Search Results (810)

Natural hydrogen is regarded as a potential resource for the global energy transition, and its accumulation is closely linked to water–rock reactions involving Fe²⁺ bearing minerals and effective sealing conditions. The Liaohe Basin, located on the northeastern margin of the North China Craton within a key metallogenic belt, is surrounded by sedimentary-metamorphic iron deposits and is a potential area for natural hydrogen accumulation. In this study, aeromagnetic and satellite gravity data were integrated to estimate basement depth through gravity interface inversion, followed by three-dimensional magnetic susceptibility and density inversion and structural–mineralization correlation analysis. The results reveal strong basement heterogeneity. Iron-rich anomalous bodies show clustered and belt-like to dome-like distributions, mainly along the transitional zone between deep depressions and basement uplifts. Combined density–magnetic zonation suggests that high-density, high-magnetic units may correspond to iron-rich bodies, whereas high-magnetic, low-density units likely indicate fractured and altered fluid pathways. Based on the measured results of surface hydrogen concentration, it is inferred that the high magnetic anomaly in the uplift transition zone at the edge of the depression might be the coupling area of iron-rich rock bodies and channel zones, which is the priority response area of natural hydrogen in the Liaohe Basin, China. Full article

This study investigates road tunnel stability in heterogeneous flysch formations using the Zenica Tunnel as a case study. A hybrid research framework integrating empirical classification, analytical modeling, and numerical simulation was applied. The approach combines the Rock Mass Rating (RMR) system, the Convergence–Confinement Method (CCM), and nonlinear two-dimensional finite element (FEM) analyses. Statistical evaluation of the results reveals a strong exponential relationship between the stability factor N_s and measured tunnel convergence, with coefficients of determination (R²) between 0.89 and 0.96. Particular attention was given to sections classified as Category V rock mass. The analysis indicates that when RMR values fall below 25, the stability factor N_s exceeds the critical value of 5, marking the onset of pronounced squeezing behavior. The results show that analytical methods provide conservative estimates of tunnel stability, while numerical modeling enables improved calibration of support system stiffness. The proposed integrated methodology contributes to more reliable stability assessment and support design in road tunnels excavated in complex flysch formations. Full article

Deep soft-rock tunnels are prone to large deformations and structural damage. This study used the Guanyinping Tunnel as a prototype and conducted 1/50-scale progressive loading model tests under three support configurations: rock-bolt-free, equal-length rock bolts, and mixed long–short rock bolts. Rock stress, radial rock displacement (u), and rock bolt axial force (F_N) at the vault, arch shoulders, sidewalls, and wall feet were monitored to reveal reinforcement mechanisms and mechanical response. The results indicated that stress evolution in the bolt-free case exhibited significant spatial heterogeneity. The vault experienced horizontal stress concentration, while the arch shoulder underwent vertical stress concentration. u underwent a three-stage nonlinear progression: elastic linear growth, plastic linear growth, and plastic-accelerated growth. Displacement at the vault was markedly larger than that at other locations. Equal-length rock bolts substantially improved the rock mass stability by delaying stress concentration and fracture propagation. This reinforcement raised the elastic response threshold to 96 kPa and substantially reduced u. F_N at the vault and shoulder followed linear growth, accelerated growth, and then gradual decline, whereas F_N at the sidewalls and wall feet exhibited a steady linear trend. Combined long and short rock bolts produced a multi-level anchoring effect. Short bolts induced a shallow arching action, while long bolts provided deep suspension. This synergy raised the elastic response threshold to a maximum of 120 kPa and moderated the stress reduction process. Deep residual stresses increased to 74.3–88.4% of peak values. The displacement gradient between shallow and deep rock masses was significantly reduced. The coordinated deformation capacity within the anchoring zone was markedly enhanced. F_N distribution exhibited spatial differentiation: short bolts carried the load initially, followed by the activation of long bolts. Both anchoring schemes increased residual stress and mitigated rock mass deformation. The deformation control effect was stronger in shallow rock mass than in deep rock mass. Improvements at the vault and arch shoulders exceeded those at the sidewalls and wall feet. The mixed short–long bolt configuration was superior because it maximized the self-bearing capacity of the deep rock mass. The findings provide experimental data and theoretical guidance for the design and optimization of rock-bolt support in deep soft-rock tunnels. Full article

To address the challenge of surrounding rock instability in deep-buried tunnels crossing fractured fault zones, this study focuses on the Xigu Tunnel of the Lanzhou–Hezuo Railway. A combination of laboratory triaxial tests, an optimized multi-source advanced geological prediction workflow, and a site-specific parameter-weakened Mohr–Coulomb numerical simulation is employed to systematically reveal the physical–mechanical properties, spatial distribution, and deformation response of fractured rock masses under excavation-induced disturbance. The triaxial test results show that the average peak strength of the surrounding rock reaches 149.04 MPa; however, significant variability is observed among samples, and the failure mode exhibits a typical brittle–shear composite feature. The measured cohesion and internal friction angle are 20.57 MPa and 49.91°, respectively, indicating high intrinsic strength of individual rock blocks. Nevertheless, due to the presence of densely developed joints and crushed structures, the overall mass is loose and highly sensitive to dynamic disturbances such as blasting and excavation, revealing a unique mechanical paradox of high-strength rock blocks with low overall rock mass stability in deep-buried fractured zones. Joint TSP (Tunnel Seismic Prediction Ahead) and ground-penetrating radar (GPR) prediction reveals decreased P-wave velocity, increased Poisson’s ratio, and intensive seismic reflection interfaces; a quantitative index system for identifying the boundaries of narrow deep-buried fractured zones is proposed based on these geophysical characteristics. Combined with geological face mapping, these results confirm the existence of a highly fractured zone approximately 130 m in width, characterized by well-developed joints, heterogeneous mechanical properties, and localized risks of blockfall and groundwater ingress. The developed numerical model, with parameters weakened based on triaxial test and geological prediction data, effectively reproduces the deformation law of the fractured zone, and the simulation results agree well with field monitoring data, with peak displacement concentrated at section DK4 + 595, thus accurately identifying the center of the fractured belt as a key engineering validation result of the integrated technical framework. During construction, based on the identified spatial characteristics of the fractured zone and the proposed targeted support insight, enhanced dynamic monitoring and targeted support measures at the fractured zone center are required to ensure structural safety and long-term stability of the tunnel. This study develops an integrated engineering-oriented technical framework for deep-buried tunnels crossing narrow fractured zones, and provides novel mechanical insights and quantitative identification indices for such complex geological engineering scenarios. Full article

The coupling between the key parameters of rock and soil particle composition and slurry diffusion paths exerts a significant influence on actual grouting effectiveness. Based on the spherical penetration grouting model for Bingham cement grout, this study optimizes the fractal permeability model by coupling the characteristic particle size, porosity, and tortuosity, overcoming the deficiency of single-factor porosity consideration in existing permeability models. Unlike existing studies that only use experimentally measured permeability coefficients, this study employs a physically meaningful permeability model that realizes the synergistic coupling of soil particle composition, pore microstructure, and macroscopic permeability, and further establishes a penetration grouting mechanism that integrates the actual slurry diffusion path tortuosity into the classical spherical diffusion framework. A novel high-precision volume measurement method for grouting stone bodies based on point cloud 3D reconstruction is proposed, and a COMSOL-based visual numerical simulation program is developed by embedding the above coupling permeability model. The accuracy of the optimized mechanism is verified by a combination of model tests, numerical simulations, and theoretical analysis, which makes up for the existing grouting mechanism for loose gravelly soil failing to consider the synergistic influence of rock–soil particle composition parameters and the actual diffusion path. The research results indicate the following: (1) Adopting loose gravelly soil—which is more consistent with actual field conditions—as the grouted medium can effectively predict the reinforcement effect of heterogeneous media in grouting engineering. (2) Compared with theoretical values calculated by mechanisms that ignore the effect of the diffusion paths, those derived from the grouting mechanism that couples the rock and soil characteristic particle size with the Bingham cement grout diffusion path are closer to the experimental values. (3) The visual simulation results exhibit high morphological consistency with the actual grouting stone bodies, and the vast majority of the grout diffusion range falls within the numerical simulation domain. The findings of this study provide targeted theoretical and technical guidance for grouting design under complex geological conditions of loose gravelly soil layers. Full article

Deep shale gas reservoirs in the southern Sichuan Basin (Weiyuan area) exhibit strong heterogeneity and complex pore-fracture networks. Traditional reservoir evaluation methods struggle to accurately capture their microscale pore characteristics and fracability, thereby restricting efficient development and precise sweet spot prediction. Therefore, integrating digital core technology with geological analysis is essential to systematically quantify key reservoir parameters, including microscale pore structure, mineral composition, and brittleness characteristics. To clarify the controlling factors of high-quality deep shale gas reservoirs in the Weiyuan area and assess their exploration and development potential, we performed digital core analysis at micron to nanometer scales. Three-dimensional digital core models of representative deep shale gas wells were constructed. Integrating mineral composition, geochemical characteristics, and pore space features, we discuss the geological conditions for deep shale gas accumulation and the fracability of horizontal wells, and we delineate favorable shale reservoir zones. The results show that digital core technology enables quantitative and visual characterization of each sublayer of the Longmaxi Formation shale reservoir, including mineral types, laminae types, pore-throat structures, and organic matter distribution. From the Long 11-1 sublayer to the Long 11-4 sublayer, the pore-throat radius, total pore volume, total throat volume, connected pore-throat percentage, and coordination number all gradually decrease. In the eastern Weiyuan area, the siliceous components in deep shale gas reservoirs at the base of the Longmaxi Formation are primarily of both biogenic and terrigenous origin. Due to local variations in the sedimentary environment, terrigenous input contributes significantly to the total siliceous content in this region. Although the Long 11-1 sublayer of the Longmaxi Formation is lithologically classified as mud shale, its particle size and mineral composition more closely resemble those of clayey siltstone or argillaceous sandstone, suggesting considerable potential for reservoir space development. Typical wells in the eastern Weiyuan area exhibit distinct lithological characteristics, including coarser grain sizes, stronger hydrodynamic conditions during deposition, and abundant terrigenous clastic supply. The rigid framework formed by silt- to sand-sized particles effectively mitigates compaction, thereby facilitating the preservation of intergranular pores and microfractures. High organic matter abundance, appropriate thermal maturity, and a considerable thickness of high-quality shale ensured sufficient hydrocarbon supply. The main types of natural fractures are intergranular and grain-edge fractures formed by differences in sedimentary grain size, and bedding-parallel fractures generated by hydrocarbon generation overpressure. Based on reservoir mineral composition, pore characteristics, areal porosity, and pore size distribution identified via digital core analysis, the bottom 0–3 m of the Long 11-1 sublayer is determined to be the optimal target interval. By delineating the microscopic characteristics of the shale reservoir and predicting rock mechanical parameters, a fracability evaluation index was established from digital core simulations. This guides the selection of target layers in deep shale gas reservoirs and optimizes hydraulic fracturing design. Full article

The safety and stability of underground coal mining are largely determined by the structural features of coal seams and surrounding rocks. Geological heterogeneities such as faults, fracture zones, and lithological variations strongly influence the distribution of rock pressure and the occurrence of geodynamic hazards. This highlights the need for reliable geophysical methods capable of identifying such zones under mining conditions. Electrical prospecting represents a promising diagnostic approach, as it is highly sensitive to changes in the physical properties of rocks. Unlike conventional geological mapping, it enables the detection of hidden structures and weakened zones often invisible to direct observation. Advances in instrumentation and data processing have further expanded the applicability of electrical methods in complex environments. This study introduces a methodology of electrical prospecting observations for the diagnosis of coal seams. The analysis focuses on conductivity anomalies that reflect tectonic disturbances, fracture systems, and lithological heterogeneities. Field investigations demonstrated the sensitivity of the method to local environmental variations. Comparison with geological records confirmed the validity of the approach: the identified anomalous zones correlated well with documented tectonic features. The methodology showed a stable performance and revealed potential for integration into mine monitoring systems. It allows the identification of areas associated with elevated rock pressure and possible geodynamic activity, thereby contributing to safer underground operations. In the longer term, electrical prospecting may be applied to other coal deposits, including those with a high gas content and complex structure. The development of automated interpretation tools and machine learning algorithms could further increase processing efficiency and improve predictive reliability. Overall, the results confirm that electrical prospecting in mining environments can become an effective instrument for enhancing safety and building more accurate geological–geophysical models of coal seams. Full article

The growing global demand for critical raw materials (CRMs) essential to renewable energy, electromobility, and digital technologies has accelerated the need for advanced exploration methods capable of operating in increasingly challenging geological environments. Traditional drilling systems, designed primarily for shallow mineral and hydrocarbon exploration, face limitations in heterogeneous and consolidated formations where rock heterogeneity, variable mechanical strength, and borehole instability restrict operational efficiency. This review bridges geological science and robotic engineering by analyzing the evolution of next-generation autonomous drilling technologies integrating sensor systems, artificial intelligence (AI), and real-time geotechnical feedback. The current work explores how robotic drilling systems can autonomously adapt to variable lithologies, optimize penetration rates, and ensure borehole stability through intelligent sensing and control. The paper reviews the geological, geomechanical and ore deposit characteristics of CRMs, discusses state-of-the-art drilling optimization strategies, and highlights advances in measurement while drilling (MWD), logging while drilling (LWD), and geochemical analysis techniques. It also suggests a list of sensor techniques for possible future integration in autonomous subsurface robotic systems. It concludes by emphasizing the need for integration between subsurface geological modeling and intelligent drilling robotics as a pathway toward sustainable and efficient CRM exploration. Full article

Groundwater fluctuations in bedrock affect the mechanical behavior of rock masses hosting geo-energy recovery systems utilizing borehole heat exchangers. To investigate the combined influencing mechanism of changes in groundwater saturation and fracture dip angle on mechanical properties of typical fractured rock masses, triaxial compressive tests were conducted using specimens containing fissures at different angles (15° and 75°) under three conditions: conventional dry, water-immersed, and immersed-dried. The results reveal a combined influencing mechanism of groundwater saturation and fracture dip angle on mechanical properties of typical fractured rock mass. Since specimens with gentle fissure angles tend to fail through fracturing of the intact rock, while those with steeper fissure angles are more prone to failure via slippage along fissure planes, the stress–strain response exhibits greater variability among samples with gentle fissures, attributable to the material heterogeneity of the rock matrix; an increase in water saturation reduces the strength of steeper fissures more pronouncedly due to the relatively homogeneous properties of these fissures, and gravitational water present along fissure planes reduces effective stress and weakens interfacial bonding. Therefore, rock masses with steeper fissures are more susceptible to water-induced weakening and pose a higher risk of shear slippage by fissure reactivation. The findings have a practical value in offering theoretical support for assessing stability risks in geo-energy structures in shallow bedrocks. Full article

Heterogeneity at the grain scale strongly influences hydraulic fracturing in crystalline rock; however, systematic studies quantifying its impacts on the evolution of injection pressure and crack propagation remain limited. To address this gap, we employ a hydro-mechanical phase-field model incorporating Voronoi-based microstructures to systematically quantify the effects of grain-scale heterogeneity on hydraulic fracturing. Two numerical experimental programs are designed to examine the effects of (i) mean grain size and (ii) mineral distribution under different axial stresses. The simulations reveal a close coupling between injection pressure and crack-length evolution, and both responses are strongly governed by grain-scale heterogeneity. When the fracture enters weak minerals, it advances rapidly and pressure drops; when it encounters on strong minerals, growth slows or arrests and pressure builds until a threshold triggers the next advance. Moreover, peak pressure statistics further indicate that mineral distribution dominates the response scatter, while axial stress plays a secondary role. Specifically, the mean peak pressures at 0 and 10 MPa are similar (about 14.31 and 14.21 MPa), whereas rearranging minerals within the same Voronoi tessellation changes peak pressure by more than 4 MPa. Higher peaks occur when strong minerals lie ahead of the initial crack tip, increasing resistance to initiation and early growth. Finally, the stress state modulates fracture trajectories: under low axial stress, fractures preferentially follow mineral boundaries, whereas higher axial stress strengthens macroscopic stress guidance and shifts the path toward a direction closer to being perpendicular to the maximum principal stress. This trend is consistent with energy minimization, since interface detouring under high axial stress incurs a larger elastic free energy penalty. Full article

Grain-scale heterogeneity strongly influences hydraulic fracture initiation and trajectory in crystalline rocks, yet its contributions to non-planar growth and the interaction of multiple nearby cracks remain insufficiently quantified. To address this gap, we perform numerical experiments on a model containing two parallel pre-existing cracks using a hydro-mechanical phase-field framework, systematically quantifying how mineral distribution and axial compression govern non-planar hydraulic fracture growth and inter-fracture competition. The results demonstrate that mineral distribution is the primary driver of fracture complexity. Even within the same Voronoi tessellation, redistributing minerals alone yields markedly different trajectories, deflections, branching patterns, and final morphologies. Furthermore, non-planar growth follows a stepwise, energy-threshold-driven mechanism. When cracks penetrate strong grains or undergo large-angle deflections, propagation is impeded, and injection pressure builds up. Once a critical energy threshold is reached, accumulated energy is rapidly released along the path of minimum incremental energy, manifested as abrupt pressure drops and rapid crack advance. Additionally, the two nearby fractures exhibit strong mechanical competition. Despite negligible hydraulic interference in low-permeability granite, early growth of one fracture redistributes stresses and suppresses the driving force of the other, resulting in asymmetric development. Finally, axial compression primarily governs the overall propagation orientation and influences local failure modes but has a limited effect on peak pressure relative to mineral distribution. Full article

Surface water–groundwater interactions within oasis–desert ecotones of arid regions play a pivotal role in sustaining regional water security and ecological stability. Taking the Niya River Basin in Xinjiang, Northwest China, as a representative inland watershed, this study systematically elucidates the mechanisms and seasonal dynamics of surface water–groundwater coupling under the combined influences of natural processes and anthropogenic activities. A total of 68 surface water and groundwater samples were collected during the dry, normal, and wet hydrological periods. Integrated hydrochemical characterization, mineral saturation index analysis, and stable isotope (δ²H and δ¹⁸O) mass balance modeling were employed to quantify recharge contributions and unravel hydrogeochemical evolution pathways. Results indicate that the waters in the study area are predominantly brackish to saline, with consistent dominant ionic assemblages (SO₄²⁻ and Na⁺) across all hydrological periods, highlighting evaporite dissolution as the primary control on solute composition. Hydrochemical evolution is jointly regulated by evaporation concentration, water–rock interactions, and cation exchange processes. Surface water chemistry reflects the combined effects of silicate weathering and evaporite dissolution, whereas groundwater chemistry is mainly governed by evaporite dissolution coupled with pronounced cation exchange. Stable isotope signatures reveal substantial secondary evaporation of regional precipitation prior to recharge. Frequent bidirectional recharge between surface water and groundwater was observed, exhibiting distinct seasonal transitions. During the dry period, groundwater provides significant baseflow support to surface water (48.6% in the oasis zone and 54.3% in the desert zone). In the normal period, recharge direction reverses, with surface water becoming the dominant source of groundwater recharge (99.0% in the oasis zone and 76.6% in the desert zone). In the wet period, spatial heterogeneity becomes evident: surface water continues to dominate groundwater recharge in the oasis zone (92.7%), whereas groundwater recharge to surface water prevails in the desert zone (50.5%). This study identifies a seasonally dynamic “discharge–infiltration–zonal regulation” bidirectional recharge pattern in arid inland river systems. The findings advance the mechanistic understanding of hydrological connectivity reconstruction within oasis–desert ecotones and provide a scientific basis for optimized regional water resource allocation and groundwater salinization risk mitigation. Full article

With the expansion of global oil and gas resource exploration and development into deep and ultra deep layers, the efficient development of deep carbonate rock fracture cave reservoirs has become the key to ensuring energy security. However, this type of reservoir commonly faces high temperatures, high salinity, and extremely strong heterogeneity, leading to increasingly severe water content spikes caused by dominant water flow channels. Although the existing traditional inorganic plugging agent has good temperature resistance, it has the defects of great brittleness and easy cracking, while the organic polymer gel is prone to degradation failure under high temperature and high salt environments. In order to solve the above problems, a new biochar-enhanced inorganic composite gel system was constructed by using biochar prepared from agricultural and forestry waste pyrolysis as a functional enhancement component. Through rheological testing, high-temperature and high-pressure mechanical experiments, long-term thermal stability evaluation, and dynamic sealing experiments of fractured rock cores, the reinforcement and toughening laws and rheological control mechanisms of biochar on inorganic matrices were systematically studied. Research has found that a biochar content of 0.5 wt% can significantly improve the micro pore structure of the matrix. By utilizing its micro aggregate filling effect and interfacial chemical bonding, the compressive strength of the solidified body can be increased to over 2 MPa, and there is no significant decline in strength after aging at 130 °C for 30 days. More importantly, the unique “adsorption slow-release” mechanism of biochar effectively stabilizes the hydration reaction kinetics at high temperatures, extending the solidification time of the system to 15 h and solving the problem of flash condensation in deep well pumping. This system exhibits excellent shear thinning characteristics and crack sealing ability, and presents a unique “yield reconstruction” toughness sealing feature. This study elucidates the multidimensional strengthening mechanism of biochar in inorganic cementitious materials, providing technical reference for stable oil and water control in deep fractured reservoirs. Full article

Canine mammary cancers (CMCs) are one of the most prevalent types of neoplasm in dogs, are frequently malignant, and display high tumour heterogeneity, making evaluating prognosis and predicting successful treatment outcomes difficult. In a previous pilot study, overexpression of the Wnt pathway-associated protein SFRP1 was found to correlate with negative metastasis status in CMCs at both mRNA and protein levels. To establish SFRP1 as a potential biomarker for CMC progression, additional verification of these results in an independent dataset is required, as well as an investigation as to whether SFRP1 expression in CMCs is associated with altered Wnt- or RANKL signalling pathways. In an independent verification cohort of 122 cases of archival CMC FFPE material, expression of SFRP1 was assessed by RT-qPCR and immunohistochemistry. The same tumours were further assessed for RANKL, phosphoROCK2, and NFkB-p65 protein expression. Our data verified that SFRP1 mRNA (p = 0.025) was negatively associated with metastasis status; however, differences in protein expression did not reach statistical significance (p = 0.139). Neither did SFRP1 significantly correlate with expression of any of the other proteins tested. Instead, a strong association was found for RANKL positivity with increased metastasis status (p < 0.001). Co-expression of SFRP1 significantly lowered the higher risk of metastatic spread when compared to RANKL_pos/SFRP1_neg CMCs (p = 0.033). Noticeably, all vascular-invasive cell clusters observed in tissue section vessels stained positive for RANKL. Our study identified RANKL expression as a strong marker for cancer progression with a strong link to vascular-invasive cells. However, SFRP1 expression may potentially suppress the pro-metastatic nature of RANKL_pos CMCs. Full article

The Ordovician system in the Shunbei area of the Tarim Basin hosts typical ultra-deep, fault-controlled fracture–vuggy hydrocarbon reservoirs. Compared with the surrounding Tabei and Tazhong areas, the genetic types of Ordovician formation water in Shunbei are more complex, and the relationships and spatial distribution of oil, gas, and water exhibit strong heterogeneity and pronounced fault control. This study systematically collected formation water geochemical and pressure data to clarify the geochemical characteristics and origin of Ordovician formation water in the Shunbei area and to investigate the indicative relationships between ion concentrations and ionic ratios of formation water and reservoir dolomitization, hydrocarbon migration, and accumulation. Research shows that, in contrast to the Tabei and Tazhong areas, the Ordovician formation water in Shunbei is predominantly of the calcium chloride (CaCl₂) type, with enrichment in Ca²⁺ and depletion in Mg²⁺, which may be related to euhedral dolomitization. In fault-controlled fracture–vuggy reservoirs, a high desulfurization coefficient—contrary to its interpretation in conventional reservoirs—corresponds to favorable zones for hydrocarbon accumulation. The rare earth element (REE) composition of the formation water is characterized by heavy REE enrichment, a distinct negative cerium (Ce) anomaly, and a positive europium (Eu) anomaly. Combined with hydrogen–oxygen and strontium isotopic data, these features indicate that the Ordovician formation water in Shunbei represents original depositional paleoseawater that has undergone cross-formational flow and concentration. The water bodies are divided into two distinct formation water systems bounded by the Shunbei No. 5 fault zone. Favorable zones for hydrocarbon enrichment are controlled by source rock distribution, and hydrocarbons migrate together with formation water along strike-slip faults within the Shunbei area, showing a northwest-to-southeast trend. The region between the middle segments of the Shunbei No. 4 and No. 8 fault zones is identified as a favorable area for hydrocarbon accumulation. Full article