Search Results (1,187)

Flexible textile membranes were prepared by impregnating woven cotton fabrics with silicone oil (SO)-based suspensions containing carbonyl iron (CI) microparticles and iron oxide microfibers ($\mu$Fe). The microfibers were obtained by a microwave-assisted microplasma process and then co-dispersed with CI in SO. In the final membranes, the CI content was kept constant at ${\mathrm{\Phi }}_{\mathrm{CI}}=10$ vol.%, whereas the microfiber fraction was 0, 10 and 20 vol.%. The resulting membranes were used as dielectric layers in planar capacitors and examined at 1 kHz under a static magnetic field of up to 150 mT and compressive pressure up to 10 kPa. In every composition, the capacitance rose with increasing magnetic flux density, but both the zero-field capacitance and the field-induced capacitance change became smaller as the microfiber content increased. A monotonic, nearly linear increase in capacitance was also observed under compression over the tested pressure range. Within a simplified parallel-plate and magnetic-stress analysis, the capacitance data were further used to estimate the apparent relative permittivity, together with capacitance-derived indicators of deformation and stiffness. These estimates suggest field-induced stiffening of the membranes and a higher apparent low-field stiffness at higher microfiber loading. The obtained hybrid CI/$\mu$Fe-based textile membranes can serve as composition-tunable dielectric layers whose electrical response is influenced by both magnetic field and compressive loading, making them relevant for flexible capacitor-based elements. Full article

Electromagnetic (EM) radiation emitted by various sources can cause malfunctions or damage to other electronic devices. Composite materials are widely used for EM field shielding. This work presents and analyzes the dielectric properties of 3D-printed composites containing carbon nanotubes (CNTs) and barium titanate (BaTiO₃) over a broad frequency range. The analyzed 3D structures included a fully filled plate (PL), a basic honeycomb (BH), a honeycomb with re-entrant auxetic features (HREA), and a hierarchical honeycomb (HH). It was found that the composite material containing 1.8 wt.% CNTs and 20 wt.% BaTiO₃ exhibits the highest absorption coefficient in the frequency range from 25 GHz to 53 GHz for all investigated 3D structures. A high concentration of BaTiO₃ increases dielectric loss and interfacial polarization, while providing a CNT network. The synergy of these mechanisms results in the highest absorption of EM waves in the 25–53 GHz range. Moreover, all samples containing BaTiO₃ inclusions exhibited a distinctive electrical conductivity behavior, attributed to the high complex dielectric permittivity of barium titanate, which enhances interfacial polarization. The highest conductivity and dielectric permittivity values were measured in samples containing 1.8 wt.% CNTs and 10 wt.% BaTiO₃, while a further increase in BaTiO₃ concentration caused a decline in dielectric performance. This effect is due to the dispersion and agglomeration of filler particles in composites with higher BaTiO₃ concentrations. Full article

The dielectric properties of cement-based composites (CBC) are highly sensitive to environmental humidity, which seriously restricts the quantitative interpretation accuracy of ground-penetrating radar (GPR) in the non-destructive testing of cement concrete pavement. In view of the lack of targeted prediction models due to the unclear mechanism of humidity influence in existing research, the core innovations of this study are: (1) the synergistic mechanism of water vapor dipole polarization and adsorbed water multi-layer polarization is clarified, revealing the intrinsic reason for the accelerated growth of permittivity in the high humidity range; (2) the constructed four-component dielectric model of “cement mortar–aggregate–water vapor–adsorbed water” achieves high-precision prediction within the range of 50~100% RH (R² > 0.94, relative error < 5%), and shows good predictive ability within the test scope of this study; (3) a GPR humidity correction protocol based on the model is proposed, which can effectively improve the accuracy of nondestructive testing of cement concrete structures. In this study, CBC samples with water–cement ratios of 0.4~0.6 were prepared using P.O 32.5/P.O 42.5 cement and limestone aggregate. Under the conditions of 20 ± 0.5 °C, relative humidity (RH) of 50~100%, and 2 GHz (common GPR frequency), the permittivity was measured using an Agilent P5001A network analyzer to verify the model. The results show that the permittivity increases monotonically with humidity, and the growth rate in the high humidity range (70~100%) is 2.2 times that of the low humidity range (50~70%); The higher the water–cement ratio, the shorter the age, and the lower the cement strength grade, the stronger the humidity sensitivity of CBC dielectric properties. This model provides a reliable humidity correction tool for GPR detection, and significantly improves the accuracy of nondestructive evaluation of cement concrete structures. Full article

Cordierite-based ceramics (Mg₂Al₄Si₅O₁₈) were successfully synthesized and comprehensively characterized to evaluate their structural and dielectric behavior for high-temperature electronic applications. Morphological, microstructural and vibrational analyses confirm the high phase purity and structural integrity of the synthesized material. Dielectric measurements reveal high real permittivity (ε′) values at low frequencies and elevated temperatures, mainly attributed to interfacial polarization arising from Schottky-type barriers at grain–grain and surface–volume interfaces, underscoring the crucial influence of heterogeneous interfaces on the dielectric response. The electrical conductivity follows a thermally activated hopping mechanism involving both intra-grain and grain-boundary charge transport. Analysis of the electric modulus formalism provides further insight into relaxation dynamics: the real (M′) and imaginary (M″) components highlight pronounced space-charge effects, with M″ exhibiting a distinct relaxation peak (M″) associated with grain contributions. The systematic shift of this peak toward higher frequencies with increasing temperature indicates enhanced charge-carrier mobility and a strongly thermally activated relaxation process. The frequency-dependent conductivity displays two regimes: a low-frequency plateau corresponding to dc conductivity and a high-frequency dispersive region following a power-law behavior characteristic of hopping conduction, with power-law exponents (α₁ and α₂) markedly lower than unity, confirming the non-Debye character of the relaxation processes. The hopping frequency (ω) increases with temperature, further supporting the thermally activated nature of charge transport. Activation energies extracted from Arrhenius plots of dc conductivity are 0.88 eV for grain boundaries and 0.83 eV for grains, demonstrating that both microstructural regions significantly contribute to the overall conduction process. Full article

Millimeter-wave and sub-millimeter-wave techniques are widely used in non-destructive testing of multilayered materials due to their ability to penetrate non-conductive media and resolve dielectric stratifications. However, conventional thickness estimation methods suffer from an inherent resolution limit dictated by the available frequency bandwidth. In this paper, a MUSIC-based approach is proposed to achieve super-resolution localization of echoes in the reflective response of the structure under test. The method exploits the sparsity of the reflective response, similarly to compressive sensing approaches, while providing improved reconstruction accuracy. Moreover, the proposed strategy enables the retrieval of dielectric permittivities and layer thicknesses without resorting to complex nonlinear fitting procedures. Finally, the method operates on magnitude-only data, with phase information recovered through an interferometric holographic technique, making the proposed framework well-suited for cost-effective industrial applications. Full article

Two spectrin-sensitive relaxations have been reported in the RBC plasma membrane: β_s (1.4 MHz, related to the interface β-relaxation) and γ1_s (9 MHz, rotation alignment of spectrin-bound dipoles by penetrating electric field). Here, a third (α_s) relaxation type is reported within the frequency region of surface (α) relaxation. With low-ion-strength outside media, the adsorption of blood plasma immunoglobulins on RBCs was found to inhibit β_s and γ1_s relaxations, while α_s relaxation was enforced with strong inflammation. The three relaxations are represented by three consecutive segments on the Cole′s plots: Δε_rd″.ω against Δε_r′ and Δε_rd″/ω against Δε_r′. Here, ω is the frequency of the field and Δε_r* = Δε_r′ + j.Δε_rd″ is the change in the relative complex dielectric permittivity of RBC suspension at the denaturation temperature of spectrin. The β_s segment in Δε_rd″.ω against the Δε_r′ plot could be regarded as a vector (complex number) whose projection on the vertical axis (the irreversible loss in energy) could express the ability of the plasma membrane to deform (under the impact of shear stress). Full article

Alumina is a commonly used ceramic material known for high permittivity, low dielectric loss, good thermal conductivity, and low cost. In the development of electronic devices, the size effect of powdery materials is crucial, particularly in applications involving composite materials. This study introduces the field-enhancement method (FEM) to measure the resonant frequency ($f_0$) and the quality factor (Q) of alumina powders packed in a Teflon container and placed on top of the central rod in the proposed cavity. The measured resonant condition ($f_0$ and Q) is mapped to a contour plot and simulated using a high-frequency structure simulator (HFSS). The contour mapping technique allows the researchers to obtain the effective complex permittivity of alumina–air composites. The complex permittivity of the alumina powder is retrieved using a hybrid model and the effective medium theories (EMTs), respectively. The Landau–Lifshitz–Looyenga (LLL) model is compared with the results using the hybrid model for its applicability. The dielectric constant and the loss tangent of the alumina powder are found to increase as the powder size reduces. A power relation is found to fit the obtained permittivity, covering sizes ranging from nanometers to micrometers, and a surface-charge scaling argument is proposed to explain the observed trend. This finding opens a new avenue for manipulation of permittivity in composite materials and has potential applications in stealth/absorber technology and as a self-limiter for grain growth during sintering. Full article

We consider the Casimir force in configurations with magnetic metal plates and analyze the reasons why the predictions of the Lifshitz theory using the dielectric permittivity of the Drude model are inconsistent with the measurement data. For this purpose, the contributions of the electromagnetic waves with the transverse magnetic and transverse electric polarizations to the Casimir force are computed using the Lifshitz theory expressed in terms of the pure imaginary Matsubara frequencies. Furthermore, the fractions of the evanescent and propagating waves in these contributions are found using the equivalent formulation of the Lifshitz theory along the real frequency axis. All computations are performed for Au–Ni and Ni–Ni plates using the Drude model and the experimentally consistent plasma model over the separation region from 0.5 to 6 $\mathsf{\mu }$m, where the total force value is determined by the conduction electrons. It is shown that the transverse magnetic contribution to the Casimir force does not depend on the model of the dielectric permittivity used, allowing the total difference between the predictions of the Lifshitz theory using the Drude model and the measurement data to be determined by the transverse electric contribution. In doing so, as opposed to the case of nonmagnetic metals, both fractions of the evanescent and propagating waves in this contribution depend on the model of the dielectric permittivity used in computations, whereas the magnetic properties of the plate metal influence the Casimir force solely through the fraction of the propagating waves in the transverse electric contribution. The issue of a more adequate theoretical description of the electromagnetic response of magnetic metals is discussed. Full article

This study investigates the combined effects of thermal and moisture aging on PVC-insulated low voltage (LV) photovoltaic (PV) cables using an accelerated-aging design to represent realistic PV operating conditions commonly encountered in hot and humid climates. Thermal aging was carried out at 90 °C for five aging cycles, with each thermal cycle followed by controlled moisture injection to simulate moisture stress. The degradation behavior was evaluated using broadband dielectric spectroscopy, FTIR analysis, and Shore D hardness measurements. Changes in dielectric dissipation factor (tanδ) and real permittivity (${\epsilon }^{\prime }$) were analyzed over a wide frequency range, with 100 kHz selected for its high sensitivity to aging-induced oxidation-related dipolar and interfacial polarization mechanisms. Degradation indices (DI) and degradation rates (DR) were derived from tanδ and correlated with mechanical and chemical changes. The results showed a 5% and 7% increase in tanδ at 100 kHz and in hardness, respectively, with decreases of 68% and 75% in the carbonyl and hydroxyl indices, respectively. Three distinct aging stages were identified: early thermo-oxidation with limited functional impact; mid-stage dehydrochlorination and moisture interaction; and late-stage chain scission, plasticizer loss, and insulation stiffening. The findings demonstrate the importance of climate-specific aging assessment and confirm the effectiveness of integrated electrical, mechanical, and chemical diagnostics for PV cable condition monitoring. Full article

Developing advanced functional materials requires the synergistic integration of nanoscale reinforcements with tailored properties. In this work, composite films of cellulose nanocrystals (CNCs), cellulose nanofibrils (CNFs), and reduced graphene oxide (rGO) were synthesized using a combination of solution casting, high shear homogenization, vacuum filtration, and environmentally friendly chemical reduction. The resulting CNC/CNF/rGO films exhibited a robust hierarchical structure with strong interfacial interactions, enabling exceptional mechanical properties, specifically a tensile strength of 215 MPa and a Young’s modulus of 18 GPa, alongside a continuous conductive network confirmed by frequency-independent electrical conductivity up to 30 kHz. Comprehensive dielectric characterization revealed frequency-dependent permittivity and low dielectric loss, aligning with Maxwell–Wagner theoretical predictions for heterogeneous composites. The composites also demonstrated thermal stability, with electrical conductivity increasing monotonically from 0 °C to 200 °C. These findings highlighted the CNC/CNF/rGO films’ suitability for applications in flexible electronics, electromagnetic shielding, packaging, and high-performance structural materials. Future optimization and modeling approaches, including fractional calculus, are recommended to further enhance multifunctionality and exploit the unique synergistic interactions intrinsic to nanocellulose–graphene oxide platforms. Full article

Magnetoelectric (ME) materials that exhibit simultaneous coupling between electric polarization and magnetization have attracted significant attention due to their potential technological applications in the emerging generation of multifunctional devices. In this research, Ba_0.85Ca_0.15Ti_0.92Zr_0.08O₃-CoFe₂O₄:x (x = 0.1, 0.2, 0.3% mol) composites were synthesized using solid-state and sol–gel combustion chemical methods to elucidate their ME coupling at ultra-low concentrations of the magnetic phase. Rietveld refinement and Raman spectroscopy results confirm a shift in the morphotropic phase boundary (MPB), evidenced by an increase in the tetragonal phase relative to the orthorhombic structure. High stability of the P4mm and Amm2 symmetries is reached at 1300 °C without diffusion of Fe and Co into the octahedral site. At this temperature, the CoFe₂O₄ spinel structure remains stable without secondary phases. The orthorhombic phase fraction decreases from 55% to 37% as the magnetic phase fraction increases, driven by stress and constraint rather than ionic interactions alone. The Curie temperature decreases from 99 to 90 °C, attributed to the grain-size reduction effect rather than structural disorder. The dielectric permittivity (ε_r) reaches an absolute value of 5070 and progressively decreases with increasing magnetic saturation. An increase in compressive residual stress is observed, which ensures the mechanical stability of the electroceramics. Magnetoelectric (ME) coupling, evaluated through measurements of electric polarization as a function of the magnetic field, shows an increase from 3.8 to 4.9 μC/cm² under a magnetic field of 50 Oe. The composites with x = 0.2 and 0.3 mol% exhibit potential for applications in fast-switching magnetoelectric devices and magnetic field sensors. Full article

We present frequency- and magnetic field-dependent measurements of the complex dielectric permittivity ε*(f, H) of a kerosene-based ferrofluid, containing Mn₀.₆Fe₀.₄Fe₂O₄ nanoparticles, over 0.8–5 GHz and static fields up to ~91 kA/m. The imaginary part, ${\epsilon }_F^{″}$, shows a peak at a characteristic frequency that shifts towards higher frequencies with increasing H, revealing a magnetic field-dependent relaxation process, interpreted using the Maxwell–Wagner–Sillars model. The dielectrophoretic extraction of nanoparticles was evaluated via the squared electric field gradient, and a threshold, ${\left(\nabla E^2\right)}_{\min }$, dependent on particle size was determined. Below that threshold, Brownian forces dominate, so the ferrofluid acts as a homogeneous dielectric. For this case, the Clausius–Mossotti factor (CM) was calculated for ferrofluid droplets in air and in water as a function of frequency and magnetic field. In air, CM exhibits modest but systematic magnetic field dependence, indicating a magnetically modulated dielectric response at GHz frequencies. In contrast, when water is used as the reference medium, CM remains negative and essentially independent of H across the entire frequency range, suggesting that the high permittivity of water masks the magneto-dielectric effects in the ferrofluid. These findings provide insight into the interplay between the magnetic field and the permittivity of ferrofluids, with implications for high-frequency applications. Moreover, using a λ/4 antenna connected to a network analyzer, the existence of the dielectrophoretic force acting on a ferrofluid-impregnated textile thread at microwave frequencies was experimentally demonstrated. Full article

This paper presents the design, modeling, and numerical validation of a compact artificial magnetic conductor (AMC)–backed flexible UHF RFID tag antenna intended for on-body biomedical and wearable sensing applications. Human tissue proximity typically causes severe detuning, radiation efficiency degradation, and increased specific absorption rate (SAR) for conventional RFID tag antennas. To address these limitations, a miniaturized AMC metasurface based on a modified Jerusalem-cross geometry with meandered and interdigitated features is developed on a high-permittivity biocompatible substrate using CST Studio Software (2025). Full-wave simulations demonstrate that the proposed design, with an ultra-compact footprint of 0.0246 λ² (32.12 mm × 64.24 mm), functions as an effective shielding element, significantly enhancing the tag antenna gain and reading range by an order of magnitude compared to conventional on-body tags, while simultaneously reducing backward radiation and SAR. The antenna demonstrates robust platform tolerance and excellent isolation from the human body, ensuring high reliability. Fabricated on a thin, flexible, biocompatible, silicon-doped dielectric substrate, this device also functions as an epidermal antenna for on-skin health parameter sampling. This research paves the way for advanced, non-invasive wearable medical devices with superior performance. Full article

This research aims to investigate the modifications of the structural, dielectric, and sensing properties of CaFeO_3−δ ceramics produced by solid-state reaction induced by varying sintering temperatures in the range of 1000–1200 °C. A single crystallographic orthorhombic (Pcmn) structure was revealed by X-ray diffraction with Rietveld analysis, both for the powders and sintered ceramics, irrespective of the sintering temperature. The increase in the sintering temperature induces better densification and a larger grain size. Dielectric measurements reveal a pronounced enhancement of the relative permittivity, reaching 2 × 10⁵ at 1 kHz and 330 °C for the sample sintered at 1200 °C/4 h. This composition also displays the highest electrical conductivity, 0.4 S/m at 1 MHz. Cole–Cole analysis indicates a clear deviation from ideal Debye behavior, while the relaxational features of the dielectric permittivity suggest a strong correlation between the dielectric response and Fe-related conduction mechanisms. Gas sensing tests show that the ferrite ceramics exhibit consistent ethanol response trends. The ceramic sintered at 1200 °C/4 h achieved the highest sensitivity, of 56.28%, which can be attributed to its higher density, larger ceramic grains, and reduced low-frequency conductivity. The CaFeO_3−δ ceramic sintered at 1200 °C/4 h shows a combination of high permittivity, enhanced conductivity, and strong ethanol sensitivity, making it a promising material for dielectric components, capacitive devices, and gas sensing applications. Full article

An inhomogeneous thin internal stratum sometimes exists between two dissimilar materials, which is usually caused by non-uniform thermal distribution, interaction of different media, diffusion impurity or material degeneration and damage. In this paper, it is considered as a functional graded (FG) piezoelectric material in surface acoustic wave devices, and we investigate its effect on Love wave propagation within the framework of the linear piezoelectric theory. Correspondingly, the power series technique is presented and applied to solve the dynamic governing equations, i.e., two-dimensional partial differential equations with variable coefficients, with the convergence and correctness being proved. In this method, the material coefficients can change in random functions along the thickness direction, which reveals the generality of this method to some extent. As the numerical case, the elastic coefficient, piezoelectric coefficient, dielectric permittivity, and mass density change in the linear form but with different graded parameters, and the influence of material inhomogeneity on the Love wave propagation is systematically investigated, including the phase velocity, electromechanical coupling factor, and displacement distribution. In addition, the FG piezoelectric material caused by piezoelectric damage and material bonding is discussed. Numerical results demonstrated that both piezoelectric damaged and material bonding can make the higher modes appear earlier for the electrically open case, decrease the initial phase velocity, and limit the existing region of the fundamental Love mode for the electrically shorted case. The qualitative conclusions and quantitative results can provide a theoretical guide for the structural design of surface wave devices and sensors. Full article