Search Results (3,646)

Binary metallic nickel–copper nanocatalysts were anchored onto a polyvinylidene fluoride-co-hexafluoropropylene membrane [NiCu/PVdF–HFP] using the electrospinning technique, followed by the chemical reduction of the relevant precursor salts by introducing sodium borohydride to the synthesis mixture. A series of varied Ni:Cu weight % proportions was developed in order to optimize the electroactivity of this binary nanocomposite towards the investigated oxidation process. A number of physicochemical tools were used to ascertain the morphology and chemical structure of the formed metallic species on polymeric films. Cyclic voltammetric studies revealed a satisfactory performance of altered NiCu/PVdF–HFP membranes in alkaline solution. Ethylene glycol molecules were successfully electro-oxidized at their surfaces, showing the highest current intensity [564.88 μA cm⁻²] at the one with Ni:Cu weight ratios of 5:5. The dependence of these metallic membranes’ behavior on the added alcohol concentration to the reaction electrolyte and the adjusted scan rate during the electrochemical measurement was carefully investigated. One hundred repeated scans did not significantly deteriorate the NiCu/PVdF–HFP nanostructures’ durability. Decay percentages of 76.90–87.95% were monitored at their surfaces, supporting the stabilized performance for prolonged periods. A much-decreased R_ct value was estimated at Ni₅Cu₅/PVdF–HFP [392.6 Ohm cm²] as a consequence of the feasibility of the electron transfer step for the electro-catalyzing oxidation process of alcohol molecules. These enhanced study results will hopefully motivate the interested workers to explore the behavior of many binary and ternary combinations of metallic nanomaterials after their deposition onto convenient polymeric films for vital electrochemical reactions. Full article

The synthesis of new corrosion inhibitors (CIs) has been significantly encouraged in recent years because of the important economic losses that the corrosion of steel alloys exposed to corrosive aqueous media cause. In the oil industry, a common and unavoidable practice is the use of CIs whose chemical configuration has to be conceived in such a way that these compounds can withstand specific operation conditions at low concentrations (parts per million). Due to the fact that current information on CIs is very vast, the present review aimed to narrow it down by analyzing the contributions to the field of corrosion control published in the last five years featuring CIs with inhibition efficiency (IE) ≥ 90% at concentrations below 100 ppm in HCl, H₂SO₄ and H₂S media and mainly evaluated by weight loss and electrochemical techniques. Full article

Understanding how redox-active ligands coordinate to metal centers of different oxidation states is essential for applications ranging from metal remediation and recycling to drug discovery. In this study, coordination complexes of nickel(II), copper(II), and zinc(II) chloride salts were synthesized by mixing the salts with either arylazoformamide (AAF) or arylazothioformamide (ATF) ligands in toluene or methanol. The AAF and ATF ligands coordinate through their 1,3-heterodienes, N=N–C=O and N=N–C=S, respectively, and, due to their known strong binding, the piperidine and pyrrolidine formamide units were selected, as was the electron-donating methoxy group on the aryl ring. A total of 12 complexes were obtained, representing potential chelation events from ligand-driven oxidation of zerovalent metals and/or coordination of oxidized metal salts. The X-ray crystallography revealed a range of coordination patterns. Notably, the Cu(II)Cl₂ complexes, in the presence of ATF, produce [ATF-CuCl]₂ dimers, supporting a potential reduction event at the copper, while other metals with ATF and all metals with AAF remain in the 2+ oxidation state. Hirshfeld analysis was performed on all complexes, and it was found that most interactions across the complexes were dominated by H…H, followed by Cl…H/H…Cl, with metals showing very little to no interaction with other atoms. Spectroscopic techniques such as UV–VIS absorption, NMR (when diamagnetic), and FTIR, in addition to electrochemical studies support the metal–ligand coordination. Full article

Electrochemical CO₂ reduction reaction (CO₂RR) is a key technology for achieving carbon neutrality and efficient utilization of renewable energy, capable of converting CO₂ into high-value-added carbon-based fuels and chemicals. Copper (Cu)-based catalysts have attracted significant attention due to their unique performance in generating multi-carbon (C₂₊) products such as ethylene and ethanol; however, there are still many controversies regarding their complex reaction mechanisms, active sites, and the dynamic evolution of intermediates. In situ Raman spectroscopy, with its high surface sensitivity, applicability in aqueous environments, and precise detection of molecular vibration modes, has become a powerful tool for studying the structural evolution of Cu catalysts and key reaction intermediates during CO₂RR. This article reviews the principles of electrochemical in situ Raman spectroscopy and its latest developments in the study of CO₂RR on Cu-based catalysts, focusing on its applications in monitoring the dynamic structural changes of the catalyst surface (such as Cu⁺, Cu⁰, and Cu²⁺ oxide species) and identifying key reaction intermediates (such as *CO, *OCCO(*O=C-C=O), *COOH, etc.). Numerous studies have shown that Cu-based oxide precursors undergo rapid reduction and surface reconstruction under CO₂RR conditions, resulting in metallic Cu nanoclusters with unique crystal facets and particle size distributions. These oxide-derived active sites are considered crucial for achieving high selectivity toward C₂₊ products. Time-resolved Raman spectroscopy and surface-enhanced Raman scattering (SERS) techniques have further revealed the dynamic characteristics of local pH changes at the electrode/electrolyte interface and the adsorption behavior of intermediates, providing molecular-level insights into the mechanisms of selectivity control in CO₂RR. However, technical challenges such as weak signal intensity, laser-induced damage, and background fluorescence interference, and opportunities such as coupling high-precision confocal Raman technology with in situ X-ray absorption spectroscopy or synchrotron radiation Fourier transform infrared spectroscopy in researching the mechanisms of CO₂RR are also put forward. Full article

Seawater has been widely used in copper–molybdenum flotation plants due to the shortage of fresh water and the high cost of seawater desalination, especially in arid regions. There have been many studies concerning the molybdenite flotation in seawater. Due to the complication of seawater flotation, it is difficult to identify the key factors affecting molybdenite recoveries. It is known that the unique structure of molybdenite plays an important role in molybdenite flotation. The anisotropic property of molybdenite leads to the different surface properties of basal and edge plane surfaces. Electrochemical properties of sulfides have a significant effect on the surface properties which affect the flotation performance. Therefore, it is important to understand the surface electrochemical properties such as surface chemistry, redox processes, and reaction kinetics of molybdenite’s two different surfaces in seawater, and to determine what affects the molybdenite flotation behaviors in seawater. In this study, the surface properties of molybdenite basal and edge plane surfaces in both fresh water and seawater were investigated through various electrochemical techniques. Open circuit potential (OCP) measurement indicated that edge plane surfaces were easier to be oxidized than basal plane surfaces. Cyclic voltammetry (CV) studies showed that the basal plane surfaces were stable with a low electrochemical reactivity, while the edge plane surfaces had relatively high electrochemical reactivity. In addition, the redox property of the molybdenite surface was enhanced in seawater, which is a key to the improvement of fine molybdenite flotation in seawater. Electrochemical impedance spectroscopy (EIS) measurements further confirmed the stability of basal plane surfaces and indicated a greater charge transfer ability of edge plane surfaces in seawater. Different molybdenite particle sizes with different basal and edge ratios were applied in the flotation in both fresh water and seawater; the results illustrated that molybdenite flotation was enhanced in seawater especially to fine particles. The flotation and electrochemical studies reveal that the electrochemical reactivity of edge plane surface plays an important role in molybdenite seawater flotation. Full article

In response to the actual needs of pure copper bonding wires, it is crucial to develop a chromium-free passivator that is environmentally friendly and has excellent corrosion resistance. In this study, three different composite organic formulations of chromium-free passivation solutions are selected: 2-Amino-5-mercapto-1,3,4 thiadiazole (AMT) + 1-phenyl-5-mercapto tetrazolium (PMTA), 2-mercaptobenzimidazole (MBI) + PMTA, and Hexadecanethiol (CHS) + sodium dodecyl sulfate (SDS). The performance analysis and corrosion mechanism were compared with traditional hexavalent chromium passivation through characterization techniques such as XRD, SEM, and XPS. The results show that the best corrosion resistance formula is the combination of the PMTA and MBI passivation agent, and all its performances are superior to those of hexavalent chromium. The samples treated with this passivation agent corrode within 18 s in the nitric acid drop test, which is better than the 16 s for Cr⁶⁺ passivation. The samples do not change color after being immersed in salt water for 48 h. Electrochemical tests and high-temperature oxidation test also indicate better corrosion resistance than Cr⁶⁺ passivation. Through the analysis of functional groups and bonding, the excellent passivation effect is demonstrated to be achieved by the synergistic action of the chemical adsorption film formation of PMTA and the anchoring effect of MBI. Eventually, a dense Cu-PMTA-BMI film is formed on the surface, which effectively blocks the erosion of the corrosive medium and significantly improves the corrosion resistance. Full article

Monitoring contamination in soil and food systems remains vital for ensuring environmental and public health, particularly in agriculture-intensive regions. Existing laboratory-based techniques are often time-consuming, equipment-dependent, and impractical for rapid on-site screening. In this study, we present a portable, non-faradaic electrochemical impedance-based sensing platform capable of simultaneously detecting Salmonella Typhimurium (S. Typhi) and Aflatoxin B1 in spiked soil run-off samples. The system employs ZnO-coated electrodes functionalized with crosslinker for covalent antibody immobilization, facilitating selective, label-free detection using just 5 µL of sample. The platform achieves a detection limit of 1 CFU/mL for S. Typhi over a linear range of 10–10⁵ CFU/mL and 0.001 ng/mL for Aflatoxin B1 across a dynamic range of 0.01–40.96 ng/mL. Impedance measurements captured with a handheld potentiostat were strongly correlated with benchtop results (R² > 0.95), validating its reliability in field settings. The duplex sensor demonstrates high precision with recovery rates above 80% and coefficient of variation below 15% in spiked samples. Furthermore, machine learning classification of safe versus contaminated samples yielded an ROC-AUC > 0.8, enhancing its decision-making capability. This duplex sensing platform offers a robust, user-friendly solution for real-time environmental and food safety surveillance. Full article

This paper investigates the combustion characteristics of promising decarbonized fuel mixtures—methane/hydrogen (CH₄/H₂) and ammonia/hydrogen (NH₃/H₂)—with a focus on how they interact with external electric fields. The key findings are that these flames possess significant electrochemical properties, allowing for non-intrusive control over their stabilization, shape, and structure using relatively weak electric fields. The research combines experimental techniques like volt-ampere characteristic (VAC) measurement and advanced Hilbert visualization to analyze flame deformation, temperature distribution, and species concentration. Two orientations of the electric field were considered: transverse and longitudinal. For the transverse field, an assessment of the degree of flame deformation was made, indicating the preservation of the laminar combustion regime. In the longitudinal electric field, a change in the combustion stabilization mode was observed, which was detected through visualization and current-voltage characteristics (CVC). Full article

This study investigates the corrosion inhibition efficiency of [2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzo[d]imidazole] and its Zn and Cu complexes for mild steel in 1.0 M HCl. The ligand was selected for its non-toxic profile and high electron density, favoring strong adsorption onto the metal surface. Electrochemical methods, including EIS, PDP, LPR, and CASP, were employed to evaluate the inhibitors’ performance. The results showed a significant decrease in corrosion current density and increased polarization resistance, with the Zn complex achieving the highest inhibition efficiency (93.8%). EIS fitting confirmed the formation of a protective film with high charge transfer and film resistance. Surface analyses by SEM and EDS revealed smoother steel morphology and inhibitor adsorption. XPS confirmed the presence of Fe³⁺, Zn²⁺and Cu²⁺ oxides, as well as all active inhibitor elements on the surface, supporting a mixed inhibition mechanism. The enhanced performance of the metal complexes is attributed to synergistic effects between the metal ions and the heterocyclic ligand, offering a promising strategy for the design of effective and environmentally friendly corrosion inhibitors. Full article

This study aims to evaluate the corrosion behavior of and morphological changes in S235JR steel exposed to 0.5 M hydrochloric acid solution over a period of 24 weeks. Corrosion resistance was assessed through weight loss measurements and electrochemical techniques (such as open circuit potential (OCP), polarization resistance (R_p), and corrosion rate (V_corr)), while surface morphology, elemental analysis, roughness, and Vickers hardness were also analyzed. All evaluations were performed at the same immersion intervals: 2, 4, 8, 12, and 24 weeks. The corrosion rate started at 0.9 mm/year after the first hour of immersion, then decreased due to the formation of corrosion products on the steel surface, and fluctuated during prolonged exposure, reaching a maximum of 8.5 mm/year after 24 weeks. Weight loss increased gradually during the first 8 weeks, followed by a more pronounced rise. Polarization resistance and corrosion rate exhibited dynamic variations. SEM analysis revealed severe surface degradation, including cracks and deep pits. Surface roughness increased significantly from an initial value of 0.91 μm to 9.03 μm at 24 weeks. Vickers hardness dropped from 148.7 HV0.5 to 87.3 HV0.5, due to non-uniform corrosion product formation. These findings highlight the progressive deterioration of S235JR steel in acidic environments and provide valuable insight into its long-term corrosion resistance. Full article

The corrosion resistance and microstructural characteristics of 17-4 PH stainless steel fabricated through Metal Binder Jetting (MBJ) were investigated through Cyclic Potentiodynamic Polarization (CPP), Open Circuit Potential (OCP) monitoring, SEM-EDX, optical microscopy, XRD, and chemical etching. Electrochemical tests revealed that as-sintered samples exhibited isotropic corrosion performance across different build-up orientations and directions. The CPP tests indicated the formation of a passive film with limited stability, while the monitoring of the OCP showed initial instability, followed by stabilization over time. Microstructural analysis indicated the presence of microporosities and a structure consisting of martensitic and ferritic grains in the as-sintered 17-4 PH, alongside copper and niobium segregations at grain boundaries, which may deeply influence localized corrosion susceptibility. These findings suggest that the as-sintered 17-4 PH fabricated through MBJ exhibits comparable corrosion behavior to 17-4 PH additive-manufactured through other techniques in which the sintering process is involved. The study highlights the influence of microstructure on electrochemical performance and underscores the need for post processing treatments to enhance corrosion resistance. Full article

Rivers, vital for life and civilizations, face severe threats from human activities such as hydropower development, with heavy metal pollution emerging as a critical concern due to altered biogeochemical cycles. Understanding how river damming affects heavy metal transport processes and developing targeted remediation strategies are essential for safeguarding the health of river-reservoir ecosystems and enabling the sustainable utilization of hydropower resources. Therefore, this review first summarizes the global hydropower development, details how damming disrupts hydrology, environments, and ecosystems, and analyzes heavy metal distribution and transport in reservoir water, suspended sediments, and riverbed sediments. It reveals that river damming promotes heavy metal adsorption onto suspended particles, deposition in riverbed sediments, and re-release during reservoir regulation, and anthropogenic activities are a primary driver of significant pollution in key reservoirs worldwide. Additionally, we further evaluate in situ (e.g., stabilizing agents, sediment capping, and phytoremediation) and ex situ (e.g., dredging, chemical washing, electrochemical separation, and ultrasonic extraction) remediation techniques, highlighting the challenges of phytoremediation in deep, stratified reservoir environments. Moreover, solidification/stabilization emerges as a promising in situ strategy, emphasizing the need for specific approaches to balance pollution control with hydropower functionality in dammed river systems. Full article

Portable and wearable sensors have gained attention in recent years to perform measurements in many different applications. Sensors based on Electrical Impedance Spectroscopy (EIS) are particularly promising, because they can make accurate measurements with minimum perturbation to the sample under test. Electrochemical biosensors are devices that use electrochemical techniques to measure a target analyte. In the case of electrochemical biosensors based on EIS, the measured impedance spectrum is fitted to that of an equivalent electrical circuit, whose component values are then used to estimate the concentration of the target analyte. Fitting EIS data is usually carried out by sophisticated algorithms running on a PC. In this paper, we have evaluated the feasibility to perform EIS data fitting using simple Artificial Neural Networks (ANNs) that can be run on resource constrained microcontrollers, which are typically used for portable and wearable sensors. We considered a typical case of an impedance spectrum in the range 0.1–10 kHz, modeled by using the simplified Randles equivalent circuit. Our analyses have shown that simple ANNs can be a low power alternative to perform EIS data fitting on low-cost microcontrollers with a memory occupation in the order of kilo bytes and a measurement accuracy between 1% and 3%. Full article

Metallic magnesium is a strategic material with applications in mobility, energy and medicine, due to its low density, biocompatibility and use as an anode in rechargeable batteries. However, industrial production methods—such as the thermal reduction of dolomite or the electrolysis of anhydrous MgCl₂—face environmental and operational challenges, including high temperatures, emissions, and dehydration of precursors like bischofite. In response, ionic liquids (ILs) have emerged as alternative electrolytes, offering low volatility, thermal stability and wide electrochemical windows that enable electrodeposition in water-free media. This study presents a systematic review of 32 peer-reviewed articles, applying the PRISMA 2020 methodology. The analysis is structured across three dimensions: (1) types of ILs employed, (2) operational parameters and (3) magnesium source materials. In addition to electrolyte composition, key factors such as temperature, viscosity control, precursor purity and cell architecture were identified as critical for achieving efficient and reproducible magnesium deposition. Furthermore, the use of elevated temperatures and co-solvent strategies has been shown to effectively mitigate viscosity-related transport limitations, enabling more uniform ion mobility and enhancing interfacial behavior. The use of alloy co-deposition strategies and multicomponent electrolyte systems also expands the technological potential of IL-based processes, especially for corrosion-resistant coatings or composite electrode materials. This review contributes by critically synthesizing current techniques, identifying knowledge gaps and proposing strategies for scalable, sustainable magnesium production. The findings position IL-based electrodeposition as a potential alternative for environmentally responsible metal recovery. Full article

The corrosion behavior of open-cell AlSn6Cu-based composites, one reinforced with SiC particles and the other with Al₂O₃ particles, was investigated. The composites were fabricated via liquid-state processing, employing both squeeze casting and the replication method, and they produced in two distinct pore size ranges (800–1000 µm and 1000–1200 µm). Corrosion performance was systematically evaluated through gravimetric (weight loss) measurements and electrochemical techniques, including open-circuit potential monitoring and potentiodynamic polarization tests. Comprehensive microstructural and phase analyses were conducted using X-ray diffraction, energy-dispersive X-ray spectroscopy, and scanning electron microscopy. The results revealed that both reinforcement type and pore architecture have a significant impact on corrosion resistance. Al₂O₃-reinforced composites consistently outperformed their SiC-containing counterparts, and pore enlargement generally improved performance for the unreinforced alloy and the Al₂O₃ composite but not for the SiC composite. Overall, the optimal corrosion resistance is achieved by pairing a coarser-pore architecture (1000–1200 µm) with Al₂O₃ reinforcement, which minimizes both instantaneous (electrochemical) and cumulative (gravimetric) corrosion metrics. This study addresses a gap in current research by providing the first detailed assessment of corrosion in open-cell AlSn6Cu-based composites with controlled pore architectures and different ceramic reinforcements, offering valuable insights for the development of advanced lightweight materials for harsh environments. Full article