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Search Results (224)

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26 pages, 6652 KB  
Article
Advancing the Capability of Additively Manufactured Continuous Fibre-Reinforced Polymers for Structural Applications: The Effect of Nitrogen-Purging and Post-Annealing on the Tensile Performance
by Zizhao Peng, Jiahui Li, Yvonne Durandet, Antonella Sola, Adrian Trinchi, Phuong Tran, Wei Gao, Xuemei Liu and Dong Ruan
Polymers 2025, 17(17), 2314; https://doi.org/10.3390/polym17172314 - 27 Aug 2025
Viewed by 527
Abstract
Additively manufactured continuous fibre-reinforced polymers (CFRPs) offer promising mechanical properties for engineering applications, including aerospace and automotive load-bearing structures. However, challenges such as weak interlayer bonding and low strength compared to traditional composites remain. This paper presents an experimental investigation into the effects [...] Read more.
Additively manufactured continuous fibre-reinforced polymers (CFRPs) offer promising mechanical properties for engineering applications, including aerospace and automotive load-bearing structures. However, challenges such as weak interlayer bonding and low strength compared to traditional composites remain. This paper presents an experimental investigation into the effects of nitrogen (N2) purging during printing and thermal annealing after printing on the tensile performance of additively manufactured CFRPs. Tensile tests were conducted on Onyx specimens produced by material extrusion and reinforced with continuous carbon fibre filaments (CFF), glass fibre filaments (GFF), or Kevlar fibre filaments (KFF). Results showed that N2-purging and post-annealing had different effects on the tensile properties of various CFRPs. Particularly, N2-purging, post-annealing, and their combination enhanced both the Young’s modulus and ultimate tensile strength (UTS) of KFF/Onyx specimens. For GFF/Onyx specimens, both treatments had a minor effect on the Young’s modulus but enhanced UTS. CFF/Onyx specimens exhibited improved Young’s modulus with N2-purging, while both treatments reduced UTS. The different response of the CFRPs was associated with diverse governing failure mechanisms, as proved by microstructural and fracture surface inspection. Additionally, differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analyses also revealed the thermal behaviour and crystal structures that influence the mechanical properties of CFRPs. Full article
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19 pages, 1142 KB  
Article
Comparative Study on Mechanical Performance and Toughness of High-Performance Self-Compacting Concrete with Polypropylene and Basalt Fibres
by Piotr Smarzewski and Anna Jancy
Materials 2025, 18(16), 3833; https://doi.org/10.3390/ma18163833 - 15 Aug 2025
Viewed by 438
Abstract
This study investigates the flexural performance, tensile splitting strength, and fracture behaviour of self-compacting concrete (SCC) reinforced with polypropylene (PP) and basalt (BF) fibres. A total of eleven SCC mixtures with varying fibre types and volume fractions (0.025–0.25%) were tested at 7 and [...] Read more.
This study investigates the flexural performance, tensile splitting strength, and fracture behaviour of self-compacting concrete (SCC) reinforced with polypropylene (PP) and basalt (BF) fibres. A total of eleven SCC mixtures with varying fibre types and volume fractions (0.025–0.25%) were tested at 7 and 28 days. In this study, the term high-performance concrete (HPC) refers to SCC mixtures with a 28-day compressive strength exceeding 60 MPa, as commonly accepted in European standards and literature. The control SCC achieved 68.2 MPa at 28 days. While fibre addition enhanced the tensile and flexural properties, it reduced workability, demonstrating the trade-off between mechanical performance and flowability in high-performance SCC. The experimental results demonstrate that both fibre types improve the tensile behaviour of SCC, with distinct performance patterns. PP fibres, owing to their flexibility and crack-bridging capability, were particularly effective at early ages, enhancing the splitting tensile strength by up to 45% and flexural toughness by over 300% at an optimal dosage of 0.125%. In contrast, BF fibres significantly increased the 28-day toughness (up to 15.7 J) and post-cracking resistance due to their superior stiffness and bonding with the matrix. However, high fibre contents adversely affected workability, particularly in BF-reinforced mixes. The findings highlight a dosage-sensitive behaviour, with optimum performance observed at 0.05–0.125% for PP and 0.125–0.25% for BF. While PP fibres improve crack distribution and early-age ductility, BF fibres offer higher stiffness and energy absorption in post-peak regimes. Statistical analysis (ANOVA and Tukey’s test) confirmed significant differences in the mechanical performance among fibre-reinforced mixes. The study provides insights into selecting appropriate fibre types and dosages for SCC structural applications. Further research on hybrid fibre systems and long-term durability is recommended. The results contribute to sustainable concrete design by promoting enhanced performance with low-volume, non-metallic fibres. Full article
(This article belongs to the Special Issue Advances in Modern Cement-Based Materials for Composite Structures)
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40 pages, 2174 KB  
Review
Bridging Genes and Sensory Characteristics in Legumes: Multi-Omics for Sensory Trait Improvement
by Niharika Sharma, Soumi Paul Mukhopadhyay, Dhanyakumar Onkarappa, Kalenahalli Yogendra and Vishal Ratanpaul
Agronomy 2025, 15(8), 1849; https://doi.org/10.3390/agronomy15081849 - 31 Jul 2025
Viewed by 1307
Abstract
Legumes are vital sources of protein, dietary fibre and nutrients, making them crucial for global food security and sustainable agriculture. However, their widespread acceptance and consumption are often limited by undesirable sensory characteristics, such as “a beany flavour”, bitterness or variable textures. Addressing [...] Read more.
Legumes are vital sources of protein, dietary fibre and nutrients, making them crucial for global food security and sustainable agriculture. However, their widespread acceptance and consumption are often limited by undesirable sensory characteristics, such as “a beany flavour”, bitterness or variable textures. Addressing these challenges requires a comprehensive understanding of the complex molecular mechanisms governing appearance, aroma, taste, flavour, texture and palatability in legumes, aiming to enhance their sensory appeal. This review highlights the transformative power of multi-omics approaches in dissecting these intricate biological pathways and facilitating the targeted enhancement of legume sensory qualities. By integrating data from genomics, transcriptomics, proteomics and metabolomics, the genetic and biochemical networks that directly dictate sensory perception can be comprehensively unveiled. The insights gained from these integrated multi-omics studies are proving instrumental in developing strategies for sensory enhancement. They enable the identification of key biomarkers for desirable traits, facilitating more efficient marker-assisted selection (MAS) and genomic selection (GS) in breeding programs. Furthermore, a molecular understanding of sensory pathways opens avenues for precise gene editing (e.g., using CRISPR-Cas9) to modify specific genes, reduce off-flavour compounds or optimise texture. Beyond genetic improvements, multi-omics data also inform the optimisation of post-harvest handling and processing methods (e.g., germination and fermentation) to enhance desirable sensory profiles and mitigate undesirable ones. This holistic approach, spanning from the genetic blueprint to the final sensory experience, will accelerate the development of new legume cultivars and products with enhanced palatability, thereby fostering increased consumption and ultimately contributing to healthier diets and more resilient food systems worldwide. Full article
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11 pages, 1578 KB  
Article
Impact of Hydrofluoric Acid, Ytterbium Fiber Lasers, and Hydroxyapatite Nanoparticles on Surface Roughness and Bonding Strength of Resin Cement with Different Viscosities to Lithium Disilicate Glass Ceramic: SEM and EDX Analysis
by Abdullah Aljamhan and Fahad Alkhudhairy
Crystals 2025, 15(7), 661; https://doi.org/10.3390/cryst15070661 - 20 Jul 2025
Cited by 1 | Viewed by 404
Abstract
This study looks at the effect of surface conditioners hydrofluoric acid (HFA), Ytterbium fibre laser (YFL), and Hydroxyapatite nanoparticles (HANPs) on the surface roughness (Ra) and shear bond strength (SBS) of different viscosity resin cements to lithium disilicate glass ceramic (LDC). A total [...] Read more.
This study looks at the effect of surface conditioners hydrofluoric acid (HFA), Ytterbium fibre laser (YFL), and Hydroxyapatite nanoparticles (HANPs) on the surface roughness (Ra) and shear bond strength (SBS) of different viscosity resin cements to lithium disilicate glass ceramic (LDC). A total of 78 IPS Emax discs were prepared and categorized into groups based on conditioning methods. Group 1 HFA–Silane (S), Group 2: YFL-S, and Group 3: HANPs-S. A scanning electron microscope (n = 1) and profilometer (n = 5) were used on each conditioned group for the assessment of surface topography and Ra. A total of 20 LDC discs for each conditioned group were subsequently categorized into two subgroups based on the application of high- and low-viscosity dual-cured resin cement. SBS and failure mode were assessed. ANOVA and post hoc Tukey tests were employed to identify significant differences in Ra and SBS among different groups. LDC conditioned with HFA-S, HANPs-S, and YFL-S demonstrated comparable Ra scores (p > 0.05). Also, irrespective of the type of conditioning regime, the use of low-viscosity cement improves bond values when bonded to the LDC. LDC treated with YFL-S and HANPs-S can serve as an effective substitute for HFA-S in enhancing the Ra and surface characteristics of LDC. The low-viscosity resin cement demonstrated superior performance by achieving greater bond strength. Full article
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22 pages, 826 KB  
Review
Inactivation of Emerging Opportunistic Foodborne Pathogens Cronobacter spp. and Arcobacter spp. on Fresh Fruit and Vegetable Products: Effects of Emerging Chemical and Physical Methods in Model and Real Food Systems—A Review
by Junior Bernardo Molina-Hernandez, Beatrice Cellini, Fatemeh Shanbeh Zadeh, Lucia Vannini, Pietro Rocculi and Silvia Tappi
Foods 2025, 14(14), 2463; https://doi.org/10.3390/foods14142463 - 14 Jul 2025
Viewed by 945
Abstract
The consumption of fresh fruit and vegetables is essential for a healthy diet as they contain a diverse composition of vitamins, minerals, fibre, and bioactive compounds. However, cross-contamination during harvest and post-harvest poses a high risk of microbial contamination. Therefore, handling fruit and [...] Read more.
The consumption of fresh fruit and vegetables is essential for a healthy diet as they contain a diverse composition of vitamins, minerals, fibre, and bioactive compounds. However, cross-contamination during harvest and post-harvest poses a high risk of microbial contamination. Therefore, handling fruit and vegetables during processing and contact with wet equipment and utensil surfaces is an ideal environment for microbial contamination and foodborne illness. Nevertheless, less attention has been paid to some emerging pathogens that are now increasingly recognised as transmissible to humans through contaminated fruit and vegetables, such as Arcobacter and Cronobacter species in various products, which are the main risk in fruit and vegetables. Cronobacter and Arcobacter spp. are recognised food-safety hazards because they pose a risk of foodborne disease, especially in vulnerable groups such as newborns and immunocompromised individuals. Cronobacter spp. have been linked to severe infant conditions—notably meningitis and sepsis—most often traced to contaminated powdered infant formula. Although Arcobacter spp. have been less extensively studied, they have also been associated with foodborne disease, chiefly from dairy products and meat. With this in mind, this review provides an overview of the main chemical and physical sanitisation methods in terms of their ability to reduce the contamination of fresh fruit and vegetable products caused by two emerging pathogens: Arcobacter and Cronobacter. Emerging chemical (organic acid compounds, extracts, and essential oils) and physical methods (combination of UV-C with electrolysed water, ultrasound, and cold atmospheric plasma) offer innovative and environmentally friendly alternatives to traditional approaches. These methods often utilise natural materials, less toxic solvents, and novel techniques, resulting in more sustainable processes compared with traditional methods that may use harsh chemicals and environmentally harmful processes. This review provides the fruit and vegetable industry with a general overview of possible decontamination alternatives to develop optimal and efficient processes that ensure food safety. Full article
(This article belongs to the Section Food Engineering and Technology)
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17 pages, 946 KB  
Article
Analysis of Fatigue and Residual Strength Estimation of Polymer Matrix Composites Using the Theory of the Markov Chain Method
by Rafał Chatys, Mariusz Kłonica and Ilmars Blumbergs
Materials 2025, 18(14), 3229; https://doi.org/10.3390/ma18143229 - 8 Jul 2025
Viewed by 405
Abstract
This paper deals with an important issue, which is the influence of failure caused by the quality of matrix post-curing on the strength of complex and difficult materials of the “new generation” such as fibre composites, particularly with a polymer matrix. In recent [...] Read more.
This paper deals with an important issue, which is the influence of failure caused by the quality of matrix post-curing on the strength of complex and difficult materials of the “new generation” such as fibre composites, particularly with a polymer matrix. In recent years, significant advances in the field of adhesive materials chemistry have led to the constant development of bonding technology. The effectiveness of bonding depends, to a large extent, on the suitable selection of the adhesive and the use of appropriate surface treatment technology. It is difficult to imagine virtually any modern industry without adhesive joints, be it the aircraft, aerospace or automotive industries, which simultaneously highlights the great importance of adhesives and adhesive materials for the present-day economy. In modern technology, it is extremely important to obtain the right combination of modern construction materials. The statistical analysis of the components showed the complexity of the layered composite structure. The proposed model of the weakest micro-volume developed in this study indirectly reflects the experimentally based curing variables that affect the stresses of the components in the composite (laminate) structure. The strength of fibrous composite structures based on the Markov chain theory considers technological aspects during hardening. The model proposed in the paper was validated on the basis of examples from the literature and experimental data obtained in the research project. The numerical results are in good agreement with the literature database and measurement data. The presented model could be a novel method, which allows better insight into the curing process of epoxy resins. Full article
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16 pages, 1753 KB  
Article
Impact of Malt Bagasse Silage on Fungal Diversity, Fusarium Species, and Mycotoxin Contamination Under a Circular Economy Approach to Climate Change Mitigation
by Tania Valicenti, Carolina Manno, Juan Ignacio Poo, María Inés Dinolfo, Mauro Martínez and Andrea Enriquez
J. Fungi 2025, 11(7), 505; https://doi.org/10.3390/jof11070505 - 4 Jul 2025
Viewed by 819
Abstract
Malt bagasse is the primary solid waste product from the brewing process, with notable environmental implications. Due to its nutritional value, it has potential as animal feed, primarily through ensilage. Alfalfa pellets can enhance this silage by adding digestible nitrogen and fibre. However, [...] Read more.
Malt bagasse is the primary solid waste product from the brewing process, with notable environmental implications. Due to its nutritional value, it has potential as animal feed, primarily through ensilage. Alfalfa pellets can enhance this silage by adding digestible nitrogen and fibre. However, the high moisture content favours microbial contamination, particularly by fungi like Fusarium, which produces harmful mycotoxins. This study evaluated the impact of winter silage on fungal diversity, Fusarium presence, and mycotoxin contamination in malt bagasse, comparing the pre- and post-silage stages with the addition of alfalfa pellets. Results showed a diverse range of fungi, including Mucor, Cladosporium, Fusarium, and Penicillium, as well as yeasts. Fungal contamination was higher before silage, although the addition of alfalfa increased it after silage was produced. Fusarium verticillioides was the most common Fusarium species. Mycotoxin analysis detected DON (1.4 ppb) in only one sample. A two-month winter silage process under cold-temperate conditions appears to reduce fungal contamination and preserve feed quality. These findings support silage as a circular strategy to manage brewery waste safely, but further research and policy measures are needed to minimise biological risks in the brewing and livestock sectors amid climate change. Full article
(This article belongs to the Special Issue Fusarium in Crops Under Climate Change Scenarios)
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31 pages, 810 KB  
Protocol
Protocol for a Trial to Assess the Efficacy and Applicability of Isometric Strength Training in Older Adults with Sarcopenia and Dynapenia
by Iker López, Juan Mielgo-Ayuso, Juan Ramón Fernández-López, Jose M. Aznar and Arkaitz Castañeda-Babarro
Healthcare 2025, 13(13), 1573; https://doi.org/10.3390/healthcare13131573 - 1 Jul 2025
Cited by 1 | Viewed by 855
Abstract
Background: Sarcopenia (loss of muscle mass) and dynapenia (loss of strength) are prevalent in older adults aged 70 years and over. Both have an impact on their functional ability and quality of life, with type II muscle fibres being particularly affected. Although traditional [...] Read more.
Background: Sarcopenia (loss of muscle mass) and dynapenia (loss of strength) are prevalent in older adults aged 70 years and over. Both have an impact on their functional ability and quality of life, with type II muscle fibres being particularly affected. Although traditional resistance training (TRT) is effective, it presents technical difficulties and an increased risk of injury among this vulnerable population. Isometric strength training (IST) is a potentially safer, more accessible and more effective alternative. Objective: To describe the protocol of a single-arm, pre-post intervention trial designed to evaluate the efficacy and applicability of a 16-week IST programme on muscle strength, skeletal muscle mass, quality of life and applicability (safety, acceptability, perceived difficulty) in 18 older adults aged 70 years and above with a diagnosis of sarcopenia and dynapenia. The influence of genetic and environmental factors on the variability of response to IST will also be explored. Methodology: The participants, who have all been diagnosed with sarcopenia according to EWGSOP2 (European Working Group on Sarcopenia in Older People 2) criteria, will perform two IST sessions per week for 16 weeks. Each 30-min session will consist of one progressive set (total duration 45 s to 90 s) for each of the eight major muscle groups. This series will include phases at 20% and 40% of individual Maximal Voluntary Isometric Contraction (MVIC), culminating in 100% Maximal Effort (ME), using the CIEX SYSTEM machine with visual feedback. The primary outcome variables will be: change in knee extensor MVIC and change in Appendicular Skeletal Muscle Mass Index (ASMMI). Secondary variables will be measured (other components of sarcopenia, quality of life by EQ-5D-5L, use of Likert scales, posture and physiological variables), and saliva samples will be collected for exploratory genetic analyses. The main statistical analyses will be performed with t-tests for related samples or their non-parametric analogues. Discussion: This protocol details a specific IST intervention and a comprehensive evaluation plan. The results are expected to provide evidence on the feasibility and effects of IST among older adults with sarcopenia and dynapenia. Understanding individual variability in response, including genetic influence, could inform the design of more personalised and effective exercise strategies for this population in the future. Full article
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26 pages, 3697 KB  
Review
Chloride-Induced Corrosion Effects on the Structural Performance of Concrete with Rebar and Fibres: A Review
by Petar Bajić, Bruno Leporace-Guimil, Carmen Andrade, Nikola Tošić and Albert de la Fuente
Appl. Sci. 2025, 15(12), 6457; https://doi.org/10.3390/app15126457 - 8 Jun 2025
Cited by 1 | Viewed by 1646
Abstract
Chloride-induced corrosion is a major contributor in the degradation of standardised steel-based products (e.g., rebars and fibres) commonly used for reinforcing concrete structures. Since cracked reinforced concrete elements are determined to be more susceptible to corrosion on the one hand, and fibres are [...] Read more.
Chloride-induced corrosion is a major contributor in the degradation of standardised steel-based products (e.g., rebars and fibres) commonly used for reinforcing concrete structures. Since cracked reinforced concrete elements are determined to be more susceptible to corrosion on the one hand, and fibres are effective in arresting crack growth and improving the post-cracking mechanical behaviour on the other hand, the use of fibres emerges as a promising strategy to enhance durability. This review is focused on the degradation of the load-bearing capacity, caused by chloride corrosion, in concrete elements reinforced with fibres and conventional rebar. Based on the recorded values of ultimate loads and the corresponding deflections in the reviewed studies, a lower decrease in the load-bearing capacity and less severe degradation of ductility were observed in elements where fibres (either steel or macro-synthetic) were used in combination with rebar compared with elements where only rebar was used. Furthermore, the recorded values of corrosion potential (Ecorr), corrosion current density (icorr) and gravimetric measurements indicated lower corrosion damage, delayed corrosion initiation and a prolonged propagation phase of corrosion. However, due to many differences in the methodology among the reviewed studies, the optimal fibre type or quantity cannot be identified unless more studies are performed. Full article
(This article belongs to the Special Issue Fiber-Reinforced Concrete: Recent Progress and Future Directions)
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14 pages, 1360 KB  
Article
Fracture Mechanics-Based Modelling of Post-Installed Adhesive FRP Composite Anchors in Structural Concrete Applications
by Amir Mofidi and Mona Rajabifard
J. Compos. Sci. 2025, 9(6), 282; https://doi.org/10.3390/jcs9060282 - 31 May 2025
Viewed by 513
Abstract
Adhesively bonded fibre-reinforced polymer (FRP) anchors have emerged as a progressive alternative to traditional steel anchors in concrete structures, owing to their superior corrosion resistance, high tensile strength, and light weight. Despite their increasing use, a robust mechanics-based bond model capable of accurately [...] Read more.
Adhesively bonded fibre-reinforced polymer (FRP) anchors have emerged as a progressive alternative to traditional steel anchors in concrete structures, owing to their superior corrosion resistance, high tensile strength, and light weight. Despite their increasing use, a robust mechanics-based bond model capable of accurately predicting the load transfer behaviour has not yet been developed. This study presents a fracture mechanics-based analytical bond model for post-installed adhesive FRP anchors embedded in concrete. The model formulation is derived from fundamental equilibrium and compatibility principles, incorporating a bilinear bond–slip law that captures both elastic and softening behaviours. A new expression for the effective bond length is also proposed. Validation of the model against a comprehensive database of direct pull-out tests reported in the literature shows excellent agreement between predicted and experimental pull-out forces (R2 = 0.980; CoV = 0.058). Future research should aim to extend the proposed model to account for confinement effects, long-term durability, the impact of adhesive type, and cyclic loading conditions. Full article
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50 pages, 1936 KB  
Review
Triathlon: Ergo Nutrition for Training, Competing, and Recovering
by Álvaro Miguel-Ortega, María-Azucena Rodríguez-Rodrigo, Juan Mielgo-Ayuso and Julio Calleja-González
Nutrients 2025, 17(11), 1846; https://doi.org/10.3390/nu17111846 - 28 May 2025
Viewed by 3461
Abstract
Triathlon is a multi-sport event that combines swimming, cycling and running. The distances vary and the physiological demands are high. Objectives: This review compiles information on nutritional strategies and ergogenic supplements for triathlon training, competition and recovery. It aims to provide an [...] Read more.
Triathlon is a multi-sport event that combines swimming, cycling and running. The distances vary and the physiological demands are high. Objectives: This review compiles information on nutritional strategies and ergogenic supplements for triathlon training, competition and recovery. It aims to provide an understanding of the specific challenges and needs of the sport to help triathletes and coaches optimise performance through effective training and nutrition plans. Methods: English-language publications were searched using the keywords triathlon, nutrition, recovery and ergogenic aids, alone or in combination, in databases. Results: Maintaining good glycogen levels, consuming enough carbohydrates and staying properly hydrated are key to athletic performance, especially for triathletes. Education regarding nutrition, the role of probiotics and supplements, and diet modification for the enhancement of performance and recovery are pivotal considerations. Conclusions: Triathletes are at risk of RED-S due to negative energy balance and high fibre/plant protein diets, especially women. Optimising muscle glycogen through tailored diet and training, especially pre- and in-race nutrition, including carbohydrate loading and hydration strategies, is critical. Education is needed to improve post-exercise nutrition, while probiotics and certain supplements may aid performance and recovery. Dietary support is important for resistance training to optimise performance and recovery. Full article
(This article belongs to the Special Issue New Strategies in Sport Nutrition: Enhancing Exercise Performance)
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36 pages, 4890 KB  
Article
Pulmonary Toxicity of Long, Thick MWCNT and Very Long, Thin Carboxylated MWCNT Aerosols Following 28 Days Whole-Body Exposure
by Chang Guo, Matthew D. Wright, Alison Buckley, Adam Laycock, Trine Berthing, Ulla Vogel, Frédéric Cosnier, Laurent Gaté, Martin O. Leonard and Rachel Smith
Toxics 2025, 13(5), 401; https://doi.org/10.3390/toxics13050401 - 16 May 2025
Cited by 1 | Viewed by 814
Abstract
Pulmonary exposure to carbon nanotubes (CNTs) has been linked to a series of adverse respiratory effects in animal models, including inflammation, genotoxicity, fibrosis, and granuloma formation, the degree and characteristics of which are considered dependent upon the detailed physicochemical properties of the material [...] Read more.
Pulmonary exposure to carbon nanotubes (CNTs) has been linked to a series of adverse respiratory effects in animal models, including inflammation, genotoxicity, fibrosis, and granuloma formation, the degree and characteristics of which are considered dependent upon the detailed physicochemical properties of the material as inhaled. To further explore the effect of variations in physicochemical properties on pulmonary effects, two different multi-walled CNTs (MWCNTs) were tested in vivo: a pristine MWCNT (pMWCNT) (NM-401) and a surface-modified MWCNT (MWCNT-COOH). Female Sprague–Dawley rats were whole-body exposed for 28 days to MWCNT aerosols (pMWCNT (0.5 and 1.5 mg/m3) and MWCNT-COOH (1.5 and 4.5 mg/m3)) and followed up to 1 year post-exposure. The inhalation exposures resulted in relatively low estimated lung deposition. Bronchoalveolar lavage fluid (BALF) analysis indicated inflammation levels broadly consistent with deposited dose levels. Lung histopathology indicated that both MWCNTs produced very limited toxicological effects; however, global mRNA expression levels in lung tissue and BALF cytokines indicated different characteristics for the two MWCNTs. For example, pMWCNT but not MWCNT-COOH exposure induced osteopontin production, suggestive of potential pre-fibrosis/fibrosis effects linked to the higher aspect ratio aerosol particles. This is of concern as brightfield and enhanced darkfield microscopy indicated the persistence of pMWCNT fibres in lung tissue. Full article
(This article belongs to the Section Human Toxicology and Epidemiology)
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24 pages, 15226 KB  
Article
Effect of Yarn-Level Fibre Hybridisation on Thermomechanical Behaviour of 3D Woven Orthogonal Flax/E-Glass Composite Laminae
by Nenglong Yang, Zhenmin Zou, Constantinos Soutis, Prasad Potluri and Kali Babu Katnam
J. Compos. Sci. 2025, 9(3), 135; https://doi.org/10.3390/jcs9030135 - 13 Mar 2025
Viewed by 957
Abstract
This study investigates the novel role of yarn-level fibre hybridisation in tailoring thermomechanical properties and thermal residual stress (TRS) fields in the resin at both micro- and meso-scales of 3D orthogonal-woven flax/E-glass hybrid composites. Unlike previous studies, which primarily focus on macro-scale composite [...] Read more.
This study investigates the novel role of yarn-level fibre hybridisation in tailoring thermomechanical properties and thermal residual stress (TRS) fields in the resin at both micro- and meso-scales of 3D orthogonal-woven flax/E-glass hybrid composites. Unlike previous studies, which primarily focus on macro-scale composite behaviour, this work integrates a two-scale homogenisation scheme. It combines microscale representative volume element (RVE) models and mesoscale repeating unit cell (RUC) models to capture the effects of hybridisation from the fibre to lamina scale. The analysis specifically examines the cooling phase from a curing temperature of 100 °C down to 20 °C, where TRS develops due to thermal expansion mismatches. Microstructures are generated employing a random sequential expansion algorithm for RVE models, while weave architecture is generated using the open-source software TexGen 3.13.1 for RUC models. Results demonstrate that yarn-level hybridisation provides a powerful strategy to balance mechanical performance, thermal stability, and residual stress control, revealing its potential for optimising composite design. Stress analysis indicates that under in-plane tensile loading, stress levels in matrix-rich regions remain below 1 MPa, while binder yarns exhibit significant stress concentration, reaching up to 8.71 MPa under shear loading. The study quantifies how varying fibre hybridisation ratios influence stiffness, thermal expansion, and stress concentrations—bridging the gap between microstructural design and macroscopic composite performance. These findings highlight the potential of yarn-level fibre hybridisation in tailoring thermomechanical properties of yarns and laminae. The study also demonstrates its effectiveness in reducing TRS in composite laminae post-manufacturing. Additionally, hybridisation allows for adjusting density requirements, making it suitable for applications where weight and thermal properties are critical. Full article
(This article belongs to the Section Fiber Composites)
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17 pages, 5843 KB  
Article
An In Situ Characterisation Method for 3-D Electrospun Foams
by Kyriakos Almpanidis, Chloe J. Howard and Vlad Stolojan
Nanomaterials 2025, 15(5), 339; https://doi.org/10.3390/nano15050339 - 22 Feb 2025
Viewed by 1263
Abstract
Three-dimensional electrospun foams are emerging in a diversity of applications. However, their characterisation involves procedures to calculate fibre diameter and porosity, which take considerable time. Hence, in this paper, an in situ characterisation method is presented based on signal features of the grounding [...] Read more.
Three-dimensional electrospun foams are emerging in a diversity of applications. However, their characterisation involves procedures to calculate fibre diameter and porosity, which take considerable time. Hence, in this paper, an in situ characterisation method is presented based on signal features of the grounding voltage. These features are combined into the in situ evaluation parameter Sr for each run r. The L9 Taguchi method was utilised to minimise the total number of experiments. Moreover, to prove the accuracy of this method, the traditional post-fabrication analysis was conducted, and the post-fabrication evaluation parameter was retrieved Qr for each run r. The analysis shows that both parameters detected the same experiment run as the optimal one (with an adjusted R2 = 0.84) for polystyrene electrospun foams for two solution concentrations: 15%wv (run 3 with mean S3 = 54.49 and mean Q3 = 0.248) and 20%wv (mean S5 = 2.49 and Q5 = 0.248), respectively. Also, the statistical analysis shows low standard deviations for the optimal and near-optimal runs, proving the method’s repeatability. Furthermore, a theoretical explanation is provided for selecting signal features based on the Maxwellian equivalent circuit approach for the electrospun jet. Finally, this fast in situ evaluation method can replace the post-fabrication time-consuming one. It can be used as a fundamental step for an intelligent artificial intelligence tool that predicts optimal foam formation. Full article
(This article belongs to the Section Nanofabrication and Nanomanufacturing)
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14 pages, 950 KB  
Review
Biological Guardians: Unveiling Microbial Solutions to Combat Cannabis sativa Fungal Pathogens
by S. M. Ahsan, Md. Injamum-Ul-Hoque, Ashim Kumar Das, Muhammad Imran, Soosan Tavakoli, Da Bin Kwon, Sang-Mo Kang, In-Jung Lee and Hyong Woo Choi
Stresses 2025, 5(1), 16; https://doi.org/10.3390/stresses5010016 - 17 Feb 2025
Cited by 3 | Viewed by 1590
Abstract
Cannabis (Cannabis sativa L.) is one of the earliest cultivated crops and is valued for its medicinal compounds, food, fibre, and bioactive secondary metabolites. The rapid expansion of the cannabis industry has surpassed the development of production system knowledge. The scientific community [...] Read more.
Cannabis (Cannabis sativa L.) is one of the earliest cultivated crops and is valued for its medicinal compounds, food, fibre, and bioactive secondary metabolites. The rapid expansion of the cannabis industry has surpassed the development of production system knowledge. The scientific community currently focuses on optimising agronomic and environmental factors to enhance cannabis yield and quality. However, cultivators face significant challenges from severe pathogens, with limited effective control options. The principal diseases include root rot, wilt, bud rot, powdery mildew, cannabis stunt disease, and microorganisms that reduce post-harvest quality. Sustainable management strategies involve utilising clean planting stocks, modifying environmental conditions, implementing sanitation, applying fungal and bacterial biological control agents, and drawing on decades of research on other crops. Plant–microbe interactions can promote growth and regulate secondary metabolite production. This review examines the recent literature on pathogen management in indoor cannabis production using biocontrol agents. Specific morphological, biochemical, and agronomic characteristics hinder the implementation of biological control strategies for cannabis. Subsequent investigations should focus on elucidating the plant–microbe interactions essential for optimising the effectiveness of biological control methodologies in cannabis cultivation systems. Full article
(This article belongs to the Collection Feature Papers in Plant and Photoautotrophic Stresses)
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