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Search Results (834)

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Keywords = exergy analysis

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18 pages, 2472 KB  
Article
Energy Consumption and Optimization Analysis of Gas Production System of Condensate Gas Reservoir-Type Gas Storage
by Hong Meng, Jingcheng Lv, Huan Yu, Shuzhen Sun, Limin Ma, Zhongli Ji and Cheng Chang
Energies 2025, 18(17), 4677; https://doi.org/10.3390/en18174677 - 3 Sep 2025
Abstract
This study investigates the energy consumption and losses associated with the gas production process in a condensate gas reservoir-type gas storage system. The energy consumption linked to each unit and key equipment was determined by HYSYS simulation, followed by a sensitivity analysis and [...] Read more.
This study investigates the energy consumption and losses associated with the gas production process in a condensate gas reservoir-type gas storage system. The energy consumption linked to each unit and key equipment was determined by HYSYS simulation, followed by a sensitivity analysis and exergy analysis. The findings reveal that the condensate oil stabilization tower is the primary energy-consuming equipment, responsible for 70.61% of the total energy consumption (3.82 × 105 kJ·h−1/1%). The temperature of the condensate reboiler is identified as the most significant influencing factor. Furthermore, the equipment exhibiting the highest exergy loss is the J-T valve (1.2 × 107 kJ·h−1), which contributes to 25.23% of the total loss. Consequently, to mitigate energy consumption in the gas production system, it is crucial to control the temperature of the condensate oil reboiler. Enhancing efficiency will rely on recovering the pressure energy loss associated with the J-T valve. The field gas gathering system lacks sub-unit energy consumption measurement and flow measurement for key process fluids. This study can provide methodological and data references for optimizing the operation of this condensate oil–gas reservoir-type storage facility. Full article
(This article belongs to the Special Issue Advances in Natural Gas Research and Energy Engineering)
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23 pages, 8434 KB  
Article
Exergy and Demography: Present Scenarios and Future Projections
by Enrico Sciubba
Energies 2025, 18(17), 4641; https://doi.org/10.3390/en18174641 - 1 Sep 2025
Abstract
The study presented in this paper is intended to be a contribution to the practical implementation of the “sustainability” concept, often misunderstood at times and incorrectly applied. The first sections describe a systematic procedure for a rigorous definition of “sustainability” and of “sustainable [...] Read more.
The study presented in this paper is intended to be a contribution to the practical implementation of the “sustainability” concept, often misunderstood at times and incorrectly applied. The first sections describe a systematic procedure for a rigorous definition of “sustainability” and of “sustainable development” based on thermodynamics. A concept tightly connected with “sustainability” is “resource thriftiness”, i.e., the reduction in the anthropic extraction of irreplaceable supplies of fossil ores and fuels contained in the Earth’ crust and the reduction in the load posed on the environment by discharges, collectively referred to as “environmental conservation”: this is another concept that must be embedded in the definition of sustainability. An environmentally friendly society ought to concentrate on minimising such consumption by implementing an efficient and rational conversion of primary resources to final commodities while maintaining acceptable life standards. A thermodynamics-based approach can help identify the boundaries of the “sustainable region”: if sustainable development depends on a balance between primary input and final consumption, the internal allocation of the latter among citizens becomes a relevant parameter. The study presented in this paper introduces a direct link between demographics and pro capite final exergy use, showing how the age distribution of a society strongly impacts primary consumption. The paper presents some considerations about the quantitative link between the so-called “demographic pyramids” and the exergy budget of a country, with specific examples based on currently available data. Full article
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36 pages, 6601 KB  
Article
A Geothermal-Driven Zero-Emission Poly-Generation Energy System for Power and Green Hydrogen Production: Exergetic Analysis, Impact of Operating Conditions, and Optimization
by Guy Trudon Muya, Ali Fellah, Sun Yaquan, Yasmina Boukhchana, Samuel Molima, Matthieu Kanyama and Amsini Sadiki
Fuels 2025, 6(3), 65; https://doi.org/10.3390/fuels6030065 - 28 Aug 2025
Viewed by 333
Abstract
Since the hydrogen-production process is not yet fully efficient, this paper proposes a poly-generation system that is driven by a geothermal energy source and utilizes a combined Kalina/organic Rankine cycle coupled with an electrolyzer unit to produce, simultaneously, power and green hydrogen in [...] Read more.
Since the hydrogen-production process is not yet fully efficient, this paper proposes a poly-generation system that is driven by a geothermal energy source and utilizes a combined Kalina/organic Rankine cycle coupled with an electrolyzer unit to produce, simultaneously, power and green hydrogen in an efficient way. A comprehensive thermodynamic analysis and an exergetic evaluation are carried out to assess the effect of key system parameters (geothermal temperature, high pressure, ammonia–water concentration ratio, and terminal thermal difference) on the performance of concurrent production of power and green hydrogen. Thereby, two configurations are investigated with/without the separation of turbines. The optimal ammonia mass fraction of the basic solution in KC is identified, which leads to an overall optimal system performance in terms of exergy efficiency and green hydrogen production rate. In both configurations, the optimal evaluation is made possible by conducting a genetic algorithm optimization. The simulation results without/with the separation of turbines demonstrate the potential of the suggested cycle combination and emphasize its effectiveness and efficiency. Exemplary, for the case without the separation of turbines, it turns out that the combination of ammonia–water and MD2M provides the best performance with net power of 1470 kW, energy efficiency of 0.1184, and exergy efficiency of 0.1258 while producing a significant green hydrogen amount of 620.17 kg/day. Finally, an economic study allows to determine the total investment and payback time of $3,342,000 and 5.37 years, respectively. The levelized cost of hydrogen (LCOH) for the proposed system is estimated at 3.007 USD/kg H2, aligning well with values reported in the literature. Full article
(This article belongs to the Special Issue Sustainability Assessment of Renewable Fuels Production)
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21 pages, 1406 KB  
Article
Energy and Exergy Assessment of a Solar Driven Single Effect H2O-LiBr Absorption Chiller Under Moderate and Hot Climatic Conditions
by Mamadou Sow and Lavinia Grosu
Energies 2025, 18(17), 4553; https://doi.org/10.3390/en18174553 - 27 Aug 2025
Viewed by 308
Abstract
This work mainly focuses on the energy and exergy analysis of a single-effect absorption cooling system operating with the couple H2O-LiBr, under different climatic conditions in Senegal and France. A simulation model was developed, using the Engineering Equation Solver V10 (EES) [...] Read more.
This work mainly focuses on the energy and exergy analysis of a single-effect absorption cooling system operating with the couple H2O-LiBr, under different climatic conditions in Senegal and France. A simulation model was developed, using the Engineering Equation Solver V10 (EES) software. Results indicate that the system can achieve a maximum COP of 0.76 and an exergy efficiency of 56%, which decreases as the generator temperature increases. Increasing the generator temperature from 87 to 95 °C significantly improves COP, but gains become marginal beyond 100 °C. The highest exergy destruction occurs in the generator, followed by the absorber, condenser, and evaporator. A temperature difference above 44 °C between the generator and the absorber is required to maintain H2O-LiBr solution stability. Optimal temperatures for hot climates like Senegal are 90 °C (generator), 42 °C (absorber/condenser), and 7 °C (evaporator), while maximum exergy efficiency (56%) is reached at 81 °C, typical of moderate climates (France). Evaporator exergy efficiency increases from 16 to 52% with rising ambient temperature, while absorber and condenser efficiencies drop. Increasing the cooling water flow rate from 0.2 to 1.4 kg/s reduces exergy losses in the absorber and the condenser by up to 36%. The solution heat exchanger (SHE) optimal effectiveness of 0.75 reduces exergy consumption in the absorber and the generator. Full article
(This article belongs to the Special Issue Solar Energy and Resource Utilization—2nd Edition)
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24 pages, 2932 KB  
Article
Exergoeconomic Analysis of a Milk Pasteurization System Assisted by Geothermal Energy with the Use of an Organic Rankine Cycle
by Fatih Akkurt and Riza Buyukzeren
Appl. Sci. 2025, 15(16), 9183; https://doi.org/10.3390/app15169183 - 21 Aug 2025
Viewed by 401
Abstract
This study investigates the exergoeconomic performance of a milk pasteurization system powered by geothermal energy, operating across geothermal source temperatures (GSTs) ranging from 80 °C to 110 °C. The system uses geothermal heat as its primary energy source, while the cooling process is [...] Read more.
This study investigates the exergoeconomic performance of a milk pasteurization system powered by geothermal energy, operating across geothermal source temperatures (GSTs) ranging from 80 °C to 110 °C. The system uses geothermal heat as its primary energy source, while the cooling process is supported by a vapor compression refrigeration cycle driven by electricity generated through an Organic Rankine Cycle (ORC). The analysis was carried out in three stages: determining system parameters for each GST level, conducting detailed energy and exergy analyses, and performing an exergoeconomic evaluation using the specific exergy costing (SPECO) method. The results show that both energy and exergy efficiencies decline as GST increases. Energy efficiency varies between 88.30% and 78.53%, while exergy efficiency ranges from 72.86% to 58.02%. In parallel, unit-specific manufacturing costs increase with higher GST. Electricity production costs range from 610 to 900 USD·MWh−1, and the cost of pasteurized milk varies between 3.76 and 6.53 USD·ton−1. These findings offer practical insights into how geothermal source temperature affects the thermodynamic and economic performance of such systems, contributing to the broader understanding of sustainable dairy processing technologies. Full article
(This article belongs to the Section Applied Thermal Engineering)
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12 pages, 5219 KB  
Article
Design of Forward Osmosis Desalination Configurations: Exergy and Energy Perspectives
by Chulwoo Park, Yonghyuk Kim and Daejoong Kim
Appl. Sci. 2025, 15(16), 9168; https://doi.org/10.3390/app15169168 - 20 Aug 2025
Viewed by 283
Abstract
This study presents a detailed energy and exergy analysis of two forward osmosis (FO) desalination systems: single-pass and regenerative configurations. Both utilize osmotic pressure from a concentrated draw solution to drive water transport through a semi-permeable membrane. The regenerative system includes extra components [...] Read more.
This study presents a detailed energy and exergy analysis of two forward osmosis (FO) desalination systems: single-pass and regenerative configurations. Both utilize osmotic pressure from a concentrated draw solution to drive water transport through a semi-permeable membrane. The regenerative system includes extra components for draw solute recovery, which increases electrical energy consumption to 188.9 kW and slightly lowers water recovery to 54%, compared to 98 kW and 60% for the single-pass FO system. Equivalent work for desalination is 1.4 kWh/m3 for single-pass and 1.8 kWh/m3 for regenerative FO systems. Exergy analysis shows the distillation column as the largest contributor to exergy destruction in both systems, responsible for over 44% of losses. The regenerative system adds 57.9 MW of chemical exergy destruction in the regenerator. Physical exergy destruction mainly occurs in the reboiler and condenser, while chemical exergy destruction is dominant in the FO membrane unit and regenerator. These findings provide valuable insights for improving the efficiency and sustainability of FO desalination technologies. Full article
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19 pages, 1953 KB  
Article
Thermodynamic Analysis and Optimization of a Regenerative Heat Exchange System for Solid Oxide Electrolyzer-Based Hydrogen Production
by Georgi Todorov, Konstantin Kamberov and Todor Todorov
Energies 2025, 18(16), 4424; https://doi.org/10.3390/en18164424 - 19 Aug 2025
Viewed by 459
Abstract
The article discusses a regenerative heat exchange system for a solid oxide electrolyzer cell (SOEC) used in the production of green hydrogen. The heating system comprises four heat exchangers, one condenser heat exchanger, and a mixer evaporator. A pump and two throttle valves [...] Read more.
The article discusses a regenerative heat exchange system for a solid oxide electrolyzer cell (SOEC) used in the production of green hydrogen. The heating system comprises four heat exchangers, one condenser heat exchanger, and a mixer evaporator. A pump and two throttle valves have been added to separate the hydrogen at an elevated steam condensation temperature. Assuming steady flow, a thermodynamic analysis was performed to validate the design and to predict the main parameters of the heating system. Numerical optimization was then used to determine the optimal temperature distribution, ensuring the lowest possible additional external energy requirement for the regenerative system. The proportions of energy gained through heat exchange were determined, and their distribution analyzed. The calculated thermal efficiency of the regenerative system is 75%, while its exergy efficiency is 73%. These results can be applied to optimize the design of heat exchangers for hydrogen production systems using SOECs. Full article
(This article belongs to the Special Issue Advances in Hydrogen Production in Renewable Energy Systems)
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36 pages, 1450 KB  
Review
Optimal Operation of Combined Cooling, Heating, and Power Systems with High-Penetration Renewables: A State-of-the-Art Review
by Yunshou Mao, Jingheng Yuan and Xianan Jiao
Processes 2025, 13(8), 2595; https://doi.org/10.3390/pr13082595 - 16 Aug 2025
Viewed by 517
Abstract
Under the global decarbonization trend, combined cooling, heating, and power (CCHP) systems are critical for improving regional energy efficiency. However, the integration of high-penetration variable renewable energy (RE) sources introduces significant volatility and multi-dimensional uncertainties, challenging conventional operation strategies designed for stable energy [...] Read more.
Under the global decarbonization trend, combined cooling, heating, and power (CCHP) systems are critical for improving regional energy efficiency. However, the integration of high-penetration variable renewable energy (RE) sources introduces significant volatility and multi-dimensional uncertainties, challenging conventional operation strategies designed for stable energy inputs. This review systematically examines recent advances in CCHP optimization under high-RE scenarios, with a focus on flexibility-enabled operation mechanisms and uncertainty-aware optimization strategies. It first analyzes the evolving architecture of variable RE-driven CCHP systems and core challenges arising from RE intermittency, demand volatility, and multi-energy coupling. Subsequently, it categorizes key flexibility resources and clarifies their roles in mitigating uncertainties. The review further elaborates on optimization methodologies tailored to high-RE contexts, along with their comparative analysis and selection criteria. Additionally, it details the formulation of optimization models, model formulation, and solution techniques. Key findings include the following: Generalized energy storage, which integrates physical and virtual storage, increases renewable energy utilization by 12–18% and reduces costs by 45%. Hybrid optimization strategies that combine robust optimization and deep reinforcement learning lower operational costs by 15–20% while strengthening system robustness against renewable energy volatility by 30–40%. Multi-energy synergy and exergy-efficient flexibility resources collectively improve system efficiency by 8–15% and reduce carbon emissions by 12–18%. Overall, this work provides a comprehensive technical pathway for enhancing the efficiency, stability, and low-carbon performance of CCHP systems in high-RE environments, supporting their scalable contribution to global decarbonization efforts. Full article
(This article belongs to the Special Issue Distributed Intelligent Energy Systems)
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19 pages, 3198 KB  
Article
Thermodynamic Analysis of Oxygenation Methods for Stationary Water: Mathematical Modeling and Experimental Investigation
by Mihaela Constantin, Cătălina Dobre and Mugurel Oprea
Thermo 2025, 5(3), 28; https://doi.org/10.3390/thermo5030028 - 8 Aug 2025
Viewed by 357
Abstract
This paper presents a detailed thermodynamic and mathematical modeling study of the oxygenation processes in stationary water bodies, focusing on improving oxygen transfer efficiency, an essential factor in sustaining aquatic ecosystem health. The study employed mathematical models implemented in MATLAB R2024a to simulate [...] Read more.
This paper presents a detailed thermodynamic and mathematical modeling study of the oxygenation processes in stationary water bodies, focusing on improving oxygen transfer efficiency, an essential factor in sustaining aquatic ecosystem health. The study employed mathematical models implemented in MATLAB R2024a to simulate the influence of temperature, bubble size, and mass transfer parameters. Key parameters, such as dissolved oxygen concentration, volumetric mass transfer coefficient (akL), and water temperature, were evaluated under different operational scenarios. The oxygenation system was powered by solar energy and included rotating fine-bubble generators mounted on a floating platform. Mathematical modeling carried out in MATLAB validated the theoretical models, showing how environmental factors such as temperature and bubble size influence oxygen dissolution. Initial experimental data, including dissolved oxygen levels (C0 = 3.12 mg/dm3), saturation concentrations at various temperatures (Cs = 8.3 mg/dm3 at 24 °C; Cs = 7.3 mg/dm3 at 30 °C), and a mass transfer coefficient of akL = 0.09 s−1, were used to support the model accuracy. The results highlight the potential of digitally controlled energy-efficient aeration technologies for applications in lake restoration, aquaculture, and sustainable water management. This paper introduces a coupled approach to oxygen transfer and temperature evolution validated experimentally, which has rarely been detailed in the literature. The novelty of this study lies in the combined thermodynamic modeling and exergy–entropy analysis along with real-time tracking, showing the relevance of energy-optimized, digitally monitored oxygenation platforms powered by solar energy. Full article
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23 pages, 2823 KB  
Article
Thermodynamic Analysis of Biomass Pyrolysis in an Auger Reactor Coupled with a Fluidized-Bed Reactor for Catalytic Deoxygenation
by Balkydia Campusano, Michael Jabbour, Lokmane Abdelouahed and Bechara Taouk
Processes 2025, 13(8), 2496; https://doi.org/10.3390/pr13082496 - 7 Aug 2025
Viewed by 446
Abstract
This research contributes to advance the sustainable production of biofuels and provides insights into the energy and exergy assessment of bio-oil, which is essential for developing environmentally friendly energy production solutions. Energy and exergy analyses were performed to evaluate the pyrolysis of beech [...] Read more.
This research contributes to advance the sustainable production of biofuels and provides insights into the energy and exergy assessment of bio-oil, which is essential for developing environmentally friendly energy production solutions. Energy and exergy analyses were performed to evaluate the pyrolysis of beech wood biomass at 500 °C in an Auger reactor. To improve the quality of the obtained bio-oil, its catalytic deoxygenation was performed within an in-line fluidized catalytic bed reactor using a catalyst based on HZSM5 zeolite modified with 5 wt.% Iron (5%FeHZSM-5). A thermodynamic analysis of the catalytic and non-catalytic pyrolysis system was carried out, as well as a comparative study of the calculation methods for the energy and exergy evaluation for bio-oil. The required heat for pyrolysis was found to be 1.2 MJ/kgbiomass in the case of non-catalytic treatment and 3.46 MJ/kgbiomass in the presence of the zeolite-based catalyst. The exergy efficiency in the Auger reactor was 90.3%. Using the catalytic system coupled to the Auger reactor, this efficiency increased to 91.6%, leading to less energy degradation. Calculating the total energy and total exergy of the bio-oil using two different methods showed a difference of 6%. In the first method, only the energy contributions of the model compounds, corresponding to the major compounds of each chemical family of bio-oil, were considered. In contrast, in the second method, all molecules identified in the bio-oil were considered for the calculation. The second method proved to be more suitable for thermodynamic analysis. The novelties of this work concern the thermodynamic analysis of a coupled system of an Auger biomass pyrolysis reactor and a fluidized bed catalytic deoxygenation reactor on the one hand, and the use of all the molecules identified in the oily phase for the evaluation of energy and exergy on the other hand. Full article
(This article belongs to the Section Chemical Processes and Systems)
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23 pages, 2663 KB  
Article
How Nanofluids May Enhance Energy Efficiency and Carbon Footprint in Buildings?
by Sylwia Wciślik
Sustainability 2025, 17(15), 7035; https://doi.org/10.3390/su17157035 - 2 Aug 2025
Viewed by 431
Abstract
Nanofluids are an innovative working medium in solar hot water installations (DHWs), thanks to their increased thermal conductivity and heat transfer coefficient. The aim of this work was to assess the effect of Al2O3 nanofluids in a water–ethylene glycol base [...] Read more.
Nanofluids are an innovative working medium in solar hot water installations (DHWs), thanks to their increased thermal conductivity and heat transfer coefficient. The aim of this work was to assess the effect of Al2O3 nanofluids in a water–ethylene glycol base (40:60%) and with the addition of Tween 80 surfactant (0.2 wt%) on thermal efficiency (ε) and exergy (ηex) in a plate heat exchanger at DHW flows of 3 and 12 L/min. The numerical NTU–ε model was used with dynamic updating of thermophysical properties of nanofluids and the solution of the ODE system using the ode45 method, and the validation was carried out against the literature data. The results showed that the nanofluids achieved ε ≈ 0.85 (vs. ε ≈ 0.87 for the base fluid) and ηex ≈ 0.72 (vs. ηex ≈ 0.74), with higher entropy generation. The addition of Tween 80 reduced the viscosity by about 10–15%, resulting in a slight increase of Re and h-factor; however, the impact on ε and ηex was marginal. The environmental analysis with an annual demand of Q = 3000 kWh/year and an emission factor of 0.2 kg CO2/kWh showed that for ε < 0.87 the nanofluids increased the emissions by ≈16 kg CO2/year, while at ε ≈ 0.92, a reduction of ≈5% was possible. This paper highlights the need to optimize nanofluid viscosity and exchanger geometry to maximize energy and environmental benefits. Nowadays, due to the growing problems of global warming, the analysis of energy efficiency and carbon footprint related to the functioning of a building seems to be crucial. Full article
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8 pages, 1843 KB  
Proceeding Paper
Designing a Sustainable Organic Rankine Cycle for Remote Geothermal Heat Sources in Pakistan
by Muhammad Shoaib Ijaz, Marig Shabbir Ansari, Aftab Sabghatullah, Intesar Alam and Muhammad Qasim Zafar
Mater. Proc. 2025, 23(1), 10; https://doi.org/10.3390/materproc2025023010 - 31 Jul 2025
Viewed by 160
Abstract
This paper discusses a thorough analysis, as well as the design, of an environmentally friendly, single-stage Organic Rankine Cycle (ORC) system, particularly optimized for untapped geothermal applications in Pakistan that are secluded and off-grid, to tackle the severe energy crises choking this country [...] Read more.
This paper discusses a thorough analysis, as well as the design, of an environmentally friendly, single-stage Organic Rankine Cycle (ORC) system, particularly optimized for untapped geothermal applications in Pakistan that are secluded and off-grid, to tackle the severe energy crises choking this country and its resources. Keeping in mind its Global Warming Potential (GWP), as well as its performance in the ORC, r600a was chosen as the operating fluid. This study focuses on varying the temperature, pressure, and mass flow rate of not only the geothermal reservoir but that of the operating fluid in the ORC as well. The impacts of adjusting these parameters on the net power output, cycle efficiency, and component-wise exergy destruction, as well as the total exergy destruction, are examined extensively. Analyses of the component-wise exergy destruction found that the maximum exergy destruction occurred in the evaporator, whereas it was discovered that decreasing the condenser pressure below 350 kPa led to negative exergy destruction values, although the total exergy destruction remained positive. Full article
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28 pages, 9135 KB  
Article
Performance Analysis of a Reciprocating Refrigeration Compressor Under Variable Operating Speeds
by Willian T. F. D. da Silva, Vitor M. Braga and Cesar J. Deschamps
Machines 2025, 13(7), 609; https://doi.org/10.3390/machines13070609 - 15 Jul 2025
Viewed by 563
Abstract
Variable-speed reciprocating compressors (VSRCs) have been increasingly used in domestic refrigeration due to their ability to modulate cooling capacity and reduce energy consumption. A detailed understanding of performance-limiting factors such as volumetric and exergetic inefficiencies is essential for optimizing their operation. An experimentally [...] Read more.
Variable-speed reciprocating compressors (VSRCs) have been increasingly used in domestic refrigeration due to their ability to modulate cooling capacity and reduce energy consumption. A detailed understanding of performance-limiting factors such as volumetric and exergetic inefficiencies is essential for optimizing their operation. An experimentally validated simulation model was developed using GT-SUITE to analyze a VSRC operating with R-600a across speeds from 1800 to 6300 rpm. Volumetric inefficiencies were quantified using a stratification methodology, while an exergy-based approach was adopted to assess the main sources of thermodynamic inefficiency in the compressor. Unlike traditional energy analysis, exergy analysis reveals where and why irreversibilities occur, linking them directly to power consumption and providing a framework for optimizing design. Results reveal that neither volumetric nor exergy efficiency varies monotonically with compressor speed. At low speeds, exergetic losses are dominated by the electrical motor (up to 19% of input power) and heat transfer (up to 13.5%). Conversely, at high speeds, irreversibilities from fluid dynamics become critical, with losses from discharge valve throttling reaching 5.8% and bearing friction increasing to 6.5%. Additionally, key volumetric inefficiencies arise from piston–cylinder leakage, which causes up to a 4.5% loss at low speeds, and discharge valve backflow, causing over a 5% loss at certain resonant speeds. The results reveal complex speed-dependent interactions between dynamic and thermodynamic loss mechanisms in VSRCs. The integrated modeling approach offers a robust framework for diagnosing inefficiencies and supports the development of more energy-efficient compressor designs. Full article
(This article belongs to the Special Issue Theoretical and Experimental Study on Compressor Performance)
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36 pages, 3682 KB  
Article
Enhancing s-CO2 Brayton Power Cycle Efficiency in Cold Ambient Conditions Through Working Fluid Blends
by Paul Tafur-Escanta, Luis Coco-Enríquez, Robert Valencia-Chapi and Javier Muñoz-Antón
Entropy 2025, 27(7), 744; https://doi.org/10.3390/e27070744 - 11 Jul 2025
Viewed by 322
Abstract
Supercritical carbon dioxide (s-CO2) Brayton cycles have emerged as a promising technology for high-efficiency power generation, owing to their compact architecture and favorable thermophysical properties. However, their performance degrades significantly under cold-climate conditions—such as those encountered in Greenland, Russia, Canada, Scandinavia, [...] Read more.
Supercritical carbon dioxide (s-CO2) Brayton cycles have emerged as a promising technology for high-efficiency power generation, owing to their compact architecture and favorable thermophysical properties. However, their performance degrades significantly under cold-climate conditions—such as those encountered in Greenland, Russia, Canada, Scandinavia, and Alaska—due to the proximity to the fluid’s critical point. This study investigates the behavior of the recompression Brayton cycle (RBC) under subzero ambient temperatures through the incorporation of low-critical-temperature additives to create CO2-based binary mixtures. The working fluids examined include methane (CH4), tetrafluoromethane (CF4), nitrogen trifluoride (NF3), and krypton (Kr). Simulation results show that CH4- and CF4-rich mixtures can achieve thermal efficiency improvements of up to 10 percentage points over pure CO2. NF3-containing blends yield solid performance in moderately cold environments, while Kr-based mixtures provide modest but consistent efficiency gains. At low compressor inlet temperatures, the high-temperature recuperator (HTR) becomes the dominant performance-limiting component. Optimal distribution of recuperator conductance (UA) favors increased HTR sizing when mixtures are employed, ensuring effective heat recovery across larger temperature differentials. The study concludes with a comparative exergy analysis between pure CO2 and mixture-based cycles in RBC architecture. The findings highlight the potential of custom-tailored working fluids to enhance thermodynamic performance and operational stability of s-CO2 power systems under cold-climate conditions. Full article
(This article belongs to the Section Thermodynamics)
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19 pages, 1252 KB  
Article
Analogy Analysis of Height Exergy and Temperature Exergy in Energy Storage System
by Yan Cui, Tong Jiang and Mulin Liu
Energies 2025, 18(14), 3675; https://doi.org/10.3390/en18143675 - 11 Jul 2025
Viewed by 314
Abstract
As a pivotal technology and infrastructure component for modern power systems, energy storage has experienced significant advancement in recent years. A fundamental prerequisite for designing future energy storage facilities lies in the systematic evaluation of energy conversion capabilities across diverse storage technologies. This [...] Read more.
As a pivotal technology and infrastructure component for modern power systems, energy storage has experienced significant advancement in recent years. A fundamental prerequisite for designing future energy storage facilities lies in the systematic evaluation of energy conversion capabilities across diverse storage technologies. This study conducted a comparative analysis between pumped hydroelectric storage (PHS) and compressed air energy storage (CAES), defining the concepts of height exergy and temperature exergy. Height exergy is the maximum work capacity of a liquid due to height differences, while temperature exergy is the maximum work capacity of a gas due to temperature differences. The temperature exergy represents innovation in thermodynamic analysis; it is derived from internal exergy and proven through the Maxwell relation and the decoupling method of internal exergy, offering a more efficient method for calculating energy storage capacity in CAES systems. Mathematical models of height exergy and temperature exergy were established based on their respective forms. A unified calculation formula was derived, and their respective characteristics were analyzed. In order to show the meaning of temperature exergy more clearly and intuitively, a height exergy model of temperature exergy was established through analogy analysis, and it was concluded that the shape of the reservoir was a cone when comparing water volume to heat quantity, intuitively showing that the cold source had a higher energy storage density than the heat source. Finally, a typical hybrid PHS–CAES system was proposed, and a mathematical model was established and verified in specific cases based on height exergy and temperature exergy. It was demonstrated that when the polytropic exponent n = 1.2, the theoretical loss accounted for the largest proportion, which was 2.06%. Full article
(This article belongs to the Section D: Energy Storage and Application)
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