Search Results (289)

Graphitic carbon nitride (g-C₃N₄)-based materials hold significant promise for environmental remediation, particularly water purification, owing to their unique electronic structure, metal-free composition, and robust chemical stability. However, powdered g-C₃N₄ faces challenges such as particle aggregation, poor recyclability, and limited exposure of active sites. Structuring g-C₃N₄ into hydrogels or aerogels—three-dimensional porous networks offering high surface area, rapid mass transport, and tunable porosity—represents a transformative solution. This review comprehensively examines recent advances in g-C₃N₄-based gels, covering synthesis strategies such as crosslinking (physical/chemical), in situ polymerization, and the sol–gel and template method. Modification approaches including chemical composition and structural engineering are systematically categorized to elucidate their roles in optimizing catalytic activity, stability, and multifunctionality. Special emphasis is placed on environmental applications, including the removal of emerging contaminants and heavy metal ions, as well as solar-driven interfacial evaporation for desalination. Throughout, the critical interplay between gel structure/composition and performance is evaluated to establish design principles for next-generation materials. Finally, this review identifies current challenges regarding scalable synthesis, long-term stability, in-depth mechanistic understanding, and performance in complex real wastewater matrices. This work aims to provide valuable insights and guidance for advancing g-C₃N₄-based hydrogel and aerogel technologies in environmental applications. Full article

The development of stable and efficient heterogeneous Fenton oxidation for organic pollutant degradation is crucial to avoid iron sludge formation and cumbersome filtration processes. In this study, iron oxide/carbon aerogel was prepared via the sol–gel method, freeze-drying, and high-temperature carbonization using iron nitrate heptahydrate, ammonium hydroxide, and cellulose as raw materials, with polyvinylimine serving as the crosslinking agent. To enhance the pH adaptability of the catalyst, copper and cerium elements were introduced. The characterization results demonstrate the iron (III) oxide within the carbon aerogel, achieving phenol degradation efficiency exceeding 95% within 120 min. Meanwhile, the introduction of copper and cerium accelerated the degradation of phenol while maintaining a certain catalytic degradation effect at pH 5-7. In addition, the catalyst exhibited excellent recyclability, retaining 85% of its initial degradation efficiency after five reaction cycles. This work offers a new method for the development of heterogeneous Fenton catalysts. Full article

Industrial pollution caused by Cu(II) ions remains one of the most critical environmental challenges worldwide. A novel green-fluorescent aerogel has been successfully developed for simultaneous sensing and adsorption of Cu(II) through the cross-linking of carboxymethyl nanocellulose and carbon dots (C dots) using epichlorohydrin as a linker. The C dots were synthesized by heating glucose and aspartate mixed solutions at 150 °C. Under UV illumination, the aerogel exhibited intense homogeneous green fluorescence originating from the uniformly dispersed C dots, whose emission can be efficiently quenched by Cu(II) ions. By leveraging smartphone-based imaging, the concentration of Cu(II) was quantified within the range of 5–200 µg/L, with a detection limit of 3.7 µg/L. The adsorption isotherm of Cu(II) onto the aerogel strictly conformed to the Freundlich isotherm model (fitting coefficient R² = 0.9992), indicating a hybrid adsorption mechanism involving both physical adsorption and chemical complexation. The maximum adsorption capacity reached 149.62 mg/g, a value surpassing many reported adsorbents. X-ray photoelectron spectroscopy and Fourier-transform infrared spectroscopy analyses confirmed that the interactions between the aerogel and Cu(II) involved chelation and redox reactions, mediated by functional groups such as hydroxyl, amino, and carboxyl moieties. The straightforward fabrication process of the aerogel, coupled with its low cost, abundant raw materials, facile synthesis, and superior Cu(II) removal efficiency, positions this bifunctional fluorescent material as a promising candidate for large-scale environmental remediation applications. Full article

The burgeoning electromagnetic pollution from 5G/6G technologies demands lightweight, broadband, and mechanically robust electromagnetic microwave absorbers (EMWAs). Conventional carbon aerogels suffer from structural fragility and inadequate electromagnetic dissipation. Herein, we propose a defect-engineering strategy through precise optimization of the chitosan (CS)/cellulose nanocrystal (CNC) ratio to fabricate elastic boron nitride nanosheet (BNNS)-embedded carbon aerogels. By fixing BNNS content for optimal impedance matching and modulating the CS/CNC ratio of the aerogel, we achieve synergistic control over hierarchical microstructure, defect topology, and electromagnetic response. The aerogel exhibits a wide effective absorption bandwidth (EAB) of 8.3 GHz at a thickness of 3.6 mm and an excellent reflection loss of −52.79 dB (>99.999% attenuation), surpassing most biomass-derived EMWAs. The performance stems from CNC-derived topological defects enabling novel polarization pathways and BNNS-triggered interfacial polarization, while optimal graphitization (I_D/I_G = 1.08) balances conductive loss. Simultaneously, the optimal CS/CNC ratio facilitates the formation of a stable and flexible framework. The long-range ordered micro-arch lamellar structure endows the aerogel with promising elasticity, which retains 82% height after 1000 cyclic compression at 50% strain. This work paves the way for biomass-derived carbon aerogels as next-generation wearable and conformal EMWAs with broadband absorption. Full article

Bionic synthesis technology has made significant breakthroughs in porous functional materials by replicating and optimizing biological structures. For instance, biomimetic titanium dioxide-coated carbon multilayer materials, prepared via biological templating, exhibit a hierarchical structure, abundant nanopores, and synergistic effects. Bionic mineralization further enhances microcapsules by forming a secondary inorganic wall, granting them superior impermeability, high elastic modulus, and hardness. Through techniques like molecular self-assembly, electrospinning, and pressure-driven fusion, researchers have successfully fabricated centimeter-scale artificial lamellar bones without synthetic polymers. In environmental applications, electrospun membranes inspired by lotus leaves and bird bones achieve 99.94% separation efficiency for n-hexane–water mixtures, retaining nearly 99% efficiency after 20 cycles. For energy applications, an all-ceramic silica nanofiber aerogel with a bionic blind bristle structure demonstrates ultralow thermal conductivity (0.0232–0.0643 W·m⁻¹·K⁻¹) across a broad temperature range (−50 to 800 °C). This review highlights the preparation methods and recent advances in biomimetic porous materials for practical applications. Full article

Amidst global imperatives for sustainable energy and environmental remediation, carbon aerogels (CAs) present a transformative alternative to conventional carbon materials (e.g., activated carbon, carbon fibers), overcoming limitations of disordered pore structures, unmodifiable surface chemistry, and functional inflexibility. This review systematically examines CA-based electrochemical systems as its primary focus, analyzing fundamental charge-storage mechanisms and establishing structure–property–application relationships critical to energy storage performance. We critically assess synthesis methodologies, emphasizing how stage-specific parameters govern structural/functional traits, and detail multifunctional modification strategies (e.g., heteroatom doping, composite engineering) that enhance electrochemical behavior through pore architecture optimization, surface chemistry tuning, and charge-transfer kinetics acceleration. Electrochemical applications are extensively explored, including the following: 1. Energy storage: supercapacitors (dual EDLC/pseudocapacitive mechanisms) and battery hybrids. 2. Electrocatalysis: HER, OER, ORR, and CO₂ reduction reaction (CO₂RR). 3. Electrochemical processing: capacitive deionization (CDI) and electrosorption. Beyond this core scope, we briefly acknowledge CA versatility in ancillary domains: environmental remediation (heavy metal removal, oil/water separation), flame retardancy, microwave absorption, and CO₂ capture. Full article

Lithium–sulfur batteries (LSBs), possessing excellent theoretical capacities, advanced theoretical energy densities, low cost, and nontoxicity, are one of the most promising energy storage battery systems. However, some issues, including poor conductivity of elemental S, the “shuttle effect” of high-order lithium polysulfides (LiPSs), and sluggish reaction kinetics, hinder the commercialization of LSBs. To solve these problems, various carbon-based aerogels with developed surface morphology, tunable pores, and electrical conductivity have been examined for immobilizing sulfur, mitigating its volume variation and enhancing its electrochemical kinetics. In this paper, an extensive generalization about the effective preparation methods of carbon-based aerogels comprising the combined method of carbonization with the gelation of precursors and drying processes (ambient pressure drying, freeze-drying, and supercritical drying) is proposed. And we summarize various carbon carbon-based aerogels, mainly including graphene aerogels (Gas) and carbon nanofiber (CNF) and carbon nanotube (CNT) aerogels as cathodes, separators, and interlayers in LSBs. In addition, the mechanism of action of carbon-based aerogels in LSBs is described. Finally, we conclude with an outlook section to provide some insights into the application of carbon-based aerogels in electrochemical energy storage devices. Based on the discussion and proposed recommendations, we provide more approaches on nanomaterials in high-performance liquid or state LSBs with high electrochemical performance in the future. Full article

In the synthesis of aerogels, the influence of the drying process on the nanostructure is an issue of utmost relevance for tailoring the final properties of these materials. Among the complex parameters affecting this process, the hydrophobicity of the aerogel structure plays a key role. Thus, herein, four different silica aerogel formulations based on tetraethyl orthosilicate and trimethoxymethylsilane were employed to produce aerogels with different wettability properties (from hydrophilic samples to highly hydrophobic). The synthesized gels were dried by three methods, namely freeze-drying, high-temperature supercritical drying with ethanol, and low-temperature supercritical drying with carbon dioxide, and the influence of each procedure on bulk density, porosity, pore size, and specific surface area of the resulting aerogels was analyzed in detail. The direct correlation between the surface hydrophobicity/hydrophilicity of the silica gels and the effects of each drying technique was analyzed, providing insights into a proper selection of the drying method depending on both the water affinity of the gel and the desired textural properties and structures. Full article

Patient-specific scaffolds for tissue and organ regeneration are still limited by the difficulty of simultaneously shaping complex geometries, preserving hierarchical porosity, and guaranteeing sterility. Additive technologies represent a promising approach for addressing problems in tissue engineering, with the potential to develop personalized matrices for the growth of tissue and organ cells. The utilization of supercritical technologies, encompassing the processes of drying and sterilization within a supercritical fluid environment, has demonstrated significant opportunities for obtaining highly effective matrices for cell growth based on biocompatible materials. We present a comprehensive methodology for fabricating intricately structured, sterile aerogels based on alginate–chitosan polyelectrolyte complexes. The target three-dimensional macrostructure is achieved through (i) direct ink writing or (ii) heterophase printing, enabling the deposition of inks with diverse rheological profiles (viscosities ranging from 0.8 to 2500 Pa·s). A coupled supercritical carbon dioxide drying–sterilization regimen at 120 bar and 40 °C is employed to preserve the highly porous architecture of the printed constructs. The resulting aerogels exhibit 96 ± 2% porosity, a BET surface area of 108–238 m² g⁻¹, and complete sterility. The proposed integration of 3D printing and supercritical processing yields sterile, intricately structured aerogels with substantial potential for the fabrication of patient-specific scaffolds for tissue and organ regeneration. Full article

Despite their outstanding thermal insulation and ultralight structure, silica aerogels suffer from inherent mechanical fragility, making the investigation of their mechanical behavior crucial for expanding their practical utility in advanced applications. To enhance their mechanical performance, this study introduces a dual-phase reinforcement strategy by anisotropically incorporating carbon nanotubes (CNTs) and graphene oxide (GO) sheets into the aerogel matrix. Using molecular dynamic simulations, we systematically investigate the tensile behavior and pore structure evolution of these hetero-structured composites. The results reveal a non-monotonic dependence of tensile strength on loading ratio, distinguishing three strain-dependent reinforcement regimes. High loading content (11.1%) significantly improves strength under low strain (0–26%), whereas low loading levels (1.8%) are more effective at preserving structural integrity under large strain (44–50%). Moderate loading (5.1%) yields balanced performance in intermediate regimes. While increasing carbon content reduces initial pore size by partially filling the framework, tensile deformation leads to interfacial debonding and the formation of larger pores due to CNT–GO hybrid structure interactions. This work elucidates a dual reinforcement mechanism—physical pore confinement and interfacial coupling—highlighting the critical role of nanostructure geometry in tuning strain-specific mechanical responses. The findings provide mechanistic insights into anisotropic nanocomposite behavior and offer guidance for designing robust porous materials for structural and functional applications. Full article

Lightweight concrete (LWC) has emerged as a transformative material in sustainable and high-performance construction, driven by innovations in engineered lightweight aggregates, supplementary cementitious materials (SCMs), fiber reinforcements, and geopolymer binders. These advancements have enabled LWC to achieve compressive strengths surpassing 100 MPa while reducing density by up to 30% compared to conventional concrete. Fiber incorporation enhances flexural strength and fracture toughness by 20–40%, concurrently mitigating brittleness and improving ductility. The synergistic interaction between SCMs and lightweight aggregates optimizes matrix densification and interfacial transition zones, curtailing shrinkage and bolstering durability against chemical and environmental aggressors. Integration of recycled and bio-based aggregates substantially diminishes the embodied carbon footprint by approximately 40%—aligning LWC with circular economy principles. Nanomaterials such as nano-silica and carbon nanotubes augment early-age strength development by 25% and refine microstructural integrity. Thermal performance is markedly enhanced through advanced lightweight fillers, including expanded polystyrene and aerogels, achieving up to a 50% reduction in thermal conductivity, thereby facilitating energy-efficient building envelopes. Although challenges persist in cost and workability, the convergence of hybrid fiber systems, optimized mix designs, and sophisticated multi-scale modeling is expanding the applicability of LWC across demanding structural, marine, and prefabricated contexts. In essence, LWC’s holistic development embodies a paradigm shift toward resilient, low-carbon infrastructure, cementing its role as a pivotal material in the evolution of next-generation sustainable construction. Full article

Advancements in thermoregulating textiles have been propelled by innovations in nanotechnology, composite materials, and smart fiber engineering. This article reviews recent scholarly papers on experimental passive and active thermoregulating textiles to present the latest advancements in these fabrics, their mechanisms of thermoregulation, and their feasibility for use. The review underscores that phase-change materials enhanced with graphene, boron nitride, and carbon nanofibers offer superior thermal conductivity, phase stability, and flexibility, making them ideal for wearable applications. Shape-stabilized phase-change materials and aerogel-infused fibers have shown promising results in outdoor, industrial, and emergency settings due to their durability and high insulation efficiency. Radiative cooling textiles, engineered with hierarchical nanostructures and Janus wettability, demonstrate passive temperature regulation through selective solar reflection and infrared emission, achieving substantial cooling effects without external energy input. Thermo-responsive, shape-memory materials, and moisture-sensitive polymers enable dynamic insulation and actuation. Liquid-cooling garments and thermoelectric hybrids deliver precise temperature control but face challenges in portability and power consumption. While thermoregulating textiles show promise, the main challenges include achieving scalable manufacturing, ensuring material flexibility, and integrating multiple functions without sacrificing comfort. Future research should focus on hybrid systems combining passive and active mechanisms, user-centric wearability studies, and cost-effective fabrication methods. These innovations hold significant potential for applications in extreme environments, athletic wear, military uniforms, and smart clothing, contributing to energy efficiency, health, and comfort in a warming climate. Full article

Building facade insulation technologies have evolved from primitive thermal barriers to high-performance, multifunctional systems that enhance energy efficiency and indoor comfort. Historical insulation methods, such as thick masonry walls and timber-based construction, have gradually been replaced by advanced materials and innovative facade designs. Studies indicate that a significant proportion of a building’s heat loss occurs through its external walls and windows, highlighting the need for effective insulation strategies. The development of double-skin facades (D-SFSs), adaptive facades (AFs), and green facades has enabled substantial reductions in heating and cooling energy demands. Materials such as vacuum insulation panels (VIPs), aerogels, and phase change materials (PCMs) have demonstrated superior thermal resistance, contributing to improved thermal regulation and reduced carbon emissions. Green facades offer additional benefits by lowering surface temperatures and mitigating urban heat island effects, while D-SF configurations can reduce cooling loads by over 20% in warm climates. Despite these advancements, challenges remain regarding the initial investment costs, durability, and material sustainability. The future of facade insulation technologies is expected to focus on bio-based and recyclable insulation materials, enhanced thermal performance, and climate-responsive facade designs. This study provides a comprehensive review of historical and modern facade insulation technologies, examining their impact on energy efficiency, sustainability, and future trends in architectural design. Full article

Rapid industrialization has escalated environmental pollution caused by organic compounds, posing critical challenges for wastewater treatment. Advanced oxidation processes based on peroxymonosulfate (PMS) suffer from metal leaching and catalyst recycling challenges. To address these limitations, this study developed a nitrogen-doped biochar aerogel (NBA) derived from poplar wood powder as an eco-friendly and easily recoverable PMS activator. The NBA catalyst, optimized by tuning the calcination temperature to achieve a specific surface area of 297.5 m² g⁻¹, achieved 97% bisphenol A (BPA) removal within 60 min with a catalyst dosage of 0.3 g/L and 1.0 mM PMS under mild conditions. The material exhibited broad pH adaptability (pH 3.5–9), recyclability (>94% efficiency after thermal treatment), and versatility in degrading seven pollutants (BPA, phenol, 4-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, rhodamine 6G, and levofloxacin) through synergistic radical (•OH, SO₄^•−, O₂^•−) and non-radical (¹O₂) pathways. X-ray photoelectron spectroscopy (XPS) analyses revealed that nitrogen doping enhanced PMS activation by optimizing electronic structures. This study highlights the potential of waste biomass-derived carbon aerogels as eco-friendly, efficient, and reusable catalysts for advanced oxidation processes in wastewater treatment. Full article

Hierarchical porous carbon materials hold great potential for energy storage applications due to their high porosity, large specific surface area, and excellent electrical conductivity. Cellulose and sodium alginate are naturally abundant high-molecular-weight biopolymer materials. Utilizing them as precursors for the fabrication of high-performance electrochemical carbon materials is highly significant for achieving carbon neutrality goals. In this study, porous carbon aerogels were successfully synthesized using a combination of freeze-drying and a simple carbonization process, with nanocellulose and sodium alginate as precursors. Among the prepared samples, SC-0.03 (sodium alginate: nanocellulose = 0.1:0.03) exhibited the best performance, achieving a specific surface area of 713.7 m² g⁻¹. This material features an optimized hierarchical pore structure and a substantial intrinsic oxygen doping content, resulting in excellent capacitance performance. Benefiting from these structural advantages and their synergistic effects, the SC-0.03 electrode demonstrated a high specific capacitance of 251.5 F g⁻¹ at a current density of 0.5 A g⁻¹. This study shows that the construction of three-dimensional porous structures by taking advantage of the self-supporting properties of natural polymer materials does not require the introduction of external binders. Due to the nanoscale dimensions and high aspect ratio, nanocellulose enables the formation of a more refined and interconnected hierarchical pore network, enhancing ion accessibility and conductivity. The hierarchical porous carbon aerogel developed in this study, based on a biomass self-reinforcement strategy, not only shows great promise as an advanced energy storage material but also possesses environmentally friendly properties, offering new insights for the development of sustainable energy materials. Full article