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Electrochemical Sensors: Recent Advances and Applications

A special issue of Sensors (ISSN 1424-8220). This special issue belongs to the section "Chemical Sensors".

Deadline for manuscript submissions: closed (15 November 2020) | Viewed by 9817

Special Issue Editor


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Guest Editor
Laboratory for Electrocatalysis, Analytical Chemistry Laboratory, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia
Interests: synthesis of functional materials; ionic liquids; electrochemical sensors
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Owing to the attractive physicochemical properties of ionic liquids and growing demand for fast and reliable on-site sensing, I would like to bring together the best of both worlds. Ionic liquids have proven many times to improve electrochemical sensor performances, especially regarding accumulation and transport of analytes, and therefore significantly increasing sensitivity and decreasing the measuring time. Such synergy can already be found in sensors for environmental and remote industrial monitoring as well as clinical diagnostics.
I would like to invite you to share your recent findings in the broad areas of ionic liquids and electrochemical (bio)sensing.

Dr. Vasko Jovanovski
Guest Editor

Manuscript Submission Information

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Keywords

  • ionic liquids
  • electrochemical sensors
  • biosensors
  • monitoring
  • toxic elements
  • clinical diagnostics
  • gas sensing

Published Papers (2 papers)

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Research

18 pages, 5226 KiB  
Article
Calibrations of Low-Cost Air Pollution Monitoring Sensors for CO, NO2, O3, and SO2
by Pengfei Han, Han Mei, Di Liu, Ning Zeng, Xiao Tang, Yinghong Wang and Yuepeng Pan
Sensors 2021, 21(1), 256; https://doi.org/10.3390/s21010256 - 2 Jan 2021
Cited by 53 | Viewed by 6366
Abstract
Pollutant gases, such as CO, NO2, O3, and SO2 affect human health, and low-cost sensors are an important complement to regulatory-grade instruments in pollutant monitoring. Previous studies focused on one or several species, while comprehensive assessments of multiple [...] Read more.
Pollutant gases, such as CO, NO2, O3, and SO2 affect human health, and low-cost sensors are an important complement to regulatory-grade instruments in pollutant monitoring. Previous studies focused on one or several species, while comprehensive assessments of multiple sensors remain limited. We conducted a 12-month field evaluation of four Alphasense sensors in Beijing and used single linear regression (SLR), multiple linear regression (MLR), random forest regressor (RFR), and neural network (long short-term memory (LSTM)) methods to calibrate and validate the measurements with nearby reference measurements from national monitoring stations. For performances, CO > O3 > NO2 > SO2 for the coefficient of determination (R2) and root mean square error (RMSE). The MLR did not increase the R2 after considering the temperature and relative humidity influences compared with the SLR (with R2 remaining at approximately 0.6 for O3 and 0.4 for NO2). However, the RFR and LSTM models significantly increased the O3, NO2, and SO2 performances, with the R2 increasing from 0.3–0.5 to >0.7 for O3 and NO2, and the RMSE decreasing from 20.4 to 13.2 ppb for NO2. For the SLR, there were relatively larger biases, while the LSTMs maintained a close mean relative bias of approximately zero (e.g., <5% for O3 and NO2), indicating that these sensors combined with the LSTMs are suitable for hot spot detection. We highlight that the performance of LSTM is better than that of random forest and linear methods. This study assessed four electrochemical air quality sensors and different calibration models, and the methodology and results can benefit assessments of other low-cost sensors. Full article
(This article belongs to the Special Issue Electrochemical Sensors: Recent Advances and Applications)
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13 pages, 2985 KiB  
Article
Characterization of Room-Temperature Ionic Liquids to Study the Electrochemical Activity of Nitro Compounds
by Ivneet Banga, Anirban Paul, Sriram Muthukumar and Shalini Prasad
Sensors 2020, 20(4), 1124; https://doi.org/10.3390/s20041124 - 19 Feb 2020
Cited by 14 | Viewed by 3010
Abstract
Over the past few years, room-temperature ionic liquid (RTIL) has evolved as an important solvent-cum-electrolyte because of its high thermal stability and excellent electrochemical activity. Due to these unique properties, RTILs have been used as a solvent/electrolyte/mediator in many applications. There are many [...] Read more.
Over the past few years, room-temperature ionic liquid (RTIL) has evolved as an important solvent-cum-electrolyte because of its high thermal stability and excellent electrochemical activity. Due to these unique properties, RTILs have been used as a solvent/electrolyte/mediator in many applications. There are many RTILs, which possess good conductivity as well as an optimal electrochemical window, thus enabling their application as a transducer for electrochemical sensors. Nitroaromatics are a class of organic compounds with significant industrial applications; however, due to their excess use, detection is a major concern. The electrochemical performance of a glassy carbon electrode modified with three different RTILs, [EMIM][BF4], [BMIM][BF4] and [EMIM][TF2N], has been evaluated for the sensing of two different nitroaromatic analytes: 2,6-dinitrotoluene (2,6 DNT) and ethylnitrobenzene (ENB). Three RTILs have been chosen such that they have either a common anion or cation amongst them. The sensory response has been measured using square wave voltammetry (SQWV). We found the transducing ability of [EMIM][BF4] to be superior compared to the other two RTILs. A low limit of detection (LOD) of 1 ppm has been achieved with a 95% confidence interval for both the analytes. The efficacy of varying the cationic and anionic species of RTIL to obtain a perfect combination has been thoroughly investigated in this work, which shows a novel selection process of RTILs for specific applications. Moreover, the results obtained from testing with a glassy carbon electrode (GCE) have been replicated using a miniaturized sensor platform that can be deployed easily for on-site sensing applications. Full article
(This article belongs to the Special Issue Electrochemical Sensors: Recent Advances and Applications)
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