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17 pages, 1105 KB  
Article
Conveyor-Based Single-Input Triple-Output Second-Order LP/BP and Cascaded First-Order HP Filters
by Riccardo Olivieri, Giuseppe Alessandro Di Lizio, Gianluca Barile, Vincenzo Stornelli, Giuseppe Ferri and Shahram Minaei
Electronics 2025, 14(17), 3514; https://doi.org/10.3390/electronics14173514 - 2 Sep 2025
Abstract
In this paper a new single-input independent multiple-output universal tunable filter employing second-generation current conveyors (CCII) and second-generation voltage conveyors (VCII) as active elements is presented. The proposed filter has been analyzed at transistor level, using a CMOS standard AMS 0.35 μm technology, [...] Read more.
In this paper a new single-input independent multiple-output universal tunable filter employing second-generation current conveyors (CCII) and second-generation voltage conveyors (VCII) as active elements is presented. The proposed filter has been analyzed at transistor level, using a CMOS standard AMS 0.35 μm technology, and implemented using discrete components based on the commercially available AD844. A detailed mathematical analysis is carried out, considering also parasitic impedances and non-ideal parameters. The low-pass, band-pass, and high-pass responses are simultaneously obtained and experimentally verified at 10 kHz central frequency where the voltage gain is about 27 dB for each output. THD analysis has been performed to evaluate the proposed work. Full article
27 pages, 8651 KB  
Article
Effect of Back-Tempering on the Wear and Corrosion Properties of Multiple-Pass Friction Stir Processed High-Speed Steel
by Quan Liu, Shiye Li, Guochong Rao, Xiaomi Chen, Kun Liu, Min Zhou, Dawei Guo, Valentino A. M. Cristino, Kin-Ho Lo, Lap-Mou Tam and Chi-Tat Kwok
Materials 2025, 18(17), 4125; https://doi.org/10.3390/ma18174125 - 2 Sep 2025
Abstract
In this study, a scalable surface modification strategy for M2 high-speed steel was applied using multiple-pass friction stir processing (FSP) with overlapping ratios of 25%, 50%, and 75%. A comprehensive investigation of the microstructure, surface hardness, wear, and corrosion resistance was conducted to [...] Read more.
In this study, a scalable surface modification strategy for M2 high-speed steel was applied using multiple-pass friction stir processing (FSP) with overlapping ratios of 25%, 50%, and 75%. A comprehensive investigation of the microstructure, surface hardness, wear, and corrosion resistance was conducted to elucidate the properties of FSPed M2 as a function of the overlapping ratio. In the single-pass FSPed M2, the major phase was martensite and the minor phases included retained austenite where refined carbides (M6C, M23C6, and MC) were detected. However, back-tempering occurred near the overlapped zone (OZ) between consecutive tracks for the multiple-pass FSPed M2. The martensite formed in the first pass was turned into tempered martensite by the thermal cycle from the subsequent pass. This back-tempering resulted in a localized decline in hardness from 900 to 650 HV0.2. Further wear tests revealed that the wear rates of the tempered zone (TZ) of the multiple-pass FSPed M2 (FSP25%: 1.40 × 10−5 mm3/N·m, FSP50%: 1.20 × 10−5 mm3/N·m and FSP75%: 1.00 × 10−5 mm3/N·m) are all higher than that of SZ of the single-pass FSPed M2 (0.75 × 10−5 mm3/N·m), indicating lower wear resistance of the TZ. Moreover, increased carbide content in the TZ led to the depletion of passivating elements near proximity of the tempered martensite, acting as the active sites for selective corrosion attack. The corrosion potential (Ecorr) and corrosion current density (Icorr) increased significantly, with values of −397.6 ± 5.6 mV and 9.5 ± 0.8 μA·cm−2 for FSP25%, −424.4 ± 6.0 mV and 14.7 ± 1.7 μA·cm−2 for FSP50%, and −440.9 ± 2.8 mV and 17.1 ± 1.9 μA·cm−2 for FSP75%. Full article
(This article belongs to the Special Issue Study on Electrochemical Behavior and Corrosion of Materials)
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22 pages, 1243 KB  
Article
ProCo-NET: Progressive Strip Convolution and Frequency- Optimized Framework for Scale-Gradient-Aware Semantic Segmentation in Off-Road Scenes
by Zihang Liu, Donglin Jing and Chenxiang Ji
Symmetry 2025, 17(9), 1428; https://doi.org/10.3390/sym17091428 - 2 Sep 2025
Abstract
In off-road scenes, segmentation targets exhibit significant scale progression due to perspective depth effects from oblique viewing angles, meaning that the size of the same target undergoes continuous, boundary-less progressive changes along a specific direction. This asymmetric variation disrupts the geometric symmetry of [...] Read more.
In off-road scenes, segmentation targets exhibit significant scale progression due to perspective depth effects from oblique viewing angles, meaning that the size of the same target undergoes continuous, boundary-less progressive changes along a specific direction. This asymmetric variation disrupts the geometric symmetry of targets, causing traditional segmentation networks to face three key challenges: (1) inefficientcapture of continuous-scale features, where pyramid structures and multi-scale kernels struggle to balance computational efficiency with sufficient coverage of progressive scales; (2) degraded intra-class feature consistency, where local scale differences within targets induce semantic ambiguity; and (3) loss of high-frequency boundary information, where feature sampling operations exacerbate the blurring of progressive boundaries. To address these issues, this paper proposes the ProCo-NET framework for systematic optimization. Firstly, a Progressive Strip Convolution Group (PSCG) is designed to construct multi-level receptive field expansion through orthogonally oriented strip convolution cascading (employing symmetric processing in horizontal/vertical directions) integrated with self-attention mechanisms, enhancing perception capability for asymmetric continuous-scale variations. Secondly, an Offset-Frequency Cooperative Module (OFCM) is developed wherein a learnable offset generator dynamically adjusts sampling point distributions to enhance intra-class consistency, while a dual-channel frequency domain filter performs adaptive high-pass filtering to sharpen target boundaries. These components synergistically solve feature consistency degradation and boundary ambiguity under asymmetric changes. Experiments show that this framework significantly improves the segmentation accuracy and boundary clarity of multi-scale targets in off-road scene segmentation tasks: it achieves 71.22% MIoU on the standard RUGD dataset (0.84% higher than the existing optimal method) and 83.05% MIoU on the Freiburg_Forest dataset. Among them, the segmentation accuracy of key obstacle categories is significantly improved to 52.04% (2.7% higher than the sub-optimal model). This framework effectively compensates for the impact of asymmetric deformation through a symmetric computing mechanism. Full article
(This article belongs to the Section Computer)
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21 pages, 10954 KB  
Article
Settlement Characteristics and Control Parameters for the Integrated Construction of Large-Section Underground Structures and Airport Terminals: A Case Study
by Rongzhen Zhang, Wei Liu, Zekun Wei, Jianyong Han, Guangbiao Shao and Shenao Li
Buildings 2025, 15(17), 3139; https://doi.org/10.3390/buildings15173139 - 1 Sep 2025
Abstract
Settlement control for tunnel–terminal co-construction projects remains undefined, despite the growing trend of integrating multiple transportation modes within large-scale transport hubs. This study investigates a large underground structure passing beneath an airport terminal, combining field investigations, statistical analyses, and finite element simulations to [...] Read more.
Settlement control for tunnel–terminal co-construction projects remains undefined, despite the growing trend of integrating multiple transportation modes within large-scale transport hubs. This study investigates a large underground structure passing beneath an airport terminal, combining field investigations, statistical analyses, and finite element simulations to examine differential settlement behavior under non-uniform loading conditions. The key contribution of this work is the proposal of a differential settlement control standard, defined by the tangent of the rotation angle between adjacent column foundations, with a recommended value of 1/625. Case analysis at cross-section E–E shows that the measured maximum tangent rotation angle was 1/839, corresponding to base slab settlements of 40.5 mm and 33.1 mm for the high-speed railway and metro structures, respectively. Application of the proposed 1/625 criterion yields allowable maximum base slab settlements of 55.28 mm for the high-speed railway and 44.83 mm for the metro, with differential settlement limits of 7.5 mm and 3.13 mm. Numerical simulations confirm the validity of this standard, ensuring the structural integrity of co-constructed systems and providing practical guidance for future airport terminal–tunnel integration projects. Full article
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20 pages, 2798 KB  
Article
Adaptive Fuzzy Fault-Tolerant Formation Control of High-Order Fully Actuated Multi-Agent Systems with Time-Varying Delays
by Yang Cui and Kaichao Liu
Mathematics 2025, 13(17), 2813; https://doi.org/10.3390/math13172813 - 1 Sep 2025
Abstract
The adaptive fuzzy fault-tolerant formation control of nonlinear high-order fully actuated multi-agent systems is studied in this paper, which contains time-varying delays and nonlinear non-affine faults. In contrast to the state-space approach, the proposed control method is based on the fully actuated system [...] Read more.
The adaptive fuzzy fault-tolerant formation control of nonlinear high-order fully actuated multi-agent systems is studied in this paper, which contains time-varying delays and nonlinear non-affine faults. In contrast to the state-space approach, the proposed control method is based on the fully actuated system approach, which does not require converting a high-order system into a first-order one but directly designs controllers for high-order nonlinear multi-agent systems. The time-varying delays of the systems can be solved using the finite covering lemma and fuzzy logic systems. Compared with the traditional Lyapunov–Krasovskii functional method, the proposed control methodology relaxes the constraint of bounded derivatives for time-varying delays. The problem of algebraic loop in controller design caused by nonlinear non-affine faults is avoided using a Butterworth low-pass filter. Based on the Lyapunov stability theory, the proposed controller methodology is demonstrated to ensure the stability of the closed-loop system, and all followers can keep ideal formation with the leader. Finally, the validity of the theoretical results is demonstrated through three simulation examples, and the design steps of the controller for the simulation examples are reduced by fifty percent compared to the state-space method. Full article
(This article belongs to the Special Issue Recent Advances in Nonlinear Control Theory and System Dynamics)
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28 pages, 3878 KB  
Article
All-Grounded Passive Component Mixed-Mode Multifunction Biquadratic Filter and Dual-Mode Quadrature Oscillator Employing a Single Active Element
by Natchanai Roongmuanpha, Jetwara Tangjit, Mohammad Faseehuddin, Worapong Tangsrirat and Tattaya Pukkalanun
Technologies 2025, 13(9), 393; https://doi.org/10.3390/technologies13090393 - 1 Sep 2025
Abstract
This paper introduces a compact analog configuration that concurrently realizes a mixed-mode biquadratic filter and a dual-mode quadrature oscillator (QO) by employing a single differential differencing gain amplifier (DDGA) and all-grounded passive components. The proposed design supports four fundamental operation modes—voltage-mode (VM), current-mode [...] Read more.
This paper introduces a compact analog configuration that concurrently realizes a mixed-mode biquadratic filter and a dual-mode quadrature oscillator (QO) by employing a single differential differencing gain amplifier (DDGA) and all-grounded passive components. The proposed design supports four fundamental operation modes—voltage-mode (VM), current-mode (CM), trans-impedance-mode (TIM), and trans-admittance-mode (TAM)—utilizing the same circuit topology without structural modifications. In filter operation, it offers low-pass, high-pass, band-pass, band-stop, and all-pass responses with orthogonal and electronic pole frequency and quality factor. In oscillator operation, it delivers simultaneous voltage and current quadrature outputs with independent tuning of oscillator frequency and condition. The grounded-component configuration simplifies layout and enhances its suitability for monolithic integration. Numerical simulations in a 0.18-μm CMOS process with ±0.9 V supply confirm theoretical predictions, demonstrating precise gain-phase characteristics, low total harmonic distortion (<7%), modest sensitivity to 5% component variations, and stable operation from −40 °C to 120 °C. These results, combined with the circuit’s low component count and integration suitability, suggest strong potential for future development in low-power IoT devices, adaptive communication front-ends, and integrated biomedical systems. Full article
(This article belongs to the Section Information and Communication Technologies)
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15 pages, 3459 KB  
Article
Modeling Thermal Energy Storage Capability of Organic PCMs Confined in a 2-D Cavity
by Abdullatif A. Gari
Computation 2025, 13(9), 209; https://doi.org/10.3390/computation13090209 - 1 Sep 2025
Abstract
Organic phase change materials (PCMs) are a useful and increasingly popular choice for thermal energy storage applications such as solar energy and building envelope thermal barriers. Buildings located in high-temperature locations are exposed to extreme weather with high solar radiation intensity. PCM envelopes [...] Read more.
Organic phase change materials (PCMs) are a useful and increasingly popular choice for thermal energy storage applications such as solar energy and building envelope thermal barriers. Buildings located in high-temperature locations are exposed to extreme weather with high solar radiation intensity. PCM envelopes could act as thermal barriers on the exterior walls to prevent excessive heat gain and save on air conditioning costs. The PCM cavity is represented as a square cavity in this project. This project studies the effect of different parameters on energy transfer through the cavity. These parameters are PCM, heat flux gain (solar radiation), and time period (day hours). One parameter was changed at a time while others remained the same. This model was simulated numerically using ANSYS FLUENT software version 6.3.26. The project was solved as a transient problem and was run for a full day in simulation time. A pressure-based model was used because it is ideal for viscous flow and suitable for mildly compressible and low-speed flow. The PISO algorithm was used here because of the transient nature of the project. Temperature and convection heat transfer flux on the inner surface were recorded to study how the inner temperature and the amount of convective heat flux gain react to different conditions after energy passes the PCM envelope. It was found that Linoleic Acid provides the highest convective heat flux gain, meaning it provides the lowest thermal resistance. On the other hand, Tricosane was found to provide the lowest convective heat flux gain, meaning it provides the highest thermal resistance. For longer days (τq < 1), the PCM was in a liquid form for a longer time, which means less conduction, while for shorter days (τq > 1), the PCM was in a solid form for a longer time. Full article
(This article belongs to the Special Issue Computational Methods for Energy Storage)
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15 pages, 16310 KB  
Article
Long GHz-Burst Laser Surface Polishing of AlSl 316L Stainless Steel Parts Manufactured by Short GHz-Burst Laser Ablation
by Théo Guilberteau, Florent Husson, Manon Lafargue, John Lopez, Marc Faucon, Laura Gemini and Inka Manek-Hönninger
Nanomaterials 2025, 15(17), 1343; https://doi.org/10.3390/nano15171343 - 1 Sep 2025
Abstract
GHz-burst laser polishing is as a promising technique for improving the surface quality of metallic materials, offering key advantages over conventional methods. In this study, two distinct approaches are investigated: a single-step polishing process, and a double-step process consisting of an initial laser [...] Read more.
GHz-burst laser polishing is as a promising technique for improving the surface quality of metallic materials, offering key advantages over conventional methods. In this study, two distinct approaches are investigated: a single-step polishing process, and a double-step process consisting of an initial laser milling step followed by a finishing/polishing pass. This distinction is critical in evaluating the performance of GHz-burst regimes under different surface conditions and roughness levels. Initial proof-of-concept trials confirm that GHz-burst irradiation can significantly reduce the surface roughness with minimal thermal damage, provided that process parameters are carefully optimized. Further analysis of spot-to-spot overlap reveals that the deposited energy density plays a crucial role in achieving uniform surface quality without inducing surface defects. The number of passes is also studied, showing that while multiple passes can improve surface finish, the benefit strongly depends on the initial roughness state of the substrate. Scalability is demonstrated by increasing both the repetition rate and scan speed proportionally while maintaining processing quality across larger areas. These results support the viability of GHz-burst laser polishing for high-throughput manufacturing. Applications in aerospace, biomedical implants, and precision optics highlight the technique’s potential for industrial adoption in demanding surface finishing contexts. Full article
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28 pages, 4471 KB  
Article
Utilizing Response Surface Methodology for Design Optimization of Stone Mastic Asphalt Containing Palm Oil Clinker Aggregates
by Ali Mohammed Babalghaith, Abdalrhman Milad, Waqas Rafiq, Shaban Shahzad, Suhana Koting, Ahmed Suliman B. Ali and Abdualmtalab Abdualaziz Ali
Eng 2025, 6(9), 213; https://doi.org/10.3390/eng6090213 - 1 Sep 2025
Abstract
This study introduces a novel approach to enhance the sustainability of road pavement construction by utilizing palm oil clinker (POC), an industrial waste product, as a replacement for fine aggregates (passing 4.75 mm) in stone mastic asphalt (SMA) mixtures. Departing from conventional practices, [...] Read more.
This study introduces a novel approach to enhance the sustainability of road pavement construction by utilizing palm oil clinker (POC), an industrial waste product, as a replacement for fine aggregates (passing 4.75 mm) in stone mastic asphalt (SMA) mixtures. Departing from conventional practices, this research comprehensively evaluates the feasibility of using POC at varying replacement levels (0% to 100%) across a range of binder contents (5.0% to 7.0%). A significant contribution of this work is the application of Response Surface Methodology (RSM) to optimize the proportions of POC and binder content (BC), achieving target Marshall and volumetric properties for superior pavement performance. The results demonstrate that POC can effectively substitute fine aggregates in SMA mixtures, meeting all requirements for Marshall stability, flow, stiffness, and volumetric properties, even at a 100% replacement rate. Statistical analysis using RSM confirmed the model’s validity, exhibiting a high R-squared value (>0.80), significant p-values, and an adequate precision exceeding 4. Optimization analysis revealed that a 60% POC content with a 6% BC yields the most desirable combination for achieving optimal SMA mixture characteristics. Further validation through experimental testing showed a strong correlation with the theoretical RSM predictions, with an error margin below 5%. This research underscores the potential of POC as a sustainable alternative to traditional aggregates, paving the way for more environmentally friendly and cost-effective road construction practices while simultaneously addressing waste management challenges in the palm oil industry. Full article
(This article belongs to the Section Chemical, Civil and Environmental Engineering)
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24 pages, 4629 KB  
Review
Wave Energy Conversion Technology Based on Liquid Metal Magnetohydrodynamic Generators and Its Research Progress
by Lingzhi Zhao and Aiwu Peng
Energies 2025, 18(17), 4615; https://doi.org/10.3390/en18174615 - 30 Aug 2025
Viewed by 210
Abstract
Wave energy is a highly concentrated energy resource with five times higher energy density than wind and at least ten times the power density of solar energy. It is expected to make a major contribution to addressing climate change and to help end [...] Read more.
Wave energy is a highly concentrated energy resource with five times higher energy density than wind and at least ten times the power density of solar energy. It is expected to make a major contribution to addressing climate change and to help end our dependency on fossil fuels. Many ingenious wave energy conversion methods have been put forward, and a large number of wave energy converters (WECs) have been developed. However, to date, wave energy conversion technology is still in the demonstration application stage. Key issues such as survivability, reliability, and efficient conversion still need to be solved. The major hurdle is the fact that ocean waves provide a slow-moving, high-magnitude force, whereas most electric generators operate at high rotary speed and low torque. Coupling the slow-moving, high-magnitude force of ocean waves normally requires conversion to a high-speed, low-magnitude force as an intermediate step before a rotary generator is applied. This, in general, tends to severely limit the overall efficiency and reliability of the converter and drives the capital cost of the converter well above an acceptable commercial target. Magnetohydrodynamic (MHD) wave energy conversion makes use of MHD generators in which a conducting fluid passes through a very strong magnetic field to produce an electric current. In contrast to alternatives, the relatively slow speed at which the fluid traverses the magnetic field makes it possible to directly couple to ocean waves with a high-magnitude, slowly moving force. The MHD generator provides an excellent match to the mechanical impedance of an ocean wave, and therefore, an MHD WEC has no rotating mechanical parts with high speeds, no complex control process, and has good response to low sea states and high efficiency under all working conditions. This review introduces the system composition, working process, and technical features of WECs based on MHD generators first. Then, the research development, key points, and issues of wave energy conversion technology based on MHD generators are presented in detail. Finally, the problems to be solved and the future research directions of wave energy conversion based on MHD generators are pointed out. Full article
(This article belongs to the Special Issue Advances in Ocean Energy Technologies and Applications)
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28 pages, 3204 KB  
Article
Design and Experiment of Self-Propelled High-Stem Chrysanthemum coronarium Orderly Harvester
by Daipeng Lu, Wei Wang, Yueyue Li, Mingxiong Ou, Jingtao Ma, Encai Bao and Hewei Meng
Agriculture 2025, 15(17), 1848; https://doi.org/10.3390/agriculture15171848 - 29 Aug 2025
Viewed by 207
Abstract
To address the issues of low efficiency, high cost of manual harvesting, and the lack of mechanized harvesting technology and equipment for high-stem Chrysanthemum coronarium, a self-propelled orderly harvester was designed to perform key harvesting operations such as row alignment, clamping and [...] Read more.
To address the issues of low efficiency, high cost of manual harvesting, and the lack of mechanized harvesting technology and equipment for high-stem Chrysanthemum coronarium, a self-propelled orderly harvester was designed to perform key harvesting operations such as row alignment, clamping and cutting, orderly conveying, and collection. Based on the analysis of agronomic requirements for cultivation and mechanized harvesting needs, the overall structure and working principle of the machine were described. Meanwhile, the key components such as the reciprocating cutting mechanism and orderly conveying mechanism were structurally designed and theoretically analyzed. The main structural and operating parameters of the harvester were determined based on the geometric and kinematic conditions of high-stem Chrysanthemum coronarium during its movement along the conveying path, as well as the mechanical model of the conveying process. In addition, a three-factor, three-level Box-Behnken field experiment was also conducted with the experimental factors including the machine’s forward, cutting, and conveying speed, and evaluation indicators like harvesting loss rate and orderliness. A second-order polynomial regression model was established to analyze the relationship between the evaluation indicators and the factors using the Design-Expert 13 software, which revealed the influence patterns of the machine’s forward speed, reciprocating cutter cutting speed, conveying device speed, and their interaction influence on the evaluation indicators. Moreover, the optimal parameter combination, obtained by solving the optimization model for harvesting loss rate and orderliness, was forward speed of 260 mm/s, cutting speed of 250 mm/s, and conveying speed of 300 mm/s. Field test results showed that the average harvesting loss rate of the prototype was 4.45% and the orderliness was 92.57%, with a relative error of less than 5% compared to the predicted values. The key components of the harvester operated stably, and the machine was capable of performing cutting, orderly conveying, and collection in a single pass. All performance indicators met the mechanized orderly harvesting requirements of high-stem Chrysanthemum coronarium. Full article
(This article belongs to the Section Agricultural Technology)
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18 pages, 4691 KB  
Article
Numerical Analysis and Experimental Verification of Radial Shear Rolling of Titanium Alloy
by Abdullah Mahmoud Alhaj Ali, Anna Khakimova, Yury Gamin, Tatiana Kin, Nikolay Letyagin and Dmitry Demin
Modelling 2025, 6(3), 93; https://doi.org/10.3390/modelling6030093 - 29 Aug 2025
Viewed by 294
Abstract
Numerical simulation of metal forming processes is finding increasingly wide applications in advanced industry for the optimization of material processing conditions and prediction of process parameters, finally delivering a reduction of production costs. This work presents a comparison between simulation results of radial [...] Read more.
Numerical simulation of metal forming processes is finding increasingly wide applications in advanced industry for the optimization of material processing conditions and prediction of process parameters, finally delivering a reduction of production costs. This work presents a comparison between simulation results of radial shear rolling (RSR) of VT3-1 titanium alloy (Ti-Al-Mo-Cr-Fe-Si) and results of experimental RSR at 1060 °C, 980 °C, and 900 °C in one, three, and five passes, respectively. The digital model (DM) demonstrates a high convergence of the calculation results (calculation error of less than 5%) with the actual geometric parameters of the experimental bars, their surface temperature, and rolling time during the experiment, which indicates a good potential for its application in the selection of deformation modes. Based on the simulation and experimental data, the conditions providing for the formation of differently sized grains in the bar cross-section have been identified. All of the as-rolled bars exhibit a gradient distribution of macrostructure grain size number (GSN), from the smallest one at the bar surface (2–4) to the greatest one in the center (4–6). The macrostructure GSN correlates with the workpiece temperature, which is the highest in the axial zone of the bars, and with the experimentally observed high plastic strain figures in the surface layers. It was found that, depending on the temperature conditions and reduction ratio per pass, any minor change in the values of process parameters can lead to the formation of macrostructures with different grain size numbers. Full article
(This article belongs to the Special Issue Finite Element Simulation and Analysis)
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11 pages, 659 KB  
Article
Spectrum Analysis of Thermally Driven Curvature Inversion in Strained Graphene Ripples for Energy Conversion Applications via Molecular Dynamics
by James M. Mangum, Md R. Kabir, Tamzeed B. Amin, Syed M. Rahman, Ashaduzzaman and Paul M. Thibado
Nanomaterials 2025, 15(17), 1332; https://doi.org/10.3390/nano15171332 - 29 Aug 2025
Viewed by 171
Abstract
The extraordinary mechanical flexibility, high electrical conductivity, and nanoscale instability of freestanding graphene make it an excellent candidate for vibration energy harvesting. When freestanding graphene is stretched taut and subject to external forces, it will vibrate like a drum head. Its vibrations occur [...] Read more.
The extraordinary mechanical flexibility, high electrical conductivity, and nanoscale instability of freestanding graphene make it an excellent candidate for vibration energy harvesting. When freestanding graphene is stretched taut and subject to external forces, it will vibrate like a drum head. Its vibrations occur at a fundamental frequency along with higher-order harmonics. Alternatively, when freestanding graphene is compressed, it will arch slightly out of the plane or buckle under the load. Remaining flat under compression would be energetically too costly compared to simple bond rotations. Buckling up or down, also known as ripple formation, naturally creates a bistable situation. When the compressed system vibrates between its two low-energy states, it must pass through the high-energy middle. The greater the compression, the higher the energy barrier. The system can still oscillate but the frequency will drop far below the fundamental drum-head frequency. The low frequencies combined with the large-scale movement and the large number of atoms coherently moving are key factors addressed in this study. Ten ripples with increasing compressive strain were built, and each was studied at five different temperatures. Increasing the temperature has a similar effect as increasing the compressive strain. Analysis of the average time between curvature inversion events allowed us to quantify the energy barrier height. When the low-frequency bistable data were time-averaged, the authors found that the velocity distribution shifts from the expected Gaussian to a heavy-tailed Cauchy (Lorentzian) distribution, which is important for energy harvesting applications. Full article
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16 pages, 7507 KB  
Article
Enhancement of Mechanical Properties and Hydrogen Embrittlement Resistance of Laser-Directed Energy Deposition-Fabricated 316L Stainless Steel by Laser Shock Peening
by Jeonghong Ha
Appl. Sci. 2025, 15(17), 9481; https://doi.org/10.3390/app15179481 - 29 Aug 2025
Viewed by 144
Abstract
316L stainless steel offers attractive characteristics for hydrogen applications, including low hydrogen diffusivity and high hydrogen solubility. However, its use is limited by relatively low strength and resistance to hydrogen embrittlement (HE) under prolonged hydrogen exposure. Laser-directed energy deposition (L-DED) can not only [...] Read more.
316L stainless steel offers attractive characteristics for hydrogen applications, including low hydrogen diffusivity and high hydrogen solubility. However, its use is limited by relatively low strength and resistance to hydrogen embrittlement (HE) under prolonged hydrogen exposure. Laser-directed energy deposition (L-DED) can not only increase the strength of 316L, but also induce significant tensile residual stresses that promote HE. In this study, 316L stainless steel samples produced by L-DED were post-processed by laser shock peening (LSP) to release the tensile residual stresses and refine the near-surface microstructure. LSP-treated samples showed refined grains, higher hardness, and the introduction of compressive residual stress, which led to improved tensile performance in hydrogen. Notably, after seven passes of LSP, the HE index (reduction in elongation due to hydrogen) was 12.5%, compared with 36.1% for the unpeened material. These results demonstrate that LSP is an effective approach to simultaneously increase strength and significantly improve HE resistance in additively manufactured 316L stainless steel. Full article
(This article belongs to the Special Issue The Applications of Laser-Based Manufacturing for Material Science)
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16 pages, 30066 KB  
Article
High Corrosion Resistance of Ti3C2Tx/Al6061 Composites Achieved via Equal Channel Angular Pressing
by Jianchao Chen, Wenjie Hu, Qihong Hu, Zhibin Liu and Hong Yan
Metals 2025, 15(9), 954; https://doi.org/10.3390/met15090954 - 28 Aug 2025
Viewed by 249
Abstract
This study systematically investigates the synergistic corrosion resistance enhancement mechanisms in aluminum matrix composites (AMCs) through the combined implementation of equal channel angular pressing (ECAP) and Ti3C2Tx MXene reinforcement. The results demonstrate that ECAP treatment significantly refines the [...] Read more.
This study systematically investigates the synergistic corrosion resistance enhancement mechanisms in aluminum matrix composites (AMCs) through the combined implementation of equal channel angular pressing (ECAP) and Ti3C2Tx MXene reinforcement. The results demonstrate that ECAP treatment significantly refines the microstructure, reducing grain sizes to an average of 8.7 µm after three passes, while improving mechanical properties such as hardness by 40.6–45.1%. Additionally, the incorporation of Ti3C2Tx enhances corrosion resistance by establishing a physical barrier that impedes the diffusion of corrosive mediators and prevents localized corrosion. Electrochemical tests reveal that the composite subjected to three ECAP passes exhibits the lowest corrosion current density (Icorr) and a remarkable 3.4-fold increase in charge transfer resistance (Rct) compared to untreated material. These findings highlight the potential of synergistically integrating ECAP and Ti3C2Tx to develop high-performance AMCs with enhanced mechanical strength and corrosion resistance, offering significant implications for applications in marine equipment, aerospace, and new energy vehicles. Full article
(This article belongs to the Special Issue Design and Development of Metal Matrix Composites (2nd Edition))
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