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Keywords = emulsified asphalt

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18 pages, 1520 KB  
Article
Research of Fog Seal Performance with Sand Materials for Airport Asphalt Pavements
by Hui Zhang, Zhe Hu, Yongsheng Guan and Dongliang Hu
Materials 2025, 18(17), 4050; https://doi.org/10.3390/ma18174050 - 29 Aug 2025
Viewed by 156
Abstract
Asphalt pavements are widely used in airports due to their excellent skid resistance, vibration damping, and ease of construction. However, traditional fog seal materials often suffer from insufficient adhesion between fine sand and the emulsified asphalt binder, resulting in limited durability of the [...] Read more.
Asphalt pavements are widely used in airports due to their excellent skid resistance, vibration damping, and ease of construction. However, traditional fog seal materials often suffer from insufficient adhesion between fine sand and the emulsified asphalt binder, resulting in limited durability of the maintenance effect. This study aims to optimize the design of traditional fog seal materials and systematically evaluate their surface and durability performance. Firstly, a composite modified emulsified asphalt was prepared as the sand suspension slurry for the sand-containing fog seal. Through the dry wheel abrasion test, the optimal fine aggregates content was determined for four different spraying amounts (0.8, 0.9, 1.0, and 1.1 kg/m2). When the proportion of fine aggregates increases, the spraying amount needs to be increased accordingly to ensure the wrapping effect. Subsequently, pavement performance evaluation was conducted based on several indicators, including surface curing time, British Pendulum Number (BPN) friction coefficient, permeability coefficient, and mass loss rate. The results showed that the designed sand-containing fog seal significantly reduced surface curing time and exhibited superior skid resistance and permeability property compared to styrene-butadiene rubber (SBR)-modified emulsified asphalt. After freeze–thaw cycles, the maximum decrease in friction coefficient was 10.2%, and the mass loss rate after abrasion was approximately 67%, which were lower than those of SBR-modified emulsified asphalt (22.2% and 81%, respectively). Finally, considering the comprehensive performance comparison and evaluation, the optimal mix proportion was determined as 1.0 kg/m2 spraying amount with 30% fine aggregates content. The findings of this study provide practical support for improving the durability and service life of airport asphalt pavements. Full article
(This article belongs to the Section Construction and Building Materials)
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24 pages, 3537 KB  
Article
Macro–Mesoscale Equivalent Evaluation of Interlayer Shear Behavior in Asphalt Pavements with a Granular Base
by Fang Wang, Zhouqi Zhang, Chaoliang Fu and Zhiping Ma
Materials 2025, 18(17), 3935; https://doi.org/10.3390/ma18173935 - 22 Aug 2025
Viewed by 522
Abstract
To reduce reflective cracking in asphalt pavements, gravel base layers are commonly employed to disperse stress and delay structural damage. However, the loose nature of gravel bases results in complex interlayer contact conditions, typically involving interlocking between gravel particles in the base and [...] Read more.
To reduce reflective cracking in asphalt pavements, gravel base layers are commonly employed to disperse stress and delay structural damage. However, the loose nature of gravel bases results in complex interlayer contact conditions, typically involving interlocking between gravel particles in the base and aggregates in the asphalt surface course. In order to accurately simulate this interaction and to improve the interlayer shear performance, a mesoscale finite element model was developed and combined with macroscopic tests. Effects due to the type and amount of binder material, type of asphalt surface layer, and external loading on shear strength were systematically analyzed. The results indicate that SBS (Styrene–Butadiene–Styrene)-modified asphalt provides the highest interlayer strength, followed by SBR (Styrene–Butadiene Rubber)-modified emulsified asphalt and unmodified base bitumen. SBS (Styrene–Butadiene–Styrene)-modified asphalt achieves optimal interlaminar shear strength at a coating rate of 0.9 L/m2. Additionally, shear strength increases with applied load but decreases with increasing void ratio and the nominal maximum aggregate size of the surface course in the analyzed spectra. Based on simulation and experimental data, an equivalent macro–meso predictive model relating shear strength to key influencing factors was established. This model effectively bridges mesoscale mechanisms and practical engineering applications, providing theoretical support for the design and performance optimization of asphalt pavements with gravel bases. Full article
(This article belongs to the Section Construction and Building Materials)
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15 pages, 2924 KB  
Article
Influence of Interlayer Bonding Conditions Between Base and Surface Layers on Structural Mechanics Response of Asphalt Pavements
by Weijun Guo, Zhanjun Bai, Qunfeng Zhang, Daizhou Tong and Songqiang Chen
Buildings 2025, 15(16), 2922; https://doi.org/10.3390/buildings15162922 - 18 Aug 2025
Viewed by 280
Abstract
The interlayer bonding strength between a cement-stabilized macadam (CSM) base and an asphalt surface layer significantly influences asphalt pavement performance. This study analyzes the calculation method for the interlayer bonding coefficient, investigates its impact on pavement structural response, and proposes a threshold value. [...] Read more.
The interlayer bonding strength between a cement-stabilized macadam (CSM) base and an asphalt surface layer significantly influences asphalt pavement performance. This study analyzes the calculation method for the interlayer bonding coefficient, investigates its impact on pavement structural response, and proposes a threshold value. Pavement mechanics software was first employed to analyze horizontal displacement at the CSM-asphalt interface, leading to a proposed method for calculating the bonding coefficient using initial stress and displacement derived from interlayer shear tests. Subsequently, the bonding coefficient was evaluated under three interface conditions: untreated, emulsified asphalt-treated, and SBS-modified hot asphalt-treated. Results reveal substantial inherent bonding strength even in untreated interfaces. SBS-modified hot asphalt increased bonding strength by 40–50% compared to untreated interfaces and by 15–20% relative to emulsified asphalt-treated interfaces. Analysis of varying bonding coefficients demonstrates that insufficient CSM-asphalt bonding readily induces asphalt layer fatigue cracking, with bonding strength exerting the dominant influence on fatigue life. Pavements with SBS-modified hot asphalt interlayers exhibited approximately 70% longer fatigue life than untreated interfaces and 30% longer than emulsified asphalt-treated interfaces. Crucially, an interlayer bonding coefficient exceeding 5000 MPa/cm is required for layers to be considered fully bonded. Full article
(This article belongs to the Special Issue The Application of Intelligence Techniques in Construction Materials)
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16 pages, 2050 KB  
Article
Effects of Activated Cold Regenerant on Pavement Properties of Emulsified Asphalt Cold Recycled Mixture
by Fuda Chen, Jiangmiao Yu, Yuan Zhang, Zengyao Lin and Anxiong Liu
Materials 2025, 18(15), 3529; https://doi.org/10.3390/ma18153529 - 28 Jul 2025
Viewed by 396
Abstract
Limited recovery of the viscoelastic properties of aged asphalt on RAP surfaces at ambient temperature reduces interface fusion and bonding with new emulsified asphalt, degrading pavement performance and limiting large-scale promotion and high-value applications of the emulsified asphalt cold recycled mixture (EACRM). Therefore, [...] Read more.
Limited recovery of the viscoelastic properties of aged asphalt on RAP surfaces at ambient temperature reduces interface fusion and bonding with new emulsified asphalt, degrading pavement performance and limiting large-scale promotion and high-value applications of the emulsified asphalt cold recycled mixture (EACRM). Therefore, a cold regenerant was independently prepared to rapidly penetrate, soften, and activate aged asphalt at ambient temperature in this paper, and its effects on the volumetric composition, mechanical strength, and pavement performance of EACRM were systematically investigated. The results showed that as the cold regenerant content increased, the air voids, indirect tensile strength (ITS), and high-temperature deformation resistance of EACRM decreased, while the dry–wet ITS ratio, cracking resistance, and fatigue resistance increased. Considering the comprehensive pavement performance requirements of cold recycled pavements, the optimal content of the activated cold regenerant for EACRM was determined to be approximately 0.6%. Full article
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15 pages, 1251 KB  
Article
Research on the Adhesion Performance of Fast-Melting SBS-Modified Emulsified Asphalt–Aggregate Based on the Surface Free Energy Theory
by Hao Zhang, Haowei Li, Fei Guo, Shige Wang and Jinchao Yue
Materials 2025, 18(15), 3523; https://doi.org/10.3390/ma18153523 - 27 Jul 2025
Viewed by 478
Abstract
Aiming at the problems of complex process flow, high energy consumption, and difficult emulsification in the preparation of traditional SBS-modified emulsified asphalt, a preparation method of fast-melting SBS (referred to as SBS-T) modified emulsified asphalt based on the integration of modification and emulsification [...] Read more.
Aiming at the problems of complex process flow, high energy consumption, and difficult emulsification in the preparation of traditional SBS-modified emulsified asphalt, a preparation method of fast-melting SBS (referred to as SBS-T) modified emulsified asphalt based on the integration of modification and emulsification is proposed. Based on surface free energy theory, the contact angles between three rapid-melting SBS-modified emulsified asphalts with different dosages and three probe liquids (deionized water, glycerol, and formamide) were measured using the sessile drop method. The adhesion performance of the asphalt–aggregate system was studied by means of micromechanical methods. The evaluation indicators such as the cohesion work of the emulsified asphalt, the adhesion work of asphalt–aggregate, the spalling work, and the energy ratio were analyzed. The results show that the SBS-T modifier can significantly improve the thermodynamic properties of emulsified asphalt. With increasing modifier content, the SBS-T-modified emulsified asphalt demonstrated enhanced cohesive work, improved asphalt–aggregate adhesive work, and increased energy ratio, while showing reduced stripping work. At equivalent dosage levels, the SBS-T-modified emulsified asphalt demonstrates a slight improvement in adhesion performance to aggregates compared to conventional SBS-modified emulsified asphalt. The SBS-T emulsified modified asphalt provides an effective technical solution for the preventive maintenance of asphalt pavements. Full article
(This article belongs to the Special Issue Advances in Sustainable Construction Materials, Third Edition)
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21 pages, 5433 KB  
Review
Research Progress on Adhesion Mechanism and Testing Methods of Emulsified Asphalt–Aggregate Interface
by Hao-Yue Huang, Xiao Han, Sen Han, Xiao Ma, Jia Guo and Yao Huang
Buildings 2025, 15(15), 2611; https://doi.org/10.3390/buildings15152611 - 23 Jul 2025
Viewed by 542
Abstract
With the deepening of the green and low-carbon concept in the field of road engineering, the cold construction asphalt pavement technology has developed rapidly due to its advantages such as low energy consumption, low pollution, and convenient construction. The adhesion between emulsified asphalt [...] Read more.
With the deepening of the green and low-carbon concept in the field of road engineering, the cold construction asphalt pavement technology has developed rapidly due to its advantages such as low energy consumption, low pollution, and convenient construction. The adhesion between emulsified asphalt and aggregates, as a core factor affecting the performance of cold-mixed mixtures and the lifespan of the pavement, has attracted much attention in terms of its mechanism of action and evaluation methods. However, at present, there are still many issues that need to be addressed in terms of the stability control of adhesion between emulsified asphalt and aggregates, the explanation of the microscopic mechanism, and the standardization of testing methods in complex environments. These problems restrict the further promotion and application of the cold construction technology. Based on this, this paper systematically analyzes the current development status, application scenarios, and future trends of the theory and testing methods of the adhesion between emulsified asphalt and aggregates by reviewing a large number of relevant studies. The research aims to provide theoretical support and practical references for the improvement of adhesion in the cold construction asphalt pavement technology. Research shows that in terms of the adhesion mechanism, the existing results have deeply analyzed the infiltration and demulsification adhesion process of emulsified asphalt on the surface of aggregates and clarified the key links of physical and chemical interactions, but the understanding of the microscopic interface behavior and molecular-scale mechanism is still insufficient. In terms of testing methods, although objective and subjective evaluation methods such as mechanical tensile tests, surface energy evaluation, and adhesion fatigue tests have been developed, the standardization of testing, data comparability, and practical engineering applicability still need to be optimized. Comprehensive analysis shows that the research on the adhesion between emulsified asphalt and aggregates is showing a trend from macroscopic to microscopic, from static to dynamic. There are challenges in predicting and controlling the adhesion performance under complex environments, as well as important opportunities for developing advanced characterization techniques and multiscale simulation methods. Full article
(This article belongs to the Special Issue Advances in Performance-Based Asphalt and Asphalt Mixtures)
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33 pages, 4942 KB  
Review
A Review of Crack Sealing Technologies for Asphalt Pavement: Materials, Failure Mechanisms, and Detection Methods
by Weihao Min, Peng Lu, Song Liu and Hongchang Wang
Coatings 2025, 15(7), 836; https://doi.org/10.3390/coatings15070836 - 17 Jul 2025
Viewed by 848
Abstract
Asphalt pavement cracking represents a prevalent form of deterioration that significantly compromises road performance and safety under the combined effects of environmental factors and traffic loading. Crack sealing has emerged as a widely adopted and cost-effective preventive maintenance strategy that restores the pavement’s [...] Read more.
Asphalt pavement cracking represents a prevalent form of deterioration that significantly compromises road performance and safety under the combined effects of environmental factors and traffic loading. Crack sealing has emerged as a widely adopted and cost-effective preventive maintenance strategy that restores the pavement’s structural integrity and extends service life. This paper presents a systematic review of the development of crack sealing technology, conducts a comparative analysis of conventional sealing materials (including emulsified asphalt, hot-applied asphalt, polymer-modified asphalt, and rubber-modified asphalt), and examines the existing performance evaluation methodologies. Critical failure mechanisms are thoroughly investigated, including interfacial bond failure resulting from construction defects, material aging and degradation, hydrodynamic scouring effects, and thermal cycling impacts. Additionally, this review examines advanced sensing methodologies for detecting premature sealant failure, encompassing both non-destructive testing techniques and active sensing technologies utilizing intelligent crack sealing materials with embedded monitoring capabilities. Based on current research gaps, this paper identifies future research directions to guide the development of intelligent and sustainable asphalt pavement crack repair technologies. The proposed research framework provides valuable insights for researchers and practitioners seeking to improve the long-term effectiveness of pavement maintenance strategies. Full article
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16 pages, 1551 KB  
Review
Cold Central Plant Recycling Mixtures for High-Volume Pavements: Material Design, Performance, and Design Implications
by Abhary Eleyedath, Ayman Ali and Yusuf Mehta
Materials 2025, 18(14), 3345; https://doi.org/10.3390/ma18143345 - 16 Jul 2025
Viewed by 430
Abstract
The cold recycling (CR) technique is gaining traction, with an increasing demand for sustainable pavement construction practices. Cold in-place recycling (CIR) and cold central plant recycling (CCPR) are two strategies under the umbrella of cold recycling. These techniques use reclaimed asphalt pavement (RAP) [...] Read more.
The cold recycling (CR) technique is gaining traction, with an increasing demand for sustainable pavement construction practices. Cold in-place recycling (CIR) and cold central plant recycling (CCPR) are two strategies under the umbrella of cold recycling. These techniques use reclaimed asphalt pavement (RAP) to rehabilitate pavement, and CCPR offers the added advantage of utilizing stockpiled RAP. While many agencies have expertise in cold recycling techniques including CCPR, the lack of pavement performance data prevented the largescale implementation of these technologies. Recent studies in high-traffic volume applications demonstrate that CCPR technology can be implemented on the entire road network across all traffic levels. This reignited interest in the widespread implementation of CCPR. Therefore, the purpose of this study is to provide agencies with the most up-to-date information on CCPR to help them make informed decisions. To this end, this paper comprehensively reviews the mix-design for CCPR, the structural design of pavements containing CCPR layers, best construction practices, and the agency experience in using this technology on high-traffic volume roads to provide in-depth information on the steps to follow from project selection to field implementation. The findings specify the suitable laboratory curing conditions to achieve the optimum mix design and specimen preparation procedures to accurately capture the material properties. Additionally, this review synthesizes existing quantitative data from previous studies, providing context for the comparison of findings, where applicable. The empirical and mechanistic–empirical design inputs, along with the limitations of AASHTOWare Pavement ME software for analyzing this non-conventional material, are also presented. Full article
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21 pages, 5109 KB  
Article
Influence Mechanism of Waterborne Polyurethane on the Properties of Emulsified Asphalt
by Jian Tan, Shuguang Hou, Rui Jin, Xiao Zhong and Xiaoxi Zou
Materials 2025, 18(14), 3280; https://doi.org/10.3390/ma18143280 - 11 Jul 2025
Viewed by 352
Abstract
To elucidate the modification mechanism of waterborne polyurethane (WPU) on emulsified asphalt, anionic and cationic WPUs are utilized as modifiers. As well, their effects on physical properties, microstructure, and compatibility are characterized using basic performance tests, Fourier transform infrared spectroscopy (FTIR), and atomic [...] Read more.
To elucidate the modification mechanism of waterborne polyurethane (WPU) on emulsified asphalt, anionic and cationic WPUs are utilized as modifiers. As well, their effects on physical properties, microstructure, and compatibility are characterized using basic performance tests, Fourier transform infrared spectroscopy (FTIR), and atomic force microscopy (AFM). The results show that WPU-modified emulsified asphalt exhibited a higher softening point, reduced penetration, and decreased ductility, suggesting enhanced high-temperature stability but diminished low-temperature flexibility. Among all samples, the combination of cationic WPU with cationic emulsified asphalt shows the highest softening point (54.1 °C), whereas cationic emulsified asphalt alone exhibits the lowest one (52.9 °C). Anionic emulsified asphalt demonstrates the highest penetration (79 mm), while non-ionic WPU combined with cationic emulsified asphalt shows the lowest one (59.3 mm). The ductility decreases from 90.3 cm to 28.7 cm. The storage stability varies with WPU ion type. Cationic WPU-modified samples showed the poorest storage stability (0.7% residue), while anionic-modified samples exhibit the best one (0.4% residue). FTIR analysis confirms the presence of characteristic WPU absorption peaks, indicating that physical blending occurs, and chemical interaction is limited. AFM observations reveal that anionic WPUs provide superior compatibility, forming fine, uniformly distributed particles with the lowest surface roughness (5.655 nm). In contrast, cationic WPUs form chain-like structures that cure effectively but exhibit poor dispersion. This study provides a basis for the development of high-performance WPU-modified emulsified asphalt. Full article
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23 pages, 11832 KB  
Article
Investigation of Flexibility Enhancement Mechanisms and Microstructural Characteristics in Emulsified Asphalt and Latex-Modified Cement
by Wen Liu, Yong Huang, Yulin He, Hanyu Wei, Ruyun Bai, Huan Li, Qiushuang Cui and Sining Li
Sustainability 2025, 17(14), 6317; https://doi.org/10.3390/su17146317 - 9 Jul 2025
Viewed by 537
Abstract
The inherent limitations of ordinary cement mortar—characterized by its high brittleness and low flexibility—result in a diminished load-bearing capacity, predisposing concrete pavements to cracking. A novel approach has been proposed to enhance material performance by incorporating emulsified asphalt and latex into ordinary cement [...] Read more.
The inherent limitations of ordinary cement mortar—characterized by its high brittleness and low flexibility—result in a diminished load-bearing capacity, predisposing concrete pavements to cracking. A novel approach has been proposed to enhance material performance by incorporating emulsified asphalt and latex into ordinary cement mortar, aiming to improve the flexibility and durability of concrete pavements effectively. To further validate the feasibility of this proposed approach, a series of comprehensive experimental investigations were conducted, with corresponding conclusions detailed herein. As outlined below, the flexibility properties of the modified cement mortar were systematically evaluated at curing durations of 3, 7, and 28 days. The ratio of flexural to compressive strength can be increased by up to 38.9% at 8% emulsified asphalt content at the age of 28 days, and by up to 50% at 8% latex content. The mechanism of emulsified asphalt and latex-modified cement mortar was systematically investigated using a suite of analytical techniques: X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TG-DTG), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). Through comprehensive analyses of microscopic morphology, hydration products, and elemental distribution, the enhancement in cement mortar toughness can be attributed to two primary mechanisms. First, Ca2+ ions combine with the carbonyl groups of emulsified asphalt to form a flexible film structure during cement hydration, thereby reducing the formation of brittle hydrates. Second, active functional groups in latex form a three-dimensional network, regulating internal expansion-contraction tension in the modified mortar and extending its service life. Full article
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12 pages, 3805 KB  
Article
Preparation of Graft-Functionalized SBS/SBS Composite Latex Modifier and Its Effect on Emulsified Asphalt Properties
by Kunyu Wang, Yifan Liu, Zhenhao Cao, Yanyan Zhang, Jia Wang and Xue Li
Processes 2025, 13(7), 2125; https://doi.org/10.3390/pr13072125 - 3 Jul 2025
Viewed by 426
Abstract
To broaden clean asphalt modification methods, this study employs a composite polymer of maleic anhydride-grafted styrene-butadiene-styrene (MA-g-SBS) and styrene-butadiene-styrene (SBS) as a modifier. The composite is formulated into polymer latex and used to modify emulsified asphalt. Routine performance tests were conducted on MA-g-SBS/SBS [...] Read more.
To broaden clean asphalt modification methods, this study employs a composite polymer of maleic anhydride-grafted styrene-butadiene-styrene (MA-g-SBS) and styrene-butadiene-styrene (SBS) as a modifier. The composite is formulated into polymer latex and used to modify emulsified asphalt. Routine performance tests were conducted on MA-g-SBS/SBS composite latex-modified emulsified asphalt (MSMEA) with varying ratios to determine the optimal composition. The ideal ratio was found to be MA-g-SBS:SBS = 1:4. Subsequently, conventional property tests, rheological analyses, microphase structure observations, and bending beam creep tests were conducted on MSMEA with the optimal ratio to assess the impact of the composite latex on asphalt performance. Findings indicated that increasing the latex content significantly enhanced the softening point and ductility while reducing penetration. These macroscopic improvements were notably superior to those achieved with single SBS latex modification. Fluorescence microscopy revealed that at low dosages, the MA-g-SBS/SBS composite dispersed uniformly as point-like structures within the asphalt. At higher dosages (above 5%), a distinct network structure emerged. The addition of the composite latex raised the complex shear modulus and rutting factor while reducing the phase angle, with pronounced fluctuations observed between 4% and 5% dosages. This suggests a substantial enhancement in the high-temperature performance of the emulsified asphalt, attributed to the formation of the network structure. FT-IR results confirmed that a chemical reaction occurred during the modification process. Additionally, the bending beam creep test demonstrated that the composite latex reduced asphalt brittleness and improved its low-temperature performance. Full article
(This article belongs to the Section Chemical Processes and Systems)
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14 pages, 4450 KB  
Article
Performance Evaluation of Waterborne Epoxy Resin-Reinforced SBS, Waterborne Acrylate or SBR Emulsion for Road
by Hao Fu and Chaohui Wang
Coatings 2025, 15(7), 787; https://doi.org/10.3390/coatings15070787 - 3 Jul 2025
Viewed by 417
Abstract
To obtain waterborne polymer-modified emulsified asphalt materials with better comprehensive performance, waterborne polymer modifiers including waterborne epoxy resin (WER)-reinforced styrene–butadiene–styrene block copolymer (SBS), waterborne acrylate (WA) or styrene butadiene rubber (SBR) emulsion were prepared. The mechanical strength, toughness, adhesion and impact resistance of [...] Read more.
To obtain waterborne polymer-modified emulsified asphalt materials with better comprehensive performance, waterborne polymer modifiers including waterborne epoxy resin (WER)-reinforced styrene–butadiene–styrene block copolymer (SBS), waterborne acrylate (WA) or styrene butadiene rubber (SBR) emulsion were prepared. The mechanical strength, toughness, adhesion and impact resistance of these waterborne polymers were evaluated. Furthermore, the correlation between the performance indicators of the waterborne polymers was analyzed. Based on Fourier transform infrared (FTIR) spectroscopy and thermogravimetric (TG) analysis, the mechanism of WER-modified SBS and WA was characterized. The results show that adding 10%–15% WER can significantly improve the mechanical properties of the waterborne polymer. The performances of modified SBS and WA are better than that of modified SBR. When the content of WER is 10%, the tensile strength, elongation at break and pull-off strength of WER-modified SBS and WA are 4.80–6.38 MPa, 476.3%–579.6% and 1.62–1.70 MPa, respectively. The mechanical strength and breaking energy of the waterborne polymers show a significant linear correlation with their application properties such as adhesion, bonding and impact resistance. FTIR and TG analyses indicate that WER-modified SBS or WA prepared via emulsion blending undergo primarily physical modifications, enhancing thermal stability while promoting crosslinking and curing. Full article
(This article belongs to the Special Issue Green Asphalt Materials—Surface Engineering and Applications)
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15 pages, 1882 KB  
Article
Predicting Rheological Properties of Asphalt Modified with Mineral Powder: Bagging, Boosting, and Stacking vs. Single Machine Learning Models
by Haibing Huang, Zujie Xu, Xiaoliang Li, Bin Liu, Xiangyang Fan, Haonan Ding and Wen Xu
Materials 2025, 18(12), 2913; https://doi.org/10.3390/ma18122913 - 19 Jun 2025
Viewed by 433
Abstract
This study systematically compares the predictive performance of single machine learning (ML) models (KNN, Bayesian ridge regression, decision tree) and ensemble learning methods (bagging, boosting, stacking) for quantifying the rheological properties of mineral powder-modified asphalt, specifically the complex shear modulus (G*) and the [...] Read more.
This study systematically compares the predictive performance of single machine learning (ML) models (KNN, Bayesian ridge regression, decision tree) and ensemble learning methods (bagging, boosting, stacking) for quantifying the rheological properties of mineral powder-modified asphalt, specifically the complex shear modulus (G*) and the phase angle (δ). We used two emulsifiers and three mineral powders for fabricating modified emulsified asphalt and conducting rheological property tests, respectively. Dynamic shear rheometer (DSR) test data were preprocessed using the local outlier factor (LOF) algorithm, followed by K-fold cross-validation (K = 5) and Bayesian optimization to tune model hyperparameters. This framework uniquely employs cross-validated predictions from base models as input features for the meta-learner, reducing information leakage and enhancing generalization. Traditional single ML models struggle to characterize accurately as a result, and an innovative stacking model was developed, integrating predictions from four heterogeneous base learners—KNN, decision tree (DT), random forest (RF), and XGBoost—with a Bayesian ridge regression meta-learner. Results demonstrate that ensemble models outperform single models significantly, with the stacking model achieving the highest accuracy (R2 = 0.9727 for G* and R2 = 0.9990 for δ). Shapley additive explanations (SHAP) analysis reveals temperature and mineral powder type as key factors, addressing the “black box” limitation of ML in materials science. This study validates the stacking model as a robust framework for optimizing asphalt mixture design, offering insights into material selection and pavement performance improvement. Full article
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22 pages, 8920 KB  
Article
Microscopic Mechanisms and Pavement Performance of Waterborne Epoxy Resin-Modified Emulsified Asphalt
by Fan Yang, Fang Yu, Hongren Gong, Liming Yang, Qian Zhou, Lihong He, Wanfeng Wei and Qiang Chen
Materials 2025, 18(12), 2825; https://doi.org/10.3390/ma18122825 - 16 Jun 2025
Viewed by 478
Abstract
To address the deficiencies of traditional emulsified asphalt-pavement maintenance material in cohesive strength, high-temperature rutting resistance, as well as adhesion to aggregates, this study developed waterborne epoxy resin-modified emulsified asphalt (WEA) binders using a two-component waterborne epoxy resin (WER) and systematically investigated their [...] Read more.
To address the deficiencies of traditional emulsified asphalt-pavement maintenance material in cohesive strength, high-temperature rutting resistance, as well as adhesion to aggregates, this study developed waterborne epoxy resin-modified emulsified asphalt (WEA) binders using a two-component waterborne epoxy resin (WER) and systematically investigated their modification mechanisms and pavement performance. The results indicated that WER emulsions and curing agents could polymerize to form epoxy resin within the emulsified asphalt dispersion medium, with the modification process dominated by physical interactions. When the WER content exceeded 12%, a continuous modifier network structure was established within the emulsified asphalt. The epoxy resin formed after curing could significantly increase the polarity component of the binder, thereby increasing the surface free energy. The linear viscoelastic range of the WEA binder exhibited a negative correlation with the dosage of the WER modifier. Notably, when the WER content exceeded 6%, the high-temperature stability (rutting resistance and elastic recovery performance) of the binder was significantly enhanced. Concurrently, stress sensitivity and frequency dependence gradually decrease, demonstrating superior thermomechanical stability. Furthermore, WER significantly enhanced the interfacial interaction and adhesion between the binder and aggregates. However, the incorporation of WER adversely affects the low-temperature cracking resistance of the binder, necessitating strict control over its dosage in practical applications. Full article
(This article belongs to the Section Polymeric Materials)
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21 pages, 2798 KB  
Article
Degradation Law of Long-Term Performance in In-Service Emulsified Asphalt Cold Recycled Mixtures
by Bingyang Wu, Shuai Wang, Ziqi Ma, Hui Zhao and Hengkang Zhu
Processes 2025, 13(5), 1561; https://doi.org/10.3390/pr13051561 - 18 May 2025
Viewed by 417
Abstract
To investigate the performance degradation of emulsified asphalt cold recycled mixtures (CRM) during service, this study selected a 10 km section of the cold recycled layer (CRL) from the Changjiu Expressway reconstruction project as the research subject. The deterioration patterns of key pavement [...] Read more.
To investigate the performance degradation of emulsified asphalt cold recycled mixtures (CRM) during service, this study selected a 10 km section of the cold recycled layer (CRL) from the Changjiu Expressway reconstruction project as the research subject. The deterioration patterns of key pavement performance indicators—including the Pavement Condition Index (PCI), Riding Quality Index (RQI), Rutting Depth Index (RDI), and Pavement Structure Strength Index (PSSI)—were analyzed in relation to cumulative equivalent axle loads over a 7-year service period. Concurrently, comparative evaluations were conducted on the mechanical properties, water stability, high-temperature performance, low-temperature crack resistance, and fatigue characteristics between in-service and laboratory-prepared emulsified asphalt CRM. The results demonstrate that after seven years of service, the emulsified asphalt cold recycled pavement maintained excellent performance levels, with PCI, RQI, RDI, and PSSI values of 92.6 (excellent), 90.1 (excellent), 88.5 (good), and 93.4 (excellent), respectively. Notably, while the indirect tensile strength and unconfined compressive strength of the CRL increased with prolonged service duration, other performance metrics—including the tensile strength ratio, shear strength, fracture work, and fracture energy—exhibited an initial improvement followed by gradual deterioration. Additionally, increased traffic loading during service led to a reduction in the residual fatigue life of the CRM. Interestingly, the study observed a temporary improvement in the fatigue performance of CRM during the service period. This phenomenon can be attributed to three key mechanisms: (1) continued cement hydration, (2) secondary hot compaction effects, and (3) diffusion and rejuvenation between fresh and aged asphalt binders. These processes collectively contributed to the partial recovery of aged asphalt strength, thereby improving both the mechanical properties and overall road performance of the CRM. The findings confirm that cold recycled pavements exhibit remarkable durability and maintain a high service level over extended periods. Full article
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