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25 pages, 8488 KB  
Article
Limestone-Based Hybrid Passive Treatment for Copper-Rich Acid Mine Drainage: From Laboratory to Field
by Joshua Pascual Pocaan, Brian Gerald Bueno, Jaica Mae Pagaduan, Johara Capingian, Michelle Airah N. Pablo, Jacob Louies Rohi W. Paulo, Arnel B. Beltran, Aileen H. Orbecido, Renan Ma. Tanhueco, Carlito Baltazar Tabelin, Mylah Villacorte-Tabelin, Vannie Joy T. Resabal, Irish Mae Dalona, Dennis Alonzo, Pablo Brito-Parada, Yves Plancherel, Robin Armstrong, Anne D. Jungblut, Ana Santos, Paul F. Schofield, Richard Herrington and Michael Angelo B. Promentillaadd Show full author list remove Hide full author list
Minerals 2025, 15(10), 1043; https://doi.org/10.3390/min15101043 - 1 Oct 2025
Abstract
Acid mine drainage (AMD) is an environmental concern that needs to be addressed by some mining industries because of its high concentrations of metals and acidity that destroy affected ecosystems. Its formation typically persists beyond the operating life of a mine site. Its [...] Read more.
Acid mine drainage (AMD) is an environmental concern that needs to be addressed by some mining industries because of its high concentrations of metals and acidity that destroy affected ecosystems. Its formation typically persists beyond the operating life of a mine site. Its management is even more challenging for sites that are abandoned without rehabilitation. In this study, a legacy copper–gold mine located in Sto. Niño, Tublay, Benguet, Philippines, generating a copper- and manganese-rich AMD (Cu, maximum 17.2 mg/L; Mn, maximum 2.90 mg/L) at pH 4.59 (minimum) was investigated. With its remote location inhabited by the indigenous people local community (IPLC), a novel limestone-based hybrid passive treatment system that combines a limestone leach bed (LLB) and a controlled modular packed bed reactor (CMPB) has been developed from the laboratory and successfully deployed in the field while investigating the effective hydraulic retention time (HRT), particle size, and redox conditions (oxic and anoxic) in removing Cu and Mn and increasing pH. Laboratory-scale and pilot-scale systems using simulated and actual AMD, respectively, revealed that a 15 h HRT and both oxic and anoxic conditions were effective in treating the AMD. Considering these results and unsteady conditions of the stream in the legacy mine, a hybrid multi-stage limestone leach bed and packed bed were deployed having variable particle size (5 mm to 100 mm) and HRT. Regular monitoring of the system showed the effective removal of Cu (88.5%) and Mn (66.83%) as well as the increase of pH (6.26), addressing the threat of AMD in the area. Improvement of the lifespan of the system needs to be addressed, as issues of Cu-armoring were observed, resulting in reduced performance over time. Nonetheless, the study presents a novel technique in implementing passive treatment systems beyond the typical treatment trains reported in the literature. Full article
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21 pages, 6851 KB  
Article
Target Area Selection for Residual Coalbed Methane Drainage in Abandoned Multi-Seam Mines
by Gen Li, Yaxin Xiu, Qinjie Liu, Bin Zhang, Minke Duan, Youxing Yang and Chenye Guo
Appl. Sci. 2025, 15(19), 10619; https://doi.org/10.3390/app151910619 - 30 Sep 2025
Abstract
To optimize the location optimization of the coalbed methane (CBM) extraction target area in abandoned mines, based on the background of the Songzao mining area in Chongqing, theoretical analysis and numerical simulation research methods were comprehensively used to systematically evaluate the potential of [...] Read more.
To optimize the location optimization of the coalbed methane (CBM) extraction target area in abandoned mines, based on the background of the Songzao mining area in Chongqing, theoretical analysis and numerical simulation research methods were comprehensively used to systematically evaluate the potential of residual CBM resources in the goaf of the Songzao mining area. The stress-fracture evolution law and permeability enhancement characteristics of overlying strata under repeated mining of inclined multi-coal seams were deeply revealed, and the location optimization of the residual CBM extraction borehole target area was carried out. The results show that the amount of CBM resources in Songzao Coal Mine is 5.248 × 107 m3, accounting for 26.57% of the total resources, which is suitable for the extraction of CBM left in goaf. The maximum height of the overburden fracture zone caused by repeated mining of K2b, K1, and K3b coal seams in Songzao Coal Mine is 72.3 m, which is basically consistent with the results of the numerical simulation (69.76 m). The fracture development of overlying strata is in the distribution form of a symmetrical trapezoid and inclined asymmetrical trapezoid, and its development height increases with an increase in coal seam mining times, and finally forms a three-dimensional ‘O’-ring fracture area, which provides a channel and enrichment area for the effective migration of CBM. The significant permeability-increasing zone of overburden rock is stable in the range of 10~40 m above the roof of the K3b coal seam and is nearly trapezoidal. According to the calculation of the height prediction model of the fracture zone in the abandoned goaf, the fracture height of the long-term compaction of the Songzao Coal Mine is reduced to 63.74 m. Based on the stress-fracture evolution characteristics of the overburden rock, combined with the permeability-increasing characteristics of the overburden rock and the migration law of the remaining CBM, it is determined that the preferred position of the remaining CBM extraction target area of the Songzao Coal Mine should be in the upper corner of the fracture development area within the range of 10~32.47 m above the K36 coal seam. Full article
14 pages, 1709 KB  
Article
An Empirical–Analytical Model of Mine Water Level Rebound
by Dmytro Rudakov, Somayeh Sharifi and Sebastian Westermann
Mining 2025, 5(4), 59; https://doi.org/10.3390/mining5040059 - 23 Sep 2025
Viewed by 115
Abstract
This paper aims to develop a robust empirical–analytical model using the statistics of mine water level rebound in abandoned mines and the basic physical principles of underground hydraulics. The data collected and treated included the time series of the mine water level for [...] Read more.
This paper aims to develop a robust empirical–analytical model using the statistics of mine water level rebound in abandoned mines and the basic physical principles of underground hydraulics. The data collected and treated included the time series of the mine water level for 35 closed and flooded mines from four European countries. Within the developed model, mine water level evolution is governed by an ordinary differential equation with one fitting parameter that depends on the floodable cavity volume in a mine and water inflow before flooding begins. The model assumes that rock properties and residual void distribution are homogeneous, and the mines being flooded are almost isolated hydraulically from the neighboring ones. The exponential formula, as the governing equation solution, was found to be the most suitable for fitting the measurements. The calculated exponential curves allow for excellent or very good fitting of the measured water levels for 17 of 35 mines, and acceptable fitting for 11 mines in terms of minimizing mean-square-root deviation. The proposed approach can be applied to preliminary assessments of mine water level rebound in developing and calibrating sophisticated numerical flow models. Full article
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14 pages, 2561 KB  
Article
First Evidence of Roman Gold Mining Obtained by Luminescence Dating of Sediments in Les Guilleteres D’All (Cerdanya, Girona, Eastern Pyrenees)
by Jorge Sanjurjo-Sánchez, Jordi Morera Camprubí and Oriol Olesti Vila
Land 2025, 14(9), 1912; https://doi.org/10.3390/land14091912 - 19 Sep 2025
Viewed by 259
Abstract
In recent years, evidence of gold mining during the Roman period has been found by archaeologists in the Cerdanya region (Girona, Catalonia). In this region, Les Guilleteres d’All has been described as a mining complex because of the erosive features observed in the [...] Read more.
In recent years, evidence of gold mining during the Roman period has been found by archaeologists in the Cerdanya region (Girona, Catalonia). In this region, Les Guilleteres d’All has been described as a mining complex because of the erosive features observed in the landscape; surveys have identified hydraulic mining opencast structures named chantier-cirques and chantier-ravins. The latter are smaller, but both require a water reservoir, specifically a water retention facility, to supply water flow. One of these buried water reservoirs has been excavated, revealing an enlarged area with a dam constructed from stone blocks. Two pottery sherds were found within the sediment layers deposited on the bottom of the reservoir—one dated to the 1st–2nd c. AD and the other to the Bronze Age—indicating that the reservoir was filled during historical times and the nearby presence of settlements from these periods. Optically Stimulated Luminescence (OSL) dating was performed on two waterlain sediment layers deposited at the bottom deposited at the reservoir. The obtained ages, dating to 2nd–4th c. AD, correspond to the final phase or abandonment of mining activities. Hence, these ages provide the first evidence of mining activities in Les Guilleteres during Roman times. Full article
(This article belongs to the Section Landscape Archaeology)
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27 pages, 3998 KB  
Article
Geochemical Features and Mobility of Trace Elements in Technosols from Historical Mining and Metallurgical Sites, Tatra Mountains, Poland
by Magdalena Tarnawczyk, Łukasz Uzarowicz, Wojciech Kwasowski, Artur Pędziwiatr and Francisco José Martín-Peinado
Minerals 2025, 15(9), 988; https://doi.org/10.3390/min15090988 - 17 Sep 2025
Viewed by 198
Abstract
Ore mining and smelting are often related to environmental pollution. This study provides information about the geochemical features of Technosols at historical mining and metallurgical sites in the Tatra Mountains, southern Poland, evaluating the contents of potentially toxic trace elements (PTTE) and their [...] Read more.
Ore mining and smelting are often related to environmental pollution. This study provides information about the geochemical features of Technosols at historical mining and metallurgical sites in the Tatra Mountains, southern Poland, evaluating the contents of potentially toxic trace elements (PTTE) and their behaviours in soils, as well as the influence of soil properties on PTTE mobility. Thirteen soil profiles were studied in eight abandoned mining and smelting sites. PTTE concentrations, including rare earth elements (REE), were measured using ICP-MS and ICP-OES. Selected elements (Cu, Zn, Pb, Cd, As, Sb, Ba, Sr, Co, Ni, Mn and Cr) were fractionated using the modified European Community Bureau of Reference (BCR) four-step sequential extraction. Contamination of soils with PTTE was compared against Polish regulatory limits, which were exceeded for Cu, Zn, Pb, Mo, Hg, As, Co, Ni and Ba, with concentrations exceeding limits by 16, 18, 34 and 160 times for Cu, Hg, As and Ba, respectively, in some profiles. Based on geochemical features depending on parent material properties, the soils examined were divided into three groups. Group I Technosols (near-neutral soils developed from Fe/Mn-ore and carbonate-bearing mining waste) were particularly enriched in Co, Ni, Mn and REE. Group II Technosols (acidic soils developed from polymetallic ore-bearing aluminosilicate mining waste) contained elevated concentrations of Cu, Zn, Hg, As, Sb, Bi, Co, Ag, Ba, Sr, U and Th; they contained lower contents of REE than Group I Technosols. Group III Technosols (soils developed in smelting-affected areas and containing metallurgical waste) were rich in Cu, As, Sb, Ba, Hg, Co and Ag and contained the lowest REE contents among the studied soils. Sequential BCR extraction revealed that PTTE mobility varied strongly according to soil group, with higher mobility of Mn, Cu and Zn in acidic polymetallic ore-derived soils (Group II), while carbonate-rich soils (Group I) showed mainly immobile forms. Metallurgical slag-derived soils (Group III) exhibited complex PTTE behaviour controlled by organic matter and Fe/Mn oxides. Soil properties (pH, carbonates and TOC) seem to control PTTE mobility. Full article
(This article belongs to the Section Environmental Mineralogy and Biogeochemistry)
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23 pages, 617 KB  
Review
Recent Advances in Treatment Technologies and Resource Utilization of Mine Tailings in Hunan Province, China
by Xiaoling Jia, Yan Zhan and Xiang Tian
Processes 2025, 13(9), 2957; https://doi.org/10.3390/pr13092957 - 17 Sep 2025
Viewed by 383
Abstract
This review presents a comprehensive summary of the recent advancements in treatment technologies and resource utilization strategies for mine tailings, and highlights the funding support provided by Hunan Province, China for scientific and technological innovation in the field. The work begins by examining [...] Read more.
This review presents a comprehensive summary of the recent advancements in treatment technologies and resource utilization strategies for mine tailings, and highlights the funding support provided by Hunan Province, China for scientific and technological innovation in the field. The work begins by examining the environmental risks associated with mine tailings, emphasizing their potential to cause ecological damage and result in significant resource waste. Building on this context, the review delves into the physical, chemical, and mineralogical characteristics of tailings, elucidating how these intrinsic properties underpin their potential for recycling and valorization. Subsequently, it explores a range of resource utilization approaches, including the recovery of valuable metals, land reclamation, backfilling of abandoned mining voids, and the production of construction materials. The current state of application and the key technical and regulatory challenges faced during implementation are critically analyzed. In conclusion, the review highlights the progress made in tailings management and valorization in Hunan Province, China, and proposes a forward-looking strategy that integrates technological innovation with policy and regulatory support to promote sustainable development in the region. Full article
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16 pages, 3546 KB  
Article
Composting of Urban Sewage Sludge and Its Application in Quarry Soil Reclamation: A Field Case Study
by Luyao Zhang, Chong Li, Zengbiao Tian, Mengchao Zhang, Xueyuan Feng, Guannan Liu, Zihan Zhu, Liming Dong and Yuhao Wang
Agronomy 2025, 15(9), 2179; https://doi.org/10.3390/agronomy15092179 - 12 Sep 2025
Viewed by 252
Abstract
Mining activities often result in ecosystem degradation and landscape destruction. The restoration of abandoned mine lands is particularly challenging due to the poor physicochemical properties and low fertility of the soil, which necessitate the use of soil amendments. Sewage sludge, which contains abundant [...] Read more.
Mining activities often result in ecosystem degradation and landscape destruction. The restoration of abandoned mine lands is particularly challenging due to the poor physicochemical properties and low fertility of the soil, which necessitate the use of soil amendments. Sewage sludge, which contains abundant nutrients, has potential for use in mine soil restoration. Four separate piles of sewage sludge, each weighing 5 tons, were subjected to aerobic composting and then applied at different rates (0%, 2%, 5%, 10%, and 20%) to reclaim an abandoned mine land site (500 m2). During the composting process, the pH, moisture content, organic matter (OM), and dissolved organic matter (DOM) of the sewage sludge all decreased, while electrical conductivity (EC) and germination index (GI) increased. The sewage sludge compost reached maturity after 83 days. Soil pH and bulk density decreased with increasing application levels, whereas soil fertility, such as OM, alkali-hydrolyzable nitrogen, available phosphorus (AP), and available potassium (AK), significantly improved after application of sewage sludge compost. Vegetation coverage (ryegrass and alfalfa) reached 100% after 2 months at the 20% application level. Fresh biomass and plant height were significantly higher at all application levels compared to the control (p < 0.05). Results from Pearson’s correlation, redundancy analysis (RDA), and the random forest model indicated that soil fertility, particularly AP, OM, and alkali-hydrolyzable nitrogen, rather than soil physicochemical properties, was the key factor influencing the restoration success of the mine site. The use of sewage sludge compost as a soil amendment for reclaiming abandoned mine lands is feasible and can help reduce the ecological restoration costs of mining. Full article
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25 pages, 5082 KB  
Article
Mechanisms of Sulfate In Situ Removal Using SRB-PRB Driven by Low-Cost Sustained-Release Carbon Source in Coal Mine Goafs: A Dynamic Column Experiment Study
by Li Zhang, Zhimin Xu, Mingan Xiahou, Liang Gao, Yating Gao, Juan Guo and Chi Li
Water 2025, 17(18), 2684; https://doi.org/10.3390/w17182684 - 11 Sep 2025
Viewed by 344
Abstract
The proportion of neutral and weakly alkaline high-sulfate mine water in China is over 50%, resulting in the problem of high treatment costs. Low-cost, sustainable, and non-secondary pollution remediation technologies for in situ application in underground coal mines have rarely been reported. Here, [...] Read more.
The proportion of neutral and weakly alkaline high-sulfate mine water in China is over 50%, resulting in the problem of high treatment costs. Low-cost, sustainable, and non-secondary pollution remediation technologies for in situ application in underground coal mines have rarely been reported. Here, the mixed packed and layered packed SRB-PRB (sulfate-reducing bacteria-permeable reactive barrier) column experiments at a flow speed of 300 mL/d using low-cost corncob as a carbon source were conducted to simulate sulfate in situ remediation in goafs. The column experiments utilized the simulated weakly alkaline mine water, with an initial sulfate concentration of 1027.45 mg/L. The results showed that during the 40 d operation, the SO42− removal kinetics included three stages: rapid reduction (0–6 d), stable reduction (6–16 d), and reduction attenuation (16–40 d). Corncob could provide a relatively long-term carbon source supply, with the maximum average removal efficiency of 65.5% for the mixed packed column and 56.6% for the layered packed column. A large number of complex organic-degrading bacteria were detected in both the effluent water samples and the solid packed media, while SRB became dominant only in the solid packed media. However, the low-abundance SRB could still maintain a high-efficiency SO42− reduction, due to the supply of readily utilizable carbon sources provided by hydrolytic and fermentative bacteria. This indicated that the synergistic effect between SRB and these organic matter-degrading bacteria was the critical limiting factor for SO42− removal. The microscopic characterizations of SEM-EDS (scanning electron microscopy and energy-dispersive spectroscopy) and FTIR (Fourier transform infrared spectroscopy) confirmed the damage of functional groups in corncobs and the generation of SO42− removal products (i.e., FeS). The engineering application schemes of the SRB-PRB under both in-production and abandoned mining scenarios were proposed. Additionally, the material cost estimate results showed that the SRB-PRB could achieve in situ low-cost remediation (0.2–1.55 USD/m3) of the characteristic pollutant SO42−. These findings would benefit the engineering application of in situ microbial remediation technology for high-sulfate mine water. Full article
(This article belongs to the Section Hydrogeology)
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21 pages, 1183 KB  
Article
A Performance Evaluation and Feasibility Study of Mine Thermal Energy Storage in Glace Bay, Nova Scotia
by Sara Sohrabikhah and Larry Hughes
Energies 2025, 18(17), 4780; https://doi.org/10.3390/en18174780 - 8 Sep 2025
Viewed by 497
Abstract
Mine Thermal Energy Storage (MTES) offers a promising solution for sustainable heating by repurposing abandoned, water-filled mines as underground thermal reservoirs. This study assesses the feasibility of implementing MTES in Nova Scotia, with a focus on the Sydney coalfield region, particularly Glace Bay. [...] Read more.
Mine Thermal Energy Storage (MTES) offers a promising solution for sustainable heating by repurposing abandoned, water-filled mines as underground thermal reservoirs. This study assesses the feasibility of implementing MTES in Nova Scotia, with a focus on the Sydney coalfield region, particularly Glace Bay. The research combines geological analysis, residential heat demand estimation, thermal storage capacity estimation, and cost–benefit evaluation to determine whether abandoned coal mines can support district heating applications. Results show that MTES can deliver substantial heating cost reductions compared to oil-based systems, while significantly lowering greenhouse gas emissions. The study also explores the integration of MTES with local renewable energy sources, including wind and solar, to enhance energy system flexibility and reliability. International case studies from Springhill (Canada), Heerlen (Netherlands), and Bochum (Germany) are referenced to contextualize the analysis and demonstrate how the findings of this study align with broader MTES scalability, performance, and operational challenges. Key technical barriers, such as water quality management, infrastructure investment, and seasonal variability in heat demand, are discussed. Overall, the findings highlight MTES as a viable and sustainable energy storage approach for Nova Scotia and other regions with legacy mining infrastructure. Full article
(This article belongs to the Special Issue Advances in Thermal Energy Storage Systems: Methods and Applications)
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20 pages, 15131 KB  
Article
Monitoring Historical Waste Coal Piles Using Image Classification and Change Detection Algorithms on Satellite Images
by Sandeep Dhakal, Ajay Shah and Sami Khanal
Remote Sens. 2025, 17(17), 3041; https://doi.org/10.3390/rs17173041 - 1 Sep 2025
Cited by 1 | Viewed by 952
Abstract
Abandoned coal mine lands, particularly waste coal piles that predate the Surface Mining Control and Reclamation Act (SMCRA) of 1977, pose significant environmental and safety risks. Unlike sites mined after SMCRA—where operators are legally mandated to conduct reclamation—there is no legal obligation for [...] Read more.
Abandoned coal mine lands, particularly waste coal piles that predate the Surface Mining Control and Reclamation Act (SMCRA) of 1977, pose significant environmental and safety risks. Unlike sites mined after SMCRA—where operators are legally mandated to conduct reclamation—there is no legal obligation for companies or individuals to restore lands disturbed before the law’s enactment. As a result, these historical sites remain largely unmanaged and understudied. This study develops a satellite imagery-based analytical workflow to identify and monitor such historical waste coal piles. Using supervised classification of Sentinel-2 imagery with four machine learning models, we identified waste coal piles in both active mining areas and regions disturbed prior to SMCRA. Among the models tested, Random Forest achieved the highest accuracy for classifying waste coal, with a precision of 86% and a recall of 77%. A subsequent time-series analysis revealed that historical waste coal piles have undergone gradual but consistent vegetation recovery since 1986, indicating a natural reclamation process. These areas showed minimal changes in disturbance magnitude, suggesting the absence of significant disturbing events. In contrast, active mining regions showed substantial disturbance consistent with ongoing operations. The combined classification and change detection approach successfully distinguished historical waste coal piles from those in active mining regions, with a precision of 78% and recall of 100%. These findings highlight the potential of remote sensing and temporal analysis to support the identification and assessment of historical waste coal piles. The proposed approach can help prioritize reclamation efforts and inform policy decisions addressing the long-term environmental impacts of historical coal mining. Full article
(This article belongs to the Special Issue Application of Advanced Remote Sensing Techniques in Mining Areas)
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29 pages, 5378 KB  
Article
Methods for Rescuing People Using Climbing Equipment in Abandoned Mines to Be Carried Out by Rescue Units of the Integrated Rescue System
by Marek Szücs, Miroslav Betuš, Martin Konček, Marian Šofranko and Andrea Šofranková
Safety 2025, 11(3), 83; https://doi.org/10.3390/safety11030083 - 1 Sep 2025
Viewed by 470
Abstract
This article discusses the possibilities and methods for rescuing people from abandoned mine workings and the cooperation of the components of the Integrated Rescue System of the Slovak Republic when carrying out rescue work in underground spaces, specifically the Bankov mine. Additionally, the [...] Read more.
This article discusses the possibilities and methods for rescuing people from abandoned mine workings and the cooperation of the components of the Integrated Rescue System of the Slovak Republic when carrying out rescue work in underground spaces, specifically the Bankov mine. Additionally, the basic legislative restrictions on the level of rescue work that can be performed in underground spaces in Slovakia and abroad are characterized. In the study itself, exercises in a mining environment were designed and tested by rescuers from the fire and rescue corps of the Slovak Republic, while several methods for rescuing people from underground spaces using climbing equipment were tested. Since the research setting was an abandoned mine, the rescue methods were carried out with regard to the maximum achievable safety of the firefighters. With the demise of the Mine Rescue Service in the Slovak Republic in 2025, rescue activities passed into the hands of the fire and rescue corps, and it is therefore necessary to determine the best method for rescue from mining spaces that can be performed by firefighters when the priority is the rescue time: the most important factor for saving human life. Using the analysis of the data obtained in this study, the most effective method specifically for rescuing people from underground spaces was determined. Based on the information obtained, proposals and measures were established to make rescue work in underground spaces more efficient. The research met all standards set for firefighters, and all rescuers agreed to publish this research. Full article
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22 pages, 6216 KB  
Article
Drivers of Vegetation Cover and Carbon Sink Dynamics in Abandoned Shaoyang City Open-Pit Coal Mines
by Daxing Liu, Zexin He, Huading Shi, Yun Zhao, Jinbin Liu, Anfu Liu, Li Li and Ruifeng Zhu
Sustainability 2025, 17(17), 7816; https://doi.org/10.3390/su17177816 - 30 Aug 2025
Viewed by 456
Abstract
As an important coal-producing region in China, open-pit coal mining in Shaoyang, Hunan Province, has a significant impact on the ecological environment. This study focuses on the three major open-pit mining areas in the city, utilizing remote sensing data from 1998 to 2024. [...] Read more.
As an important coal-producing region in China, open-pit coal mining in Shaoyang, Hunan Province, has a significant impact on the ecological environment. This study focuses on the three major open-pit mining areas in the city, utilizing remote sensing data from 1998 to 2024. By calculating the normalized difference vegetation index (NDVI) and fractional vegetation cover (FVC), and combining climate factors such as temperature and precipitation with Net Primary Productivity (NPP), this study analyzes the spatiotemporal evolution characteristics of vegetation cover and carbon sinks, and explores the impact of climate and environmental policies on vegetation recovery. The study employed trend analysis and autoregressive integrated moving average (ARIMA) model predictions, which showed that vegetation cover in the mining areas decreased overall from 1998 to 2011, gradually recovered after 2011, and reached a relatively high level by 2024. Changes in carbon sinks were consistent with the trends in vegetation cover. Spatially, the north mining area experienced the most severe vegetation degradation in the early stages, the middle area recovered earliest, and the south area had the fastest vegetation cover recovery rate. Climate factors had a certain influence on vegetation recovery, but precipitation, temperature, and FVC showed no significant correlation. The study indicates that vegetation recovery in mining areas is jointly influenced by mining intensity, climate conditions, and policy interventions, with geological environment management policies in Hunan mining areas playing a key role in promoting vegetation recovery. Full article
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18 pages, 7865 KB  
Article
Effect of Burial Depth, Cavern Shape, and Sealing Layer on the Mechanical Behaviour of Abandoned Mines for Compressed Air Energy Storage
by Lihui Niu, Shiji Yan, Fuchao Zhao, Xinchun Bai, Yaosheng Zhang and Pengju Qin
Processes 2025, 13(9), 2737; https://doi.org/10.3390/pr13092737 - 27 Aug 2025
Viewed by 563
Abstract
As renewable energy adoption intensifies, the demand for efficient and large-scale storage technologies such as compressed air energy storage (CAES) has become critical. Abandoned mine caverns present a cost-effective and sustainable option for CAES, enabling the reuse of existing underground spaces while minimizing [...] Read more.
As renewable energy adoption intensifies, the demand for efficient and large-scale storage technologies such as compressed air energy storage (CAES) has become critical. Abandoned mine caverns present a cost-effective and sustainable option for CAES, enabling the reuse of existing underground spaces while minimizing new excavation. This study aims to quantitatively evaluate the stability of abandoned mine caverns for CAES under varying burial depths (150 m, 300 m, 450 m), cavern geometries (rectangular, trapezoidal, straight-wall arch, and circular) and sealing layer (steel, polymer) in Class II rock mass conditions. Finite element modelling employing ABAQUS was employed to simulate excavation, lining installation, and high-pressure gas storage, incorporating an analysis of surrounding rock strain, plastic zone development, and sealing layer performance. Results indicate that geometry and burial depth are dominant factors controlling deformation, with straight-wall arch caverns inducing relatively minimal disturbance to the ground surface after excavation and lining, and circular caverns showing the highest stability after pressurization. Steel sealing layers significantly improve structural performance, while polymer layers have a limited effect. The findings provide engineering guidance for the safe retrofit and design of CAES facilities in abandoned mines. Full article
(This article belongs to the Section Energy Systems)
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27 pages, 5754 KB  
Article
Use of Abandoned Copper Tailings as a Precursor to the Synthesis of Fly-Ash-Based Alkali Activated Materials
by Arturo Reyes-Román, Tatiana Samarina, Daniza Castillo-Godoy, Esther Takaluoma, Giuseppe Campo, Gerardo Araya-Letelier and Yimmy Fernando Silva
Materials 2025, 18(17), 3926; https://doi.org/10.3390/ma18173926 - 22 Aug 2025
Viewed by 663
Abstract
This study evaluated the feasibility of reusing abandoned copper mine tailings (Cu tailings) as a precursor in the production of fly-ash-based alkali-activated materials (FA-AAMs). Two formulations were developed by combining FA and Cu tailings with a mixture of sodium silicate and sodium hydroxide [...] Read more.
This study evaluated the feasibility of reusing abandoned copper mine tailings (Cu tailings) as a precursor in the production of fly-ash-based alkali-activated materials (FA-AAMs). Two formulations were developed by combining FA and Cu tailings with a mixture of sodium silicate and sodium hydroxide as alkaline activators at room temperature (20 °C). Formulation G1 consisted of 70% Cu tailings and 30% fly ash (FA), whereas G2 included the same composition with an additional 15% ordinary Portland cement (OPC). The materials were characterized using X-ray fluorescence (XRF), -X-ray diffraction (XRD), field emission scanning electron microscopy with energy-dispersive spectroscopy (FESEM-EDS), and particle size analysis. While FA exhibited a high amorphous content (64.4%), Cu tailings were largely crystalline and acted as inert fillers. After 120 days of curing, average compressive strength reached 24 MPa for G1 and 41 MPa for G2, with the latter showing improved performance due to synergistic effects of geopolymerization and OPC hydration. Porosity measurements revealed a denser microstructure in G2 (35%) compared to G1 (52%). Leaching tests confirmed the immobilization of hazardous elements, with arsenic concentrations decreasing over time and remaining below regulatory limits. Despite extended setting times (24 h for G1 and 18 h for G2) and the appearance of surface efflorescence, both systems demonstrated good chemical stability and long-term performance. The results support the use of Cu tailings in FA-AAMs as a sustainable strategy for waste valorization, enabling their application in non-structural and moderate-load-bearing construction components or waste encapsulation units. This approach contributes to circular economy goals while reducing the environmental footprint associated with traditional cementitious systems. Full article
(This article belongs to the Section Advanced Materials Characterization)
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21 pages, 2091 KB  
Article
Evaluation of the Ecological and Health Risk Associated with Abandoned Tailings Storage Facilities: The Case of Montevecchio Levante (Sardinia, Italy)
by Giulio Sogos, Francesco Pinna, Giorgia De Gioannis, Alessio Lai, Valentina Dentoni, Angela Serpe, Aldo Muntoni and Battista Grosso
Processes 2025, 13(8), 2629; https://doi.org/10.3390/pr13082629 - 20 Aug 2025
Viewed by 429
Abstract
The environmental legacy of mining operations presents significant challenges in managing impacts on ecosystems, public health, and safety. In Sardinia (Italy), the mining history has left a particularly severe burden of abandoned sites, making remediation a regional priority. To address this issue and [...] Read more.
The environmental legacy of mining operations presents significant challenges in managing impacts on ecosystems, public health, and safety. In Sardinia (Italy), the mining history has left a particularly severe burden of abandoned sites, making remediation a regional priority. To address this issue and to effectively prioritize interventions at abandoned mining sites, a relative risk assessment approach was developed by the Sardinia Regional Administration and the Italian National Institute for Environmental Protection and Research. The aim of this paper is to highlight the results and information obtainable with the above-mentioned approach through its application to a real case: the Montevecchio Levante mining district in southwestern Sardinia. The study provides a detailed identification of the factors underlying the high intervention priority associated with the site under investigation. An analytical quantification of the contribution of the main contaminants to the overall risk was carried out through the calculation of specific risk indices. At the same time, the environmental matrices most involved in the contamination mechanisms were identified. The results indicate that the overall risk is largely driven by the presence of carcinogenic contaminants, with cadmium and lead contributing primarily to the risks associated with surface water and soil, respectively. The findings provide a solid basis for developing targeted strategies to mitigate ecological and public health risks in abandoned mining areas. Full article
(This article belongs to the Section Environmental and Green Processes)
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