Search Results (5,803)

Polyvinyl chloride (PVC) is widely used in engineering applications; however, its inherent thermal instability associated with dehydrochlorination limits its processing window and long-term performance. While blending with thermoplastic polyurethane (TPU) and plasticization are common strategies to improve flexibility, their combined influence on the thermal behavior and stability of PVC, particularly when bio-based plasticizers are employed, has not been thoroughly investigated. In this study, the thermal behavior and stability of PVC/TPU blends plasticized with glycerol diacetate monolaurate, a bio-based plasticizer derived from waste cooking oil, were investigated. Dynamic mechanical analysis (DMA) and Fourier transform infrared spectroscopy (FTIR) were used to examine segmental mobility and intermolecular interactions, while scanning electron microscopy (SEM) provided insight into microstructural organization. Thermal stability was evaluated through conductivity-based dehydrochlorination measurements, complemented by thermogravimetric and derivative thermogravimetric analyses (TGA/DTG) to assess degradation behavior. The results showed that neither TPU nor the bio-plasticizer alone improved the resistance of PVC to dehydrochlorination. In contrast, ternary PVC/TPU/bio-plasticizer blends exhibited a pronounced delay in HCl evolution, accompanied by a more homogeneous phase distribution and interaction-driven modification of the molecular environment. TGA/DTG analysis indicated that this stabilization arises from altered degradation kinetics rather than a simple shift in degradation onset. Overall, the findings clarify the thermal behavior of PVC-based blends and demonstrate a sustainable formulation approach for achieving flexible and thermally balanced PVC materials while reducing reliance on potentially toxic phthalate plasticizers. Full article

Aluminum–graphene nanoplatelet (Al/GNP) composites have attracted significant attention as lightweight structural materials, yet their mechanical performance is strongly influenced by interfacial reactions and the formation of carbides. In this study, Al/GNP composites containing 0.1–1.1 wt.% graphene were produced via powder metallurgy and hot extrusion at 400 °C and 500 °C. Hot extrusion at the higher temperature enables the controlled in situ formation of aluminum carbide (Al₄C₃). A comprehensive microstructural characterization using SEM and HRTEM was combined with tensile testing to elucidate the influence of carbide size on mechanical behavior. Hot extrusion at 500 °C promotes the formation of uniformly distributed, nanoscale Al₄C₃ carbides whose size, morphology, and aspect ratio depend on graphene content. Composites containing nano-sized carbides exhibit a markedly improved strength–ductility balance compared to carbide-free counterparts, with optimal performance achieved at 0.3 and 0.7 wt.% GNPs. The enhancement is attributed to synergistic strengthening mechanisms involving improved interfacial bonding, efficient load transfer, nanoscale dispersion strengthening, and carbide–dislocation interactions. The results indicate that the controlled formation of nanoscale Al₄C₃ is not detrimental; rather, it contributes to the optimization of the mechanical properties of Al/GNP composites. Unlike most previous studies that treat carbide formation as a detrimental effect, this work demonstrates that its controlled nanoscale evolution can be used as a deliberate strengthening strategy through its influence on microstructural mechanisms. Full article

Large-scale reuse of copper tailings can mitigate environmental hazards and recover strategic elements; this work investigates the feasibility of producing foam glass-ceramics with high copper-tailing content (>70 wt%) by tuning the CaO/SiO₂ ratio to couple melt viscosity and crystallisation. The comprehensive utilisation of these tailings helps mitigate environmental pollution and enhance resource efficiency. In this study, foam glass-ceramics with varying CaO/SiO₂ ratios were synthesised through melt quenching followed by foaming heat treatment. The effects of different CaO/SiO₂ ratios on the foaming behaviour, crystallisation, and microstructure were investigated using DSC, FTIR, viscosity, XRD, SEM, and CT. The results indicate that increasing the CaO/SiO₂ ratio disrupts the three-dimensional network structure of the glass, which lowers the glass viscosity and influences the bubble size and distribution in the foam glass-ceramics. Additionally, the increased CaO content promotes crystal precipitation and enhances the compressive strength of the foam glass-ceramics. At a CaO/SiO₂ mass ratio of 0.22, the foam glass-ceramics exhibited the lower bulk density (240 kg/m³) and thermal conductivity (0.07 W/m·K). The materials also demonstrated good water absorption and compressive strength. This study highlights the potential of using copper tailings in foam glass-ceramics to improve their overall performance, offering promising energy-saving and environmentally friendly solutions. Full article

The efficient recovery of coalbed methane (CBM) is critically constrained by the inherent low permeability of coal reservoirs, a challenge predominantly attributed to mineral blockages within the pore-fracture structure. In this study, the deashing efficacy of several acid solutions (HCl, HNO₃, HF, and CH₃COOH) on bituminous coals from the Yushuwan (YSW) and Jiangna (JN) mines was initially assessed to determine the optimal acidizing system. Subsequently, the multi-scale evolution of pore-fracture structures and the fractal characteristics of coal samples treated with the optimized acids were systematically investigated. A multi-analytical approach, integrating scanning electron microscopy (SEM), X-ray diffraction (XRD) with microcrystalline peak-fitting, and low-temperature nitrogen gas adsorption (LT-N₂GA), was employed to quantitatively elucidate the underlying transformation mechanisms. The experimental results indicate that HCl and HNO₃ emerged as the most effective agents for the YSW and JN coals, respectively. Optimized acidification achieved significant reductions in ash content (specifically, an ash removal efficiency of 83.99% for HCl-treated YSW coal) through the selective dissolution of carbonate and clay minerals, thereby facilitating the exposure of the organic matrix and the induction of extensive dissolution pits and secondary fractures. Although the dissolution-induced collapse of mineral-supported fine pores led to a reduction in both total pore volume and BET specific surface area, the average pore diameter undergoes a substantial increase (e.g., nearly doubling from 9.0068 nm to 16.5126 nm for the JN coal). Furthermore, the reduction in Frenkel–Halsey–Hill (FHH) fractal dimensions (D₁ and D₂) indicates a decrease in pore-surface complexity and structural heterogeneity. These findings reveal that optimized acidification induces significant alterations in pore structure and mineral composition. The treatment facilitates the conversion of isolated pores into interconnected networks, accompanied by an increase in pore volume and a shift in pore size distribution toward larger dimensions. This research elucidates the mechanisms of mineral dissolution and pore expansion, providing a fundamental characterization of the microstructural evolution of coal in response to acid treatment. Full article

The stabilization of soft, organic-rich soils with cement is often hindered by retarded hydration and poor long-term performance under cyclic loads. While nano-silica or sand are known modifiers, their individual efficacy in high-organic environments remains limited, and a systematic comparison of their composite effect across different soil types is lacking. This study investigates the synergistic enhancement of cement-stabilized soils using a combined nano-SiO₂ and sand composite, comparing its effectiveness in high-organic soft soil and low-organic clay. Laboratory tests, including unconfined compressive strength (UCS), cyclic loading, scanning electron microscopy (SEM), and X-ray diffraction (XRD), were conducted. Results showed a stark contrast in 28-day UCS between unmodified soft soil cement (0.13 MPa) and clay cement (1.04 MPa). The optimal composite of 3.5% nano-SiO₂ and 40% sand increased the 28-day UCS to 1.39 MPa for soft soil (a 969% improvement) and 5.51 MPa for clay (a 430% improvement), respectively. Notably, under a cyclic stress ratio (CSR) of 0.7~0.8, unmodified specimens failed after fewer than 120 load cycles, whereas the composite-modified soils withstood 20,000 cycles without failure, demonstrating exceptional fatigue resistance independent of static strength gain. Microstructural analysis revealed that the composite effectively promoted the formation of cementitious hydration products, counteracting the inhibitory effect of organic matter. This research demonstrates that the nano-silica sand composite provides a superior and more broadly applicable improvement for cement-stabilized soils across the tested organic content range (3.3–7.7% LOI) compared to single-additive approaches, significantly enhancing both mechanical strength and long-term durability. Full article

High-content cemented soils are critical for modern geotechnical technologies (e.g., pre-bored precast piles), yet their long-term durability remains underexplored. This study investigates the 28- to 365-day mechanical and microstructural evolution of high-content cemented silty clay under freshwater and seawater curing via UCS, SEM, MIP, and XRD. Under freshwater, cement content directly dictated strength, with the 8:2 mix reaching 24.31 MPa at 365 days. However, marginal efficiency analysis confirmed diminishing returns for excessive binder, establishing the 7:3 ratio as the optimal baseline. Seawater exposure induced a biphasic response: a 4.6% early strength gain at 28 days, followed by severe degradation (a 23.5% drop at 365 days). Concurrently, the failure mode shifted to macroscopic “pseudo-ductility,” with peak strain increasing from 2.37% to 3.04%. Crucially, a micro–macro inconsistency emerged: although seawater physically refined the pore structure (micropore proportion doubled to 30.2% at 90 days) via expansive salts filling mesopores, macroscopic strength declined. XRD confirmed this degradation coincides with severe long-term alkaline buffer (Ca(OH)₂) depletion. Consequently, lifecycle durability assessments for high-binder marine systems must not rely solely on physical metrics like porosity, but adopt a coupled multi-factor framework prioritizing chemical stability. Full article

Steel slags are major by-products of steelmaking, and their variable composition complicates recycling and valorization strategies. This study investigates four representative slag samples obtained from different production pathways at an industrial steel plant in Uzbekistan, using a combined multi-scale characterization approach. Bulk elemental composition was determined using X-ray fluorescence (XRF), while microstructural and phase-level analysis was carried out using scanning electron microscopy with energy-dispersive spectroscopy (SEM–EDS), including both point analysis and automated phase mapping. The XRF results revealed two distinct compositional groups, with one slag dominated by Mn–Si–O chemistry and three slags characterized by high Ca content. SEM–EDS phase mapping further resolved these differences at the microscale, identifying manganese silicate and oxide phases in the Mn-rich slag, Ca–F–O dominant phases in two slags associated with fluorite flux addition, and a more heterogeneous Ca-based system with localized enrichments of Mn, Zn, and Cu in the fourth sample. The combined results demonstrate that slag composition strongly reflects steel grade and fluxing practice. The integration of XRF and SEM–EDS provides a robust framework for linking bulk chemistry with phase distribution, improving slag classification and supporting informed decisions for reuse and environmental management. Full article

This study investigates the hardening behavior of adhesives used in retard-bonded prestressed tendons, with a focus on establishing a quantitative relationship between aging time and Shore hardness to enable rapid on-site assessment of curing degree. Accelerated curing tests were conducted at a constant temperature of 45 °C on three adhesive series with different standard curing periods. Cone penetration, Shore hardness, and tensile shear strength were measured at regular intervals throughout the curing process. Microstructural evolution was characterized using SEM-EDX. The results show that cone penetration decreases stepwise with aging time, while Shore hardness and tensile shear strength increase monotonically. A significant linear correlation (R² > 0.995) between Shore hardness and tensile shear strength was observed across all specimens. A novel logarithmic model is proposed to describe the evolution of relative Shore hardness as a function of relative aging time, achieving an R² of 0.911. This model enables prediction of vadhesive hardness at any given time under 45 °C conditions, providing a practical tool for construction quality control. The findings offer a new pathway for non-destructive evaluation of adhesive curing in retard-bonded prestressed systems. Full article

Nickel-based superalloy GH3625 is widely used in extreme environments due to its exceptional high-temperature strength and corrosion resistance; however, optimizing its comprehensive performance through precise microstructural control remains a critical challenge. In this study, the effect of withdrawal rate (10–200 μm/s) on the microstructural evolution, mechanical properties, and corrosion resistance of GH3625 alloy was investigated using a liquid-metal-cooled directional solidification system. The microstructural characteristics, elemental segregation, and phase distributions were systematically analyzed via OM, SEM, and EDS, followed by uniaxial tensile and electrochemical polarization tests. The results show that with increasing withdrawal rate, the solid–liquid interface morphology evolves from cellular to cellular-dendritic and finally to fully dendritic. Correspondingly, the primary dendrite arm spacing decreases from 270.4 μm to 100.2 μm, and the secondary dendrite arm spacing decreases from 66.5 μm to 12.3 μm. The area fraction of the detrimental Laves phase first decreases and then increases, reaching a minimum at 100 μm/s. Correspondingly, the yield strength increases from 282 MPa to 409 MPa, and the corrosion resistance is optimized at 100 μm/s. The microstructure–property relationships are discussed based on second-phase strengthening theory and microstructural refinement. This study provides a theoretical basis and practical process windows for optimizing directional solidification parameters to achieve enhanced mechanical and corrosion performance in GH3625 alloy. Full article

Alkali-activated solid waste-based geopolymer represents a novel form of inorganic cementitious material, which is one of the key research directions in the building materials field to achieve the targets of carbon peak and carbon neutrality. Therefore, taking solid waste materials as raw materials to prepare the alkali-activated solid waste-based geopolymers with better mechanical properties is of significant importance for expanding the utilization channels of industrial solid waste materials in Hebei Province. In this study, three solid waste materials, slag, iron tailings sand and coal gangue powder, were used as the precursors of geopolymer, and solid sodium silicate was used as the activator to prepare the solid waste-based geopolymer. Response surface methodology was adopted to design the composition of the geopolymer, and the dosages of slag, Na₂O and coal gangue powder were taken as design variables, and the compressive strength of the geopolymer at 7 days and 28 days were taken as response variables. The results show that it is feasible to optimize the composition of solid sodium silicate-activated solid waste-based geopolymer (SSG) by using response surface methodology. The error value of the SSG-mortar compressive strength prediction model is below 2.0%. The slag contents exhibit a positive correlation with the compressive strength of SSG-mortar, but the coal gangue powder contents and Na₂O contents have a negative correlation. The optimized compositions of SSG-mortar are 20% iron tailings sand, 26% coal gangue powder, 54% slag, and 6.41% Na₂O (regulated by 6.23% solid sodium silicate and 6.23% solid NaOH granules), and the corresponding compressive strengths of SSG-mortar at 7 days and 28 days are 37.1 MPa and 44.9 MPa, respectively. In addition, dry shrinkage tests, wet–dry cycling tests, freeze–thaw cycling tests, salt corrosion tests, SEM analysis and XRD analysis were conducted on the SSG-mortar with the optimal composition to evaluate its shrinkage behavior, freeze–thaw resistance, salt corrosion resistance and microstructural strengthening mechanisms. The results show that SSG-mortar has relatively good frost resistance and salt erosion resistance. The mass loss rate value and compressive strength loss rate value of SSG-mortar are 1.67% and 18.7%, respectively, after 100 freeze–thaw cycles. Furthermore, the corrosion resistance coefficient value of SSG-mortar is greater than 92%, and the mass loss rate value is lower than 2.4%. The SEM and XRD test results display that, in an alkaline environment, the interwoven consolidation of hydrated gels (including C-S-H gel, C-A-S-H gel, C-(N)-A-S-H gel and N-A-S-H gel) and the filling effect of solid wastes jointly achieve an improvement in the properties of SSG-mortar. Full article

Gravity casting and semi-solid extrusion were employed to prepare Mg₂Si-Al composites. X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), EDS analysis, Vickers hardness testing, and tensile testing were used to compare the microstructures and mechanical properties of the two composites, aiming to clarify the effects of the fabrication processes and aging times on their microstructures and mechanical performance. The findings show that semi-solid extrusion converts dendritic α-Al into spherical or ellipsoidal grains (60 ± 25 μm) and induces the spheroidization of Mg₂Si reinforcing phases (29 ± 12 μm). Vickers hardness data show that both composites exhibit a rise-and-fall hardness trend with an increasing aging time, reaching a maximum at 8 h. At this aging stage, the semi-solid extruded composite has a Vickers hardness of 214 ± 32.71 HV, 22.99% higher than that of the gravity-cast composite under the same treatment. Tensile tests demonstrate that the semi-solid extruded composite attains its best tensile strength (254 MPa) and elongation (3.26%) at 8 h of aging. Compared with the semi-solid extruded composites aged for 4 h and 16 h, the 8 h-aged sample exhibits 32.30%/49.41% higher tensile strength and 52.34%/38.72% higher elongation, respectively. After 8 h of aging, the semi-solid extruded composite shows a 59.75% increase in tensile strength and an 88.44% increase in elongation compared with the gravity-cast composite. Full article

Polyacrylamides (PAMs) exhibit variable molecular characteristics, exerting different effects on the macro- and micro-properties of cement when used as cement modifiers. In this study, three different ionic polyacrylamides, namely anionic PAM (APAM), cationic PAM (CPAM), and nonionic PAM (NPAM), were employed to investigate their impacts on the microstructure, hydration, mechanical properties, and electrochemical energy storage characteristics of magnesium phosphate cement (MPC). Microstructural characterization methods, including Mercury Intrusion Porosimetry (MIP), Scanning Electron Microscopy (SEM), Fourier transform infrared (FTIR), etc., were employed to elucidate the phase composition, micromorphology, and pore structure of the modified MPC. Furthermore, electrochemical testing methods such as Cyclic Voltammetry (CV), Galvanostatic Charge–Discharge (GCD), and Electrochemical Impedance Spectroscopy (EIS) were conducted to reveal the energy storage characteristics of supercapacitors. The results indicate that all three PAMs retarded the hydration of MPC, optimized the pore size distribution, and increased the compressive strength of MPC. In terms of electrochemical performance, the ionic conductivity of MPC electrolyte modified by NPAM and APAM exhibited an opposite trend to that of CPAM as the dosage increased. At dosages of 0.5% (NPAM), 1.5% (CPAM), and 0.75% (APAM), the assembled supercapacitors using PAM-modified MPC electrolyte exhibited excellent areal capacitance and energy density, reaching a maximum areal capacitance of 1060 mF cm⁻² and an energy density of 0.147 mWh cm⁻². Full article

The clinker grinding stage in Portland cement production is highly energy-intensive, primarily due to particle agglomeration and intensified interparticle attractive forces that hinder efficient comminution. Grinding aids (GAs) are routinely employed to mitigate these issues, enhancing grinding efficiency and improving cement performance. However, the undesirable side effects associated with conventional GAs on cementitious systems have spurred interest in modification strategies that can concurrently optimize grinding efficiency and final product quality. In this study, widely used commercial GAs, triisopropanolamine (TIPA), diisopropanolamine (DEIPA), and diethylene glycol (DEG), were chemically modified via esterification with organic acids of different carbon chain lengths. Cement specimens incorporating these modified GAs were produced at two dosages (0.05% and 0.1% by mass of clinker + gypsum), resulting in 24 distinct Portland cement formulations alongside a control mix. The influence of modification on grinding efficiency, particle size distribution (PSD), and powder flowability was investigated. Furthermore, scanning electron microscopy (SEM) was utilized to analyze particle morphology and concrete microstructural characteristics with powder flow behavior. The results indicate that organic acid modification not only facilitates achieving target fineness with lower energy consumption but also markedly improves both the PSD profile and the powder’s flow properties. Specifically, hexanoic acid-modified TIPA and DEIPA, along with propanoic acid-modified DEG, delivered the most favorable outcomes across the evaluated parameters. These findings underscore the potential of developing next-generation, modified GAs that simultaneously enhance energy efficiency and powder handling in cement grinding operations. Full article

Although 45 steel is widely used in the manufacture of mechanical parts, its application in harsh working conditions is limited owing to its low hardness, poor wear resistance, and corrosion resistance. Laser cladding can enhance the performance of the working surface without sacrificing substrate toughness. CoCuNiTi HEACs with different cBN additions were successfully prepared on a 45-steel substrate. The phase structure, microstructure, elemental composition, wear, and corrosion behavior of CoCuNiTi + x cBN (x = 0.0, 0.5, and 1.0 wt.%) HEACs were investigated using XRD, OM, SEM, EDS, friction and wear tester, and electrochemical workstation, respectively. The results show that all three coatings exhibit a dual-phase structure composed of FCC and BCC phases. The addition of cBN transforms the alloy phase structure from the original FCC main phase to the BCC main phase. The incorporation of cBN significantly reduces the lattice constant and cell volume of the alloy phase. The change in the alloy phase density is negatively correlated with the cell volume. CoCuNiTi + x cBN (x = 0.0, 0.5, and 1.0 wt.%) alloys have a dendritic structure. No pores were observed in the cBN-containing sample. The content of Ti in the primary phase is the highest. Co is enriched in the dendrite region, and Cu is enriched in the interdendrite region. The significant reduction in the average segregation coefficient for cBN-containing samples is attributed to the heterogeneous nucleation of the alloy melt at lower undercooling levels and the significant increase in the diffusion rate. The friction coefficient of the alloy decreases significantly with increasing cBN content. The sample with 1.0 wt.% cBN shows the best wear resistance, mainly due to the combined effects of hard particle support, solid solution strengthening, phase interface reduction, and high thermal conductivity of cBN. The sample with 1.0 wt.% cBN has the largest capacitive arc radius and charge-transfer resistance, along with the lowest annual corrosion rate, indicating optimal corrosion resistance. This is primarily related to the reduction in pore defects caused by cBN addition, hindrance of uniform penetration of the corrosive medium by dispersed cBN particles, and increased complexity of the anodic dissolution process. CoCuNiTi HEACs reinforced by cBN can simultaneously improve the wear and corrosion resistance of the surface of the 45-steel substrate, providing a feasible strategy for the design of high-performance protective coatings. Full article

To investigate how the content of silica fume (SF) influences the performance of foam concrete (FC) after high-temperature exposure and the underlying mechanisms, this study prepared standard FC cube specimens with SF contents of 0%, 0.15%, 0.2%, 0.25%, and 0.3%. The working properties of the material at room temperature were systematically tested, and the mass loss, residual compressive strength, failure mode, microstructure and acoustic emission (AE) data at different temperatures (100 °C, 200 °C, 300 °C and 400 °C) were analyzed. The test results indicate that increasing the SF content reduces the fluidity of the fresh paste yet significantly enhances the compressive strength and lowers the water absorption of FC at room temperature. After high-temperature exposure, the effect of SF exhibits a dual character: at 200 °C and below, SF effectively mitigates the performance degradation of FC. However, when the temperature reaches 300–400 °C, specimens with an excessively high SF content (e.g., 0.3%) experience rapidly built-up internal steam pressure that cannot escape in time, which triggers the formation and propagation of a microcrack network and leads to a sharp drop in strength. Based on AE detection and scanning electron microscopy (SEM) image analysis, the failure process of silica fume foam concrete (SFFC) proceeds through three stages: free water evaporation at low temperatures, dehydration shrinkage of the C-S-H gel at medium temperatures, and finally, structural failure marked by the collapse of the C-S-H gel network at high temperatures. This study indicates that an SF content of 0.25% allows FC to achieve an optimal balance between mechanical properties and high-temperature stability. The findings provide a theoretical basis for optimizing FC mix proportions and enhancing fire prevention design. Full article