Search Results (488)

Efficient recycling of polyamide 6 (PA6) requires selective depolymerization routes that recover monomers under moderate conditions. This study investigates microwave-assisted acid hydrolysis of four PA6 waste streams, two oligomer-rich residues (WS-13, WS-24), an industrial fiber (C-fiber), and a commercial resin (C-resin) to elucidate degradation kinetics, activation energies, and product yields. Thermogravimetric analysis revealed multi-step solid-state decomposition, while microwave hydrolysis (125–200 °C, 15–60 min, 400 W) demonstrated strong dependence on acid type. HCl achieved complete conversion, whereas phosphoric and formic acids exceeded 95%. Kinetic analysis under H₃PO₄ followed pseudo-first-order behavior, with rate constants (0.015–0.141 min⁻¹ at 200 °C) and activation energies reflecting feedstock structure: 53.1 kJ mol⁻¹ (WS-13), 56.5 kJ mol⁻¹ (WS-24), 87.1 kJ mol⁻¹ (C-resin), and 99.9 kJ mol⁻¹ (C-fiber). Monomer yields varied by substrate: WS-13 achieved 62.4% at 200 °C and 45 min (ACA 46%, CPL 16%), WS-24 yielded 62.0% (primarily ACA), C-fiber reached 69.7% (ACA-dominant), and C-resin produced 53.8%. These results show that oligomer-rich wastes are kinetically favored for rapid hydrolysis at lower energy cost, while C-fiber maximizes aminocaproic acid recovery. Overall, microwave-assisted hydrolysis provides a selective, energy-efficient pathway for PA6 circularity, offering design parameters for reactor operation and process optimization. Full article

In this study, we numerically investigate the equilibrium dynamics of a rotating system consisting of two masses connected by a massless rod within the framework of the circular restricted three-body problem. The larger primary is modeled as a radiating body and the smaller as an oblate spheroid. We explore the influence of the involved parameters, i.e., mass ratio ($\mu$), force ratio (k), radiation pressure factor ($q_1$), and oblateness coefficient ($A_2$), on the number, positions, and linear stability of equilibrium points. Zero velocity curves are presented in the equatorial plane for varying values of the Jacobi constant. Up to five equilibrium points are identified of which three are collinear ($L_1$, $L_2$, $L_3$) and two are non-collinear ($L_4$, $L_5$). The positions of all equilibria shift under variations in the perturbing parameters. While the collinear points are generally unstable, $L_1$ can exhibit stability for certain combinations of $\mu$, k, and $q_1$. The non-collinear points may also be stable under specific conditions with stability zones expanding with increased parameter values. The model is applied to the irregular, elongated asteroid 951 Gaspra, for which five equilibrium points are found. Despite positional dependence on oblateness and radiation, the perturbations do not significantly affect the equilibrium points’ stability and the motion near them remains linearly unstable. The Lyapunov families of periodic orbits emanating from the collinear equilibria of this particular system are also investigated. Full article

Water contamination by heavy metals, particularly lead, derived from industrialization, climate change, and urbanization, represents a critical risk to human health and the environment. Several agricultural biomass residues have demonstrated efficacy as contaminant adsorbents. In this context, the study aimed to evaluate the potential of sugarcane tip (ST) waste biomass treated by hydrothermal carbonization (HTC) to produce hydrochar as an adsorbent material for Pb²⁺ in aqueous solutions. Samples were synthesized from the waste biomass at temperatures of 180 °C, 215 °C, and 250 °C, with a constant pressure of 6 MPa. Aqueous solutions of Pb²⁺ were prepared at concentrations of 10, 25, 50, 75, and 100 mg/L. Each solution was stirred at 1 g of hydrochar at 150 rpm, 25 °C, and pH 5 for 15 to 120 min. The solutions were filtered and stored at 4 °C for flame atomic absorption spectrophotometry analysis. In all cases, equilibrium was reached rapidly—within 15 min or less—as indicated by the stabilization of q_t values over time. At an initial concentration of 100 mg L⁻¹, the highest equilibrium uptake was observed for the hydrochar synthesized at ST HTC 180 °C (4.90 mg g⁻¹), followed by 4.58 mg g⁻¹ and 4.52 mg g⁻¹ for ST HTC 215 °C and ST HTC 250 °C, respectively. For the ST HTC 180 °C, the Sips model provided the best correlation with the experimental data, exhibiting a high maximum capacity (q_max = 240.8 mg g⁻¹; K_s = 0.007; n = 1.09; R² = 0.975), which reinforces the heterogeneous nature of the material’s surface. Hydrothermal synthesis increased the amount of acidic active sites in the ST HTC 180 °C material from 1.3950 to 3.8543 meq g⁻¹, which may influence the electrical charge of the Pb²⁺ adsorption process. HTC-treated sugarcane tip biomass represents a promising alternative for the synthesis of adsorbent materials, contributing to water remediation and promoting the circular economy by sustainably utilizing agricultural waste. Full article

The presence of discontinuities in fractured reservoirs, their mechanical and physical characteristics, and fluid flow through them are important factors influencing their effective large-scale properties. In this paper, the variation of elastic moduli in a block measuring 100 × 100 × 100 m³ that hosts a discrete fracture network (DFN) is evaluated using the discrete element method (DEM). Fractures are characterised by (1) constant, (2) interlocked, and (3) mismatched stiffness properties. First, three uniaxial verification tests were performed on a block (1 × 1 × 2 m³) containing a circular finite fracture (diameter = 0.5 m) to validate the developed numerical algorithm that implements the three fracture stiffnesses mentioned above. The validated algorithms were generalised to fractures in a DFN embedded in a 100 × 100 × 100 m³ rock block that reproduces in situ conditions at various depths (4.7 km, 2.3 km, and 0.5 km) of the Soultz-sous-Forêts geothermal site. The effective elastic moduli of this large-scale rock mass were then numerically evaluated through a triaxial loading scenario by comparing to the numerically evaluated stress field using the DFN, with the stress field computed using an effective homogeneous elastic block. Based on the results obtained, we evaluate the influence of fracture interaction and stress perturbation around fractures on the effective elastic moduli and subsequently on the large-scale P-wave velocity. The numerical results differ from the elastic moduli of the rock matrix at higher fracture densities, unlike the other methods. Additionally, the effect of nonlinear fracture stiffness is reduced by increasing the depth or stress level in both the numerical and semi-analytical methods. Full article

This paper explores the application of the Value of Information, (VoI), based on the Claude Shannon/Ruslan Stratonovich framework within economic contexts. Unlike previous studies that examine circular settings and strategic interactions, we focus on a non-strategic linear setting. We employ standard economically motivated utility functions, including linear, quadratic, constant absolute risk aversion (CARA), and constant relative risk aversion (CRRA), across various priors of the stochastic environment, and analyse the resulting specific VoI forms. The curvature of these VoI functions play a decisive role in determining whether acquiring additional costly information enhances the efficiency of the decision making process. We also outline potential implications for broader decision-making frameworks. Full article

Continuum robots have garnered significant attention for their high flexibility and adaptability to complex environments. However, achieving the same level of high-precision control as rigid robots remains a significant challenge. This paper introduces an innovative Multi-Segment Extendable Soft Manipulator (MSESM) that employs a pneumatic–tendon hybrid drive mechanism. The design, utilizing off-the-shelf industrial bellows and 3D-printed components, allows the manipulator to achieve an extension ratio of up to 156.85%. By adopting a differential stiffness design, its bending stiffness was increased by approximately 4–5 times, its axial stiffness was increased by approximately 10 times, and its torsional resistance was enhanced, preventing inter-segment coupling during motion. At the control level, this paper proposes a hybrid control method that integrates a Constant Curvature (CC) physical prior with a data-driven neural network. Experimental results show that in tracking rectangular, triangular, and circular trajectories, this hybrid method reduced the average tracking error by 60.43% compared to a purely neural network-based controller, with the error reduction for the rectangular trajectory reaching 74.19%. This research validates a practical and effective approach for creating soft manipulators that successfully merge high flexibility with high-precision control. Full article

In this research, we explore the computational and experimental optimization of compliant constant-torque mechanisms (CTMs) fabricated via injection molding using polymeric materials. We investigate how geometric variations influence the torsional strength of CTMs through numerical simulation, experimental validation, and artificial neural network (ANN) modeling. Four different geometries with the same overall dimensions were designed and analyzed to quantify their mechanical performance. The results reveal that the geometric configuration significantly affected the torsional behavior of the CTMs, with circular cross-sections demonstrating superior strength. Moreover, the ANN model exhibited a high prediction accuracy and minimal relative errors, closely aligning with the experimental outcomes. Despite this, discrepancies between our numerical and experimental results suggest that further refinements in material modeling and manufacturing processes are warranted. In this paper, we emphasize the importance of integrating computational (CAE), artificial neural networks (ANNs) and experimental techniques for optimizing polymer-based CTMs. CAE simulations for Model 4 showed a constant-torque section from 23–44 degrees with 0.142 N·m torque, while experimental and ANN results indicated a longer range (20–45/46 degrees) with higher torque values (0.164 N·m). Experimental and ANN predictions for Model 4 showed an approximate 97% similarity. While these findings represent a foundational step, the characteristics of polymer CTMs suggest potential relevance for advancing applications in precision engineering, biomedical devices, and soft robotics, pending further application-specific validation. Full article

A potential flow theory-based fully nonlinear 2D NWT is developed in the time domain to investigate the hydrodynamic performance of a submerged circular cylindrical WEC device under combined wave–current conditions. The hydrodynamic force on the submerged cylinder is evaluated using the acceleration potential method coupled with the desingularized boundary integral equation method (DBIEM). The impacts of the wave height, current speed, and parameters of the power take-off mechanism on the extracted power capability of the WEC device are investigated. The results show that for the scenario of an opposing current, the dimensionless mean extracted power is reduced by as much as 14.3% with increasing wave height. Except for long waves, the extracted power under a co-flowing current exceeds that of the current-free case and an opposing current yields lower power. In contrast to the current-free scenario, the peak power extraction point shifts to slightly higher values of the spring and damper constants when the current is co-flowing, whereas the opposite trend is observed for the opposing current. Full article

The preservation of architectural heritage must extend beyond historic city centres to include the large-scale prefabricated housing stock that characterises many post-socialist urban environments. These structures, often overlooked, hold both material and social value. This study focuses on prefabricated residential buildings and proposes a scalable methodology for sustainable rehabilitation through a prototype tool: the building identity passport (BIP). The proposed approach integrates multi-layered diagnostics—combining building integrated modelling (BIM), thermographic surveys, occupant questionnaires, and expert interviews—into a replicable decision-support framework. Results demonstrate that the passport can synthesise tangible (physical) and intangible (perceptual, social) resources of prefabricated blocks into a coherent framework, highlighting both technical pathologies and lived experiences. Thermographic validation of BIM simulations confirms the feasibility of combining digital and on-site diagnostics, while community surveys and expert insights reveal the tensions between comfort, health, and energy efficiency. The resulting prototype provides a transparent overview of building identity, making rehabilitation strategies easier to compare, communicate, and adapt. Beyond its local application, the study underscores the broader replicability of the method: core diagnostic layers remain constant, while context-sensitive indicators can be tailored to different regions. The proposed framework thus offers municipalities and communities a practical tool to align rehabilitation with circular resource use and occupant well-being. Future work will focus on automating data processing and extending validation to diverse housing contexts, strengthening its potential as a platform for sustainable urban regeneration. Full article

This paper presents the design of a circularly polarized RFID ground mat antenna for UHF-band sports-event applications. Considering a practical sports-event timing system, the ground-based mat antenna with characteristics of a low-backward radiation and circular polarization is proposed. A multilayer square patch antenna using an acrylic dielectric substrate with a wideband branch-line coupler feeding network is employed to improve overall radiation efficiency, which, in turn, provides two excitation port with a phase difference of 90°. Thus, right-hand circular polarization can be obtained. Instead of a conventional FR4–air–FR4 structure, the proposed FR4–acrylic–FR4 composite configuration is adopted to substantially increase the antenna’s mechanical strength and durability against external pressure from runners. The antenna’s performance is attributed to the use of an effective composite dielectric constant and an optimized design of its parameters. Additionally, the patch antenna’s low-backward radiation characteristic helps reduce multipath interference in real-world applications. The measured results are in good agreement with the simulated data, validating the proposed antenna design. In order to further assess the practical performance of the antenna, outdoor measurements are carried out to validate the estimated reading distances derived from controlled anechoic chamber tests. The measured return loss remained below −10 dB across the frequency range of 755–990 MHz, exhibiting a slight discrepancy compared to the simulated bandwidth of 800–1030 MHz. For the characteristic of the circular polarization, the measured axial ratio is below 3 dB within the range of 860–920 MHz. While a more relaxed criterion of an axial ratio below 6 dB is considered, the operating frequency range extends from 560 MHz to 985 MHz, which falls within the frequency band relevant for RFID reader applications. Full article

Orthogonal Frequency Division Multiplexing (OFDM) modulation currently dominates the physical layer design in modern transmission systems. Its primary advantage is the simple reconstruction of channel frequency response (CFR). However, the Least Squares (LS) algorithm commonly used here is prone to significant estimation errors due to noise interference. A promising and relatively simple alternative is a DFT-based strategy that uses a pre-computed refinement/correction matrix to improve estimation performance. This paper investigates two implementation approaches for CFR reconstruction with pre-computed matrices. Focusing on multiplication operations, a threshold number of active subcarriers was identified at which these two implementations exhibit comparable numerical complexity. A numerical performance factor was defined and a detailed performance analysis was carried out for different guard interval (GI) lengths and the number of active subcarriers in the OFDM signal. Additionally, to maintain channel estimation quality irrespective of GI length, a channel impulse response (CIR) energy detection procedure was introduced. This procedure refines the results of the symbol synchronization process and, by using the circular shift property, preserves constant values of the precomputed matrix coefficients without system performance loss, as measured by Bit Error Rate (BER) and Mean Square Error (MSE) metrics. Full article

The continuous-wave (CW) illuminator, whose fundamentals are related to the theoretical understanding of loop antennas loaded with ferrite materials, is a device which plays an important role in electromagnetic pulse (EMP) susceptibility assessment. However, existing theoretical formulas do not consider cases where ferrite materials are loaded into the loop antenna. This paper provides a new explicit theoretical formula for the impedance of a circular loop antenna loaded with ferrite materials for CW illuminator design, and explores the variation regularity of its input impedance. Loading ferrite materials affects the internal impedance of the loop antenna and forces some modifications to the classical calculation procedure, resulting in an asymptotic numerical calculation method and a closed-form solution. The full-wave simulation results from CST Studio Suite show a maximum error of less than 0.99%, compared to the classical theory. With ferrite material loaded, the input impedance of the loop antenna is significantly reduced and smoothed in a wide range of normalized radii. For a loop antenna with a fixed circumference, the input impedance indicates that the Q-factor decreases as the thickness of the ferrite material increases. Conversely, for a ferrite-loaded loop antenna with a constant material thickness, a larger loop circumference results in a higher Q-factor. In summary, this study provides a fast and accurate computational method for the input impedance design of CW illuminators, while also offering an effective tool for further research on the performance of ferrite-loaded loop antennas. Full article

Tomato brown rugose fruit virus (ToBRFV) has been causing severe agricultural damage worldwide since its recent discovery. While related to tobacco mosaic virus, its properties and infection mechanisms are poorly understood. To uncover their structure and nanomechanics, we carried out atomic force microscopy (AFM) measurements on individual ToBRFV particles. The virions are rod-shaped with a height and width of 9 and 30 nm, respectively. Length is widely distributed (5–1000 nm), with a mode at 30 nm. ToBRFV rods displayed a 22.4 nm axial periodicity related to structural units. Force spectroscopy revealed a Young’s modulus of 8.7 MPa, a spring constant of 0.25 N/m, and a rupture force of 1.7 nN. In the force curves a step was seen at a height of 3.3 nm, which is related to virion wall thickness. Wall thickness was also estimated by predicting coat protein structure with AlphaFold, yielding a protein with a length of 7.3 nm. Accordingly, the structural element of ToBRFv is a right circular cylinder with an equal height and diameter of ~22 nm and a wall thickness between 3.3 and 7.3 nm. Thus, at least four to nine serially linked units are required to encapsidate a single, helically organized RNA genome. Fragmentation of ToBRFV into these cylindrical structural units may result in a facilitated release of the genome and thus efficient infection. Full article

The presence of PET (polyethylene terephthalate) in the environment is a global problem due to soil and water microplastic contamination. There is a constant demand for new technologies that expand the possibilities of PET disposal or recycling while reducing energy consumption and anthropogenic carbon footprint. In this study, we developed a comprehensive zero-waste management system for PET recycling (rPET) to cyclic ketals and terephthalic acid. The developed method is based on the hydrolysis of rPET flakes in an inert environment with the separation and purification of terephthalic acid and the dehydration of ethylene glycol. For the first time, we present the use of cheap and readily available Cr/SiO₂ and Fe/SiO₂ nanocatalysts for direct acetalization of ethylene glycol without organic co-solvents. The catalysts were characterized by EDXRF, XPS and TEM techniques. The 2,2-dimethyl-1,3-dioxolane (DMD), a product of ethylene glycol’s direct acetalization with acetone, was tested as a solvent for polymers with satisfactory results in the solubility of epoxy resins. The addition of unpurified terephthalic acid and residues constituting post-production waste to concrete allows for a reduction in the mass of concrete in the range of 11.3–23.4% and the material modified in this way allows for a reduction in concrete consumption. This rPET waste management methodology is consistent with the assumptions of the circular economy and allows for a significant reduction of anthropogenic CO₂ emissions. Full article

This paper presents a combined theoretical, numerical, and experimental analysis to investigate the lateral plastic crushing behavior and energy absorption of circular and non-circular thin-walled rings between two rigid plates. Theoretical solutions incorporating both linear material hardening and power-law material hardening models are solved via numerical shooting methods. The theoretically predicted force-denting displacement relations agree excellently with both FEA and experimental results. The FEA simulation clearly reveals the coexistence of an upper moving plastic region and a fixed bottom plastic region. A robust automatic extraction method of the fully plastic region at the bottom from FEA is proposed. A modified criterion considering the unloading effect based on the resultant moment of cross-section is proposed to allow accurate theoretical estimation of the fully plastic region length. The detailed study implies an abrupt and almost linear drop of the fully plastic region length after the maximum value by the proposed modified criterion, while the conventional fully plastic criterion leads to significant over-estimation of the length. Evolution patterns of the upper and lower plastic regions in FEA are clearly illustrated. Furthermore, the distribution of plastic energy dissipation is compared in the bottom and upper regions through FEA and theoretical results. Purely analytical solutions are formulated for linear hardening material case by elliptical integrals. A simple algebraic function solution is derived without necessity of solving differential equations for general power-law hardening material case by adopting a constant curvature assumption. Parametric analyses indicate the significant effect of ovality and hardening on plastic region evolution and crushing force. This paper should enhance the understanding of the crushing behavior of circular and non-circular rings applicable to the structural engineering and impact of the absorption domain. Full article