Search Results (31)

This work studies the Purcell effect of two quasiperiodic multilayers of gold and titanium dioxide following the Thue–Morse and Fibonacci sequence, respectively. We systematically investigated the impacts of polarization direction, dipole height, and wavelength on the Purcell factor. Additionally, we compared the normalized field distribution profiles across all multilayer structures. Concurrently, under varying polarizations, we computed the radiative part of the Purcell factor, photoluminescence at the reflection and transmission side of multilayers, respectively. Our findings indicate that under near-field excitation conditions, the Purcell factor is predominantly governed by its non-radiative component rather than the radiative one. We attribute the observed discrepancies in the Purcell factor to variations in the intensity and spatial distribution of non-radiative losses within the metallic components of the multilayers. This mechanism provides a robust physical foundation for exploring and extending the applications of photonic quasicrystals in the modulation of nanoscale light–matter interactions. Furthermore, we examined cavities constructed from symmetric multilayers. Under z-polarization and long-wavelength conditions, the cavity effect was observed to enhance the radiative part of the Purcell factor, thereby further boosting spontaneous emission efficiency. This work offers novel insights into the design of semiconductor devices with improved quantum emission efficiency and photoluminescence. Full article

Magnetic anapole states associated with the destructive interference between magnetic dipole and magnetic toroidal moments result in suppressed scattering accompanied by strongly enhanced near fields. Here, we demonstrate the existence of such modes in the gap of a gold oblate nano-ellipsoid on gold mirror (ONEOM) structures and observe a pronounced Purcell factor enhancement for magnetic dipole radiation upon introducing magnetic dipoles into the gap. We systematically investigate the dependence of the magnetic radiation Purcell factor on gap size and structural parameters. Notably, a 230-fold Purcell factor enhancement is achieved for the ONEOM configuration. This result highlights the potential of ONEOM structures in applications requiring efficient magnetic dipole emission, including nonlinear frequency conversion, plasmonic sensing, and single-photon sources. Full article

In recent years, in situ blasting–leaching, in the stope has emerged as an economically viable and environmentally sustainable mining technique for low-grade ore deposits. While the leaching efficiency is influenced by factors such as ore type, solution composition, and spraying speed, the most significant factor is the effect of post-blasting crushed-stone particle size and gradation on the pore structure, which subsequently influences seepage and leaching performance. To investigate how particle size and gradation affect the pore structure of granular media, physical models of ore particles with varying sizes and gradations were constructed. These models were scanned and three-dimensionally reconstructed using CT scanning technology and Avizo software (Avizo, Version 2023.1; Thermo Fisher Scientific: Waltham, MA, USA, 2023) enabling quantitative analysis of pore structure parameters. The results indicate that the coefficient of uniformity (Cu) is approximately negatively correlated with porosity, while the vertical absolute permeability (kz) follows an attenuated exponential trend. When the fine-particle content (L8 > L3 > L1) increases by 1.5-fold and 9-fold, the number of pore throats increases by 8.71% and 30.91%, respectively, the average pore size decreases by 75.1% and 64.4%, the average throat size decreases by 66.3% and 60%, and the connectivity rate decreases by 92% and 77.8%. This study further evaluates permeability based on the aforementioned pore structure parameters. Multiple regression analysis reveals that the connectivity rate and throat size have the most significant influence on permeability. Accordingly, permeability analysis and prediction are conducted using the improved Purcell formula, which demonstrates a strong correlation with the experimentally measured results. Full article

Integrated light-emitting diodes (LEDs) with waveguides play an important role in applications such as augmented reality (AR) displays, particularly regarding coupling efficiency optimization. Quantum dot light-emitting diodes (QLEDs), an emerging high-performance optoelectronic device, demonstrate substantial potential for next-generation display technologies. This study investigates the influence of microcavity modulation on the output of QLEDs coupled with a silicon nitride (SiNx) waveguide by simulating a white light QLED (W-QLED) with a broad spectrum and mixed RGB QDs (RGB-QLED) with a comparatively narrower spectrum. The microcavity converts both W-QLED and RGB-QLED emissions from broadband white-light emissions into narrowband single-wavelength outputs. Specifically, both of them have demonstrated wavelength tuning and full-width at half-maximum (FWHM) narrowing across the visible spectrum from 400 nm to 750 nm due to the microcavity modulation. The resulting RGB-QLED achieves a FWHM of 11.24 nm and reaches 110.76% of the National Television System Committee 1953 (NTSC 1953) standard color gamut, which is a 20.95% improvement over W-QLED. Meanwhile, due to the Purcell effect of the microcavity, the output efficiency of the QLED coupled with a SiNx waveguide is also significantly improved by optimizing the thickness of the Ag anode and introducing a tilted reflective mirror into the SiNx waveguide. Moreover, the optimal output efficiency of RGB-QLED with the tilted Ag mirror is 10.13%, representing a tenfold increase compared to the sample without the tilted Ag mirror. This design demonstrates an efficient and compact approach for the near-eye full-color display technology. Full article

We propose a micro-electromechanical system (MEMS)-integrated Fabry–Pérot (F–P) microcavity designed for a tunable single-photon source based on a single semiconductor quantum dot (QD). Through theoretical simulations, our design achieved a Purcell factor of 23, a photon extraction efficiency exceeding 88%, and an optical cavity mode tuning range of more than 30 nm. Experimentally, we fabricated initial device prototypes using a micro-transfer printing process and demonstrated a tuning range exceeding 15 nm. The device exhibits high mechanical stability, full reversibility, and minimal hysteresis, ensuring reliable operation over multiple tuning cycles. Our findings highlight the potential of MEMS-integrated F–P microcavities for scalable, tunable single-photon sources. Furthermore, reaching a strong coupling regime could enable efficient single-photon routing, opening new possibilities for integrated quantum photonic circuits. Full article

Metasurfaces, composed of engineered nanoantennas, enable unprecedented control over electromagnetic waves by leveraging multipolar resonances to tailor light–matter interactions. This review explores key physical mechanisms that govern their optical properties, including the role of multipolar resonances in shaping metasurface responses, the emergence of bound states in the continuum (BICs) that support high-quality factor modes, and the Purcell effect, which enhances spontaneous emission rates at the nanoscale. These effects collectively underpin the design of advanced photonic devices with tailored spectral, angular, and polarization-dependent properties. This review discusses recent advances in metasurfaces and applications based on them, highlighting research that employs full-wave numerical simulations, analytical and semi-analytic techniques, multipolar decomposition, nanofabrication, and experimental characterization to explore the interplay of multipolar resonances, bound and quasi-bound states, and enhanced light–matter interactions. A particular focus is given to metasurface-enhanced photodetectors, where structured nanoantennas improve light absorption, spectral selectivity, and quantum efficiency. By integrating metasurfaces with conventional photodetector architectures, it is possible to enhance responsivity, engineer photocarrier generation rates, and even enable functionalities such as polarization-sensitive detection. The interplay between multipolar resonances, BICs, and emission control mechanisms provides a unified framework for designing next-generation optoelectronic devices. This review consolidates recent progress in these areas, emphasizing the potential of metasurface-based approaches for high-performance sensing, imaging, and energy-harvesting applications. Full article

The Purcell’s swimmer, consisting of three links with two one-degree-of-freedom joints as defined by Edward M. Purcell, has been studied by several authors since its introduction in 1977. Researchers have delved into its mathematical foundations, analysing and optimising its motion for efficient propulsion. However, despite these theoretical advances, the practical realisation and experimental characterisation of Purcell’s swimmers remains relatively unexplored. Critical aspects such as material selection, manufacturing techniques, and experimental validation under real conditions represent important knowledge gaps. This paper contributes to bridging this gap by presenting a prototype of such a swimmer using ionic polymer-metal composites (IPMC) as link actuators. A simulation model is developed based on physical modelling tools in MATLAB^®/Simulink^®. Both simulation and experimental results at low-Reynolds-number ($Re$) conditions are presented to demonstrate the performance of the swimmer. Full article

The use of nanostructures to enhance the emission of single-photon sources has attracted some attention in the last decade due to the development of quantum technologies. In particular, the use of metallic and high-refractive-index dielectric materials has been proposed. However, the utility of moderate-refractive-index dielectric nanostructures to achieve more efficient single-photon sources remains unexplored. Here, a systematic comparison of various metallic, high-refractive-index and moderate-refractive-index dielectric nanostructures was performed to optimize the excitation and emission of a CdSe/ZnS single quantum dot in the visible spectral region. Several geometries were evaluated in terms of electric field enhancement and Purcell factor, considering the combination of metallic, high-refractive-index and moderate-refractive-index dielectric materials conforming to homogeneous and hybrid nanoparticle dimers. Our results demonstrate that moderate-refractive-index dielectric nanoparticles can enhance the photoluminescence signal of quantum emitters due to their broader electric and magnetic dipolar resonances compared to high-refractive-index dielectric nanoparticles. However, hybrid combinations of metallic and high-refractive-index dielectric nanostructures offer the largest intensity enhancement and Purcell factors at the excitation and emission wavelengths of the quantum emitter, respectively. The results of this work may find applications in the development of single-photon sources. Full article

Advanced ¹H Nuclear Magnetic Resonance (NMR) relaxometry and diffusometry methods and VIS-nearIR spectroscopy combined with pH, electrical conductivity (EC) and totally dissolved solids (TDSSs) measurements were used to assess the properties of wastewater collected from a chicken slaughterhouse in each step of the treatment process (wastewater before treatment, biologically treated wastewater, chemically treated wastewater and discharged wastewater) and from sludge. The ¹H NMR Carr–Purcell–Meiboom–Gill (CPMG) and Pulsed-Gradient-Stimulated-Echo (PGSE) decay curves recorded for all samples of wastewater were analyzed by inverse Laplace transform (ILT) to obtain the distributions of transverse relaxation times T₂ and diffusion coefficient D. The VIS-nearIR total absorbance, T₂-values, D-values, pH, EC and TDSS parameters were used for statistical analysis in principal component (PCA). The ¹H T₂-distributions measured for the slaughterhouse wastewater lie in two main regions reflecting the number of dissolved solids or the distribution of undissolved solids. The PCA analysis successfully differentiates between polluted and less polluted wastewaters and sludge. The wastewater treatment applied by the slaughterhouse is efficient. The recommended methods for wastewater monitoring are the NMR T₂- and D-distributions and EC, TDSSs and NMR-D diffusion coefficient. Finally, Machine Learning algorithms are used to provide prediction maps of wastewater treatment stage. Full article

The advent of low-field nuclear magnetic resonance (LF-NMR) has revolutionized the petroleum industry by providing a swift and straightforward method for the spectroscopic characterization of crude oil. This review paper delves into the significant strides made in LF-NMR technology since its inception by Felix Bloch and Edward Purcell in 1946, particularly its application in determining the composition, viscosity, and water content of crude oil, alongside SARA (Saturates, Aromatics, Resins, and Asphaltenes) analysis. LF-NMR’s ability to noninvasively quantify the total water and oil content, differentiate between bound and mobile phases, and measure the SARA fractions underscores its superiority over traditional analysis methods, which often suffer from interference and lack of precision. This manuscript not only highlights LF-NMR’s pivotal role in enhancing crude-oil characterization but also reviews recent developments that solidify its position as an indispensable tool in the petroleum industry. The convergence of empirical studies and technological advancements points toward a pressing need for further research to fully exploit LF-NMR’s potential and refine its application, ensuring its continued contribution to the efficient and accurate analysis of petroleum products. Full article

We investigate the utilization of advanced single photons produced by quantum dots (QDs) in a microcavity for quantum metrology. Through the integration of lateral excitation and the Purcell effect in an Fabry–Perot microcavity, we realized single-photon emission with an extraction efficiency of 46.39%, high purity of 96.91%, and high indistinguishability of 98.32%. Our QD-generated single photons enabled the creation of high-quality NOON states (N = 2) for phase measurement, yielding an interference contrast of 79.79% and surpassing the standard quantum limit (SQL) with phase super-sensitivity. Our results underscore the immense potential of QD-derived single photons for propelling quantum metrology forward, facilitating enhanced precision measurements across diverse applications. Full article

High directional emission and high radiative quantum efficiency are strongly needed when moving a single optical nano-emitter (such as a quantum dot) into the practical realm. However, a typical optical nano-emitter struggles to meet the requirements above, which limits its practical applications in next-generation nano-photonic devices such as single-photon sources. Here, to achieve these features simultaneously, we propose and theoretically investigate a composite plasmonic antenna consisting of a hemispherical solid immersion lens (SIL) and a bowtie plasmonic nano-antenna, wherein a high directional emission of 10° and 2.5 × 10³ of Purcell factor have both been enabled. Moreover, we find that directionality and the Purcell factor can be manipulated independently in our antenna, which provides a novel platform for the optimization of single-photon sources. Full article

With the aim to develop novel scaffolds for the sustained release of drugs, we initially developed an easy approach for the synthesis of α,ω-homobifunctional mercaptoacyl poly(alkyl oxide)s. This was based on the esterification of the terminal hydroxyl groups of poly(alkyl oxide)s with suitably S-4-methoxytrityl (Mmt)-protected mercapto acids, followed by the removal of the acid labile S-Mmt group. This method allowed for the efficient synthesis of the title compounds in high yield and purity, which were further used in the development of a thioether cross-linked liposome scaffold, by thia–Michael reaction of the terminal thiol groups with pre-formed nano-sized liposomes bearing maleimide groups on their surface. The reaction process was followed by ¹H-NMR, using a Carr–Purcell–Meiboom–Gill (CPMG) relaxation dispersion NMR experiment (¹H-NMR CPMG), which allowed for real-time monitoring and optimization of the reaction process. The thioether cross-linked liposomal scaffold that was synthesized was proven to preserve the nano-sized characteristics of the initial liposomes and allowed for the sustained release of calcein (which was used as a hydrophilic dye and a hydrophilic drug model), providing evidence for the efficient synthesis of a novel drug release scaffold consisting of nanoliposome building blocks. Full article

Optimal design of a silicon nitride waveguide structure composed of resonant nanoantennas for efficient light coupling with interlayer exciton emitters in a MoSe${}_2$–WSe${}_2$ heterostructure is proposed. Numerical simulations demonstrate up to eight times coupling efficiency improvement and twelve times Purcell effect enhancement in comparison with a conventional strip waveguide. Achieved results can be beneficial for development of on-chip non-classical light sources. Full article

In this paper, we describe the effect of local electric field enhancement due to the existence of photonic edge states in a nanoplasmonic crystal. These states can be excited by a normal incident wave and are localized along the continuous line defect, where translational symmetry is broken. The nanoplasmonic crystal is formed by a triangular lattice of SiO₂ cylinders on top of SiO₂ and Ag thin films. Numerical simulations demonstrated that edge modes that are concentrated around a defect in a nanophotonic crystal may result in 12 field enhancements of the electric field for the incident plane wave of wavelength 545 nm. This effect can be employed for improving the sensitivity of surface-enhanced Raman scattering (SERS) spectroscopy, increasing the Purcell factor of quantum systems and improving the efficiency of higher harmonic generation. Full article