Search Results (9)

Phosphates are key pollutants involved in the eutrophication of water bodies, creating the need for efficient and low-cost strategies for their removal in order to meet environmental quality standards. This study presents a comparative thermodynamic evaluation of phosphate ion adsorption from aqueous solutions using two sustainable and readily available materials: autoclaved aerated concrete (AAC) and pumice stone (PS). Batch experiments were conducted under acidic (pH 3) and alkaline (pH 9) conditions to determine equilibrium adsorption capacities, and kinetic experiments were carried out for the best-performing adsorbent. Adsorption data were fitted to the Langmuir and the Freundlich isotherm models, while kinetic data were evaluated using pseudo-first-order and pseudo-second-order models. The Freundlich model showed the best correlation (R² = 0.90 − 0.97), indicating the heterogeneous nature of the adsorbent surfaces, whereas the Langmuir parameters suggested monolayer adsorption, with maximum capacities of 1006.69 mg/kg for PS and 859.20 mg/kg for AAC at pH 3. Kinetic results confirmed a pseudo-second-order behavior, indicating chemisorption as the main mechanism and the rate-limiting step in the adsorption process. To the best of our knowledge, this is the first study to compare the thermodynamic performance of AAC and PS for phosphate removal under identical experimental conditions. The findings demonstrate the potential of both materials as efficient, low-cost, and thermodynamically favorable adsorbents. Furthermore, the use of AAC, an industrial by-product, and PS, a naturally abundant volcanic material, supports resource recovery and waste valorization, aligning with the principles of the circular economy and sustainable water management. Full article

Cellular materials such as aluminum and polyurethane foams are recognized for their effectiveness in energy absorption. They commonly serve as crushable cores in sacrificial cladding for blast mitigation purposes. This study delves into the effectiveness of autoclaved aerated concrete (AAC), a lightweight, porous material known for its energy-absorbing properties as a crushable core in sacrificial cladding. The experimental set-up features a rigid frame made of steel measuring 1000 × 1000 × 15 mm³ with a central square opening (300 × 300 mm²) holding a 2 mm thick aluminum plate representing the structure. The dynamic response of the aluminum plate is captured using two high-speed cameras arranged in a stereoscopic configuration. Three-dimensional digital image correlation is used to compute the transient deformation fields. Blast loading is achieved by detonating 20 g of C4 explosive set at 250 mm from the plate’s center. The study assesses the mineral foam’s absorption capacity by comparing out-of-plane displacement and mean permanent deformation of the aluminum plate with and without the protective solution. Six foam configurations (A to F) are tested experimentally and numerically, varying in the foam’s free space for expansion relative to its total volume. Results show positive protective effects, with configuration F reducing maximum deflection by at least 30% and configuration C by up to 70%. Foam configuration influences energy dissipation, with an optimal lateral surface-to-volume ratio (ζ) enhancing protective effects, although excessive ζ leads to non-uniform foam crushing. To address the influence of front skin deformability, a non-deformable front skin has been adopted. The latter demonstrates an increased effectiveness of the sacrificial cladding, particularly for ζ values above the optimal value obtained when using a deformable front skin. Notably, using a non-deformable front skin increases maximum deflection reduction and foam energy absorption by up to approximately 30%. Full article

The paper describes the process of obtaining geopolymer composites using raw materials from critical waste, i.e., mixed power plant ash and furnace slag powder. Using such geopolymer composites, structural insulation panels were made in the laboratory, which were subjected to tests specific to construction applications. At the same time, some special properties, such as sound insulation and electromagnetic shielding properties for special applications, were tested. The results obtained from the functional tests led to the conclusion that the panels made of geopolymer composites provided both sound and electromagnetic attenuation values clearly superior to those obtained from autoclaved cellular concrete, brick, or concrete structures, which encourages us to suggest such material concepts for complex shielding purposes. The sustainability of the technology for producing such geopolymer composites was fully demonstrated from the economic, environmental, and social perspectives. Full article

The subject of this research is sustainable construction and energy saving, which is most reflected in the technological aspects of building construction. This article focuses on single-family buildings, and the subject of this research is hollow blocks (blocks) created as a result of hydrothermal treatment, in this case, autoclaved aerated concrete (AAC) and autoclaved cellular concrete (ACC), both traditional and modified plastics (HIPS). There are two types of materials resulting from hydrothermal treatment: autoclaved sand-lime bricks and autoclaved concrete. Both in the case of ACC and silicates bricks, the basic substrates used during their production are lime, sand and water (cement is also added to cellular concrete). This article presents the methodology of testing the porous structure of autoclaved materials with the use of computed tomography. Aerated concrete (light autoclaved concrete) has a compressive strength of 2–6 MPa. The tests included aerated concrete modified with high-impact polystyrene, commonly known as HIPS. HIPS high-impact polystyrene is a thermoplastic polymer that is obtained by block suspension polymerization of styrene with the addition of synthetic rubber. As a result of polymerization, small particles of polybutadiene remain in the polystyrene male, changing its physical and mechanical properties. The results from the content of air voids in the autoclaved concrete sample were, on average, 52.53%. Full article

The use of waste in the production of building materials is one of the possible ways to solve problems related to the sustainable management of non-degradable waste and difficult-to-recycle secondary resources. In this paper, a method is proposed for the non-autoclave production of an ultra-lightweight cellular concrete based on Portland cement, glass waste and liquid glass. A mixture of sodium hexafluorosilicate and hydroxide is used as a hardening activator, an aluminum powder serves as a gas-forming agent. The setting and hardening of raw mixtures occurs under the action of exothermal heat release due to a complex of chemical reactions occurring in the system, and the resulting material does not require additional heat treatment. It is optimal to use two fractions of glass waste to achieve acceptable material strength: coarse crushed (fineness modulus F_m = 0.945) and finely ground (specific surface S_sp = 450–550 m²/kg) glass. Glass particles of the fine fraction of glass, along with Portland cement, participate in hydrolytic and structure-forming processes, while glass particles of the coarse fraction play the role of reinforcing filler. The influence of the dispersion of glass and the density of liquid glass on the density, porosity, strength, water absorption and water resistance of the resulting cellular material was determined. At an average density of cellular concrete in the dry state of 150–320 kg/m³, the following characteristics can be achieved: a compressive strength up to 2.0 MPa, bending strength up to 0.38 MPa, thermal conductivity coefficient of the material in the range 0.05–0.09 W/(K·m), and a maximum operating temperature of 800 °C. The proposed ultra-lightweight cellular concrete can be used as a non-combustible heat and sound insulation material, as well as a repairing composition; the cellular concrete blocks can be used as filling masonry and for the construction of non-bearing internal walls. Full article

Alkali-activated binders have the potential to consume various types of waste materials. Low initial molar ratios of SiO₂/Al₂O₃ geopolymer mortars were considered in this article. Here we studied alkali-activated binders produced with photovoltaic glass powder in 5%; kaolin clay in 15%; ground granulated blast furnace slag in 30%; alumina-lime cement in 30%; and, interchangeably, fly ash from coal combustion in 5%, fly ash from biomass combustion in 5%, or granulated autoclaved cellular concrete in 5%. The influence of clay dehydroxylation, curing conditions, glass presence, and a kind of waste material was investigated. According to the experimental results, strength (compressive and tensile) gradually increased with increasing time and with the use of calcined clay. Significant improvement in compressive strength was seen with the additional 3 days curing time in 105 °C when non-sintered clay was used. The presence of photovoltaic glass in alkali-activated mortars immobilised mercury and arsenic but released zinc, chromium, and sulphates. The microscopic observations confirmed the greater densification of the microstructure of the binder made of calcined clay due to its greater surface development and dehydroxylation. The binder of non-calcined clay was granular, and the interfacial transitional zone was more porous. The C–A–S–H gel seemed to be the main phase. XRD examination confirmed the presence of C–A–S–H, C–S–H, zeolites, and many other phases in minor amount. The presented research was a pilot study, and its main goal was to develop it further. Full article

Autoclaved aerated concrete (AAC) is one of the most common types of lightweight cellular concrete, having a density of approximately one-fourth of that of conventional plain cement concrete. The use of industrial waste materials in concrete as a replacement for cement has garnered a lot of attention in recent years as a way to reduce the environmental effect of concrete. In this study, an attempt has been made to study the effect of AAC blocks made of industrial wastes such as fly Ash (FA) and ground granulated blast furnace slag (GGBS). Fly ash, along with different dosages of GGBS, was used as a partial replacement for cement in the production of AAC. For all the different dosages, microstructural analysis was performed using a Scanning electron microscope (SEM), X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDAX), and Fourier transform infrared spectroscopy (FTIR). Mechanical performances of AAC were determined by conducting various tests like compressive strength, modulus of rupture, dry density, and water absorption. The results revealed that the dosage of “15% GGBS + 85% cement” has maximum compressive strength, modulus of elasticity, and modulus of rupture made of Class F Fly Ash when compared to Class C Fly Ash based AAC blocks. Besides, the incorporation of GGBS in the manufacturing process would increase the compressive strength of AAC up to 68%. Hence, it is recommended to use 15% GGBS + 85% cement as a potential rate of replacement, to improve the mechanical properties of AAC blocks significantly. Full article

At present, the load-bearing enclosing structures of buildings and structures are designed and built considering the increasing requirements for energy efficiency and energy saving of such structures. This is due to the need for a thrifty attitude to the energy consumed and the need to strive for the greening of construction and increase the energy efficiency of buildings and structures. In this regard, one of the most effective and proven building materials is cellular concrete. The purpose of this study was to study the influence of some prescription factors on the structure formation and properties of non-autoclaved aerated concrete with improved characteristics. Standard test methods were used, as well as SEM analysis of the structure of aerated concrete. Non-autoclaved aerated concrete with the replacement of part of the cement with microsilica in an amount from 4% to 16% MS showed higher strength characteristics compared to aerated concrete, where part of the cement was replaced by the addition of granulated blast-furnace slag and a complex additive. The maximum value of compressive strength was recorded for aerated concrete with 16% MS addition. The largest increase in the coefficients of constructive quality was observed in compositions of aerated concrete with the addition of silica fume from 11% to 46% compared with the control composition. The addition of microsilica makes it possible to achieve an improvement in the thermal conductivity characteristics of non-autoclaved aerated concrete (up to 10%). Replacing part of the cement with slag and complex additives does not have a significant effect on thermal conductivity. The obtained dependencies were confirmed by the analysis of the structure formation of the studied aerated concrete at the micro level. An improvement in the microstructure of aerated concrete with the addition of microsilica in comparison with samples of the control composition has been proven. Full article

Aerated concrete (AC), such as cellular concrete, autoclaved aerated concrete (AAC), and non-autoclaved aerated concrete (NAAC), having excellent insulation properties, is commonly used in buildings located in cold regions, such as Nur-Sultan in Kazakhstan, the second coldest capital city in the world, because it can contribute to a large energy saving. However, when the AC is directly exposed to the repeated freeze and thaw (F-T) cycles, its F-T resistance can be critical because of lower density and scaling resistance of the AC. Moreover, the evaluation of the F-T resistance of the AC based on the durability factor (DF) calculated by using the relative dynamic modulus of elasticity may overestimate the frost resistance of the AC due to the millions of evenly distributed air voids in spite of its weak scaling resistance. In the present study, the F-T resistance of NAAC mixtures with various binary or ternary combinations of ground granulated blast-furnace slag (GGBFS) and micro-silica was assessed mainly using the ASTM C 1262/C1262M-16 Standard Test Method for Evaluating the Freeze-Thaw Durability of Dry-Cast Segmental Retaining Wall Units and Related Concrete Units. Critical parameters to affect the F-T resistance performance of the NAAC mixture such as compressive strength, density, water absorption, air–void ratio (VR), moisture uptake, durability factor (DF), weight loss (W_loss), the degree of saturation (S_d), and residual strength (S_res) were determined. Based on the determined parameter values, frost resistance number (FRN) has been developed to evaluate the F-T resistance of the NAAC mixture. Test results showed that all NAAC mixtures had good F-T resistance when they were evaluated with DF. Binary NAAC mixtures generally showed higher S_d and W_loss and lower DF and S_res than those of ternary NAAC mixtures. It was determined that the S_d was a key factor for the F-T resistance of NAAC mixtures. Finally, the developed FRN could be an appropriate tool to evaluate the F-T resistance of the NAAC mixture. Full article