Electrogravimetric and Electrochemical Studies on New Nanostructured Materials

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Energy and Catalysis".

Deadline for manuscript submissions: closed (31 August 2021) | Viewed by 5421

Special Issue Editor

Laboratoire Interfaces et Systèmes Electrochimiques (LISE), UMR 8235, CNRS, Sorbonne Université, Campus Pierre et Marie Curie, 4 place Jussieu, 75005 Paris, France
Interests: electroactive materials; nanostructured electrodes; energy storage/conversion; electrode/electrolyte interface; ion transfer and transport; electrochemical quartz crystal microbalance (EQCM) based methods; electrochemical impedance spectroscopy (EIS); coupled electrochemical methods.

Special Issue Information

Dear Colleagues,

Advanced characterization tools have undoubtedly contributed to recent developments in nanostructured materials, presenting great application potential for next-generation electrochemical devices (rechargeable batteries, supercapacitors, electrochemical (bio)sensors, in electrochromic and capacitive deionization processes, etc.).

The design of novel electrodes with suitable properties relies on the understanding of their fundamental properties at the nanoscale, including the comprehension of ions’ insertion/electroadsorption at the electrode/electrolyte interfaces and their interactions with the active material. To elucidate these phenomena, coupled analytical methods that combine electrochemical analysis with simultaneous mass variation measurements (electrochemical quartz crystal microbalance, EQCM) have been actively employed in the study of nanostructured electrode materials. The new generation of EQCM with dissipation monitoring (EQCM-D) has offered the possibility to account for the morphological and mechanical property changes of the electrode materials during operation, and the results are very valuable to improve the performance of existing systems and to design new electroactive materials (e.g., for energy storage applications).

Thus, this Special Issue of Nanomaterials will attempt to cover the most recent advances in the EQCM-based studies of a wide range of nanostructured electrode materials (metal oxides, carbons, conducting polymers, and their composites) that are promising for a vast range of electrochemical applications. Suitable topics include, but are not limited to, the contributions in the field of energy storage and conversion, environment (e.g., water treatment with capacitive desalination), as well as electrochemical (bio)sensors, focusing on the nanostructured electrodes investigated by EQCM and EQCM-D based methods.

Dr. Ozlem Sel
Guest Editor

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Keywords

  • Electrogravimetric studies of nanostructures
  • Electrochemical quartz crystal microbalance (EQCM)
  • EQCM with dissipation monitoring (EQCM-D)
  • Nanostructured electrodes (metal oxides, carbons, conducting polymers, composites)
  • Electrode/electrolyte interface
  • Ion insertion/electroadsorption phenomena
  • Energy storage and conversion (batteries, supercapacitors, fuel cells)
  • Electrochromic devices capacitive desalination process
  • Electrochemical (bio)sensors

Published Papers (2 papers)

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Research

17 pages, 3691 KiB  
Article
Deciphering the Influence of Electrolytes on the Energy Storage Mechanism of Vertically-Oriented Graphene Nanosheet Electrodes by Using Advanced Electrogravimetric Methods
by Tao Lé, Gérard Bidan, Florence Billon, Marc Delaunay, Jean-Michel Gérard, Hubert Perrot, Ozlem Sel and David Aradilla
Nanomaterials 2020, 10(12), 2451; https://doi.org/10.3390/nano10122451 - 7 Dec 2020
Viewed by 2334
Abstract
Electrolyte composition is a crucial factor determining the capacitive properties of a supercapacitor device. However, its complex influence on the energy storage mechanisms has not yet been fully elucidated. For this purpose, in this study, the role of three different types of electrolytes [...] Read more.
Electrolyte composition is a crucial factor determining the capacitive properties of a supercapacitor device. However, its complex influence on the energy storage mechanisms has not yet been fully elucidated. For this purpose, in this study, the role of three different types of electrolytes based on a propylene carbonate (PC) solution containing tetrabutylammonium perchlorate (TBAClO4), lithium perchlorate (LiClO4) and butyltrimethylammonium bis(trifluoromethylsulfonyl)imide (N1114TFSI) ionic liquid on vertically-oriented graphene nanosheet electrodes has been investigated. Herein, in situ electrochemical quartz crystal microbalance (EQCM) and its coupling with electrochemical impedance spectroscopy (EIS), known as ac-electrogravimetry, have allowed the dynamic aspects of the (co)electroadsorption processes at the electrode-electrolyte interface to be examined. A major contribution of ClO4 anions (TBAClO4) was evidenced, whereas in the PC/N1114TFSI mixture (50:50 wt%) both anions (TFSI) and cations (N1114+) were symmetrically exchanged during cycling. In the particular case of LiClO4, solvation of Li+ cations in PC was involved, affecting the kinetics of electroadsorption. These results demonstrate the suitability of dynamic electrogravimetric methods to unveil the interfacial exchange properties of mobile species for the conception of new high performance energy storage devices. Full article
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7 pages, 1213 KiB  
Communication
Tuning Redox State and Ionic Transfers of Mg/Fe-Layered Double Hydroxide Nanosheets by Electrochemical and Electrogravimetric Methods
by Elise Duquesne, Stéphanie Betelu, Alain Seron, Ioannis Ignatiadis, Hubert Perrot and Catherine Debiemme-Chouvy
Nanomaterials 2020, 10(9), 1832; https://doi.org/10.3390/nano10091832 - 14 Sep 2020
Cited by 6 | Viewed by 2439
Abstract
Studying the electrogravimetric behavior of Mg/Fe-layered double hydroxide (LDH) nanoparticles with an electrochemical quartz crystal microbalance demonstrates its pseudocapacitance properties of mix cation and anion exchanger. The electrochemical control of the oxidation state of iron constituting the layered sheets allowed anion intercalation/deintercalation into [...] Read more.
Studying the electrogravimetric behavior of Mg/Fe-layered double hydroxide (LDH) nanoparticles with an electrochemical quartz crystal microbalance demonstrates its pseudocapacitance properties of mix cation and anion exchanger. The electrochemical control of the oxidation state of iron constituting the layered sheets allowed anion intercalation/deintercalation into the LDH interlayer space. Concomitantly, in agreement with the pH of zero point of net charge of the Mg/Fe-LDH, the interfacial pH increase via catalyzed hydrogen evolution reaction allows cation electroadsorption onto the external surfaces of the nanoplatelets. Full article
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