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Keywords = hybrid solutions (HbSs)

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14 pages, 1884 KB  
Article
Ag/ZrO2 Hybrid Coating for Tribological and Corrosion Protection of Ti45Nb Alloy in Biomedical Environments
by Mevra Aslan Çakir
Metals 2025, 15(8), 831; https://doi.org/10.3390/met15080831 - 24 Jul 2025
Viewed by 330
Abstract
In this study, a Ag/ZrO2 hybrid coating prepared by the sol–gel method on a β-type Ti45Nb alloy was applied by the spin coating technique, and the microstructural, mechanical, electrochemical, and tribological properties of the surface were evaluated in a multi-dimensional manner. The [...] Read more.
In this study, a Ag/ZrO2 hybrid coating prepared by the sol–gel method on a β-type Ti45Nb alloy was applied by the spin coating technique, and the microstructural, mechanical, electrochemical, and tribological properties of the surface were evaluated in a multi-dimensional manner. The hybrid solution was prepared using zirconium propoxide and silver nitrate and stabilized through a low-temperature two-stage annealing protocol. The crystal structure of the coating was determined by XRD, and the presence of dense tetragonal ZrO2 phase and crystalline Ag phases was confirmed. SEM-EDS analyses revealed a compact coating structure of approximately 1.8 µm thickness with homogeneously distributed Ag nanoparticles on the surface. As a result of the electrochemical corrosion tests, it was determined that the open circuit potential shifted to more noble values, the corrosion current density decreased, and the corrosion rate decreased by more than 70% on the surfaces where the Ag/ZrO2 coating was applied. In the tribological tests, a decrease in the coefficient of friction, narrowing of wear marks, and significant reduction in surface damage were observed in dry and physiological (HBSS) environments. The findings revealed that the Ag/ZrO2 hybrid coating significantly improved the surface performance of the Ti45Nb alloy both mechanically and electrochemically and offers high potential for biomedical implant applications. Full article
(This article belongs to the Special Issue Corrosion Behavior and Surface Engineering of Metallic Materials)
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20 pages, 4572 KB  
Article
Stainless Steel 304 and Carbon Mild Steel A36 Activity in Chloride-Containing Hybrid Pumice-Portland Cement Extract Pore Environment
by David Bonfil, Lucien Veleva and Jose Ivan Escalante-Garcia
Materials 2025, 18(6), 1216; https://doi.org/10.3390/ma18061216 - 9 Mar 2025
Viewed by 891
Abstract
The effect of chlorides on the corrosion activities of SS304 and carbon steel A36 was investigated during immersion in a hybrid pumice–Portland cement extract solution, containing high concentration of chlorides (5 g L1 NaCl), in order to simulate the concrete–pore marine [...] Read more.
The effect of chlorides on the corrosion activities of SS304 and carbon steel A36 was investigated during immersion in a hybrid pumice–Portland cement extract solution, containing high concentration of chlorides (5 g L1 NaCl), in order to simulate the concrete–pore marine environment. The hybrid pumice–Portland cement (HB1) has been considered an alternative “green” cement system. The initial pH of the extract (12.99) decreased to 9.5 after 14 days, inducing a severe corrosion risk for A36, as suggested by the very negative corrosion potential (OCP ≈ −363 mV). Meanwhile, the SS304 tended to passivate and its OCP shifted to positive values (≈+72 mV). Consequently, the surface of the A36 presented a corrosion layer mainly of FeOOH, while that of the SS304 was composed of Cr2O3, Fe3O4 and NiO, according to the SEM-EDS and XPS analysis. An extended area of an almost uniform corrosion attack was observed on the A36 surface, due to the less protective Fe-corrosion products, while the SS304 surface presented some small pits of ≈1 µm. Based on electrochemical impedance measurements, the polarization resistance (Rp) and thickness of the passive layer were calculated. The Rp of the SS304 surface increased by two orders of magnitude up to ≈11,080 kΩ cm2, and the thickness of the layer reached ≈1.5 nm after 30 days of immersion. The Rp of carbon steel was ≈2.5 kΩ cm2  due to the less protective properties of its corrosion products. Full article
(This article belongs to the Special Issue Corrosion Electrochemistry and Protection of Metallic Materials)
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32 pages, 6159 KB  
Article
Geotechnical Aspects of N(H)bSs for Enhancing Sub-Alpine Mountain Climate Resilience
by Tamara Bračko, Primož Jelušič and Bojan Žlender
Land 2025, 14(3), 512; https://doi.org/10.3390/land14030512 - 28 Feb 2025
Viewed by 591
Abstract
Mountain resilience is the ability of mountain regions to endure, adapt to, and recover from environmental, climatic, and anthropogenic stressors. Due to their steep topography, extreme weather conditions, and unique biodiversity, these areas are particularly vulnerable to climate change, natural hazards, and human [...] Read more.
Mountain resilience is the ability of mountain regions to endure, adapt to, and recover from environmental, climatic, and anthropogenic stressors. Due to their steep topography, extreme weather conditions, and unique biodiversity, these areas are particularly vulnerable to climate change, natural hazards, and human activities. This paper examines how nature-based solutions (NbSs) can strengthen slope stability and geotechnical resilience, with a specific focus on Slovenia’s sub-Alpine regions as a case study representative of the Alps and similar mountain landscapes worldwide. The proposed Climate-Adaptive Resilience Evaluation (CARE) concept integrates geomechanical analysis with geotechnical planning, addressing the impacts of climate change through a systematic causal chain that connects climate hazards, their effects, and resulting consequences. Key factors such as water infiltration, soil permeability, and groundwater dynamics are identified as critical elements in designing timely and effective NbSs. In scenarios where natural solutions alone may be insufficient, hybrid solutions (HbSs) that combine nature-based and conventional engineering methods are highlighted as essential for managing unstable slopes and restoring collapsed geostructures. The paper provides practical examples, including slope stability analyses and reforestation initiatives, to illustrate how to use the CARE concept and how NbSs can mitigate geotechnical risks and promote sustainability. By aligning these approaches with regulatory frameworks and climate adaptation objectives, it underscores the potential for integrating NbSs and HbSs into comprehensive, long-term geotechnical strategies for enhancing mountain resilience. Full article
(This article belongs to the Special Issue Impact of Climate Change on Land and Water Systems)
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19 pages, 5236 KB  
Article
Optimal Scheduling for Hybrid Battery Swapping System of Electric Vehicles
by Ziqi Wang and Sizu Hou
Processes 2023, 11(6), 1604; https://doi.org/10.3390/pr11061604 - 24 May 2023
Cited by 3 | Viewed by 2209
Abstract
Range anxiety seriously restricts the development of electric vehicles (EVs). To address the above issue, a hybrid battery swapping system (HBSS) is developed in this paper. In the system, EVs can swap their battery at battery swapping stations or by the roadside via [...] Read more.
Range anxiety seriously restricts the development of electric vehicles (EVs). To address the above issue, a hybrid battery swapping system (HBSS) is developed in this paper. In the system, EVs can swap their battery at battery swapping stations or by the roadside via battery swapping vans. The proposed scheduling strategy aims to achieve the best service quality for the HBSS by controlling the mobile swapping service fee. In the model, the uncertainty of EV selection is managed by leveraging the Sigmoid function. Based on proving the uniqueness of the solution, the particle swarm optimization algorithm is used to solve the problem. Simulations validate the effectiveness of the proposed strategy in alleviating range anxiety. Moreover, the impacts of maximum service capacity and the operating rule have been analyzed. Full article
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16 pages, 6519 KB  
Article
Filterless, Digital Class-BD Audio Amplifiers with Constant Common Mode Output Voltage
by Stanisław Kuta, Witold Machowski, Wojciech Kołodziejski and Łukasz Chlastawa
Energies 2021, 14(21), 7014; https://doi.org/10.3390/en14217014 - 26 Oct 2021
Cited by 2 | Viewed by 2779
Abstract
This paper presents new and original architectures and implementations of two filterless, open-loop digital Class-BD audio amplifiers with constant common mode (CM) output voltage. The first, low-power amplifier consists of four ultrahigh-current EL7158 pin drivers, the OUT pins of which form the H [...] Read more.
This paper presents new and original architectures and implementations of two filterless, open-loop digital Class-BD audio amplifiers with constant common mode (CM) output voltage. The first, low-power amplifier consists of four ultrahigh-current EL7158 pin drivers, the OUT pins of which form the H bridge. The drivers are controlled from the extended LBDD PWM modulator and have appropriately set voltage levels on the VL and VH pins. The second proposed amplifier consists of two cooperating H-bridge power stages (HBS) implemented on complementary MOSFET pairs and powered by two different voltages. Both HBSs are driven by four EL7158 pin drivers having appropriately adjusted voltage levels on the VL and VH pins and controlled by an extended LBDD PWM modulator. The hybrid 9 bit DPWM modulator uses a linearized Class-BD double-sided modulation scheme with pre-compensation, enabling the most faithful emulation of natural NBDD PWM and, thus, providing attractive spectral characteristics at the DM output. Basic SPICE simulations and experimental results of the proposed digital Class-BD amplifiers were compared with the conventional digital Class-BD amplifiers. The elimination of CM signals significantly contributes to the reduction in electromagnetic interference (EMI), particularly those produced on the cables connecting the loudspeaker to the HBS terminal. Proposed Class-BD amplifiers with original and new topologies, due to their simple design and easy control (no galvanic isolation of control signals and no floating bias power supplies), which generate no CM voltage and feature excellent DM performance, similar to conventional Class-BD amplifiers, are very attractive solutions for filterless Class-BD amplifiers. Full article
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17 pages, 4540 KB  
Article
Influence of Controlled Cooling on Crystallinity of Poly(L-Lactic Acid) Scaffolds after Hydrolytic Degradation
by Javier Vazquez-Armendariz, Raquel Tejeda-Alejandre, Aida Rodriguez-Garcia, Yadira I. Vega-Cantu, Christian Mendoza-Buenrostro and Ciro A. Rodriguez
Materials 2020, 13(13), 2943; https://doi.org/10.3390/ma13132943 - 30 Jun 2020
Cited by 9 | Viewed by 2996
Abstract
The use of hybrid manufacturing to produce bimodal scaffolds has represented a great advancement in tissue engineering. These scaffolds provide a favorable environment in which cells can adhere and produce new tissue. However, there are several areas of opportunity to manufacture structures that [...] Read more.
The use of hybrid manufacturing to produce bimodal scaffolds has represented a great advancement in tissue engineering. These scaffolds provide a favorable environment in which cells can adhere and produce new tissue. However, there are several areas of opportunity to manufacture structures that provide enough strength and rigidity, while also improving chemical integrity. As an advancement in the manufacturing process of scaffolds, a cooling system was introduced in a fused deposition modeling (FDM) machine to vary the temperature on the printing bed. Two groups of polylactic acid (PLA) scaffolds were then printed at two different bed temperatures. The rate of degradation was evaluated during eight weeks in Hank’s Balanced Salt Solution (HBSS) in a controlled environment (37 °C–120 rpm) to assess crystallinity. Results showed the influence of the cooling system on the degradation rate of printed scaffolds after the immersion period. This phenomenon was attributable to the mechanism associated with alkaline hydrolysis, where a higher degree of crystallinity obtained in one group induced greater rates of mass loss. The overall crystallinity was observed, through differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA), and Fourier transformed infrared spectroscopy (FTIR) analysis, to increase with time because of the erosion of some amorphous parts after immersion. Full article
(This article belongs to the Special Issue Additive Manufacturing (AM) of Biomaterials)
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