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Keywords = bottom-up method

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21 pages, 5467 KB  
Article
Study on Seismic Behavior of Earthquake-Damaged Joints Retrofitted with CFRP in Hybrid Reinforced Concrete–Steel Frames
by Xiaotong Ma, Tianxiang Guo, Yuxiao Xing, Ruize Qin, Huan Long, Chao Bao, Fusheng Cao and Ruixiao Hong
Materials 2025, 18(21), 4857; https://doi.org/10.3390/ma18214857 (registering DOI) - 23 Oct 2025
Abstract
Mixed structures with lightweight steel added stories are particularly vulnerable to damage and failure at the joints during seismic events. To evaluate the secondary seismic behavior of the joints in lightweight steel added stories after seismic damage repair, a low-cycle load test was [...] Read more.
Mixed structures with lightweight steel added stories are particularly vulnerable to damage and failure at the joints during seismic events. To evaluate the secondary seismic behavior of the joints in lightweight steel added stories after seismic damage repair, a low-cycle load test was conducted in this study. Following the initial damage, carbon fiber-reinforced polymer (CFRP) was applied for reinforcement, along with epoxy resin for the repair of concrete cracks. The experimental analysis focused on the structural deformation, failure characteristics, and energy dissipation capacity in both the original and repaired joint states. On the basis of the experimental findings, finite element analysis was carried out to examine the influence of varying CFRP layer configurations on the seismic performance of the repaired joints. The results revealed a significant change in the damage pattern of the repaired specimen, shifting from secondary surface damage to significant concrete deterioration localized at the bottom of the column. The failure mechanism was characterized by the CFRP-induced tensile forces acting on the concrete at the column base, following considerable deformation at the beam’s end. When compared to the original joint, the repaired joints exhibited markedly improved performance, with a 33% increase in horizontal ultimate strength and an 85% increase in energy dissipation capacity at failure. Additionally, the rotation angle between the beams and columns was effectively controlled. Joints repaired with two layers of CFRP demonstrated superior performance in contrast to those with a single layer. However, once the repaired joints met the required strength, further increasing the number of CFRP layers had a minimal influence on the mechanical properties of the joints. The proposed CFRP-based seismic retrofit method, which accounts for the strength degradation of concrete in damaged joints due to earthquake-induced damage, has proven to be both feasible and straightforward, offering an easily implementable solution to improve the seismic behavior of structures. Full article
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32 pages, 4242 KB  
Review
Chemistry, Technology and Utilization of Nanolime
by Yaroslav Yakymechko, Roman Jaskulski, Daria Jóźwiak-Niedźwiedzka and Maciej Banach
Materials 2025, 18(21), 4846; https://doi.org/10.3390/ma18214846 - 23 Oct 2025
Abstract
This article provides a comprehensive review of the chemistry, production technology, and utilization of nanolime. Particular attention is given to the synthesis of Ca(OH)2 nanoparticles through both bottom-up and top-down approaches, highlighting how modern techniques enable precise control of particle size, morphology, [...] Read more.
This article provides a comprehensive review of the chemistry, production technology, and utilization of nanolime. Particular attention is given to the synthesis of Ca(OH)2 nanoparticles through both bottom-up and top-down approaches, highlighting how modern techniques enable precise control of particle size, morphology, and stability. The physicochemical properties of nanolime are discussed in relation to its role as a highly reactive, multifunctional additive, i.a., for cementitious systems, asphalt, and autoclaved products. Its applications are explored with emphasis on performance improvement in construction engineering, including enhanced strength, durability, self-healing potential, and compatibility with low-carbon binders. Beyond construction, nanolime is also examined as a material with relevance to environmental protection, CO2 sequestration, and heritage conservation. The review demonstrates that nanolime is a versatile and strategic material whose properties can be tailored to specific engineering needs, though challenges such as agglomeration, carbonation control, scalability, and long-term durability remain. Future research directions are outlined, focusing on sustainable production methods, functional integration into next-generation binders, and cross-disciplinary applications. Full article
(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)
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21 pages, 1214 KB  
Article
Wave Scattering and Trapping by C-Type Floating Breakwaters in the Presence of Bottom-Standing Perforated Semicircular Humps
by Prakash Kar, Harekrushna Behera and Dezhi Ning
Mathematics 2025, 13(21), 3372; https://doi.org/10.3390/math13213372 - 23 Oct 2025
Abstract
In this paper, the propagation of surface gravity waves over multiple bottom-standing porous semicircular humps is examined in the absence and presence of double floating C-type detached asymmetric breakwaters. Both wave scattering and trapping phenomena are investigated within the framework of small-amplitude [...] Read more.
In this paper, the propagation of surface gravity waves over multiple bottom-standing porous semicircular humps is examined in the absence and presence of double floating C-type detached asymmetric breakwaters. Both wave scattering and trapping phenomena are investigated within the framework of small-amplitude linear water wave theory, with the governing problem numerically solved using the multi-domain Boundary Element Method (BEM) in finite-depth water. A detailed parametric analysis is conducted to evaluate the effects of key physical parameters, including hump radius, porosity, spacing between adjacent humps, and the separation between the two C-type detached breakwaters. The study presents results for reflection and transmission coefficients, free-surface elevations, and the horizontal and vertical forces acting on the first perforated semicircular hump, as well as on the shore-fixed wall. The findings highlight the significant role of porous humps in altering Bragg scattering characteristics. For larger wavenumbers, wave reflection increases notably in the presence of a vertical shore-fixed wall, while it tends to vanish in its absence. Reflection is also observed to decrease with an increase in semicircle radius. Furthermore, as the wavenumber approaches zero, the vertical force on multiple permeable semicircles converges to zero, whereas for impermeable semicircles, it approaches unity. In addition, the horizontal force acting on the shore-fixed wall diminishes rapidly with increasing porosity of the semicircular humps. Full article
(This article belongs to the Section E: Applied Mathematics)
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16 pages, 7276 KB  
Article
Influence of Hydrogen-Based Direct Reduction Shaft Furnace Interior Structure on Shaft Furnace Performance
by Qingbin Xue, Haotian Liao, Jianliang Zhang and Kejiang Li
Materials 2025, 18(20), 4794; https://doi.org/10.3390/ma18204794 - 20 Oct 2025
Viewed by 258
Abstract
Hydrogen-based direct reduction of iron ore is a promising route to reduce CO2 emissions in steelmaking, where uniform particle flow inside shaft furnaces is essential for efficient operation. In this study, a full-scale three-dimensional Discrete Element Method (DEM) model of a shaft [...] Read more.
Hydrogen-based direct reduction of iron ore is a promising route to reduce CO2 emissions in steelmaking, where uniform particle flow inside shaft furnaces is essential for efficient operation. In this study, a full-scale three-dimensional Discrete Element Method (DEM) model of a shaft furnace was developed to investigate the effects of a diverter device on granular flow. By systematically varying the radial width and top/bottom diameters of the diverter, particle descent velocity, residence time, compressive force distribution, and collision energy dissipation were analyzed. The results demonstrate that introducing a diverter effectively suppresses funnel flow, prolongs residence time, and improves radial flow uniformity. Among the tested configurations, the smaller central diameter diverter showed the most favorable performance, achieving a faster and more uniform descent, reduced compressive force concentration, and lower collision energy dissipation. These findings highlight the critical role of diverter design in regulating particle dynamics and provide theoretical guidance for optimizing shaft furnace structures to enhance the efficiency of hydrogen-based direct reduction processes. Full article
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34 pages, 5792 KB  
Article
Recent Developments in Cross-Shore Coastal Profile Modeling
by L. C. van Rijn, K. Dumont and B. Malherbe
J. Mar. Sci. Eng. 2025, 13(10), 2011; https://doi.org/10.3390/jmse13102011 - 20 Oct 2025
Viewed by 60
Abstract
Coastal profile models are frequently used for the computation of storm-induced erosion at (nourished) beaches. Attention is focused on new developments and new validation exercises for the detailed process-based CROSMOR-model for the computation of storm-induced morphological changes in sand and gravel coasts. The [...] Read more.
Coastal profile models are frequently used for the computation of storm-induced erosion at (nourished) beaches. Attention is focused on new developments and new validation exercises for the detailed process-based CROSMOR-model for the computation of storm-induced morphological changes in sand and gravel coasts. The following new model improvements are studied: (1) improved runup equations based on the available field data; (2) the inclusion of the uniformity coefficient (Cu = d60/d10) of the bed material affecting the settling velocity of the suspended sediment and thus the suspended sediment transport; (3) the inclusion of hard bottom layers, so that the effect of a submerged breakwater on the beach–dune morphology can be assessed; and (4) the determination of adequate model settings for the accretive and erosive conditions of coarse gravel–shingle types of coasts (sediment range of 2 to 40 mm). The improved model has been extensively validated for sand and gravel coasts using the available field data sets. Furthermore, a series of sensitivity computations have been made to study the numerical parameters (time step, grid size and bed-smoothing) and key physical parameters (sediment size, wave height, wave incidence angle, wave asymmetry and wave-induced undertow), conditions affecting the beach morphodynamic processes. Finally, the model has been used to study various alternative methods of reducing beach erosion. Full article
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26 pages, 11507 KB  
Article
PLD-DETR: A Method for Defect Inspection of Power Transmission Lines
by Jianing Chen, Xin Zhang, Dawei Feng, Jiahao Li and Liang Zhu
Electronics 2025, 14(20), 4107; https://doi.org/10.3390/electronics14204107 - 20 Oct 2025
Viewed by 164
Abstract
Unmanned Aerial Vehicle (UAV)-based computer vision has emerged as a crucial approach for transmission line defect detection. However, transmission lines contain multi-scale components in complex environments, thereby complicating the accurate extraction of multi-scale features and necessitating a careful balance between model complexity with [...] Read more.
Unmanned Aerial Vehicle (UAV)-based computer vision has emerged as a crucial approach for transmission line defect detection. However, transmission lines contain multi-scale components in complex environments, thereby complicating the accurate extraction of multi-scale features and necessitating a careful balance between model complexity with detection accuracy. This paper proposes a Transformer-based framework called Power Line Defect Detection Transformer (PLD-DETR). To simultaneously capture shallow texture and deep semantic information while avoiding single-path limitations, a dual-domain selection mechanism block is designed as the backbone network, enabling collaborative feature extraction at different levels. Subsequently, an adaptive sparse self-attention mechanism is introduced to dynamically adjust attention weights for improved processing of critical feature regions, aiming to enhance attention to semantically rich regions and reduce background interference. Finally, we construct a multi-branch auxiliary bidirectional feature pyramid network to address information loss in traditional feature fusion. It fuses multi-scale features from four backbone layers through top-down and bottom-up bidirectional information flow, significantly improving feature representation capability. While maintaining model lightness, experimental results demonstrate that PLD-DETR achieves 2.7%, 7.01%, and 5.58% improvements in AP50, AP75, and AP50–95, respectively, compared to the baseline model. Compared with other transmission line defect detection methods, PLD-DETR demonstrates superior performance in both accuracy and efficiency Full article
(This article belongs to the Special Issue AI Applications for Smart Grid)
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24 pages, 8375 KB  
Article
Analysis of the Transcriptome Response to Low Nitrogen in Populus ussuriensis
by He Feng, Yue Chang, Runze Liu, Wenlong Li, Zhiwei Liu, Ming Wei, Zhibin Luo and Chenghao Li
Biology 2025, 14(10), 1448; https://doi.org/10.3390/biology14101448 - 20 Oct 2025
Viewed by 121
Abstract
(1) Background: Nitrogen is a key element that is essential for plant growth, and it is absorbed by roots from the soil. Nitrogen stress severely limits forest tree productivity; therefore, elucidating the molecular mechanisms underlying nitrogen stress tolerance in forest trees is critical [...] Read more.
(1) Background: Nitrogen is a key element that is essential for plant growth, and it is absorbed by roots from the soil. Nitrogen stress severely limits forest tree productivity; therefore, elucidating the molecular mechanisms underlying nitrogen stress tolerance in forest trees is critical for sustainable forestry. (2) Methods: Phenotypic analyses of wild-type (WT) Populus ussuriensis (P. ussuriensis) plantlets grown in vitro were carried out at different time points under both normal and low-nitrogen conditions. Transcriptome analyses of roots were performed at 0, 12, 24, 48, 96, and 336 h under low-nitrogen stress via RNA-seq. A gene regulatory network (GRN) for nitrogen-metabolism-associated DEGs was constructed using a three-gene module framework and a bottom-up Gaussian Graphical Model algorithm. (3) Results: WT P. ussuriensis plantlets grown in vitro exhibited a synergistic response characterized by increased root biomass and suppressed shoot growth. Transcriptome analyses identified 8289 DEGs enriched in nitrogen metabolism, ROS scavenging, root development, and phytohormone signaling. A total of 443 differentially expressed transcription factors (TFs) (mainly MYB, AP2/ERF, and bHLH) were detected. A nitrogen-metabolism-associated GRN comprising 60 nodes was established. (4) Conclusions: Transcriptomic data and nitrogen metabolism pathway predictions from this study establish a systematic foundation for investigating molecular adaptation mechanisms in P. ussuriensis roots under nitrogen stress. Full article
(This article belongs to the Special Issue Adaptation Mechanisms of Forest Trees to Abiotic Stress)
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15 pages, 1593 KB  
Article
Influence of Sampling Effort and Taxonomic Resolution on Benthic Macroinvertebrate Taxa Richness and Bioassessment in a Non-Wadable Hard-Bottom River (China)
by Jiaxuan Liu, Hongjia Shan, Chengxing Xia and Sen Ding
Biology 2025, 14(10), 1444; https://doi.org/10.3390/biology14101444 - 20 Oct 2025
Viewed by 167
Abstract
Benthic macroinvertebrates are widely used for river ecosystem health monitoring, yet challenges remain in non-wadable rivers, particularly regarding sampling effort. We evaluated hand-net sampling efficiency at three sites along the Danjiang River (a Yangtze River tributary) by analyzing taxa richness across taxonomic levels [...] Read more.
Benthic macroinvertebrates are widely used for river ecosystem health monitoring, yet challenges remain in non-wadable rivers, particularly regarding sampling effort. We evaluated hand-net sampling efficiency at three sites along the Danjiang River (a Yangtze River tributary) by analyzing taxa richness across taxonomic levels under varying replicate numbers. In total, 61 taxa (41 families) of benthic macroinvertebrates were identified. Non-metric multidimensional scaling analysis indicated no significant spatiotemporal variation in community composition. However, sampling effort increased, and the benthic macroinvertebrate taxa richness at both genus/species and family levels also increased. At eight sample replicates, the taxa accumulation curve at the genus/species level did not show an asymptote, with the observed richness reaching 67–80% of the predicted values calculated by Jackknife 1. In contrast, the family-level curve exhibited a clear asymptotic trend, with the observed richness reaching 82–100% of the predicted values. As sampling effort increased, bias decreased and accuracy improved, particularly for family-level taxa. Additionally, the BMWP scores also increased with the sampling effort. When the replicate number was no less than six, the BMWP reached stable assessment grades for all cases. From the perspective of bioassessment in non-wadable rivers, the hand net is suitable for collecting benthic macroinvertebrates. However, there is a risk of underestimating taxa richness due to insufficient sampling effort. Using family-level taxa can partially mitigate the impacts caused by insufficient sampling efforts to a certain extent, but further validation is needed for other non-wadable rivers (e.g., those with soft substrates). In conclusion, our research results indicate that six replicate hand-net samplings in non-wadable hard-bottom rivers can be regarded as a cost-effective and reliable sampling method for benthic macroinvertebrate BMWP assessment. This strategy provides a relatively practical reference for the monitoring of benthic macroinvertebrate in the same type of rivers in China. Full article
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29 pages, 3118 KB  
Article
Impact of Compaction Parameters and Techniques on MUPS Tablets
by Daniel Robin Thio, Paul Wan Sia Heng and Lai Wah Chan
Pharmaceutics 2025, 17(10), 1347; https://doi.org/10.3390/pharmaceutics17101347 - 18 Oct 2025
Viewed by 181
Abstract
Background/Objectives: Compaction of sustained release coated pellets into tablets is associated with damage to the functional coat and loss in sustained release. The influences of precompression, trilayering, and tableting rate on the compaction of sustained release coated pellets into tablets are not well [...] Read more.
Background/Objectives: Compaction of sustained release coated pellets into tablets is associated with damage to the functional coat and loss in sustained release. The influences of precompression, trilayering, and tableting rate on the compaction of sustained release coated pellets into tablets are not well defined and were herein investigated to enhance the current limited understanding of these factors. Methods: Pellets coated with acrylic polymer (AC) or ethylcellulose (EC) were combined with filler material and compacted into multi-unit pellet system (MUPS) tablets prepared using different levels of precompression, as a trilayered MUPS tablet and at different tableting rates. The physical properties of the resulting MUPS tablets were evaluated. Trilayering was achieved by adding cushioning layers at the top and bottom of the MUPS tablet to avoid direct contact of pellets with punch surfaces. Results: With precompression, slightly stronger MUPS tablets were made compared to the tablets without precompression for EC pellets but not AC pellets. However, precompression led to a slight reduction in pellet coat damage for AC pellets but not EC pellets. Trilayering led to significant reductions in pellet coat damage and significant increases in tablet tensile strength. When EC pellets were lubricated with sodium stearyl fumarate, pellet coat damage was significantly lower. Increasing the tableting rate from 20 to 100 rpm did not result in increased pellet coat damage but in significantly weaker tablets due to the shorter dwell time. Conclusions: This study provides key insights on how compaction parameters and techniques could be altered to produce better MUPS tablets. Full article
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17 pages, 5189 KB  
Article
Total Solution-Processed Zr: HfO2 Flexible Memristor with Tactile Sensitivity: From Material Synthesis to Application in Wearable Electronics
by Luqi Yao and Yunfang Jia
Sensors 2025, 25(20), 6429; https://doi.org/10.3390/s25206429 - 17 Oct 2025
Viewed by 278
Abstract
In the pursuit of advanced non-volatile memory technologies, ferroelectric memristors have attracted great attention. However, traditional perovskite ferroelectric materials are hampered by environmental pollution, limited applicability, and the complexity and high cost of conventional vacuum deposition methods. This has spurred the exploration of [...] Read more.
In the pursuit of advanced non-volatile memory technologies, ferroelectric memristors have attracted great attention. However, traditional perovskite ferroelectric materials are hampered by environmental pollution, limited applicability, and the complexity and high cost of conventional vacuum deposition methods. This has spurred the exploration of alternative materials and fabrication strategies. Herein, a flexible Pt/Zr: HfO2 (HZO)/graphene oxide (GO)/mica memristor is successfully fabricated using the total solution-processed method. The interfacial oxygen competition mechanism between the HZO layer and the GO bottom electrode facilitates the formation of the HZO ferroelectric phase. The as-prepared device exhibits a switching ratio of approximately 150 and can maintain eight distinct resistance levels, and it can also effectively simulate neural responses. By integrating the ferroelectric polarization principle and the piezoelectric effect of HZO, along with the influence of GO, the performance variations of the as-prepared device under mechanical and thermal influences are further explored. Notably, Morse code recognition is achieved by utilizing the device’s pressure properties and setting specific press rules. The as-prepared device can accurately convert and store information, opening new avenues for non-volatile memory applications in silent communication and promoting the development of wearable electronics. Full article
(This article belongs to the Section Wearables)
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24 pages, 26148 KB  
Article
An Open-Source 3D Bioprinter Using Direct Light Processing for Tissue Engineering Applications
by Daniel Sanchez-Garcia, Anuar Giménez-El-Amrani, Armando Gonzalez-Muñoz and Andres Sanz-Garcia
Inventions 2025, 10(5), 92; https://doi.org/10.3390/inventions10050092 - 17 Oct 2025
Viewed by 157
Abstract
The demand for organ transplantation continues to rise worldwide, intensifying the gap between supply and demand and driving research in tissue engineering (TE). Bioprinting, particularly light-based vat photopolymerization (VP) methods such as digital light processing (DLP), has emerged as a promising strategy to [...] Read more.
The demand for organ transplantation continues to rise worldwide, intensifying the gap between supply and demand and driving research in tissue engineering (TE). Bioprinting, particularly light-based vat photopolymerization (VP) methods such as digital light processing (DLP), has emerged as a promising strategy to fabricate complex, cell-compatible tissue constructs with high precision. In this study, we developed an open-source, bottom-up DLP bioprinter designed to provide a cost-effective and modular alternative to commercial systems. The device was built from commercially available components and custom-fabricated parts, with tolerance allocation and deviation analyses applied to ensure structural reliability. Mechanical and optical subsystems were modeled and validated, and the control architecture was implemented on the Arduino platform with a custom Python-based graphical interface. The system achieved a theoretical Z-axis resolution of 1 μm and a vertical travel range of 50 mm, with accuracy and repeatability comparable to research-grade bioprinters. Initial printing trials using polyethylene glycol diacrylate (PEGDA) hydrogels demonstrated high-fidelity microfluidic constructs with adequate dimensional precision. Collectively, these results validate the functionality of the proposed system and highlight its potential as a flexible, precise, and cost-effective platform that is also easy to customize to advance the democratization of biofabrication in TE. Full article
(This article belongs to the Section Inventions and Innovation in Advanced Manufacturing)
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23 pages, 3759 KB  
Article
Taguchi-Based Experimental Optimization of PET and Bottom Ash Cement Composites for Sustainable Cities
by Arzu Cakmak, Hacer Mutlu Danaci, Salih Taner Yildirim and İsmail Veli Sezgin
Sustainability 2025, 17(20), 9206; https://doi.org/10.3390/su17209206 - 17 Oct 2025
Viewed by 261
Abstract
Waste valorization in construction materials offers a promising pathway to reducing environmental burdens while promoting circular resource strategies in the built environment. This study develops a novel composite mortar formulated with sustainable materials and alternative aggregates, namely polyethylene terephthalate (PET) particles recovered from [...] Read more.
Waste valorization in construction materials offers a promising pathway to reducing environmental burdens while promoting circular resource strategies in the built environment. This study develops a novel composite mortar formulated with sustainable materials and alternative aggregates, namely polyethylene terephthalate (PET) particles recovered from post-consumer plastic waste and bottom ash from thermal power generation. Natural pumice was incorporated to improve the lightness and the thermal insulation, with cement serving as the binder. The mix design was systematically optimized using the Taguchi method to enhance performance while minimizing carbon emissions. The resulting mortar, produced at both laboratory and small-scale commercial levels, demonstrated favorable technical properties: dry density of 1.3 g/cm3, compressive strength of 5.96 MPa, thermal conductivity of 0.27 W/(m*K), and water absorption of 16.1%. After exposure to 600 °C, it retained 60.6% of its strength and exhibited only a 10.1% mass loss. These findings suggest its suitability for non-load-bearing urban components where sustainability, thermal resistance, and durability are essential. The study contributes to global sustainability goals, particularly Sustainable Development Goal (SDG) 11, 12, and 13, by illustrating how waste valorization can foster resilient construction while reducing the environmental footprint of cities. Full article
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32 pages, 2854 KB  
Article
Construction of Consistent Fuzzy Competence Spaces and Learning Path Recommendation
by Ronghai Wang, Baokun Huang and Jinjin Li
Axioms 2025, 14(10), 768; https://doi.org/10.3390/axioms14100768 - 16 Oct 2025
Viewed by 159
Abstract
Artificial intelligence is playing an increasingly important role in education. Learning path recommendation is one of the key technologies in artificial intelligence education applications. This paper applies knowledge space theory and fuzzy set theory to study the construction of consistent fuzzy competence spaces [...] Read more.
Artificial intelligence is playing an increasingly important role in education. Learning path recommendation is one of the key technologies in artificial intelligence education applications. This paper applies knowledge space theory and fuzzy set theory to study the construction of consistent fuzzy competence spaces and their application to learning path recommendation. With the help of the outer fringe of fuzzy competence states, this paper proves the necessary and sufficient conditions for a fuzzy competence space to be a consistent fuzzy competence space and designs an algorithm for verifying consistent fuzzy competence spaces. It also proposes methods for constructing and reducing consistent fuzzy competence spaces, provides learning path recommendation algorithms from the competence perspective and combined with a disjunctive fuzzy skill mapping, and constructs a bottom-up gradual and effective learning path tree. Simulation experiments are carried out for the construction and reduction in consistent fuzzy competence spaces and for learning path recommendation, and the simulation studies show that the proposed methods achieve significant performance improvement compared with related research and produce a more complete recommendation of gradual and effective learning paths. The research of this paper can provide theoretical foundations and algorithmic references for the development of artificial intelligence education applications such as learning assessment systems and intelligent testing systems. Full article
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14 pages, 1479 KB  
Article
Transport of Phosphorus from Three Fertilizers Through High- and Low-Phosphorus Soils
by Lily DuPlooy, Joshua Heitman, Luke Gatiboni and Aziz Amoozegar
Agronomy 2025, 15(10), 2395; https://doi.org/10.3390/agronomy15102395 - 15 Oct 2025
Viewed by 212
Abstract
Chemical fertilizers are commonly used to supply phosphorus and other nutrients to crops, but due to high affinity of soils for P fixation, over-application of P fertilizer is common, which may result in groundwater and surface water pollution. To increase P use efficiency, [...] Read more.
Chemical fertilizers are commonly used to supply phosphorus and other nutrients to crops, but due to high affinity of soils for P fixation, over-application of P fertilizer is common, which may result in groundwater and surface water pollution. To increase P use efficiency, different strategies, including different fertilizer formulations and types, have been developed. Two struvite-based fertilizers, Crystal Green® (CG) and Crystal Green Pearl® (CGP), are touted as environmentally safe, because they are insoluble in water but soluble in organic acids exuded from crop roots. The objective of this study was to assess fate and transport of P from diammonium phosphate (DAP), CG, and CGP through two loam soils with a significant difference in their initial P content. Two loamy soils, one collected from an experimental field receiving fertilizer continuously since 1985 and one from an adjacent area receiving no fertilizer, and a pure sand control were packed in 5 cm diameter and 5 cm long columns. Several grains equivalent to approximately 80 mg P from each fertilizer were imbedded at the bottom of the column. Distilled water was passed through the soil columns from the bottom at a relatively constant rate, and the outflow was collected every two hours using a fraction collector. Outflow samples from each treatment combination were analyzed for P by the colorimetric method, and the amount of P retained by the soils along the column at the end of the water application was determined by the nitric acid digestion method. Approximately 91% of P in DAP, 34% in CG, and only 3.8% in CGP was transported through the sand column. In contrast, the amounts of P transported were approximately 42.2% for DAP, 6.4% for CG, and 0.4% for CGP through the high-P soil and 22.4% for DAP, 0.6% for CG, and almost zero for CGP through the low-P soil. Overall, the results show a high solubility and transport for DAP, very low transport for CGP, and somewhat low to medium transport for CG fertilizers. In addition, the results show that even the high-P soil that has received fertilizer for about 40 years has the capacity to fix significant amounts of P. Full article
(This article belongs to the Special Issue Conventional and Alternative Fertilization of Crops)
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23 pages, 16775 KB  
Article
Development of Carbide-Reinforced Al-7075 Multi-Layered Composites via Friction Stir Additive Manufacturing
by Adeel Hassan, Khurram Altaf, Mokhtar Che Ismail, Srinivasa Rao Pedapati, Roshan Vijay Marode, Imtiaz Ali Soomro and Naveed Ahmed
J. Compos. Sci. 2025, 9(10), 568; https://doi.org/10.3390/jcs9100568 - 15 Oct 2025
Viewed by 348
Abstract
Friction stir additive manufacturing (FSAM) is a promising solid-state technique for fabricating high-strength aluminum alloys, such as Al-7075, which are difficult to process using conventional melting-based additive manufacturing (AM) methods. This study investigates the mechanical properties and tool wear behavior of seven-layered Al-7075 [...] Read more.
Friction stir additive manufacturing (FSAM) is a promising solid-state technique for fabricating high-strength aluminum alloys, such as Al-7075, which are difficult to process using conventional melting-based additive manufacturing (AM) methods. This study investigates the mechanical properties and tool wear behavior of seven-layered Al-7075 multi-layered composites reinforced with silicon carbide (SiC) and titanium carbide (TiC) fabricated via FSAM. Microstructural analysis confirmed defect-free multi-layered composites with a homogeneous distribution of SiC and TiC reinforcements in the nugget zone (NZ), although particle agglomeration was observed at the bottom of the pin-driven zone (PDZ). The TiC-reinforced composite exhibited finer grains than the SiC-reinforced composite in both as-welded and post-weld heat-treated (PWHT) conditions, achieving a minimum grain size of 1.25 µm, corresponding to a 95% reduction compared to the base metal. The TiC-reinforced multi-layered composite demonstrated superior mechanical properties, attaining a microhardness of 93.7 HV and a UTS of 263.02 MPa in the as-welded condition, compared to 88.6 HV and 236.34 MPa for the SiC-reinforced composite. After PWHT, the TiC-reinforced composite further improved to 159.12 HV and 313.46 MPa UTS, along with a higher elongation of 11.14% compared to 7.5% for the SiC-reinforced composite. Tool wear analysis revealed that SiC reinforcement led to greater tool degradation, resulting in a 1.17% weight loss. These findings highlight the advantages of TiC reinforcement in FSAM, offering enhanced mechanical performance with reduced tool wear in multi-layered Al-7075 composites. Full article
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