Search Results (215)

This study systematically evaluates the influence of the recycled coarse aggregate (RCA) replacement rate and the number of freeze–thaw cycles (FTCs) on the frost damage of recycled aggregate concrete (RAC) through rapid freeze–thaw tests, and delves into the underlying damage mechanisms. The findings demonstrate that the incorporation of recycled aggregates deteriorates the frost resistance of concrete to a certain extent, primarily manifested by increased apparent damage with rising FTC numbers and RCA content. Specimens with an RCA replacement rate exceeding 50% exhibited extensive mortar spalling and aggregate exposure after 50 FTCs. The mass loss rate initially decreased in the early freezing-thawing stage, then began to increase after approximately 20 cycles, reaching a maximum of 5.09%. The relative dynamic elasticity modulus (RDEM) decreased with an increase in both FTCs and RCA content, dropping to a minimum of 71.99%. Furthermore, based on the relative dynamic elastic modulus, this study developed a GM(1, 1) freeze–thaw damage prediction model applicable to a full replacement range of 0%–100% RCA with a precision level of Grade I. Microstructural analysis revealed that microcracks and pores within the interfacial transition zones (ITZs) and the surrounding matrix of both NCA and RCA are critical for the initiation and propagation of freeze–thaw damage, thereby elucidating the damage mechanism in RAC. Full article

Balancing stress wave attenuation with structural integrity is recognized as a critical challenge for protective materials in underground defense systems. A novel high-titanium slag (HTS) concrete featuring multiscale pores is proposed to address this dilemma. Large-particle porous HTS aggregates are embedded into cement mortar, enabling mechanical robustness comparable to conventional concrete alongside significant stress wave dissipation. Wave scattering and gas–solid interfacial reflections are induced by the multiscale pore architecture, effectively attenuating energy propagation. A dense interface transition zone between HTS aggregates and the cement mortar is confirmed through microscopic characterization, ensuring structural coherence. Wave attenuation is revealed by Split Hopkinson Pressure Bar tests to primarily originate from pore-driven reflections rather than impedance mismatch. A groundbreaking strategy is offered for designing blast-resistant materials that harmonize dynamic energy dissipation with structural durability, advancing the development of resilient underground infrastructure. Full article

This study elucidated the evolution and catastrophic failure mechanisms of concrete’s mechanical properties under high-temperature and moisture-coupled environments. Specimens underwent hygrothermal shock simulation via constant-temperature drying (100 °C/200 °C, 4 h) followed by water quenching (20 °C, 30 min). Uniaxial compression tests were performed using a uniaxial compression test machine with synchronized multi-scale damage monitoring that integrated digital image correlation (DIC), acoustic emission (AE), and infrared thermography. The results demonstrated that hygrothermal coupling reduced concrete ductility significantly, in which the peak strain decreased from 0.36% (ambient) to 0.25% for both the 100 °C and 200 °C groups, while compressive strength declined to 42.8 MPa (−2.9%) and 40.3 MPa (−8.6%), respectively, with elevated elastic modulus. DIC analysis revealed the temperature-dependent failure mode reconstruction: progressive end cracking (max strain 0.48%) at ambient temperature transitioned to coordinated dual-end cracking with jump-type damage (abrupt principal strain to 0.1%) at 100 °C and degenerated to brittle fracture oriented along a singular path (principal strain band 0.015%) at 200 °C. AE monitoring indicated drastically reduced micro-damage energy barriers at 200 °C, where cumulative energy (4000 mV·ms) plummeted to merely 2% of the ambient group (200,000 mV·ms). Infrared thermography showed that energy aggregation shifted from “centralized” (ambient) to “edge-to-center migration” (200 °C), with intensified thermal shock effects in fracture zones (ΔT ≈ −7.2 °C). The study established that hygrothermal coupling weakens the aggregate-paste interfacial transition zone (ITZ) by concentrating the strain energy along singular weak paths and inducing brittle failure mode degeneration, which thereby provides theoretical foundations for fire-resistant design and catastrophic failure warning systems in concrete structures exposed to coupled environmental stressors. Full article

River sediments have attracted increasing attention as alternative raw materials for sustainable cementitious materials due to their abundant availability and silica–alumina-rich composition. In this study, a systematic literature search was conducted in Web of Science and Google Scholar using combinations of the keywords “river sediment,” “cementitious materials,” “activation,” and “pozzolanic activity,” covering publications up to July 2025. In addition, a citation network tool (Connected Papers) was employed to trace related works and ensure comprehensive coverage of emerging studies. This review systematically examines the properties of river sediments from diverse regions, along with activation and modification techniques such as alkali/acid activation, thermal calcination, and mechanical milling. Their applications in various cementitious systems are analyzed, with mix design models compared to elucidate the effects of replacing fine aggregates, coarse aggregates, and cement on workability, strength, and durability. Multi-scale characterization via XRD, FTIR, and TG-DSC reveals the mechanisms of C–S–H and C–A–S–H gel formation, pore refinement, and interfacial transition zone densification. The review highlights three key findings: (1) moderate sediment replacement (20–30%) improves strength without compromising flowability; (2) alkali–water glass activation and calcination at 600–850 °C effectively enhance pozzolanic activity; and (3) combining the minimum paste thickness theory with additives such as water reducers, fibers, or biochar enables high-performance and low-carbon concrete design. This review provides a comprehensive theoretical foundation and technical pathway for the high-value utilization of river sediments, carbon reduction in concrete, and sustainable resource recycling. Full article

Concrete pavements frequently develop subsurface voids between surface and base layers during long-term service due to cyclic loading, environmental effects, and subgrade instability, which compromise structural integrity and traffic safety. Ground-penetrating radar (GPR) has been widely used as a non-destructive method for detecting such voids. However, the presence of coarse aggregates with strong electromagnetic scattering properties often introduces pseudo-reflection signals in radar images, hindering accurate void identification. To address this challenge, this study develops a high-fidelity three-phase concrete model incorporating aggregates, mortar, and the interfacial transition zone (ITZ). The Finite-Difference Time-Domain (FDTD) method is used to simulate electromagnetic wave propagation in both voided and intact structures. Simulation results reveal that aggregate-induced scattering can blur or distort reflection interfaces, generating pseudo-hyperbolic anomalies even in the absence of voids. In cases of thin-layer voids, real echo signals may be masked by aggregate scattering, leading to missed detections. GPR systems can be broadly classified into impulse, continuous-wave, and multi-frequency types. To validate the simulations, field tests using multi-frequency 2D/3D GPR systems and borehole verification were conducted. The results confirm the consistency between simulated and actual radar anomalies and validate the proposed model. This work provides theoretical insight and modeling strategies to enhance the interpretation accuracy of GPR data for subsurface void detection in concrete pavements. Full article

Nanoparticles leverage their unique nanoscale effects to optimize concrete performance through synergistic multi-mechanism interactions. Core mechanisms include micro-filling effects (graded pore filling, optimized pore structure), nucleation (promoting crystallization of hydration products, refining microstructure), chemical reactivity (e.g., pozzolanic reaction of nano-SiO₂, enhancing interfacial transition zones), and interfacial strengthening (improving ITZ structure and stress transfer). Common nanomaterials (e.g., nano-SiO₂, Al₂O₃, carbon nanotubes) significantly enhance concrete’s mechanical properties, durability, and functionalities (e.g., self-sensing, electromagnetic shielding). However, nano-modified concrete still faces challenges such as poor dispersion, high cost, and environmental/health risks. Future efforts should focus on multi-scale mechanism research, green low-cost synthesis processes, and intelligent composite systems development to advance the engineering applications pf nano-modified concrete. Full article

Hybrid fiber-reinforced concrete (HFRC), renowned for its significantly enhanced mechanical properties and structural integrity, is widely used in infrastructure construction and has become a key avenue of modern high-performance concrete development. The hybrid application of basalt fiber (BF) and polypropylene fiber (PPF) at optimized ratios generates synergistic effects, improving both mechanical performance and material service reliability. To explore and evaluate the synergistic mechanism of BF-PPF hybrid fibers on concrete’s mechanical properties and performance, this study employs an orthogonal experimental design and mechanical testing methods, measuring the materials’ static compressive strength (loading rate: 0.6 mm/min), splitting tensile strength (loading rate: 0.12–0.14 MPa/s), dynamic elastic modulus (measured by the ultrasonic method), and dynamic compressive strength (loading rates: 0.6 mm/min, 6 mm/min, and 60 mm/min). For these tests, we prepared 100 mm × 100 mm × 100 mm cubic specimens (for static compressive, dynamic compressive, and splitting tensile tests) and 400 mm × 100 mm × 100 mm prismatic specimens (for dynamic elastic modulus tests), with three parallel specimens in each test group. In addition, the microstructure was characterized by scanning electron microscopy (SEM) to observe the fiber-matrix interaction. The results show that when the BF/PPF volume ratio is 1:2 (BF0.05PPF0.1), the concrete’s compressive strength, splitting tensile strength, and elastic modulus increase by 13.7%, 76.3%, and 116.0%, respectively, with corresponding synergistic effect indices (Q) of 0.057, 0.213, and 0.241, indicating obvious positive synergy. Under dynamic loading, hybrid combinations with higher PPF content (e.g., BF0.05PPF0.1) exhibit strain-rate-dependent enhancements in compressive strength and better impact resistance. SEM analysis reveals that fibers inhibit microcrack propagation through fiber bridging, network distribution, and pull-out resistance, while also improving the interfacial transition zone’s structure. These findings provide theoretical support for the engineering application of composite fiber-reinforced concrete materials. Full article

This study investigates the fracture behavior of recycled aggregate concrete by integrating fractal theory and empirical modeling to quantify how recycled coarse aggregates (RCAs) and recycled fine aggregates (RFAs) influence crack complexity and maximum crack width under varying content and loads. The results reveal distinct scale-dependent behaviors between RCA and RFA. For RCA, moderate dosages enhance fractal complexity (a measure of surface roughness) by promoting micro-crack proliferation, while excessive RCA reduces complexity due to matrix homogenization. In contrast, RFA significantly increases both fractal complexity and crack width under equivalent loads, reflecting its susceptibility to micro-scale interfacial transition zone (ITZ) degradation. Non-linear thresholds are identified: RCA’s fractal complexity plateaus at high loads as cracks coalesce into fewer dominant paths, while RFA’s crack width growth decelerates at extreme dosages due to balancing effects like particle packing. Empirical models link aggregate dosage and load to fractal dimension and crack width with high predictive accuracy (R² > 0.85), capturing interaction effects such as RCA’s load-induced complexity reduction and RFA’s load-driven crack width amplification. Secondary analyses further demonstrate that fractal dimension correlates with crack width through non-linear relationships, emphasizing the coupled nature of micro- and macro-scale damage. These findings challenge conventional design assumptions by differentiating the impacts of RCA (macro-crack coalescence) and RFA (micro-crack proliferation), providing actionable thresholds for optimizing mix designs. The study also advances sustainable material design by offering a scientific basis for updating standards to accommodate higher recycled aggregate percentages, supporting circular economy goals through reduced carbon emissions and waste diversion, and laying the groundwork for resilient, low-carbon infrastructure. Full article

Due to the shortage of construction aggregates, carbonate rock aggregates—including mainly limestone aggregates—have long been used in structural concrete in many countries worldwide. On the other hand, earlier tests on the shear fracture toughness of concretes with limestone aggregates were very limited and were even abandoned for many years. For the above reasons, in this paper, completely new fracture toughness tests were performed according to the mode II fracture for limestone concretes with different grain size distributions. Two types of aggregate grain were used, i.e., two with maximum grain sizes of 8 mm (M1 series concrete) and 16 mm (M2 series concrete). During the experiments, the critical stress-intensity factor (K_IIc) and critical unit work of failure (J_IIc) were determined. Based on the conducted studies, it was found that higher values of fracture mechanics parameters were noted as the grain sizes of the aggregate used increased. The increases in the analyzed fracture mechanics parameters were noticeably greater in the M2 series concrete compared to the results for the M1 series concrete, specifically by 27% for K_IIc and 35% for J_IIc. In addition to macroscopic tests, detailed microstructural analyses of the ITZ area between the coarse aggregate grains and the cement matrix were conducted. Based on the captured images, it was determined that, in the M1 series concrete, the contacts between the aggregate grains and the cement paste exhibit a loose structure with visible microcracks. In contrast, the M2 series concrete showed no visible damages within the ITZ area itself nor at their displacement at a distance of approximately a few μm away from this area. This microstructure of both materials resulted in the M1 series concrete being more prone to rapid and sudden fracture propagation, leading to its brittle behavior during the fracture process. In contrast, the large, well-developed limestone aggregate grains in the M2 series concrete facilitated improved stress transfer beyond the ITZ area into the cement matrix, preserving the continuity of the material structure and consequently leading to quasi-plastic behavior of the concrete during the fracture process. The novelty and utilitarianism of the research undertaken result from the fact that exploring the properties of concretes with limestone aggregates using mode II fracture is an important aspect of evaluating the durability and safety of concrete structures subjected mainly to shear forces. Full article

The poor quality of recycled coarse aggregate (RCA), particularly its high water absorption and low strength, has long restricted the development of recycled aggregate concrete (RAC). In this study, a novel combined spraying treatment method integrating cement slurry and a methyl sodium silicate (MSS) solution was proposed to improve the comprehensive performance of RCA. The effects of the treatment on RCA properties, including crushing value, water absorption, dynamic water absorption, apparent density, micromorphology, and contact angle, were systematically investigated. Furthermore, the treated RCA was incorporated into concrete to evaluate the mechanical strength, water absorption, and interfacial transition zone (ITZ) properties of the resulting RAC. The results indicated that cement slurry treatment alone significantly reduced the crushing value of the RCA by 30.1% but had little effect on water absorption. Conversely, MSS solution treatment reduced RCA water absorption by 29.6% without affecting its strength. The combined spraying method successfully enhanced both strength and water absorption performance. When applied in the RAC, cement slurry-treated RCA improved compressive and splitting tensile strengths, while MSS-treated RCA notably reduced water absorption. RAC prepared with combined-treated RCA achieved further strength improvement, and although its water absorption was not as low as that of MSS-only treated RAC, it still showed a substantial decrease compared to untreated RCA. Nanoindentation and microstructural analyses revealed that MSS enhanced the ITZ by forming a hydrophobic molecular film and reacting with new mortar, inhibiting water transport and improving RAC durability. An optimal MSS concentration of 10% was identified for achieving the best combined performance in strength and durability. Full article

With the continuous depletion of natural river sand resources and the escalating ecological degradation caused by excessive sand mining, manufactured sand has emerged as a sustainable and environmentally favorable alternative aggregate, playing an increasingly important role in the advancement of green construction materials. Nevertheless, the shrinkage behavior of manufactured sand concrete (MSC) exhibits significant deviations from that of conventional natural sand concrete due to differences in the material characteristics. Existing shrinkage prediction models—such as ACI 209, CEB-FIP 2010, B3, and GL 2000—fail to adequately incorporate the specific properties and substitution effects of manufactured sand, thereby limiting their predictive accuracy and applicability. To bridge this gap, the present study conducted a systematic evaluation of the four aforementioned classical shrinkage prediction models based on experimental data from MSC specimens incorporating varying replacement rates of manufactured sand. The findings revealed that models such as B3 and CEB-FIP 2010 neglected the influence of critical characteristics of manufactured sand—namely, particle morphology, gradation, and stone powder content—on the cementitious matrix and interfacial transition zone, which led to substantial prediction discrepancies. Accordingly, a nonlinear regression-based correction function was developed, introducing the manufactured sand content as a key influencing variable to recalibrate and enhance the ACI 209 and GL 2000 models for a more accurate application to MSC. The modified models exhibited markedly improved fitting performance and predictive robustness across the full range of manufactured sand replacement ratios (0–100%), thereby offering a more reliable framework for modeling the shrinkage development of MSC. Full article

The interfacial transition zone (ITZ) significantly influences the mechanical properties and durability of lightweight aggregate concrete (LWAC), yet existing research on the ITZ in LWAC remains fragmented due to varied characterization techniques, inconsistent definitions of ITZ thickness and porosity, and the absence of standardized performance metrics. This review focuses primarily on structural LWAC produced with artificial and natural lightweight aggregates, with intended applications in high-performance civil engineering structures. This review systematically analyzes the microstructure, composition, and physical properties of the ITZ, including porosity, microhardness, and hydration product distribution. Quantitative data from recent studies are highlighted—for instance, incorporating 3% nano-silica increased ITZ bond strength by 134.12% at 3 days and 108.54% at 28 days, while using 10% metakaolin enhanced 28-day compressive strength by 24.6% and reduced chloride diffusion by 81.9%. The review categorizes current ITZ enhancement strategies such as mineral admixtures, nanomaterials, surface coatings, and aggregate pretreatment methods, evaluating their mechanisms, effectiveness, and limitations. By identifying key trends and research gaps—particularly the lack of predictive models and standardized characterization methods—this review aims to synthesize key findings and identify knowledge gaps to support future material design in LWAC. Full article

While acetic acid has proven effective as a mild acidic treatment for removing adhered mortar from recycled concrete aggregate (RCA) surfaces, its potential for dissolving damage to the surface of the original natural coarse aggregate (NCA) within the RCA and its impact on the resultant concrete properties require careful consideration. This investigation systematically evaluates the effects of varying concentrations of dilute acetic acid solutions, commonly used in RCA treatment protocols, through a multi-methodological approach that includes comprehensive physical characterization, stylus and 3D optical profilometry, scanning electron microscopy (SEM), and nanoindentation analysis. The results show that even dilute acid solutions have an upper concentration limit, as excessive acid concentration, specifically 0.4 M, induces significant textural dislocations on NCA surfaces, creating millimeter-scale erosion pits that increase aggregate water absorption by 18.5%. These morphological changes significantly impair concrete workability and reduce compressive strength performance. Furthermore, microstructural analysis reveals a 45.24% expansion in interfacial transition zone (ITZ) thickness, accompanied by notable reductions in elastic modulus and microhardness characteristics. In practical RCA treatment applications, for RCA containing limestone-based NCA, it is recommended to use acetic acid concentrations between 0.1 and 0.3 M to avoid substantial physical and microstructural degradation of aggregates and concrete. Full article

In marine engineering applications, substituting conventional crushed stone coarse aggregates with coral aggregates offers dual advantages: reduced terrestrial quarrying operations and minimized construction material transportation costs. However, the inherent characteristics of coral aggregates—low bulk density, high porosity, and elevated water absorption capacity—adversely influence concrete workability and mechanical performance. To address these limitations, this investigation employed microbial-induced carbonate precipitation (MICP) for aggregate modification. The experimental design systematically evaluated the impacts of substrate concentration (1 mol/L) and mineralization period (14 days) on three critical parameters, mass gain percentage, water absorption reduction, and apparent density enhancement, across distinct particle size fractions (4.75–9.5 mm, 9.5–20 mm) and density classifications. Subsequent application trials assessed the performance of MICP-treated aggregates in marine concrete formulations. Results indicated that under a substrate concentration of 1 mol/L and mineralization period of 14 days, lightweight coral aggregates and coral aggregates within the 4.75–9.5 mm size fraction exhibited favorable modification effects. Specifically, their mass gain rates reached 11.75% and 11.22%, respectively, while their water absorption rates decreased by 32.22% and 34.75%, respectively. Apparent density increased from initial values of 1764 kg/m³ and 1930 kg/m³ to 2050 kg/m³ and 2207 kg/m³. Concrete mixtures incorporating modified aggregates exhibited enhanced workability and strength improvement at all curing ages. The 28-day compressive strengths reached 62.1 MPa (11.69% increment), 46.2 MPa (6.94% increment), and 60.1 MPa (14.91% increment) for the 4.75–9.5 mm, 9.5–20 mm, and continuous grading groups, respectively, compared to untreated counterparts. Full article

Polypropylene (EPP) concrete offers advantages such as low density and good thermal insulation properties, but its relatively low strength limits its engineering applications. Waste steel fibers (WSFs) obtained during the sorting and processing of machining residues can be incorporated into EPP concrete (EC) to enhance its strength and toughness. Using the volume fractions of EPP and WSF as variables, specimens of EPP concrete (EC) and waste steel fiber-reinforced EPP concrete (WSFREC) were prepared and subjected to cube compressive strength tests, splitting tensile strength tests, and four-point flexural strength tests. The results indicate that EPP particles significantly improve the toughness of concrete but inevitably lead to a considerable reduction in strength. The incorporation of WSF substantially enhanced the splitting tensile strength and flexural strength of EC, with increases of at least 37.7% and 34.5%, respectively, while the improvement in cube compressive strength was relatively lower at only 23.6%. Scanning electron microscopy (SEM) observations of the interfacial transition zone (ITZ) and WSF surface morphology in WSFREC revealed that the addition of EPP particles introduces more defects in the concrete matrix. However, the inclusion of WSF promotes the formation of abundant hydration products on the fiber surface, mitigating matrix defects, improving the bond between WSF and the concrete matrix, effectively inhibiting crack propagation, and enhancing both the strength and toughness of the concrete. Full article