Search Results (4)

Magnesian suite (Mg-suite) rocks represent plutonic materials from the lunar crust, and their global distribution can provide critical information for the early magmatic differentiation and crustal asymmetries of the Moon. Visible and near-infrared (VNIR) spectrometers mounted on orbiters and rovers have been proven to be powerful approaches for planetary mineral mapping, which are instrumental in diagnosing Mg-suite rocks. However, due to the scarcity and diversity of Mg-suite samples, laboratory measurements with variable proportions of minerals are imperative for spectral characterization. In this study, spectroscopic investigation and petrographic study were conducted on lunar Mg-suite meteorite Northwest Africa 8687. We classify the sample as a pink spinel-bearing anorthositic norite through spectral and petrographic characteristics. The ground-truth information of the Mg-suite rock is provided for future exploration. Meanwhile, the results imply that the VNIR technique has the potential to identify highland rock types by mineral modal abundance and could further be applied in extraterrestrial samples for primary examination due to its advantage of being fast and non-destructive. Full article

On the basis of geochemical whole-rock and mineralogical point analyses, the concentrations of V and Co were determined in magnetite-ilmenite oxide ores, associated with sulphides, at the Krzemianka and Udryn deposits in the Mesoproterozoic Suwałki Anorthosite Massif (SAM) in NE Poland. EPMA analyses showed that the main carrier of vanadium was magnetite (mean = 0.42 wt%) and, to a lesser extent, ilmenite (mean = 0.14 wt%) and minor Al-spinels (mean = 0.04 wt%). In turn, cobalt was found mainly in the form of isomorphic substitutions in magmatic sulphides such as pentlandite (mean = 4.41 wt% Co), pyrrhotite (mean = 0.16 wt%), and chalcopyrite (mean = 0.11 wt%). Moreover, Co-enrichments were also recognized in the secondary sulphides, such as pyrite and bravoite, replacing pyrrhotite (means = 1.6 and 2.7 wt% Co, respectively), and in the form of different thiospinels ((Fe, Ni) (Co, Ni)₂S₄), mainly siegenite (mean = 22.0 wt% Co), replacing pyrrhotite and pentlandite. Vanadium cations were substituted in Fe, Ti oxide minerals in place of Fe⁺³ cations, and in the case of cobalt, Fe⁺² cations were substituted in sulphides and thiospinels. Vanadium and cobalt showed high Person’s correlation coefficients (r = 0.70), indicating their close spatial coexistence and a common source, which was parental anorthosite-norite magma of the SAM suites. The common magma genesis of magnetite-ilmenite and sulphide mineralization was also confirmed by the very similar shapes of the curves of REE content in the oxide-sulphide ores in relation to chondrite, in which negative Eu anomalies and positive Sm anomalies are clearly visible. Although the average contents of vanadium and cobalt were low (arithmetic means = 960 ppm, and 122 ppm, respectively), the resources of these metals were estimated to be large due to the enormous reserves of magnetite-ilmenite ores hosted by the SAM. However, the Fe-Ti-V ores associated with Fe, Ni, Co, and Cu sulphides were considered to be sub-economic because of their depth of occurrence (mainly 1.0 km below the surface level); their metal contents, which were usually too low; and additionally the fact that the location is in a highly environmentally protected landscape and lake area. Full article

We present a mineral chemical stratigraphy across the UG2 Unit, situated in the Upper Critical Zone of the Bushveld Complex. The magmatic evolution of the rocks hosting this world-class ore deposit for chromium and platinum group elements (PGEs) is still under debate. Orthopyroxene is a common phase across the magmatic stratigraphy of the unit. It hosts trace metals, whose relative contents can record information about magmatic processes. This study determined laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) trace element data for orthopyroxene and spot LA multi-collector ICP-MS Sr-isotope data for plagioclase. Mapping of trace element distributions revealed internal zoning in Cr, V, Y, and Th. Unlike in conventional spot analysis, quantitative trace element concentrations were extracted post-analysis from two-dimensional LA-ICP-MS maps. This approach offered advantages over spot analysis. The maps revealed internal complexities (e.g., inclusions, exsolved phases, zonations and diffusion halos) that could be avoided with suitable thresholds for chemical filter elements (i.e., 100 ppm < Cr < 4000 ppm, Y < 6 ppm), permitting fast, automated extraction of pure orthopyroxene data pixels from elemental maps covering noritic, troctolitic, anorthositic and chromititic mineral assemblages. Diffusive equilibration in orthopyroxene was evaluated by comparing zonations in elements with different known diffusivities. Magnesium and Ni are homogenously distributed, indicative of rapid diffusive processes, while Cr and V show zonations, interpreted to largely reflect primary distribution. Thorium and Y apparently diffused along discrete pathways, indicated by concentration anomalies following orthopyroxene lamellae. A systematic study of the trace element inventory of orthopyroxene across the succession of the UG2 Unit, complemented with Sr isotope signatures of plagioclase, revealed clear evidence for open-system processes: compatible elements (Cr, Ni) are decoupled from Mg# variations in orthopyroxene from specific UG2 subunits; distinct Mg# peaks coincide with negative V excursions in orthopyroxene from chromite-bearing subunits; towards the top of the unit, plagioclase shows a distinct ⁸⁷Sr/⁸⁶Sr_initial peak and orthopyroxene shows Cr-depleted and Th-enriched rims. These chemical features cannot be explained by crystal mixing alone and argue for the involvement of at least two chemically distinct melts in the formation of the studied UG2 section. Full article

The NE Fennoscandian Shield comprises the Northern Belt in Finland and the Southern Belt in Karelia. They host mafic-ultramafic layered Cu-Ni-Cr and Pt-Pd-bearing intrusions. Precise U-Pb and Sm-Nd analyses indicate the 130-Ma evolution of these intrusions, with major events at 2.53, 2.50, 2.45, and 2.40 Ga. Barren phases were dated at 2.53 Ga for orthopyroxenites and olivine gabbro in the Fedorovo-Pansky massif. PGE-bearing phases of gabbronorites (Pechenga, Fedorovo-Pansky, Monchetundra massifs) and norites (Monchepluton) are 2.50 Ga old. Anorthosites of Mt. Generalskaya (Pechenga), the Fedorovo-Pansky, and Monchetundra massifs occurred at 2.45 Ga. This event produced layered PGE-bearing intrusions in Finland (Penikat, Kemi, Koitelainen) and mafic intrusions in Karelia. The Imandra lopolith dikes occurred at the final phase (2.40 Ga). Slightly negative εNd and I_Sr values (0.703–0.704) suggest that intrusions originated from an enriched mantle reservoir. Low ³He/⁴He ratios in accessory minerals (ilmenite and magnetite) indicate an upper mantle source. Large-scale correlations link the Fennoscandian Shield with the Superior and Wyoming cratons. Full article