Search Results (17)

Groundwater–surface water interactions in volcanic hydrogeological systems represent a key process in river dynamics and were preliminarily investigated along a river draining the southern sector of the Sabatini Mountains (central Italy) using an integrated hydrogeological and geochemical approach. Serial discharge measurements, combined with physico-chemical parameters, major ions, stable oxygen isotopes, and radon analyses, reveal marked spatial variability in river–aquifer exchanges along distinct river reaches. The Arrone River exhibits clear differences between upstream, intermediate, and downstream sections, reflecting the relative influence of localized anthropogenic inputs, diffuse groundwater discharge from the volcanic aquifer, and subsurface flow contributions. Upstream reaches are characterized by pronounced modifications in discharge and chemistry, whereas intermediate and downstream reaches show progressive groundwater influence, resulting in distinct geochemical signatures and changes in water quality. Correlation and cluster analyses identify reach-specific processes controlling water composition and support the recognition of gaining and mixed river conditions under varying hydrological regimes. These results constrain a conceptual model in which river behavior is governed by spatially heterogeneous groundwater inflows, modulated by seasonal discharge dynamics and local human pressures. This study highlights the importance of reach-scale investigations for understanding SW–GW interactions in volcanic settings and provides transferable insights relevant to groundwater-dependent river systems. Full article

Groundwater is a critical resource in the arid Chili River sub-basin (3246 km²) in Arequipa, southern Peru, yet the aquifer systems, their recharge mechanisms, and chemical evolution remain poorly characterized. This study integrates hydrogeological mapping, major-ion hydrochemistry (31 samples from springs and wells), and stable-isotope tracing (δ¹⁸O and δ²H, 11 sources) to delineate aquifer types, groundwater flow systems, and recharge dynamics across an elevation gradient of 2000–4000 m a.s.l. Three principal aquifer groups were identified: unconsolidated porous aquifers beneath the Arequipa urban area, fracture-controlled volcanic aquifers associated with the Chachani, Misti, and Pichupichu volcanic complexes, and sedimentary fractured aquifers of the Yura Group. Piper and Stiff diagrams reveal a chemical evolution from calcium-bicarbonate waters at high elevations to sodium-chloride waters in the lowlands, while scatter-plot analysis distinguishes local, intermediate, and regional flow systems. Elevated boron concentrations linked to borate deposits on Pichupichu volcano pose a potential health risk in supply springs such as La Bedoya. Isotopic signatures confirm that wells are recharged predominantly by high-altitude rainfall (>4000 m a.s.l.), whereas springs integrate water from multiple elevations through fractured volcanic formations. These findings provide a scientific basis for recharge-zone protection, abstraction planning, and water-quality monitoring to sustain groundwater supply under increasing urbanization and climatic variability. Full article

The southeastern Iberian Peninsula, particularly the Águilas Arc within the Neogene Volcanic Province (NVP), represents a promising geothermal domain with complex tectonics and geology. The Palomares Fault Zone (PFZ), a key shear structure initiated during the Late Miocene, acts as a conduit for fluid migration, promoting mineralization and potential anomalies of rare and critical metals through fluid–rock interaction. This study investigates such interactions in the southernmost Águilas Arc, focusing on the El Arteal fault segment within the eastern PFZ strand. Mineralogical, geochemical, and hydrogeological analyses were performed using XRD, SEM, and ICP-MS techniques. Results reveal six mineral assemblages (MA) within the fault segment where the fault gouge samples were characterized by cataclastic textures and the occurrence of authigenic minerals, including halite, kaolinite, illite, paragonite, goethite, hematite, gypsum, barite, celestine, and quartz. Geochemical data indicate enrichment signatures in large-ion lithophile elements (LILE) and minor chalcophile and light rare-earth elements (LREE). Two thermal hydrofacies with alkaline metals enrichment were identified in wells and mine shafts: (1) Na⁺SO₄²⁻ and (2) Na⁺Cl⁻, where the latter exhibits high Na⁺ and Cl⁻ concentrations toward deeper sectors. These findings suggest multiple stages of fluid–rock interaction controlled by temperature: an early phase dominated by epithermal mineralization, followed by late-stage circulation of hypersaline fluids. This evolution provides an abnormal geochemical signature that is unique in the Aguilas Arc Geothermal System. Full article

The purpose of this study was to enhance the understanding and sustainable groundwater management of volcanic aquifer systems by estimating key hydrogeological parameters. The transmissivity of a volcanic aquifer system was estimated using analytical solutions based on 68 constant rate and recovery data sets collected from various sources. A combination of hydro-lithostratigraphy and diagnostic plots was employed to identify the aquifer types and flow conditions, which facilitated model selection. Transmissivity of the confined aquifer was modeled using both Theis and Cooper–Jacob methods, with the Theis residual drawdown solution utilized for estimation. For the unconfined aquifer, the Neuman method was used, and the Hantush/Jacob method was employed for leaky aquifers. The results showed that the transmissivity of the Tertiary basalt varied from 0.38 m²/d to 860 m²/d, while the Quaternary aquifer system ranged from 2.33 m²/d to 1.8 × 10⁴ m²/d, indicating an increase in transmissivity with younger volcanic flows. Specific capacity (SC) was estimated for 74 wells and the values ranged from 0.62 to 5860 m²/d. This wide variation of specific capacity and transmissivity showed significant heterogeneity within the volcanic aquifers. This study introduces the innovative application of derivative diagnostic plots in groundwater research, offering an efficient approach for analyzing and interpreting pumping test data to characterize aquifer systems in various hydrogeologic units. This study focuses on aquifer characterization in hard rock formation, demonstrating methods that can be applied to similar geological environments globally. For the Blue Nile basin in general and for the Lake Tana basin in particular, the study result of aquifer characterization will contribute to exploration, development, and improved groundwater management in the region. Full article

Water quality is a fundamental aspect of public health and environmental sustainability. In rural areas, the physicochemical and microbiological quality of drinking water depends not only on hydrogeological conditions but also on anthropogenic activities carried out on the surface of the basin. This study aimed to identify natural and anthropogenic influences related to the quality of drinking water in rural areas of southern Chile. In order to perform this, six rural drinking water systems were evaluated. A total of two types of catchment sources (groundwater and surface water) that were located in a longitudinal gradient were used, where coverage and sequences of rocks and soils could be differentiated. The results show that the water delivered by the majority of rural drinking water systems studied was of good quality, meeting the standards of Chilean and international regulations. No fecal coliforms or Escherichia coli were recorded. In addition, we recorded that turbidity, color, pH, concentration of total dissolved solids and fecal coliforms showed significant differences between groundwater and surface water. We also recorded that in two groundwater systems, iron and manganese levels slightly exceeded the regulations, endangering the acceptability of the water. These increases can be related to the natural origins of the metals, linked to the presence of oxides in Andisol- and Utisol-type volcanic soils. Full article

Groundwater resource management requires understanding the groundwater basin’s hydrogeology and would be improved with the development of a three-dimensional hydrogeologic framework model (HFM). A wide range of methods and software exist to quantify the extent, structure, and properties of geologic systems. However, most geologic software is proprietary and cost-prohibitive for use in developing countries. GemPy is a Python-based, open-source (no-cost) tool for generating three-dimensional geological models. This study uses available data and GemPy to develop the Kobo Valley Hydrogeologic Framework Model (KV-HFM), a three-dimensional HFM for Kobo Valley in northern Ethiopia, which is part of the East African Rift System. The KV-HFM is a conceptual model that comprises the hydrostratigraphy, structural features, and hydraulic properties of the Kobo Valley groundwater system. The limited data described the extent and altitude of the hydrostratigraphic units using the GemPy implicit potential–field interpolation. The KV-HFM showed the existence of an east-to-west, structural-based groundwater divide composed of volcanic rock and clay. This divide splits the catchment into two groundwater systems with limited interconnected flow. This study illustrates the use of open-source software for developing an HFM using sparse, existing geologic data. Full article

In this study, we present the hydrogeological, hydrogeochemical and isotopic characterisation and monitoring activity of a closed landfill located in the northern sector of the Phlegrean Fields groundwater body in the Campania Region (Southern Italy). The aim of the study is to distinguish between natural enrichments (e.g., geogenic sources) and anthropogenic pressures (e.g., leakages from the landfill body) causing anomalously high concentrations of some metals (As, F, Fe, Mn) in groundwater. Major anions, cations, metals, water-stable isotopes, carbon isotopes and tritium were analysed. The results show that high As, F and Fe concentrations are due to adsorption–desorption processes occurring in the aquifer hosted in the volcanic rocks/deposits or the occurrence of upwelling hydrothermal fluids related to the volcanic activity of the Phlegrean Fields, which may cause metal mobilisation. High localised Mn concentrations cannot be solely related to natural processes or to groundwater contamination due to leachate leakage from the landfill body. Instead, we hypothesise a leakage from the landfill gas system. The outcomes of this study show the advantages of the coupled use of physico-chemical and isotopic analyses in improving the comprehension of geochemical processes in areas characterised by the presence of municipal landfills. Full article

A database consisting of 163 data on the uranium content and ²³⁴U/²³⁸U initial activity ratio of 15 Italian travertine and calcareous tufa sites was created using data from the relevant literature. Using a graphical method, data were interpreted considering the U geochemistry in natural environments as well as the geological, hydrogeological and hydrogeochemical settings of each site. The U content and ²³⁴U/²³⁸U initial activity ratio in travertine and tufa appear to be affected by different factors, such as the availability of U in the aquifer rocks, the redox state of the waters, and the alpha-active radionuclide recoil phenomenon. The data allow the identification of four groups of travertines/tufas: (i) those precipitated from circulating groundwater, with a short/fast flow path, in volcanic rocks with a high radionuclide content; (ii) those precipitated from circulating groundwater, with a long, deep flow path in carbonate/evaporite formations with a relatively low radionuclide content; and (iii) those precipitated from cold waters associated with riverine systems, which are characterized by oxidizing conditions and fed by high-discharge springs recharged by carbonate aquifers. The fourth group represents the intermediate situations frequently occurring due to the mixing of waters from different aquifers. The results suggest an interpretative model that might contribute to the paleo-environmental reconstruction of fossil travertine and calcareous tufa depositing systems. Full article

This study focused on 13 water samples collected from two of the main active volcanoes (Furnas and Fogo) at São Miguel, Azores. Based on the major element composition, the waters are classified into Na-HCO₃ and Na-Cl types. While the concentrations of chloride seem to reflect the contribution of sea salt aerosols, the behavior of the main cationic species and Sr in the analyzed waters appear to have been largely controlled by the interaction between meteoric waters and the underlying bedrock. The temperature and input of CO₂ from the secondary volcanic activity are enhancing the silicate leaching. The stable isotopic data show that these waters have a meteoric origin (δ¹⁸O = −2.03 to −4.29‰; δ²H = −7.6 to −17.4‰) and are influenced by a deep hydrothermal/volcanic carbon source (δ¹³C = −4.36 to −7.04‰). The values of δ³⁴S (0.13 to 12.76‰) reflects a juvenile sulfur source derived from the leaching of volcanic rocks. The Sr isotopic ratios show a slight difference between the values from Furnas (⁸⁷Sr/⁸⁶Sr = 0.705235–0.705432) and Fogo (⁸⁷Sr/⁸⁶Sr = 0.705509–0.707307) whereas the Furnas waters are less radiogenic. The Sr isotope also shows that the hydrochemical signatures of the groundwater was controlled by the rock leaching, and the samples Furnas reached water-rock isotopic equilibrium. Full article

In the Western United States, volcanic spring-fed rivers are anticipated to become increasingly more important for salmonids and other native fishes, as these rivers will retain coldwater habitats as the climate warms. Despite this, little is known about the hydro-biogeochemical interactions within these ecosystems. A review of existing literature on spring-fed rivers, coupled with a decade of research on volcanic spring-fed rivers of northern California, finds that these systems are exceptionally productive and exhibit stable environmental conditions. These unique conditions stem from hydrogeologic processes typical of young volcanic terrains. Aquatic macrophytes, common to some nutrient-rich spring-fed systems, play a disproportionate role in hydrologic and geomorphic processes by facilitating ecological interactions and velocity conditions that improve juvenile salmonid growth. We find that volcanic spring-fed rivers are also resilient to climate change, due not only to their ability to dampen water temperature changes through deep groundwater flow but also because of their nutrient-driven high ecosystem productivity, which may enable coldwater species to metabolically compensate for marginal increases in water temperature. Understanding the fundamental geomorphic and ecological differences between these rare ecosystems and their numerically dominant runoff rivers is essential for developing long-term conservation strategies for coldwater species under a rapidly changing climate. Full article

The Lake Tana Basin, comprising the largest natural lake in Ethiopia, is the source and the uppermost part of the Upper Blue Nile Basin. In this review paper, research papers, mainly on the rainfall-runoff modeling and lake water balance, and on the hydrogeology, have been reviewed. The earlier water balance estimation attempts used simple conceptual and statistical approaches and calculate on a monthly timescale. More recent research has been using advanced semi-physically or physically based distributed hydrological models. Accordingly, mean annual precipitation over the lake was estimated in the range 36.1–53.1%; lake evaporation at 45.3–57.5%; river inflow (all gauged and estimated ungauged) at 43.6–63.9%; and river (lake) water outflow at 0–9.2%. With the few isotope studies, groundwater inflow and outflow are found insignificant. Different studies had estimated groundwater recharge, ranging from 57 mm to 850 mm. The basin has a heterogenous aquifer system consisting of different volcanic rocks and alluvio-lacustrine sediments. Generally, groundwater with low TDS, Ca–Mg–HCO₃ type, isotopically relatively enriched, and high TDS, Na–HCO₃ type, isotopically relatively depleted, water types have been identified. In this paper, major research gaps such as aquifer hydraulic characterization, surface-groundwater interaction, groundwater flow and groundwater balance have been identified. Hence, future research shall focus on the groundwater resources, so that existing surface water studies are updated and future water usage options are explored. Full article

The Pannonian basin is a major geothermal heat system in Central Europe. Its peripheral basin, the East Slovakian basin, is an example of a geothermal structure with a linear, directed heat flow ranging from 90 to 100 mW/m² from west to east. However, the use of the geothermal source is limited by several critical tectono-geologic factors: (a) Tectonics, and the associated disintegration of the aquifer block by multiple deformations during the pre-Paleogene, mainly Miocene, period. The main discontinuities of NW-SE and N-S direction negatively affect the permeability of the aquifer environment. For utilization, minor NE-SW dilatation open fractures are important, which have been developed by sinistral transtension on N–S faults and accelerated normal movements to the southeast. (b) Hydrogeologically, the geothermal structure is accommodated by three water types, namely, Na-HCO₃ with 10.9 g·L⁻¹ mineralization (in the north), the Ca-Mg-HCO₃ with 0.5–4.5 g·L⁻¹ mineralization (in the west), and Na-Cl water type containing 26.8–33.4 g·L⁻¹ mineralization (in the southwest). The chemical composition of the water is influenced by the Middle Triassic dolomite aquifer, as well as by infiltration of saline solutions and meteoric waters along with open fractures/faults. (c) Geothermally anomalous heat flow of 123–129 °C with 170 L/s total flow near the Slanské vchy volcanic chain seems to be the perspective for heat production. Full article

Archeological sites close to coastal volcanic-sedimentary aquifers are threatened by groundwater contaminated by natural and anthropogenic processes. The paper reports on a hydrogeological, chemical (major, minor and trace elements) and isotopic (δD-H₂O, δ¹⁸O-H₂O, δ¹⁵N-NO₃, δ¹⁸O-NO₃, δ¹¹B, ²²²Rn) survey of groundwater at the Cumae archaeological site, which is located in the coastal north-western sector of the volcanic district of Phlegraean Fields (southern Italy), where groundwater flooding phenomena occur. Results show the presence of a complex coastal volcanic-sedimentary aquifer system where groundwater quality is influenced mainly by: (i) aquifer lithology and localized ascent of magmatic fluids along buried volcano-tectonic discontinuities, (ii) mixing of groundwater, deep mineralized fluids and seawater during groundwater pumping, and (iii) nitrate contamination >50 mg/L from non-point agricultural sources. Moreover, δD and δ¹⁸O point toward fast recharge from seasonal precipitations, while the isotopic ratios of N and O in nitrate reveal the contribution of mineral and organic fertilizers as well as leakage from septic tanks. Results can assist the local archaeological authority for the safeguarding and management of the archaeological heritage of the Cumae site. Full article

The hydrogeological system of the Goda Mountains Range (GMR) in the Republic of Djibouti (Horn of Africa), hosted by volcanic and sedimentary formations, is the only water resource in the Tadjourah region for more than 85,000 inhabitants. Water needs are expected to drastically increase in the coming years, due to fast socio-economic development of the region. Accordingly, this system is under high pressure and should sustainably be exploited. However, little is known about the hydrogeology of this system. This study aims to improve the understanding of the hydrochemistry and the recharge processes of this system. The study is based on the combined interpretation of major ions, stable isotopes (¹⁸O, ²H), and radiogenic isotopes (³H, ¹⁴C). The interpretation of major ions contents using classical hydrochemical methods and principal component analysis highlighted that alteration of volcanic rocks minerals, coastal rainfall infiltration, and evaporation are the main processes from which groundwater acquires mineralization. Stable isotopes revealed that groundwater is of meteoric origin and has undergone high evaporation during infiltration. Radiogenic isotopes showed that groundwater in the basalts is mostly submodern to old, in relation with low hydraulic conductivity of the rocks and/or longer pathways through fissures from outcrop to subsurface. Groundwater in the rhyolites is much younger compared to the basalts due to faster infiltration. The sedimentary part, in connection with the rhyolites, has younger waters compared to the basalts, but older compared to the rhyolites. The overall results show that GMR is a fairly complex hydrogeological system, containing a resource made up of a mixture of waters of different ages. This study has made significant progress in understanding this system and is an initial step towards the sustainable exploitation of resources. Full article

The major springs in the Infranz catchment are a significant source of water for Bahir Dar City and nearby villages, while sustaining the Infranz River and the downstream wetlands. The aim of the research was to understand the hydrogeological conditions of these high-discharge springs and the recharge–discharge relations in the Infranz catchment. The Infranz catchment is covered by highly pervious and young quaternary volcanic rocks, consisting of blocky, fractured, and strongly vesicular scoriaceous basalt. At the surface, these rocks crop out as lineaments forming ridges, delimiting closed depressions in which water accumulates during the rainy season without causing surface runoff. Geology and geomorphology thus combine to produce very favorable conditions for groundwater recharge. Three groundwater recharge methods were applied to estimate groundwater recharge and the results were compared. Groundwater recharge was calculated to be 30% to 51% of rainfall. Rapid replenishment raises the groundwater level during the rainfall period, followed by a rapid decline during the dry season. Shallow local flow paths discharge at seasonal springs and streams, while more regional and deeper flow systems downstream sustain the high-discharge springs and perennial Infranz River. The uptake of 75% of spring water for the water supply of Bahir Dar City, local extraction for domestic and small-scale irrigation use from springs, rivers and hand-dug wells, encroaching farming, and overgrazing are exacerbating wetland degradation. Full article