Search Results (227)

Ti150 has potential applications in aeroengine components. However, the lack of research on its flame resistance, combustion behavior, and mechanisms makes it difficult to assess the risk of “titanium fire” and leaves fire protection design without theoretical support. This study aimed to determine the combustion resistance of Ti150 and elucidate its combustion behavior and mechanisms to address these issues. Through comparative Promoted Ignition-Combustion (PIC) tests between Ti150 and TC11 alloys, microstructural characterization, and thermodynamic/kinetic analyses, the following conclusions were drawn. Ti150 alloy exhibited a higher critical oxygen pressure and a higher ignition temperature but a significantly faster burning velocity, compared with TC11 alloy. The relationship between pressure and ignition temperature was in good agreement with the modified Frank-Kamenetskii ignition model. The ignition activation energy of Ti150 alloy was determined to be 118.41 kJ/mol, which was approximately 21% higher than that of TC11 alloy (97.72 kJ/mol). Moreover, post-combustion microstructural observations of Ti150 alloy revealed a higher oxygen content in the melting zone and an enrichment of Zr at the solid–liquid interface, both of which contribute to the higher burning velocity of Ti150 alloy compared with TC11 alloy. Full article

This study explores the differences in oxidation color, oxidation products, and high-temperature oxidation resistance between TA1 and Ti-6Al-4V (TC4) titanium alloys following a 50 h oxidation treatment at 450 °C and 750 °C. A combination of analytical techniques—optical microscopy, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and micro-Vickers hardness testing—was employed to characterize the morphology of the oxide layers, elemental distribution, phase composition, and microhardness variations. The results reveal that at 450 °C, both alloys develop relatively compact oxide films. TA1 exhibits a yellow–gray coloration, while TC4 displays a characteristic blue–violet interwoven color. At 750 °C, however, the oxide layers become porous and prone to spallation, with a brown appearance and predominance of TiO₂. XPS analysis confirms that Ti⁴⁺ (TiO₂) is the dominant oxidation state on both alloy surfaces at 750 °C, with TC4 showing a significantly higher content of Al₂O₃. Microhardness measurements indicate that high-temperature oxidation increases the hardness of both alloys, with TC4 consistently exhibiting higher hardness than TA1. TC4 demonstrates superior oxidation resistance: at 450 °C, it forms a denser oxide layer with lower oxygen uptake, while at 750 °C, its oxide layer thickens more significantly, likely due to increased brittleness and spallation. This study underscores the profound impact of high-temperature oxidation on the microstructure and mechanical properties of titanium alloys and highlights the critical role of oxide layer density and stability in determining oxidation resistance. These findings provide valuable insights for the application of TA1 and Ti-6Al-4V alloys in high-temperature environments. Full article

Achieving high efficiency and quality in millisecond pulsed laser drilling of metallic through-holes is contingent on precise process control. This study introduces a penetration detection-based method to determine the pulse count threshold, effectively overcoming the limitations of conventional approaches. We systematically investigated the effects of pulse energy, defocus, and beam expansion ratio on the drilling of 3 mm thick 304 stainless steel and TC4 titanium alloy. The experiments revealed that for stainless steel 304, the minimum taper angle was achieved at a pulse energy of 2.2 J, a defocus amount of −0.5 mm, and a beam expansion ratio of 2.5. Additionally, relatively high drilling efficiency was observed when the pulse energy ranged from 2.6 to 2.8 J, the defocus amount was −1 to 0 mm, and the beam expansion ratio was 3 to 4. For titanium alloy TC4, the minimum taper angle was achieved at a pulse energy of 2.6 J, a defocus amount of −0.5 mm, and a beam expansion ratio of 3.5. High drilling efficiency was recorded when the pulse energy was 2.8 J, the defocus amount was −0.5 mm, and the beam expansion ratio ranged from 2.5 to 3. When stainless steel 304 and titanium alloy TC4 were processed using the same laser parameters, the drilling efficiency of stainless steel 304 was higher than that of titanium alloy TC4 under the same conditions. This work provides a practical process control strategy and a valuable parameter database for high-quality, efficient laser drilling of these industrially important metals. Full article

This study addresses the challenge of drilling film-cooling holes in the turbine blades of aircraft engines. Titanium alloy TC4 was selected as the experimental material. The laser-drilling process was simulated with ANSYS to determine optimal parameters, which were subsequently applied in machining trials. An impact-drilling method was then used to evaluate how pulse width, pulse energy, and pulse count affect micro-hole entrance and exit diameters, taper, and roundness. Simulations revealed that pulse energy and pulse count predominantly govern entrance and exit diameters, whereas pulse count and pulse width exert a stronger influence on taper. Experiments confirmed that entrance and exit diameters increased as pulse energy rose from 2.0 J to 2.8 J; taper increased as pulse width widened from 0.6 ms to 1.4 ms; and entrance diameter, exit diameter, and taper all grew as pulse count rose from 40 to 60. Pulse width and pulse count also significantly affected hole roundness. Full article

A void closure analytic model for the diffusion bonding of titanium TC4 alloy is developed in this study, in which an FEA-based deformation mechanism is coupled with a numerical analysis for diffusion. The focus was to evaluate the effect of pressure and the temperature on the bonded ratio. As the value of bonding pressure or the bonding temperature increased, the bonding time decreased. The dependence of bonded ratio and time was modeled as an exponential curve. The geometrical model for the mechanism was utilized so that it can incorporate the void division aspect in the process of diffusion bonding. Full article

To optimize the laser drilling process and reduce the processing time, this study investigates picosecond laser trepan drilling on the titanium alloy TC4, analyzing the effects of laser parameters on micro-hole diameter, taper, and roundness. Four independent variables were selected: laser power, defocusing distance, scanning speed, and the number of scans. An L₂₅ (5⁶) orthogonal array was employed for experimental design. The mean response and range analyses evaluated parameter impacts on micro-hole quality, revealing the influence mechanisms of these variables at different levels. The results indicate the following: (1) the scanning speed and laser power significantly affect entrance and exit micro-hole diameters; (2) the defocusing distance substantially influences micro-hole taper; (3) the laser power most critically impacts inlet roundness; (4) the defocusing distance, scanning speed, and laser power directly correlate with outlet roundness; (5) the number of scans exhibits weaker relationships with inlet/outlet diameters, taper, and roundness. A comprehensive balance method applied to orthogonal test results for process optimization yielded the following optimal parameters: 90% laser power (30 W total), −0.2 mm defocus, a 27 mm/s scanning speed, and 15 scans. Full article

This study develops an optimized femtosecond laser welding process for joining quartz glass and TC4 titanium alloy (Ti-6Al-4V) under non-optical contact conditions, specifically addressing the manufacturing needs of specialized photoelectric effect research containers. The joint primarily consists of parallel laser-welded zones (WZ) interspersed with base material. The defocus distance of the femtosecond laser predominantly influences the depth and phase composition of the WZ, while the weld spacing influences the crack distribution in the joint region. The maximum shear strength of 14.4 MPa was achieved at a defocusing distance of +0.1 mm (below the interface) and a weld spacing of 40 μm. The XRD stress measurements indicate that the defocusing distance mainly affects the stress along the direction of laser impact (DLI), whereas the weld spacing primarily influences the stress along the direction of spacing (DS). GPA results demonstrate that when the spacing is less than 30 μm, the non-uniform shrinkage inside the WZ induces tensile stress in the joint, leading to significant fluctuations in DS residual stress and consequently affecting the joint’s shear strength. This study investigates the effects of process parameters on the mechanical properties of dissimilar joints and, for the first time, analyzes the relationship between joint residual strain and femtosecond laser weld spacing, providing valuable insights for optimizing femtosecond laser welding processes. Full article

Low-surface-energy and wettability-based antifouling coatings have garnered increasing attention in marine applications owing to their environmentally friendly characteristics. However, their limited functionality often results in suboptimal long-term antifouling performance, particularly under dynamic marine conditions. To address these limitations, a polydimethylsiloxane (PDMS)-based slippery (PSL) coating was fabricated on TC4 titanium alloy by integrating surface silanization via (3-Aminopropyl)triethoxysilane (APTES), antimicrobial Ag-TiO₂ nanoparticles, laser-induced hierarchical microtextures, and silicone oil infusion. The resulting PSL coating exhibited excellent oil retention and stable interfacial slipperiness even after thermal aging. Compared with bare TC4, low-surface-energy Ag-containing coatings, Ag-containing superhydrophobic coatings, and conventional slippery liquid-infused porous surfaces (SLIPS), the PSL coating demonstrated markedly superior resistance to protein adsorption, bacterial attachment, and diatom settlement, indicating an enhanced synergistic antifouling effect. Furthermore, it significantly reduced the diatom concentration in the surrounding medium without complete eradication, underscoring its eco-friendly and non-disruptive antifouling mechanism. This study offers a scalable, durable, and environmentally benign antifouling strategy for marine surface protection. Full article

Traditional narrow gap welding of thick titanium alloy plates easily produces dynamic molten pool flow instability, poor sidewall fusion, and excessive residual stress after welding, which leads to defects such as pores, cracks, and large welding deformations. In view of the above problems, this study takes 16-mm-thick TC4 titanium alloy as the research object, uses low-power pulsed laser-GTA flexible heat source welding technology, and uses the flexible regulation of space between the laser, arc, and wire to promote good fusion of the molten pool and side wall metal. By implementing instant ultrasonic impact treatment on the weld surface, the residual stress of the welded specimen is controlled within a certain range to reduce deformation after welding. The results show that the new welding process makes the joint stable, the side wall is well fused, and there are no defects such as pores and cracks. The weld zone is composed of a large number of α′ martensites interlaced with each other to form a basketweave structure. The tensile fracture of the joint occurs at the base metal. The joint tensile strength is 870 MPa, and the elongation after fracture can reach 17.1%, which is 92.4% of that of the base metal. The impact toughness at the weld is 35 J/cm², reaching 81.8% of that of the base metal. After applying ultrasound, the average residual stress decreased by 96% and the peak residual stress decreased by 94.8% within 10 mm from the weld toe. The average residual stress decreased by 95% and the peak residual stress decreased by 95.5% within 10 mm from the weld root. The residual stress on the surface of the whole welded test plate could be controlled within 200 MPa. Finally, a high-performance thick Ti-alloy plate welded joint with good forming and low residual stress was obtained. Full article

Laser–MIG hybrid welding–brazing was performed to join TC4 titanium alloy and 5083 aluminum alloy with ER5356, ER4043 and ER2319 filler wires. The effects of the different filler wires on the microstructural features and mechanical properties of Ti/Al welded–brazed butt joints were investigated in detail. The wetting and spreading effect of the ER4043 filler wire was the best, especially on the weld’s rear surface. Serrated-shaped and rod-like IMCs were generated at the top region of the interface of the joint with ER4043 filler wire, but rod-like IMCs did not appear at the joints with the other filler wires. Only serrated-shaped IMCs appeared in the middle and bottom regions for the three filler wires. The phase compositions of all the IMCs were inferred as being made up of TiAl₃. The average thickness of the IMC layer of joints with the ER5356 and ER2319 filler wires was almost the same and thinner than that of the joint with the ER4043 filler wire. The average thickness was largest in the middle region and smallest in the bottom region for all the joints with the three filler wires. The average microhardness in the weld metal of ER5356, ER4043 and ER2319 filler wires could reach up to 77.7 HV, 91.2 HV and 85.4 HV, respectively. The average tensile strength of joints with the ER5356, ER4043 and ER2319 filler wires was 106 MPa, 238 MPa and 192 MPa, respectively. The tensile samples all fractured at the IMC interface and showed a mixed brittle–ductile fracture feature. These research results could help confirm the appropriate filler wire for the laser–MIG hybrid welding–brazing of Ti/Al dissimilar butt joints. Full article

The residual stress induced during the processing of titanium alloy materials can significantly influence the deformation control of precision-machined workpieces, especially for workpieces characterized by low stiffness and high-precision requirements. In this study, TC18 titanium alloy forgings with a dense structure were manufactured via forging. By conducting turning and heat treatment experiments on the workpiece, the distribution and evolution of residual stress and the deformation characteristics of TC18 titanium alloy on slender shafts were systematically investigated under different turning and heat treatment conditions. Based on the experimental results, the effects of the turning parameters, including feed rate, cutting speed, cutting depth, and axial thrust force of machine tool center, on workpiece deformation were quantitatively analyzed, and an optimal heat treatment strategy was proposed. The findings indicate that between-centers turning is recommended to control workpiece deformation. Optimal turning parameters include a cutting speed of 640–800 r/min, a feed rate of 0.05–0.1 mm/r, a cutting depth of 0.1 mm, and a thrust force of the center set to 10% of the rated value, resulting in minimal deformation and superior surface quality. In addition, during the heat treatment annealing of slender shaft titanium alloys, residual stress is effectively eliminated at temperatures ranging from 640 to 680 °C with a holding time of 1–3 h. Furthermore, the vertically fixed placement method during heat treatment reduced deformation by approximately 50% compared to free placement. These results provide valuable insights for optimizing machining and heat treatment processes to enhance the dimensional stability of titanium alloy components. Full article

Medical titanium alloy Ti-6Al-4V (TC4) is widely used as a surgical implant material in biomedical fields owing to its superior biocompatibility, corrosion resistance, and mechanical performance, particularly for osseous integration applications. However, long-term contact of medical titanium-based implants with human soft tissues may induce infection and inflammation. To address these limitations, a drug-loading gel was designed to be synthesized on a TC4 surface to improve biointegration. Considering the critical regulatory roles of temperature and pH in physiological environments, this study synthesized a dual-responsive hydrogel using the temperature-sensitive monomers 2-(2-methoxyethoxy)ethyl methacrylate (MEO₂MA) and oligoethylene glycol methacrylate (OEGMA) and the pH-sensitive monomer diethylaminoethyl methacrylate (DEAEMA), employing stereocomplexed polylactic acid as a physical crosslinker and N,N′-methylenebisacrylamide (MBA) as a chemical crosslinker. A polydopamine-based initiator was synthesized via dopamine functionalization with 2-bromoisobutyryl bromide (BIBB). The amphiphilic co-network hydrogel was grafted onto a modified TC4 surface through atom transfer radical polymerization (ATRP). Integration of the drug-loading gel and TC4 gives the implant an “active therapeutic” function by localized drug release. The results demonstrated that the energy storage modulus of the double-crosslinked gel matched that of human soft tissues. The gels exhibited efficient drug release. Full article

TC4 titanium alloy and 5083 aluminum alloy with different groove shapes were joined by laser-MIG hybrid welding–brazing using ER4043 filler wire. The effects of groove shape on the weld formation, intermetallic compounds and tensile property of the Ti/Al butt joints were investigated. The welds without obvious defects could be obtained with grooves of I-shape and V-shape on Ti side, while welds quality with grooves of V-shape on Al side and V-shape on both sides were slightly worse. The interfacial intermetallic compounds (IMCs) on the brazing interface were homogeneous in the joints with groove of V-shape on Ti side, and V-shape on both sides, which had similar thickness and were both composed of TiAl₃. Unlike the IMCs mainly composed of TiAl₃ at the I-shape groove interface, TiAl₃, TiAl, and Ti₃Al constituted the IMCs at the V-shape on Al side interface. The average tensile strength of Ti/Al joints with groove of I-shape was the highest at 238 MPa, and was lowest at 140 MPa with groove of V-shape on Al side. The tensile samples mainly fractured at IMCs interface and the fractured surfaces all exhibited mixed brittle–ductile fracture mode. Based on the above research results, I-shape groove was recommended for laser-arc hybrid welding–brazing of 4 mm thick Ti/Al dissimilar butt joints. Full article

The torsional behavior during the deformation process of the axial closed die rolling the axial closed rolling (ACDR) forming is studied in this paper using a numerical simulation technique on TC11 titanium alloy. The axial and radial pinch angles, as well as the degree of specimen torsion, increased with the amount of deformation. The orientation distribution function (ODF) maps of the α-phase and β-phase were obtained by Electron Back Scatter Diffraction (EBSD) treatment of the TC11 titanium alloy. It can be noticed that there were different types of texture with different strengths in the ACDR samples, and in the xz and yz planes, textures in the direction of the column were predominantly of {0001} <2$\overline{1}\overline{1}$0> and {01$\overline{1}$0} <2$\overline{1}\overline{1}$0>; the weaker the texture was, the closer to the edge of the sample. In the xy plane, the texture structure was mainly distributed along the cone direction, and the textures were {$\overline{1}$2$\overline{1}$0} <10$\overline{1}$0> and {01$\overline{1}$0} <2$\overline{1}\overline{1}$0>. However, the closer to the edge position of the specimen, the higher the intensity of the texture, and the texture was {1$\overline{2}$1$\overline{2}$} <1$\overline{2}$16>. The β-phase is mainly distributed as {001} <100>, {110} <1$\overline{1}$0>, and {110} <001> textures within the specimen, and the texture strength is about 8.5 times. However, owing to the small proportion of the β-phase content in the specimen, the distribution pattern of its texture has a weak impact on the texture distribution of the overall specimen. A high degree of isotropy in the radial and tangential tensile properties, with a strength isotropy of over 99 percent and a plasticity isotropy of over 95 percent, resulted from the distribution of texture types with varying strengths and orientations within the ACDR specimens, which weakened the TC11 discs’ overall orientation. Full article

The dual-pole magnetic abrasive finishing (DMAF) method was proposed to achieve a smooth surface on TC4 titanium alloy. Firstly, both the distribution of the magnetic field and the intensity of magnetic induction produced by nine combinations of magnetic poles of different shapes were simulated using Ansys Maxwell software (2024R2). According to the results of the simulation, the optimal combination of magnetic poles was determined. Then, the machining parameters of multi-stage DMAF were optimized through comparative experiments on major single factors. Finally, combinations of the mixed magnetic abrasive in three polishing stages were obtained as follows: #100 electrolytic iron powder (Fe₃O₄) + #2000 white abrasive (WA), #200 Fe₃O₄ + #8000 WA, and #450Fe₃O₄ + #w1 diamond (DMD). The gap between the upper and lower magnetic poles was set to 5 mm, the rotational speed of the magnetic pole was set to 300 rpm, and the quality ratio of the abrasive was 2:1. The experiments indicated that the average surface roughness Ra was reduced from an initial value of 0.433 μm to 8 nm after 30 min of multi-stage DMAF, and a nano-level mirror polishing effect was essentially achieved in the polishing zone. Full article