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Keywords = flexural tensile stress

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28 pages, 7145 KB  
Article
Mechanical Properties of a New Type of Link Slab for Simply Supported Steel–Concrete Composite Bridges
by Liang Xiao, Qingtian Su and Qingquan Wang
Appl. Sci. 2025, 15(19), 10851; https://doi.org/10.3390/app151910851 - 9 Oct 2025
Abstract
This study investigates the mechanical behavior of a new type of link slab through experimental testing and numerical simulation. A full-scale segmental specimen of an I-shaped steel–concrete composite beam was designed, and a vertical active plus horizontal follow-up loading system was employed to [...] Read more.
This study investigates the mechanical behavior of a new type of link slab through experimental testing and numerical simulation. A full-scale segmental specimen of an I-shaped steel–concrete composite beam was designed, and a vertical active plus horizontal follow-up loading system was employed to realistically simulate the stress state of the link slab. In parallel, a nonlinear finite element model was established in ABAQUS to validate and extend the experimental findings. Test results indicate that the link slab exhibits favorable static performance with a ductile flexural tensile failure mode. At ultimate load, tensile reinforcement yielded while compressive concrete remained uncrushed, demonstrating high safety reserves. Cracks propagated primarily in the transverse direction, showing a typical flexural tensile cracking pattern. The maximum crack width was limited to 0.4 mm and remained confined within the link slab region, which is beneficial for long-term durability, maintenance, and repair. The FE model successfully reproduced the experimental process, accurately capturing both the crack development and the ultimate bending capacity of the slab. The findings highlight the reliability of the proposed structural system, demonstrate that maximum crack width can be evaluated as an eccentric tension member, and confirm that bending capacity may be assessed using existing design specifications. Full article
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23 pages, 5519 KB  
Article
A Study on the Early-Stage Mechanical Properties and Uniaxial Compression Constitutive Model of Coral Concrete with Polyoxymethylene Fiber
by Jing Wang, Wenchong Shan and Lipeng Tan
Buildings 2025, 15(18), 3344; https://doi.org/10.3390/buildings15183344 - 15 Sep 2025
Viewed by 324
Abstract
To investigate the regulatory mechanism of polyoxymethylene (POM) fiber on the workability and mechanical properties of C30-grade coral aggregate concrete (CAC), this study designed six groups of CAC specimens with varying POM fiber volume fractions (0%, 0.2%, 0.4%, 0.6%, 0.8%, and 1.0%). Cube [...] Read more.
To investigate the regulatory mechanism of polyoxymethylene (POM) fiber on the workability and mechanical properties of C30-grade coral aggregate concrete (CAC), this study designed six groups of CAC specimens with varying POM fiber volume fractions (0%, 0.2%, 0.4%, 0.6%, 0.8%, and 1.0%). Cube compressive test, axial compressive test, split tensile test, and flexural tests of CAC specimens after 28 days of curing were conducted, while observing their failure modes under ultimate load and stress–strain curves. The experimental results indicate that POM fiber incorporation significantly reduced the slump and slump flow of the CAC mixtures. The cube compressive strength, axial compressive strength, split tensile strength, and flexural strength of CAC initially increased and then decreased with increasing POM fiber volume fraction, peaking at 0.6% fiber content. Compared to the fiber-free group, these properties improved by 14.78%, 15.50%, 17.01%, 46.13%, and 3.69%, respectively. Analysis of failure modes under ultimate load revealed that POM fibers effectively reduced crack quantity and main crack width, producing a favorable bridging effect that promoted a transition from brittle fracture to ductile failure. However, when fiber volume fraction exceeded 0.8%, fiber agglomeration led to diminished mechanical performance. Based on experimental data, the constitutive relationship established using the Carreira and Chu model achieved a goodness-of-fit exceeding 0.99 for CAC stress–strain curves, effectively predicting mechanical behavior and providing theoretical support for marine engineering applications of coral aggregate concrete. This study provides a theoretical basis for exploiting coral aggregates as low-carbon resources, promoting CAC application in marine engineering, and leveraging POM fibers’ reinforcement of CAC to reduce reliance on high-carbon cement. Combined with coral aggregates’ local availability (cutting transportation emissions), it offers a technical pathway for marine engineering material preparation. Full article
(This article belongs to the Special Issue Research on the Crack Control of Concrete)
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31 pages, 7277 KB  
Article
Multi-Performance Evolution and Elasto-Plastic Damage Modeling of Basalt Fiber-Reinforced EPS Geopolymer Lightweight Concrete
by Feng Liang, Qingshun Yang and Jutao Tao
Polymers 2025, 17(18), 2471; https://doi.org/10.3390/polym17182471 - 12 Sep 2025
Viewed by 496
Abstract
To elucidate the multi-performance evolution mechanisms of basalt fiber-reinforced lightweight expanded polystyrene geopolymer concrete (LEGC), a two-tiered investigation was conducted. In the first part, a series of LEGC mixtures with varying volume fractions of EPS (10–40%) and basalt fiber (BF) (0.4–0.8%) were designed. [...] Read more.
To elucidate the multi-performance evolution mechanisms of basalt fiber-reinforced lightweight expanded polystyrene geopolymer concrete (LEGC), a two-tiered investigation was conducted. In the first part, a series of LEGC mixtures with varying volume fractions of EPS (10–40%) and basalt fiber (BF) (0.4–0.8%) were designed. Experimental tests were carried out to evaluate density, flowability, compressive strength, flexural strength, and splitting tensile strength. Crack propagation behavior was monitored using DIC-3D speckle imaging. Additionally, X-ray CT scanning revealed the internal clustering of EPS particles, porosity distribution, and crack connectivity within LEGC specimens, while SEM analysis confirmed the bridging effect of basalt fibers and the presence of dense matrix regions. These microstructural observations verified the consistency between the synergistic effects of EPS weakening and fiber reinforcement at the microscale and the macroscopic failure behavior. The results indicated that increasing EPS content led to reduced mechanical strength, whereas the reinforcing effect of basalt fiber followed a rising-then-falling trend. Among all specimens, LEGC20BF06 exhibited the best comprehensive performance, achieving a compressive strength of 40.87 MPa and a density of 1747.6 kg/m3, thus meeting the criteria for structural lightweight concrete. In the second part, based on the experimental data, predictive models were developed for splitting tensile and flexural strengths using compressive strength as a reference, as well as a dual-factor model incorporating EPS and fiber contents. Both models were validated and demonstrated high predictive accuracy. Furthermore, a splitting tensile elasto-plastic damage constitutive model was proposed based on composite mechanics and energy dissipation theory. The model showed excellent agreement with experimental stress–strain curves, with all fitting coefficients of determination (R2) exceeding 0.95. These findings offer robust theoretical support for the performance optimization of LEGC and its application in green construction and prefabricated structural systems. Full article
(This article belongs to the Special Issue Fiber-Reinforced Polymer Composites: Progress and Prospects)
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15 pages, 2800 KB  
Article
Repairable, Degradable and Recyclable Carbon Fiber-Reinforced Bio-Based Epoxy Vitrimer Composites Enabled by Facile Transesterification
by Haidan Lin, Kai Dong, Jingyao Luan, Chenggang Li, Di Zhao, Chengji Zhao and Xuefeng Li
Polymers 2025, 17(17), 2387; https://doi.org/10.3390/polym17172387 - 31 Aug 2025
Viewed by 1119
Abstract
Developing high-performance bio-based epoxy resins as sustainable alternatives to petroleum-derived bisphenol A (BPA) epoxies for recyclable carbon fiber-reinforced polymers (CFRPs) is pivotal in materials research. Herein, the bio-based bisphenol monomer BDEF was synthesized from the lignin derivative 4-propylguaiacol. The derived epoxy monomer BDEF-EP [...] Read more.
Developing high-performance bio-based epoxy resins as sustainable alternatives to petroleum-derived bisphenol A (BPA) epoxies for recyclable carbon fiber-reinforced polymers (CFRPs) is pivotal in materials research. Herein, the bio-based bisphenol monomer BDEF was synthesized from the lignin derivative 4-propylguaiacol. The derived epoxy monomer BDEF-EP was cured with adipic acid to form a bio-based vitrimer. Stress relaxation synergistically accelerates through intrinsic dynamic carboxylic acid ester exchange and enhanced chain mobility from the flexible propyl structure. At 220 °C, this vitrimer shows rapid stress relaxation (τ* < 30 s) and repairs ~90% of surface scratches in 30 min. It exhibits tensile and flexural strengths of 69 MPa and 105 MPa, respectively. BDEF-EP’s low viscosity reduces diluent needs in composite fabrication, lowering costs and improving efficiency. The resulting bio-based CFRP achieves tensile and flexural strengths of 543 MPa and 414 MPa, respectively, which are comparable to commercially available petroleum-derived CFRP. In addition, CFRP containing dynamic crosslinked networks demonstrates degradable recyclability in ethylene glycol solvent, preserving the surface morphology and chemical structure of recovered carbon fibers. The results demonstrate that this bio-based epoxy vitrimer has promising potential for developing sustainable, degradable, and recyclable CFRP composites. Full article
(This article belongs to the Special Issue Epoxy Resins and Epoxy-Based Composites: Research and Development)
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23 pages, 6505 KB  
Article
Study of the Equivalent Stiffness of a Non-Contact Piezoelectric Actuator’s Micro-Displacement Amplification Mechanism
by Huaiyong Li, Dongya Zhang, Yusheng Lin, Yue Yang, Zhiwei Shi and Chong Li
Micromachines 2025, 16(9), 974; https://doi.org/10.3390/mi16090974 - 25 Aug 2025
Viewed by 1069
Abstract
To address the issues of mechanical wear and limited service life in conventional contact piezoelectric actuators, this study proposes a non-contact piezoelectric actuator employing compressed air for energy transmission; we elucidate its structure and operating principle. The working performance of the actuator is [...] Read more.
To address the issues of mechanical wear and limited service life in conventional contact piezoelectric actuators, this study proposes a non-contact piezoelectric actuator employing compressed air for energy transmission; we elucidate its structure and operating principle. The working performance of the actuator is significantly affected by the amplification performance of its micro-displacement amplification mechanism, which itself is closely dependent on the mechanism’s stiffness. Mathematical models for both the filleted straight-beam flexure hinge and the micro-displacement amplification mechanism are established. Analytical equations for calculating the equivalent stiffness of the hinge and the mechanism are derived. The variations in the hinge’s bending stiffness and tensile stiffness, as well as the mechanism’s equivalent stiffness with key structural parameters, are investigated. The stress distribution of the micro-displacement amplification mechanism is analyzed to evaluate the rationality and reliability of its structural design. A prototype is fabricated and equivalent stiffness tests are conducted. The theoretical calculation is basically consistent with the experimental results, verifying the accuracy of the stiffness model. The results show that flexure hinge tensile stiffness significantly exceeds the bending stiffness, permitting the simplification of the hinge stiffness model. Hinge minimum thickness and beam length critically affect mechanism stiffness; reducing thickness or increasing beam length lowers stiffness, boosting displacement amplification. Full article
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22 pages, 3484 KB  
Article
Study on Mechanical Properties of Coarse-Fine Polypropylene Fiber Blended Concrete
by Pengcheng Li, Mingyao Huang, Yingying Shang, Yanwen Kuang, Gang Xiong and Xinyi Tang
Buildings 2025, 15(16), 2971; https://doi.org/10.3390/buildings15162971 - 21 Aug 2025
Viewed by 887
Abstract
Polypropylene fiber, as a micro-scale reinforcement material, has been widely recognized for its ability to effectively inhibit crack propagation during the service life of concrete, thereby enhancing both its crack resistance and durability. This study presents an experimental investigation of the mechanical properties [...] Read more.
Polypropylene fiber, as a micro-scale reinforcement material, has been widely recognized for its ability to effectively inhibit crack propagation during the service life of concrete, thereby enhancing both its crack resistance and durability. This study presents an experimental investigation of the mechanical properties of polypropylene fiber-reinforced concrete specimens. The primary objective of this study was to assess the influence of varying fiber lengths and volumetric fiber contents on the load-bearing behavior of concrete. Seven sets of concrete specimens with different polypropylene fiber parameters (dosage and length) were prepared and subjected to a series of tests, including compressive strength, splitting tensile strength, flexural strength, and axial compressive stress–strain behavior. Specifically, coarse polypropylene fibers with two lengths (30 mm and 50 mm) and three dosages (0.5%, 1%, and 1.5%) were investigated. Experimental results facilitated the identification of the optimal fiber dosage and length at which the mechanical properties of the concrete specimens were maximized. Subsequently, a constitutive model for polypropylene fiber-reinforced concrete was established. The analysis elucidated the relationships between the parameters within the constitutive model, axial compressive strength of the concrete, and characteristic fiber parameters. The derived formulations provide a theoretical foundation for subsequent finite element analyses of polypropylene-fiber-reinforced concrete. Full article
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16 pages, 700 KB  
Article
Mechanical Properties of Basalt Fiber-Reinforced Coal Gangue Coarse Aggregate-Fly Ash Geopolymer Concrete
by Zheng Yang and Xianzhang Ling
Buildings 2025, 15(16), 2860; https://doi.org/10.3390/buildings15162860 - 13 Aug 2025
Viewed by 461
Abstract
Excellent mechanical properties are a prerequisite for the widespread application of different types of concrete in practical engineering. However, when coal gangue (CG) is used as coarse aggregate (CA) and geopolymer cement is used as auxiliary cementitious material, while reducing the demand for [...] Read more.
Excellent mechanical properties are a prerequisite for the widespread application of different types of concrete in practical engineering. However, when coal gangue (CG) is used as coarse aggregate (CA) and geopolymer cement is used as auxiliary cementitious material, while reducing the demand for ordinary cement and industrial waste emissions, it has a negative impact on mechanical performance. Therefore, in response to the data gap in the study of mechanical properties of coal gangue coarse aggregate-fly ash geopolymer concrete (CG-FA-GPC), inspired by a large number of research results on fiber-reinforced concrete, this study uses basalt fiber (BF) as a reinforcing material to investigate the enhancing effect of BF on the mechanical properties of CG-FA-GPC. We selected compressive strength, flexural strength, splitting tensile strength, and stress–strain curve as evaluation indicators to compare and analyze the mechanical properties of ordinary concrete, CG-FA-GPC, and basalt fiber-reinforced coal gangue coarse aggregate-fly ash geopolymer concrete (BF-CG-FA-GPC), and to explore the reinforcement effect of BF. The results showed that with the increase in CG substitution rate, the compressive strength, flexural strength, and splitting tensile strength of CG-FA-GPC significantly decreased. A 100% CG substitution reduced the compressive strength, flexural strength, and splitting tensile strength of CG-FA-GPC by 34.5%, 43.4%, and 31.8%, respectively. The stress–strain curve reveals the dual effects of BF on the strength enhancement and deformation modification of CG-FA-GPC. With the increase in BF content, the three mechanical strengths of CG-FA-GPC show a pattern of first increasing and then decreasing, and the optimal BF content is 0.4% (volume fraction). This experiment lays the foundation for promoting research on the mechanical properties and durability of different fiber-reinforced CG-FA-GPC, advancing the feasibility of its large-scale engineering applications. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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15 pages, 2101 KB  
Article
Hybrid Laminates Reinforced with Natural and Synthetic Fibers: Experimental Characterization and Preliminary Finite Element Assessment for Prosthetic Applications
by Angel D. Castro-Franco, Miriam Siqueiros-Hernández, Virginia García-Angel, Ismael Mendoza-Muñoz, Benjamín González-Vizcarra, Hernán D. Magaña-Almaguer and Lidia E. Vargas-Osuna
Fibers 2025, 13(8), 107; https://doi.org/10.3390/fib13080107 - 11 Aug 2025
Cited by 1 | Viewed by 524
Abstract
Four configuration laminates made of flax, glass, and basalt were fabricated via vacuum-assisted hand lay-up with added weight and tested under ASTM D3039 and D790. The flax–glass–flax lay-up exhibited the highest tensile strength and flexural strength. Orthotropic elastic properties were determined from remanufactured [...] Read more.
Four configuration laminates made of flax, glass, and basalt were fabricated via vacuum-assisted hand lay-up with added weight and tested under ASTM D3039 and D790. The flax–glass–flax lay-up exhibited the highest tensile strength and flexural strength. Orthotropic elastic properties were determined from remanufactured 90°-rotated specimens. A hexahedral-meshed finite element model using these inputs under a 5256 N load predicted the stress and strain within 1% and 5% of the experimental values. These findings demonstrate that flax–glass hybrids offer mechanical reliability, sustainability, and affordability for next-generation prosthetic applications. Full article
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19 pages, 14190 KB  
Article
A Comprehensive Evaluation Method for Cement Slurry Systems to Enhance Zonal Isolation: A Case Study in Shale Oil Well Cementing
by Xiaoqing Zheng, Weitao Song, Xiutian Yang, Jian Liu, Tao Jiang, Xuning Wu and Xin Liu
Energies 2025, 18(15), 4138; https://doi.org/10.3390/en18154138 - 4 Aug 2025
Viewed by 462
Abstract
Due to post-cementing hydraulic fracturing and other operational stresses, inadequate mechanical properties or suboptimal design of the cement sheath can lead to tensile failure and microcrack development, compromising both hydrocarbon recovery and well integrity. In this study, three field-deployed cement slurry systems were [...] Read more.
Due to post-cementing hydraulic fracturing and other operational stresses, inadequate mechanical properties or suboptimal design of the cement sheath can lead to tensile failure and microcrack development, compromising both hydrocarbon recovery and well integrity. In this study, three field-deployed cement slurry systems were compared on the basis of their basic mechanical properties such as compressive and tensile strength. Laboratory-scale physical simulations of hydraulic fracturing during shale oil production were conducted, using dynamic permeability as a quantitative indicator of integrity loss. The experimental results show that evaluating only basic mechanical properties is insufficient for cement slurry system design. A more comprehensive mechanical assessment is re-quired. Incorporation of an expansive agent into the cement slurry system can alleviate the damage caused by the microannulus to the interfacial sealing performance of the cement sheath, while adding a toughening agent can alleviate the damage caused by tensile cracks to the sealing performance of the cement sheath matrix. Through this research, a microexpansive and toughened cement slurry system, modified with both expansive and toughening agents, was optimized. The expansive agent and toughening agent can significantly enhance the shear strength, the flexural strength, and the interfacial hydraulic isolation strength of cement stone. Moreover, the expansion agents mitigate the detrimental effects of microannulus generation on the interfacial sealing, while the toughening agents alleviate the damage caused by tensile cracking to the bulk sealing performance of the cement sheath matrix. This system has been successfully implemented in over 100 wells in the GL block of Daqing Oilfield. Field application results show that the proportion of high-quality well sections in the horizontal section reached 88.63%, indicating the system’s high performance in enhancing zonal isolation and cementing quality. Full article
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17 pages, 588 KB  
Article
The Effect of Methacrylate-POSS in Nanosilica Dispersion Addition on Selected Mechanical Properties of Photo-Cured Dental Resins and Nanocomposites
by Norbert Sobon, Michal Krasowski, Karolina Kopacz, Barbara Lapinska, Izabela Barszczewska-Rybarek, Patrycja Kula and Kinga Bociong
J. Compos. Sci. 2025, 9(8), 403; https://doi.org/10.3390/jcs9080403 - 1 Aug 2025
Viewed by 556
Abstract
Background: This study aimed to assess the impact of methacrylate-functionalized polyhedral oligomeric silsesquioxanes dispersed in nanosilica (MA/Ns-POSS) on the mechanical properties of light-curable dental resins and composites. The primary goal was to evaluate how different concentrations of MA/Ns-POSS (0.5–20 wt.%) affect the hardness, [...] Read more.
Background: This study aimed to assess the impact of methacrylate-functionalized polyhedral oligomeric silsesquioxanes dispersed in nanosilica (MA/Ns-POSS) on the mechanical properties of light-curable dental resins and composites. The primary goal was to evaluate how different concentrations of MA/Ns-POSS (0.5–20 wt.%) affect the hardness, flexural strength, modulus, diametral tensile strength, polymerization shrinkage stress, and degree of conversion of these materials. Methods: A mixture of Bis-GMA, UDMA, TEGDMA, HEMA, and camphorquinone, with a tertiary amine as the photoinitiator, was used to create resin and composite samples, incorporating 45 wt.% silanized silica for the composites. Hardness (Vickers method, HV), flexural strength (FS), and flexural modulus (Ef) were assessed using three-point bending tests, while diametral tensile strength (DTS) polymerization shrinkage stresses (PSS), and degree of conversion (DC) analysis were analyzed for the composites. Results: The results showed that resins with 10 wt.% MA/Ns-POSS exhibited the highest Ef and FS values. Composite hardness peaked at 20 wt.% MA/Ns-POSS, while DTS increased up to 2.5 wt.% MA/Ns-POSS but declined at higher concentrations. PSS values decreased with increasing MA/Ns-POSS concentration, with the lowest values recorded at 15–20 wt.%. DC analysis also showed substantial improvement for 15–20 wt.% Conclusion: Incorporating MA/Ns-POSS improves the mechanical properties of both resins and composites, with 20 wt.% showing the best results. Further studies are needed to explore the influence of higher additive concentrations. Full article
(This article belongs to the Special Issue Innovations of Composite Materials in Prosthetic Dentistry)
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17 pages, 2862 KB  
Article
Crack Assessment Using Acoustic Emission in Cement-Free High-Performance Concrete Under Mechanical Stress
by Muhammad Ali Rostampour, Davood Mostofinejad, Hadi Bahmani and Hasan Mostafaei
J. Compos. Sci. 2025, 9(7), 380; https://doi.org/10.3390/jcs9070380 - 19 Jul 2025
Cited by 3 | Viewed by 795
Abstract
This study investigates the cracking behavior of high-performance calcium oxide-activated concrete incorporating basalt and synthetic macro fibers under compressive and flexural loading. Acoustic emission (AE) monitoring was employed to capture real-time crack initiation and propagation, offering insights into damage evolution mechanisms. A comprehensive [...] Read more.
This study investigates the cracking behavior of high-performance calcium oxide-activated concrete incorporating basalt and synthetic macro fibers under compressive and flexural loading. Acoustic emission (AE) monitoring was employed to capture real-time crack initiation and propagation, offering insights into damage evolution mechanisms. A comprehensive series of uniaxial compression and four-point bending tests were conducted on fiber-reinforced and plain specimens. AE parameters, including count, duration, risetime, amplitude, and signal energy, were analyzed to quantify crack intensity and classify fracture modes. The results showed that tensile cracking dominated even under compressive loading due to lateral stresses, while fiber inclusion significantly enhanced toughness by promoting distributed microcracking and reducing abrupt energy release. Basalt fibers were particularly effective under flexural loading, increasing the post-peak load-bearing capacity, whereas synthetic macro fibers excelled in minimizing tensile crack occurrence under compression. Full article
(This article belongs to the Section Composites Applications)
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15 pages, 7412 KB  
Article
Effect of Sequence-Based Incorporation of Fillers, Kenaf Fiber and Graphene Nanoplate, on Polypropylene Composites via a Physicochemical Compounding Method
by Soohyung Lee, Kihyeon Ahn, Su Jung Hong and Young-Teck Kim
Polymers 2025, 17(14), 1955; https://doi.org/10.3390/polym17141955 - 17 Jul 2025
Viewed by 509
Abstract
Natural-fiber-reinforced polypropylene (PP) composites are gaining increasing interest as lightweight, sustainable alternatives for various packaging and applications. This study investigates the effect of filler addition sequence on the mechanical, morphological, thermal, and dynamic mechanical properties of PP-based composites reinforced with graphite nanoplatelets (GnP) [...] Read more.
Natural-fiber-reinforced polypropylene (PP) composites are gaining increasing interest as lightweight, sustainable alternatives for various packaging and applications. This study investigates the effect of filler addition sequence on the mechanical, morphological, thermal, and dynamic mechanical properties of PP-based composites reinforced with graphite nanoplatelets (GnP) and kenaf fiber (KF). Two filler incorporation sequences were evaluated: GnP/KF/PP (GnP initially mixed with KF before PP addition) and GnP/PP/KF (KF added after mixing GnP with PP). The GnP/KF/PP composite exhibited superior mechanical properties, with tensile strength and flexural strength increasing by up to 25% compared to the control, while GnP/PP/KF showed a 13% improvement. SEM analyses revealed that initial mixing of GnP with KF significantly improved filler dispersion and interfacial bonding, enhancing stress transfer within the composite. XRD and DSC analyses showed reduced crystallinity and lower crystallization temperatures in the addition of KF due to restricted polymer chain mobility. Thermal stability assessed by TGA indicated minimal differences between the composites regardless of filler sequence. DMA results demonstrated a significantly higher storage modulus and enhanced elastic response in the addition of KF, alongside a slight decrease in glass transition temperature (Tg). The results emphasize the importance of optimizing filler addition sequences to enhance mechanical performance, confirming the potential of these composites in sustainable packaging and structural automotive applications. Full article
(This article belongs to the Special Issue Natural Fiber-Based Green Materials, Second Edition)
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29 pages, 2673 KB  
Article
Process Parameters Optimization and Mechanical Properties of Additively Manufactured Ankle–Foot Orthoses Based on Polypropylene
by Sahar Swesi, Mohamed Yousfi, Nicolas Tardif and Abder Banoune
Polymers 2025, 17(14), 1921; https://doi.org/10.3390/polym17141921 - 11 Jul 2025
Viewed by 737
Abstract
Nowadays, Fused Filament Fabrication (FFF) 3D printing offers promising opportunities for the customized manufacturing of ankle–foot orthoses (AFOs) targeted towards rehabilitation purposes. Polypropylene (PP) represents an ideal candidate in orthotic applications due to its light weight and superior mechanical properties, offering an excellent [...] Read more.
Nowadays, Fused Filament Fabrication (FFF) 3D printing offers promising opportunities for the customized manufacturing of ankle–foot orthoses (AFOs) targeted towards rehabilitation purposes. Polypropylene (PP) represents an ideal candidate in orthotic applications due to its light weight and superior mechanical properties, offering an excellent balance between flexibility, chemical resistance, biocompatibility, and long-term durability. However, Additive Manufacturing (AM) of AFOs based on PP remains a major challenge due to its limited bed adhesion and high shrinkage, especially for making large parts such as AFOs. The primary innovation of the present study lies in the optimization of FFF 3D printing parameters for the fabrication of functional, patient-specific orthoses using PP, a material still underutilized in the AM of medical devices. Firstly, a thorough thermomechanical characterization was conducted, allowing the implementation of a (thermo-)elastic material model for the used PP filament. Thereafter, a Taguchi design of experiments (DOE) was established to study the influence of several printing parameters (extrusion temperature, printing speed, layer thickness, infill density, infill pattern, and part orientation) on the mechanical properties of 3D-printed specimens. Three-point bending tests were conducted to evaluate the strength and stiffness of the samples, while additional tensile tests were performed on the 3D-printed orthoses using a home-made innovative device to validate the optimal configurations. The results showed that the maximum flexural modulus of 3D-printed specimens was achieved when the printing speed was around 50 mm/s. The most significant parameter for mechanical performance and reduction in printing time was shown to be infill density, contributing 73.2% to maximum stress and 75.2% to Interlaminar Shear Strength (ILSS). Finally, the applicability of the finite element method (FEM) to simulate the FFF process-induced deflections, part distortion (warpage), and residual stresses in 3D-printed orthoses was investigated using a numerical simulation tool (Digimat-AM®). The combination of Taguchi DOE with Digimat-AM for polypropylene AFOs highlighted that the 90° orientation appeared to be the most suitable configuration, as it minimizes deformation and von Mises stress, ensuring improved quality and robustness of the printed orthoses. The findings from this study contribute by providing a reliable method for printing PP parts with improved mechanical performance, thereby opening new opportunities for its use in medical-grade additive manufacturing. Full article
(This article belongs to the Special Issue Latest Progress in the Additive Manufacturing of Polymeric Materials)
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20 pages, 2334 KB  
Article
Study on Mechanical Properties of Alkali-Activated Coal Gasification Slag Concrete
by Rongjian Shen, Xiaojun Li and Shen Li
Materials 2025, 18(14), 3240; https://doi.org/10.3390/ma18143240 - 9 Jul 2025
Cited by 1 | Viewed by 359
Abstract
Coal gasification slag (CGS) is a solid byproduct generated during coal gasification. Stacking and land-filling of CGS wastes substantial land resources and has significant environmental risks. In this paper, based on the Ca/Si and Si/Al ratios of the raw materials, the mix design [...] Read more.
Coal gasification slag (CGS) is a solid byproduct generated during coal gasification. Stacking and land-filling of CGS wastes substantial land resources and has significant environmental risks. In this paper, based on the Ca/Si and Si/Al ratios of the raw materials, the mix design of alkali-activated CGS concrete was optimized using a pure center-of-gravity design method. The compressive and flexural strengths of geopolymer concrete with varying mix proportions were measured to investigate the effects of sodium silicate modulus, material content, and dry density on its mechanical properties. Specimens of different sizes were prepared to analyze the influence of testing methods on the compressive, flexural, and tensile properties. The results indicate that the mechanical properties of geopolymer concrete are significantly influenced by the raw material composition and the modulus of the activator. With increasing curing age, both compressive and flexural strengths exhibit varying degrees of improvement. The stress-strain behavior of alkali-activated CGS concrete aligns closely with that of ordinary concrete. A comparative analysis of 100 mm length and 20 mm length cubic specimens revealed a compressive strength size conversion coefficient of approximately 0.456, while the flexural specimen exhibited a coefficient of 0.599. For tensile strength evaluation, both the Brazilian splitting method and the double punch test method yielded consistent and reliable results, demonstrating their suitability for assessing CGS-based concrete. Full article
(This article belongs to the Special Issue Towards Sustainable Low-Carbon Concrete)
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13 pages, 1628 KB  
Article
Effect of Vinyl Acetate-Ethylene on the Performance of Silicate Cement–Silica Fume Repair Mortar
by Bo Li, Tianhao Ye, Kaixuan Deng and Min Zhang
Buildings 2025, 15(13), 2224; https://doi.org/10.3390/buildings15132224 - 25 Jun 2025
Viewed by 558
Abstract
The regulatory mechanism of vinyl acetate-ethylene (VAE) in the interfacial properties of silicate cement–silica fume repair mortar was investigated by examining the effects of varying VAE contents (0 wt.% to 10.0 wt.%) on mortar fluidity, mechanical strength, and interfacial bonding strength. The interface [...] Read more.
The regulatory mechanism of vinyl acetate-ethylene (VAE) in the interfacial properties of silicate cement–silica fume repair mortar was investigated by examining the effects of varying VAE contents (0 wt.% to 10.0 wt.%) on mortar fluidity, mechanical strength, and interfacial bonding strength. The interface microstructure was also examined to reveal its evolution. Results indicate that VAE enhances mortar fluidity through micro-filling and interfacial activity. At 10% VAE content, fluidity reached 265 mm, a 14.97% increase. However, VAE introduction reduced compressive and flexural strength due to pore induction at low dosages and polymer network interference at high dosages. By improving interfacial stress transfer and refining calcium sulfoaluminate (AFt) and C-S-H crystals in the interfacial transition zone, VAE increased the tensile bonding strength of the repaired mortar to 2.1 MPa at 28 days, a 133.3% increase, according to microscopic analysis. Based on performance analysis, 5.0 wt.% VAE is optimal, increasing interfacial bonding strength by 133.3% while limiting compressive strength loss to 9.4%, thus achieving interfacial collaborative optimization of the repaired mortar. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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