1245; https://doi.org/10.3390/nano14151245 - 24 Jul 2024
Viewed by 371
Abstract
In view of their potential applicability in technology fields where magnets are required to operate at higher temperatures, the class of nanocomposite magnets with little or no rare earth (RE) content has been widely researched in the last two decades. Among these nanocomposite [...] Read more.
In view of their potential applicability in technology fields where magnets are required to operate at higher temperatures, the class of nanocomposite magnets with little or no rare earth (RE) content has been widely researched in the last two decades. Among these nanocomposite magnets, the subclass of magnetic binary systems exhibiting the formation of L10 tetragonal phases is the most illustrious. Some of the most interesting systems are represented by the Mn-based alloys, with addition of Al, Bi, Ga, Ge. Such alloys are interesting as they are less costly than RE magnets and they show promising magnetic properties. The paper tackles the case of MnGa binary alloys with various compositions around the Mn3Ga stoichiometry. Four MnGa magnetic alloys, with Mn content ranging from 70 at% to 75 at% were produced using rapid solidification to form the melt. By combining structural information arising from X-ray diffractometry and transmission electron microscopy with magnetic properties determined by vibrating sample magnetometry, we are able to document the nature and properties of the structural phases formed in the alloys in their as-cast state and upon annealing, the evolution of the phase structure after annealing and its influence on the magnetic behavior of the MnGa alloys. After annealing at 400 °C and 500 °C, MnGa alloys are showing a multiple-phase microstructure, consisting of co-existing crystallites of L10 and D022 tetragonal phase. As a consequence of these structurally and magnetically different phases, co-existing within the microstructure, promising magnetic features are obtained, with both coercive fields and saturation magnetization exceeding values previously reported for both alloys and layers of MnGa. Full article
(This article belongs to the Special Issue Advanced Nanocomposite Magnets with the L10 Phase)
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