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22 pages, 1989 KB  
Article
Modeling Magnetic Transition Temperature of Rare-Earth Transition Metal-Based Double Perovskite Ceramics for Cryogenic Refrigeration Applications Using Intelligent Computational Methods
by Sami M. Ibn Shamsah
Materials 2025, 18(19), 4594; https://doi.org/10.3390/ma18194594 (registering DOI) - 3 Oct 2025
Abstract
Rare-earth transition metal-based double perovskite ceramics E2TMO6 (where E = rare-earth metals, T = transition metals, and M = metal) have received impressive attention lately for cryogenic applications as a result of their intrinsic physical features such as multiferroicity, dielectric [...] Read more.
Rare-earth transition metal-based double perovskite ceramics E2TMO6 (where E = rare-earth metals, T = transition metals, and M = metal) have received impressive attention lately for cryogenic applications as a result of their intrinsic physical features such as multiferroicity, dielectric features, and adjustable magnetic transition temperature. However, determination and enhancement of magnetic transition temperature of E2TMO6 ceramic are subject to experimental procedures and processes with a significant degree of difficulties and cumbersomeness. This work proposes an extreme learning machine (ELM)-based intelligent method of determining magnetic transition temperature of E2TMO6 ceramics with activation function sigmoid (SM) and sine (SE) at varying magnetic field. The outcomes of the SE-ELM and SM-ELM models were compared with genetically optimized support vector regression (GEN-SVR) predictive models using RMSE, CC, and MAE metrics. Using the testing samples of E2TMO6 ceramics, SE-ELM predictive model outperforms GEN-SVR with a superiority of 6.3% (using RMSE metric) and 15.7% (using MAE metric). The SE-ELM predictive model further outperforms the SM-ELM model, with an improvement of 5.3%, using CC computed with training ceramic samples. The simplicity of the employed descriptors, coupled with the outstanding performance of the developed predictive models, would potentially strengthen E2TMO6 ceramics exploration for low-temperature cryogenic applications and circumvent energy challenges in different sectors. Full article
(This article belongs to the Section Materials Simulation and Design)
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17 pages, 560 KB  
Article
Development of Fructooligosaccharide-Rich Sugarcane Juice by Enzymatic Method and Enhancement of Its Microbial Safety Using High-Pressure Processing
by Tanyawat Kaewsalud, Jessica Michelle Liony, Sitthidat Tongdonyod, Suphat Phongthai and Wannaporn Klangpetch
Foods 2025, 14(19), 3417; https://doi.org/10.3390/foods14193417 (registering DOI) - 3 Oct 2025
Abstract
Sugarcane juice (SJ) is a naturally sweet beverage rich in sucrose but prone to microbial contamination, raising concerns among health-conscious consumers. This study aimed to develop a functional SJ enriched with fructooligosaccharides (FOS) using enzymatic treatment, followed by high-pressure processing (HPP) to enhance [...] Read more.
Sugarcane juice (SJ) is a naturally sweet beverage rich in sucrose but prone to microbial contamination, raising concerns among health-conscious consumers. This study aimed to develop a functional SJ enriched with fructooligosaccharides (FOS) using enzymatic treatment, followed by high-pressure processing (HPP) to enhance its safety and quality. The enzymatic conversion of sucrose to FOS was achieved using Pectinex® Ultra SP-L (commercial enzyme), with varying enzyme concentrations, temperatures and incubation times to identify the optimal conditions via response surface methodology (RSM). Under optimal conditions (1000 U/g enzyme concentration, 48 °C, 13 h), sucrose in raw SJ (124.33 g/L) decreased by 59.17 g/L, resulting in maximum reducing sugars (16.02 ± 0.58 g/L) and enhanced FOS yields, notably kestose (2.37 g/L) and nystose (9.35 g/L). After being treated with HPP at 600 MPa for 3 min, E. coli K12 and L. innocua were effectively inactivated by achieving > 5 log reduction, meeting USFDA standards. Furthermore, it was also observed that HPP could reduce yeast (6.56 × 102 CFU/mL). Meanwhile, mold, E. coli, and coliforms were not detected. Additionally, HPP maintained the juice’s physicochemical properties, outperforming thermal pasteurization (85 °C for 10 min) in quality preservation. This study highlights the potential of enzymatic treatment and HPP in improving SJ safety and functionality. Full article
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13 pages, 7780 KB  
Article
Population Structure and Genetic Diversity of Oysters from a Natural Reef on Magu Island, Shandong, China
by Yumeng Liu, Sichao Pu, Liang Zhang, Yinglu Ji, Jie Feng, Peizhen Ma and Lan Wang
Diversity 2025, 17(10), 693; https://doi.org/10.3390/d17100693 (registering DOI) - 3 Oct 2025
Abstract
Oyster reefs are receiving increasing attention due to severe survival challenges and their significant ecological service functions. Despite increased restorations worldwide, both natural and restored reefs have often not been monitored to an extent. Reef-building oyster populations are the foundation for the development [...] Read more.
Oyster reefs are receiving increasing attention due to severe survival challenges and their significant ecological service functions. Despite increased restorations worldwide, both natural and restored reefs have often not been monitored to an extent. Reef-building oyster populations are the foundation for the development of oyster reefs. In order to provide basic data for further protection and potential restoration of the oyster reef in the muddy tidal flats of Magu Island, in the middle of Dingzi Bay, the population structure and genetic diversity of the reef-building oysters were assessed through field investigation and molecular experiments. Results showed that the area of the oyster reef was 20,689 square meters and the oysters were Magallana gigas. The distribution of oyster patches revealed a reef building-up stage. The mean densities of the oysters were 3260.80 ind·m−2 and 3097.60 ind·m−2 in spring and autumn, respectively, and the biomasses were 25,209.38 g·m−2 and 30,137.44 g·m−2. The frequent distribution of shell height indicated two primary sizes divided by ages. Population genetic analyses based on partial mitochondrial cox1, cox3, and nad2 showed low nucleotide diversity and moderate haplotype diversity, proposing the population growth stage. Both the results of the population structure and genetic diversity suggested a developing status of the oyster reef on Magu Island. Full article
(This article belongs to the Section Biodiversity Conservation)
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15 pages, 2386 KB  
Article
Chlorogenic Acid Targets Cell Integrity and Virulence to Combat Vibrio parahaemolyticus
by Huan Liu, Jie Zhao, Yile Shi, Juanjuan Cao and Yanni Zhao
Foods 2025, 14(19), 3416; https://doi.org/10.3390/foods14193416 (registering DOI) - 3 Oct 2025
Abstract
Vibrio parahaemolyticus is a primary foodborne pathogen in seafood that endangers consumers’ health. It is vital to develop novel prevention and control strategies due to its extensive transmission and drug resistance. This work aimed to examine the antibacterial and anti-virulence efficiency of chlorogenic [...] Read more.
Vibrio parahaemolyticus is a primary foodborne pathogen in seafood that endangers consumers’ health. It is vital to develop novel prevention and control strategies due to its extensive transmission and drug resistance. This work aimed to examine the antibacterial and anti-virulence efficiency of chlorogenic acid (CA) against V. parahaemolyticus. The minimum inhibitory concentration (MIC) of CA is 6 mg/mL. CA realized its antibacterial effect by damaging the cell wall and membrane, evidenced by the leakage of alkaline phosphatase, intracellular proteins and nucleic acids, potassium ion, and glucose, the increasing malondialdehyde and reactive oxygen species, as well as morphological observations under scanning and transmission microscopes and live and dead cell observations under laser confocal microscopy. When V. parahaemolyticus was treated with CA at sub-inhibitory doses, its hydrophobicity, extracellular polysaccharide synthesis, motility, and biofilm formation were all significantly inhibited. Moreover, CA effectively protected salmon from the contamination of V. parahaemolyticus with a prolonged shelf life. These findings indicate that CA possesses antibacterial activity against V. parahaemolyticus, suggesting its potential value for controlling V. parahaemolyticus-associated seafood infections. Full article
(This article belongs to the Section Foods of Marine Origin)
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14 pages, 2233 KB  
Article
Efficient Bioproduction of p-Hydroxybenzaldehyde β-Glucoside from p-Hydroxybenzaldehyde by Glycosyltransferase Mutant UGTBL1-Δ60
by Bo Fan, Shunuan Fu, Yijun Zhu, Wei Tang and Yucai He
Biology 2025, 14(10), 1358; https://doi.org/10.3390/biology14101358 (registering DOI) - 3 Oct 2025
Abstract
Lignin, as one of the three primary components of renewable lignocellulosic biomass, can be converted into aromatic platform chemicals and holds significant potential for high-value applications. p-Hydroxybenzaldehyde is a compound derived from lignin. In this study, the mutant Δ60 of the glycosyltransferase [...] Read more.
Lignin, as one of the three primary components of renewable lignocellulosic biomass, can be converted into aromatic platform chemicals and holds significant potential for high-value applications. p-Hydroxybenzaldehyde is a compound derived from lignin. In this study, the mutant Δ60 of the glycosyltransferase UGTBL1 derived from Bacillus licheniformis was adopted to catalyze the glycosylation reaction of p-hydroxybenzaldehyde, producing a bioactive compound Helicid analogue (p-hydroxybenzaldehyde β-glucoside). Truncation mutations targeting loop regions may reduce local flexibility, thereby facilitating enhanced access of p-hydroxybenzaldehyde to the active site pocket and promoting relative activity. Under optimal conditions (35 °C, pH 7.5, and glucose 200 mM), a high yield of 97.8% for p-hydroxybenzaldehyde β-glucoside was achieved from 2 mM p-hydroxybenzaldehyde within 10 h. The conversion of 3 mM p-hydroxybenzaldehyde (366.4 mg/L) yielded up to 2.7 mM (767.5 mg/L) of p-hydroxybenzaldehyde β-glucoside within 48 h. According to the molecular docking results, the CDOCKER energy value of mutant Δ60 was lower than that of the wild-type, at −16.0 kcal/mol. To our knowledge, this is the first example of an efficient and environmentally sustainable approach for the synthesis of p-hydroxybenzaldehyde β-glucoside, providing a new insight for the valorization of lignin into valuable biobased chemicals. Full article
(This article belongs to the Section Biotechnology)
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15 pages, 2125 KB  
Article
Surface Mapping by RPAs for Ballast Optimization and Slip Reduction in Plowing Operations
by Lucas Santos Santana, Lucas Gabryel Maciel do Santos, Josiane Maria da Silva, Aldir Carpes Marques Filho, Francesco Toscano, Enio Farias de França e Silva, Alexandre Maniçoba da Rosa Ferraz Jardim, Thieres George Freire da Silva and Marco Antonio Zanella
AgriEngineering 2025, 7(10), 332; https://doi.org/10.3390/agriengineering7100332 (registering DOI) - 3 Oct 2025
Abstract
Driving wheel slippage in agricultural tractors is influenced by soil moisture, density, and penetration resistance. These surface variations reflect post-tillage composition, enabling dynamic mapping via Remotely Piloted Aircraft (RPAs). This study evaluated ballast recommendations based on soil surface data and slippage percentages, correlating [...] Read more.
Driving wheel slippage in agricultural tractors is influenced by soil moisture, density, and penetration resistance. These surface variations reflect post-tillage composition, enabling dynamic mapping via Remotely Piloted Aircraft (RPAs). This study evaluated ballast recommendations based on soil surface data and slippage percentages, correlating added wheel weights at different speeds for a tractor-reversible plow system. Six 94.5 m2 quadrants were analyzed for slippage monitored by RPA (Mavic3M-RTK) pre- and post-agricultural operation overflights and soil sampling (moisture, density, penetration resistance). A 2 × 2 factorial scheme (F-test) assessed soil-surface attribute correlations and slippage under varying ballasts (52.5–57.5 kg/hp) and speeds. Results showed slippage ranged from 4.06% (52.5 kg/hp, fourth reduced gear) to 11.32% (57.5 kg/hp, same gear), with liquid ballast and gear selection significantly impacting performance in friable clayey soil. Digital Elevation Model (DEM) and spectral indices derived from RPA imagery, including Normalized Difference Red Edge (NDRE), Normalized Difference Water Index (NDWI), Bare Soil Index (BSI), Green–Red Vegetation Index (GRVI), Visible Atmospherically Resistant Index (VARI), and Slope, proved effective. The approach reduced tractor slippage from 11.32% (heavy ballast, 4th gear) to 4.06% (moderate ballast, 4th gear), showing clear improvement in traction performance. The integration of indices and slope metrics supported ballast adjustment strategies, particularly for secondary plowing operations, contributing to improved traction performance and overall operational efficiency. Full article
(This article belongs to the Special Issue Utilization and Development of Tractors in Agriculture)
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12 pages, 7595 KB  
Article
Predictive Modeling of Shear Strength for Lotus-Type Porous Copper Bonded to Alumina
by Sang-Gyu Choi, Sangwook Kim, Jinkwan Lee, Keun-Soo Kim and Soongkeun Hyun
Metals 2025, 15(10), 1103; https://doi.org/10.3390/met15101103 (registering DOI) - 3 Oct 2025
Abstract
This study investigates the shear strength of lotus-type unidirectional porous copper bonded to alumina substrates using the Direct Bonded Copper (DBC) process. Porous copper specimens with various porosities (38.7–50.9%) and pore sizes (150–800 μm) were fabricated and joined to alumina discs. Shear [...] Read more.
This study investigates the shear strength of lotus-type unidirectional porous copper bonded to alumina substrates using the Direct Bonded Copper (DBC) process. Porous copper specimens with various porosities (38.7–50.9%) and pore sizes (150–800 μm) were fabricated and joined to alumina discs. Shear testing revealed that both porosity and pore size significantly affect the interfacial strength. While higher porosity led to reduced shear strength, larger pore sizes enhanced the maximum shear strength owing to increased local contact areas and crack coalescence in the alumina substrate. Fractographic analysis using optical microscopy and SEM-EDS confirmed that failure mainly occurred in the alumina, with local fracture associated with pore distribution and size. To improve strength prediction, a modified model was proposed, reducing the error from 12.3% to 7.5% and increasing the coefficient of determination (R²) from 0.43 to 0.74. These findings highlight the necessity of considering both porosity and pore size when predicting the shear strength of porous copper/alumina DBC joints, and they provide important insights for optimizing metal structures in metal–ceramic bonding for high-performance applications. Full article
(This article belongs to the Special Issue Fracture Mechanics of Metallic Materials—the State of the Art)
21 pages, 3715 KB  
Article
SPIRIT: Symmetry-Prior Informed Diffusion for Thangka Segmentation
by Yukai Xian, Yurui Lee, Liang Yan, Te Shen, Ping Lan, Qijun Zhao and Yi Zhang
Symmetry 2025, 17(10), 1643; https://doi.org/10.3390/sym17101643 (registering DOI) - 3 Oct 2025
Abstract
Thangka paintings, as intricate forms of Tibetan Buddhist art, present unique challenges for image segmentation due to their densely arranged symbolic elements, complex color patterns, and strong structural symmetry. To address these difficulties, we propose SPIRIT, a structure-aware and prompt-guided diffusion segmentation framework [...] Read more.
Thangka paintings, as intricate forms of Tibetan Buddhist art, present unique challenges for image segmentation due to their densely arranged symbolic elements, complex color patterns, and strong structural symmetry. To address these difficulties, we propose SPIRIT, a structure-aware and prompt-guided diffusion segmentation framework tailored for Thangka images. Our method incorporates a support-query-encoding scheme to exploit limited labeled samples and introduces semantic guided attention fusion to integrate symbolic knowledge into the denoising process. Moreover, we design a symmetry-aware refinement module to explicitly preserve bilateral and radial symmetries, enhancing both accuracy and interpretability. Experimental results on our curated Thangka dataset and the artistic ArtBench benchmark demonstrate that our approach achieves 88.3% mIoU on Thangka and 86.1% mIoU on ArtBench, outperforming the strongest baseline by 6.1% and 5.6% mIoU, respectively. These results confirm that SPIRIT not only captures fine-grained details, but also excels in segmenting structurally complex regions of artistic imagery. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry in Image Processing and Computer Vision)
37 pages, 10380 KB  
Article
FEWheat-YOLO: A Lightweight Improved Algorithm for Wheat Spike Detection
by Hongxin Wu, Weimo Wu, Yufen Huang, Shaohua Liu, Yanlong Liu, Nannan Zhang, Xiao Zhang and Jie Chen
Plants 2025, 14(19), 3058; https://doi.org/10.3390/plants14193058 (registering DOI) - 3 Oct 2025
Abstract
Accurate detection and counting of wheat spikes are crucial for yield estimation and variety selection in precision agriculture. However, challenges such as complex field environments, morphological variations, and small target sizes hinder the performance of existing models in real-world applications. This study proposes [...] Read more.
Accurate detection and counting of wheat spikes are crucial for yield estimation and variety selection in precision agriculture. However, challenges such as complex field environments, morphological variations, and small target sizes hinder the performance of existing models in real-world applications. This study proposes FEWheat-YOLO, a lightweight and efficient detection framework optimized for deployment on agricultural edge devices. The architecture integrates four key modules: (1) FEMANet, a mixed aggregation feature enhancement network with Efficient Multi-scale Attention (EMA) for improved small-target representation; (2) BiAFA-FPN, a bidirectional asymmetric feature pyramid network for efficient multi-scale feature fusion; (3) ADown, an adaptive downsampling module that preserves structural details during resolution reduction; and (4) GSCDHead, a grouped shared convolution detection head for reduced parameters and computational cost. Evaluated on a hybrid dataset combining GWHD2021 and a self-collected field dataset, FEWheat-YOLO achieved a COCO-style AP of 51.11%, AP@50 of 89.8%, and AP scores of 18.1%, 50.5%, and 61.2% for small, medium, and large targets, respectively, with an average recall (AR) of 58.1%. In wheat spike counting tasks, the model achieved an R2 of 0.941, MAE of 3.46, and RMSE of 6.25, demonstrating high counting accuracy and robustness. The proposed model requires only 0.67 M parameters, 5.3 GFLOPs, and 1.6 MB of storage, while achieving an inference speed of 54 FPS. Compared to YOLOv11n, FEWheat-YOLO improved AP@50, AP_s, AP_m, AP_l, and AR by 0.53%, 0.7%, 0.7%, 0.4%, and 0.3%, respectively, while reducing parameters by 74%, computation by 15.9%, and model size by 69.2%. These results indicate that FEWheat-YOLO provides an effective balance between detection accuracy, counting performance, and model efficiency, offering strong potential for real-time agricultural applications on resource-limited platforms. Full article
(This article belongs to the Special Issue Advances in Artificial Intelligence for Plant Research)
18 pages, 4581 KB  
Article
Metamaterial-Enhanced Microstrip Antenna with Integrated Channel Performance Evaluation for Modern Communication Networks
by Jasim Khudhair Salih Turfa and Oguz Bayat
Appl. Sci. 2025, 15(19), 10692; https://doi.org/10.3390/app151910692 (registering DOI) - 3 Oct 2025
Abstract
This paper investigates the channel performance through a high-gain, circularly polarized microstrip patch antenna that is developed for contemporary wireless communication systems. The proposed antenna creates two orthogonal modes for circular propagation with slightly varying resonance frequencies by using a cross line and [...] Read more.
This paper investigates the channel performance through a high-gain, circularly polarized microstrip patch antenna that is developed for contemporary wireless communication systems. The proposed antenna creates two orthogonal modes for circular propagation with slightly varying resonance frequencies by using a cross line and truncations to circulate surface currents. Compactness, reduced surface wave losses, and enhanced impedance bandwidth are made possible by the coaxial probe feed, periodic electromagnetic gap (EBG) slots, and fractal patch geometry. For in-phase reflection and beam focusing, a specially designed single-layer metasurface (MTS) reflector with an 11 × 11 circular aperture array is placed 20 mm behind the antenna. A log-normal shadowing model was used to test the antenna in real-world scenarios, and the results showed a strong correlation between the model predictions and actual data. At up to 250 m, the polarization-agile, high-gain antenna demonstrated reliable performance across a variety of channel conditions, enabling accurate characterization of the Channel Quality Indicator (CQI), Signal-to-Noise Ratio (SNR), and Reference Signal Received Power (RSRP). By combining cutting-edge antenna architecture with an empirical channel performance study, this research presents a compact, affordable, and fabrication-friendly solution for increased wireless coverage and efficiency. Full article
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21 pages, 879 KB  
Article
Marine Mammals’ Fauna Detection via eDNA Methodology in Pagasitikos Gulf (Greece)
by Elena Akritopoulou, Athanasios Exadactylos, Anastasia Komnenou, Joanne Sarantopoulou, Christos Domenikiotis and Georgios A. Gkafas
Diversity 2025, 17(10), 692; https://doi.org/10.3390/d17100692 - 3 Oct 2025
Abstract
Marine mammals are important ecological bio-indicators of marine ecosystems impacted by a plethora of anthropogenic and environmental threats. Genomics detects genetic variation, adaptation to environmental shifts, and susceptibility to diseases in marine mammal species. In this study, eDNA was utilized for the first [...] Read more.
Marine mammals are important ecological bio-indicators of marine ecosystems impacted by a plethora of anthropogenic and environmental threats. Genomics detects genetic variation, adaptation to environmental shifts, and susceptibility to diseases in marine mammal species. In this study, eDNA was utilized for the first time in the Pagasitikos Gulf over three consecutive years (2022–2024) in order to detect marine mammal species. Additionally, visual monitoring and eDNA results were compared to reveal the pros and cons of the two methodologies. The gulf was zoned into five different areas with respect to oceanographic features for sampling. DNA extraction was assessed by using a standard protocol of phenol–chloroform followed by PCR amplification using the 16S rRNA gene. A total of 5,209,613 highly filtered sequence reads were attributed to 108 species. Among these, Monachus monachus, Tursiops truncatus, and Ziphius cavirostris species were detected. This novel detection of Z. cavirostris in the relatively shallow waters of the Gulf of Pagasitikos raised the question of whether it was a random event or a new ecological trend. Z. cavirostris and M. monachus appeared to share the same marine areas within the gulf. In the era of the climate crisis, eDNA provides essential information on marine mammals’ ecological status, yields novel detections, and predicts behavioral changes essential to deep-diving species. Full article
13 pages, 2022 KB  
Article
Assessment of Standing and Felled Tree Measurements for Volume Estimation
by Maria Triantafyllidou, Elias Milios and Kyriaki Kitikidou
Forests 2025, 16(10), 1540; https://doi.org/10.3390/f16101540 - 3 Oct 2025
Abstract
Accurate stem-volume estimation supports inventory, valuation and carbon accounting, but Pressler’s single-section formula has never been tested in the highly productive European-beech forests of the Central Rhodope Mountains, Greece. We quantified the bias of Pressler estimates and developed size-specific correction factors. Sixty Fagus [...] Read more.
Accurate stem-volume estimation supports inventory, valuation and carbon accounting, but Pressler’s single-section formula has never been tested in the highly productive European-beech forests of the Central Rhodope Mountains, Greece. We quantified the bias of Pressler estimates and developed size-specific correction factors. Sixty Fagus sylvatica L. trees felled in 2023–2024 were measured destructively at 1-m intervals. Pressler standing volumes were compared with Smalian-plus-cone reference volumes (hereafter referred to as true volumes) and analysed with generalized additive models. Pressler underestimated true volume (mean bias = −0.088 m3; RMSE = 0.204 m3; MAPE = 21%). Under-estimation increased with diameter. A GAM with DBH and height explained 96.7% of the variance in true volume. We also fit a Random Forest as a complementary check. Multipliers of 1.30 (<25 cm DBH), 1.20 (25–45 cm), 1.30 (45–55 cm) and ≥1.35 (≥55 cm) cut residual error to ≤20% overall and <10% inside the well-sampled 35–45 cm class. A simple DBH-class correction table restores Pressler’s speed while meeting modern accuracy standards for inventory and carbon reporting. Full article
(This article belongs to the Section Forest Inventory, Modeling and Remote Sensing)
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22 pages, 16284 KB  
Article
C5LS: An Enhanced YOLOv8-Based Model for Detecting Densely Distributed Small Insulators in Complex Railway Environments
by Xiaoai Zhou, Meng Xu and Peifen Pan
Appl. Sci. 2025, 15(19), 10694; https://doi.org/10.3390/app151910694 - 3 Oct 2025
Abstract
The complex environment along railway lines, characterized by low imaging quality, strong background interference, and densely distributed small objects, causes existing detection models to suffer from low accuracy in practical applications. To tackle these challenges, this study aims to develop a robust and [...] Read more.
The complex environment along railway lines, characterized by low imaging quality, strong background interference, and densely distributed small objects, causes existing detection models to suffer from low accuracy in practical applications. To tackle these challenges, this study aims to develop a robust and lightweight insulator detection model specifically optimized for these challenging railway scenarios. To this end, we release a dedicated comprehensive dataset named complexRailway that covers typical railway scenarios to address the limitations of existing insulator datasets, such as the lack of small-scale objects in high-interference backgrounds. On this basis, we present CutP5-LargeKernelAttention-SIoU (C5LS), an improved YOLOv8 variant with three key improvements: (1) optimized YOLOv8’s detection head by removing the P5 branch to improve feature extraction for small- and medium-sized targets while reducing computational redundancy, (2) integrating a lightweight Large Separable Kernel Attention (LSKA) module to expand the receptive field and improve contextual modeling, (3) and replacing CIoU with SIoU loss to refine localization accuracy and accelerate convergence. Experimental results demonstrate that it reaches 94.7% in mAP@0.5 and 65.5% in mAP@0.5–0.95, outperforming the baseline model by 1.9% and 3.5%, respectively. With an inference speed of 104 FPS and a model size of 13.9 MB, the model balances high precision and lightweight deployment. By providing stable and accurate insulator detection, C5LS not only offers reliable spatial positioning basis for subsequent defect identification but also builds an efficient and feasible intelligent monitoring solution for these failure-prone insulators, thereby effectively enhancing the operational safety and maintenance efficiency of the railway power system. Full article
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28 pages, 7165 KB  
Article
Phosphate Low-Melting Glasses as Synergist in Flame-Retardant Cable Sheath Composition: Performance and Mode of Action
by Diana Amin Alsayed, Rodolphe Sonnier, Belkacem Otazaghine, Patrick Jean, Yves Brocheton and Laurent Ferry
Polymers 2025, 17(19), 2679; https://doi.org/10.3390/polym17192679 - 3 Oct 2025
Abstract
Nowadays, fiber optic cables are a strategic issue because of their importance in telecommunications. Due to the densification of optic cables and the reduction in polymeric layer thickness, the flammability of the external sheath has to be improved. Three novel flame-retardant compositions using [...] Read more.
Nowadays, fiber optic cables are a strategic issue because of their importance in telecommunications. Due to the densification of optic cables and the reduction in polymeric layer thickness, the flammability of the external sheath has to be improved. Three novel flame-retardant compositions using phosphate low-melting glasses (LMGs) as aluminum trihydrate (ATH) synergist were assessed in a polyethylene–ethylene vinyl acetate (PE-EVA) matrix. It was highlighted that LMG at a 10 wt% content reduced the peak and mean value of heat release rate (HRR), respectively, to 142 and 90 kW/m2 corresponding to 52% and 42% reduction compared to ATH only. Potassium phosphate LMG was shown to perform better than sodium or zinc phosphate LMG. The improvement was assigned to the formation of an expanded mineral layer at the surface of the material during combustion that acts as a thermal shield slowing down the pyrolysis rate. The structural analysis revealed that the presence of alkaline cations in glasses led to short phosphate chains that resulted in low softening point and low-viscosity liquid. It was evidenced that under heat exposure the melted glass is likely to flow between the dehydrating ATH particles, creating a cohesive layer that expands. Additionally, interactions between ATH and LMG were also evidenced. The new crystalline species may also play a role in the cohesion of the layer. Full article
(This article belongs to the Special Issue Flame-Retardant Polymer Composites II)
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19 pages, 2645 KB  
Article
Sol–Gel Synthesis of Carbon-Containing Na3V2(PO4)3: Influence of the NASICON Crystal Structure on Cathode Material Properties
by Oleg O. Shichalin, Zlata E. Priimak, Alina Seroshtan, Polina A. Marmaza, Nikita P. Ivanov, Anton V. Shurygin, Danil K. Tsygankov, Roman I. Korneikov, Vadim V. Efremov, Alexey V. Ognev and Eugeniy K. Papynov
J. Compos. Sci. 2025, 9(10), 543; https://doi.org/10.3390/jcs9100543 (registering DOI) - 3 Oct 2025
Abstract
With the rapid advancement of energy storage technologies, there is a growing demand for affordable, efficient, and environmentally benign battery systems. Sodium-ion batteries (SIBs) present a promising alternative to lithium-ion systems due to sodium’s high abundance and similar electrochemical properties. Particular attention is [...] Read more.
With the rapid advancement of energy storage technologies, there is a growing demand for affordable, efficient, and environmentally benign battery systems. Sodium-ion batteries (SIBs) present a promising alternative to lithium-ion systems due to sodium’s high abundance and similar electrochemical properties. Particular attention is given to developing NASICON -sodium (Na) super ionic conductor, type cathode materials, especially Na3V2(PO4)3, which exhibits high thermal and structural stability. This study focuses on the sol–gel synthesis of Na3V2(PO4)3 using citric acid and ethylene glycol, as well as investigating the effect of annealing temperature (400–1000 °C) on its structural and electrochemical properties. Phase composition, morphology, textural characteristics, and electrochemical performance were systematically analyzed. Above 700 °C, a highly crystalline NASICON phase free of secondary impurities was formed, as confirmed by X-ray diffraction (XRD). Microstructural evolution revealed a transition from a loose amorphous structure to a dense granular morphology, accompanied by changes in specific surface area and porosity. The highest surface area (67.40 m2/g) was achieved at 700 °C, while increasing the temperature to 1000 °C caused pore collapse due to sintering. X-ray photoelectron spectroscopy (XPS) confirmed the predominant presence of V3+ ions and the formation of V4+ at the highest temperature. The optimal balance of high crystallinity, uniform elemental distribution, and stable texture was achieved at 900 °C. Electrochemical testing in a Na/NVP half-cell configuration delivered an initial capacity of 70 mAh/g, which decayed to 55 mAh/g by the 100th cycle, attributed to solid-electrolyte interphase (SEI) formation and irreversible Na+ trapping. These results demonstrate that the proposed approach yields high-quality Na3V2(PO4)3 cathode materials with promising potential for sodium-ion battery applications. Full article
(This article belongs to the Special Issue Composite Materials for Energy Management, Storage or Transportation)
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