Search Results (375)

This study was focused on addressing the performance degradation in core microstructures of ultra-heavy steel plates (thickness ≥ 50 mm) caused by non-uniform cooling during thermo-mechanical controlled processing. Using microalloyed DH36 steel as the research subject, we systematically investigated the effects of cooling rate on the nucleation and growth of acicular ferrite and its consequent microstructure-property relationships through an integrated approach combining in situ observation via high-temperature laser scanning confocal microscopy with multiscale characterization techniques. Results demonstrate that the cooling rate significantly affects acicular ferrite formation, with the range of 3–7 °C/s being most conducive to acicular ferrite formation. At 5 °C/s, the acicular ferrite volume fraction reached a maximum of 74% with an optimal aspect ratio (5.97). Characterization confirmed that TiOx-Al₂O₃·SiO₂-MnO-MnS complex inclusions act as effective nucleation sites for acicular ferrite, where the MnS outer layer plays a key role in reducing interfacial energy and promoting acicular ferrite radial growth. Furthermore, the interlocking acicular ferrite structure was shown to enhance microhardness by 14% (HV0.1 = 212.5) compared to conventional ferrite through grain refinement strengthening and dislocation strengthening (with a dislocation density of 2 × 10⁸ dislocations/mm²). These results provide crucial theoretical insights and a practical processing window for strengthening-toughening control of heavy plate core microstructures, offering a viable pathway for improving the comprehensive performance of ultra-heavy plates. Full article

This study investigates the influence of heavy-layer thickness on shock-accelerated interfacial instabilities in single-mode stratifications using high-order discontinuous Galerkin simulations at a fixed shock Mach number ($M_s=1.22$). By systematically varying the layer thickness, we quantify how acoustic transit time, shock attenuation, and phase synchronization modulate vorticity deposition, circulation growth, and interface deformation. The results show that thin layers ($d=2.5$–5 mm) generate strong and early baroclinic vorticity due to frequent reverberations, leading to rapid circulation growth, vigorous Kelvin–Helmholtz roll-up, and early jet pairing. In contrast, thick layers ($d=20$–40 mm) attenuate and dephase shock returns, producing weaker baroclinic reinforcement, delayed shear-layer growth, and smoother interfaces with reduced small-scale activity, while the intermediate case ($d=10$ mm) exhibits transitional behavior. Integral diagnostics reveal that thin layers amplify dilatational, baroclinic, and viscous vorticity production; sustain stronger circulation and enstrophy growth; and transfer bulk kinetic energy more efficiently into interface deformation and small-scale mixing. Full article

Spread-tow woven fabrics (STWs) have attracted considerable attention owing to their thin-layered characteristics, high fiber strength utilization rate and superior designability, finding wide application in the aerospace field. To meet the application requirements for materials with high specific strength/specific modulus in the aerospace field, this study designed an anti-sandwich structured composite with high specific load-bearing capacity. Herein, the core layer was a load-bearing structure composed of STW, while the surface layers were hybrid lightweight structures made of STW and nonwoven (NW) felt. Repeated impact test results showed that increasing the thickness ratio of the core layer enhanced the impact resistant stiffness of the overall structure, whereas increasing the proportion of NW felt in the surface layers improved the energy absorption of the composites but reduced their load-bearing stiffness and strength. The composite exhibited superior repeated impact resistance, achieving a peak impact load of 17.43 kN when the thickness ratio of the core layer to the surface layers was 2:1 and the hybrid ratio of the surface layers was 3:1. No penetration occurred after 20 repeated impacts at the 50 J or 3 repeated impacts at 100 J. Meanwhile, both the maximum displacement and impact duration increased, whereas the bending stiffness declined as the number of impacts increased. The failure mode was mainly characterized by progressive interfacial cracking in the surface layers and fracture in the core layer. Full article

A duplex coating system, consisting of a laser-cladded Fe-Cr-based interlayer and a silicon-doped diamond-like carbon (Si-DLC) top layer, was deposited on medium carbon steel substrate using laser cladding (LC) followed by plasma-enhanced chemical vapor deposition (PECVD). The LC interlayer (thickness of 1.5 mm, hardness of 455–620 HV0.3) was applied on both argon ion-etched and non-etched substrate surfaces. The microstructure and adhesion strength of the coatings were systematically investigated. The results show that the LC interlayer significantly enhanced the mechanical support for the Si-DLC coating, increasing adhesion strength by 4~5 times compared to direct deposition. Argon ion etching introduced micro-roughened surface features, increasing interfacial contact area and further boosting adhesion. A synergistic effect was observed between substrate hardness and ion etching in enhancing Si-DLC coating adhesion. Full article

This study presents a multiphysics simulation approach to optimize graphite-buffered bilayer anodes for enhanced energy density in lithium-ion batteries, assessing the electrochemical impact of diverse inner-layer materials, including silicon, hard carbon, lithium titanate (LTO), and metallic lithium, in pure and graphite-composite forms. A coupled finite-element model implemented in COMSOL Multiphysics 6.2 was used to integrate spherical lithium diffusion, charge conservation, and the solid electrolyte interphase (SEI) formation kinetics. The evaluated anode structure consisted of a 60 µm-thick bilayer: a 30 µm graphite surface layer coupled with a 30 µm inner layer of alternative active materials. Simulations were performed using an NMC622 cathode, LiPF₆ in EC:EMC electrolyte, at room temperature, under a charge rate of 1 C, considering realistic particle sizes (graphite: 2.5 µm; Si: 0.1 µm; hard carbon: 2.5 µm; LTO: 0.2 µm; Li metal: 0.5 µm), and evaluated over 2000 cycles. The hard carbon/graphite configuration exhibited a capacity fade of 5.8% compared with 7.1% in pure graphite. Additionally, the SEI thickness decreased to 0.20 µm (from 0.25 µm), the overpotential dropped to −17 mV (from −59 mV), and the electrolyte consumption was reduced to 20.8% (from 42.9%). The analysis highlights hard carbon and LTO inner layers as optimal trade-offs between capacity and cycle stability, whereas silicon and lithium metal significantly increased the initial capacity but accelerated SEI formation and impedance growth. These findings demonstrate the graphite-buffered bilayer’s potential to decouple interfacial degradation from high-capacity materials, providing valuable guidelines for the design of advanced lithium-ion battery anodes. Full article

Cu-20Pb-5Sn/45 steel bimetallic composites were prepared using the solid–liquid composite method. The interfacial microstructure, bonding strength, and wear performance were systematically characterized to elucidate the mechanisms governing the solid-solution interface and copper alloy layer wear behavior. The results reveal that mutual diffusion of Cu and Fe forms a metallurgically bonded α-(Cu,Ni)/α-Fe interface with a diffusion layer thickness of approximately 10.7 µm and an interfacial shear strength of 227.58 MPa. Under dry sliding conditions, the average coefficient of friction was 0.145, with a wear rate of 7.3665 × 10⁻⁶ mm³/(N·m). The α-(Cu,Ni) matrix was reinforced by hard Cu₃P and Ni-rich phases, which resist frictional shear stresses, while dispersed Pb particles provide self-lubricating properties, while the solid-solution interface hindered dislocation propagation, reducing dislocation pile-up and ensuring stable frictional performance. Full article

This study analytically investigates shear horizontal (SH) wave propagation in a layered structure consisting of a piezoflexoelectric (PFE) layer bonded to an elastic substrate, considering an imperfect interface. A frequency equation is derived by applying appropriate boundary and interfacial conditions, capturing the effects of flexoelectric coupling, interface imperfections, the layer thickness, and the material properties. The resulting dispersion relation reveals that both interface imperfections and the flexoelectric strength significantly alter the phase velocity of SH waves. Numerical simulations show that increasing flexoelectric coefficients or interface imperfections lead to notable changes in dispersion behavior. Comparative analyses under electrically open (EO)- and electrically short (ES)-circuited boundary conditions demonstrate their impacts on wave propagation. These findings offer new insights into the design and analysis of piezoflexoelectric devices with realistic interface conditions. Full article

In this study, electron beam welding (EBW) experiments for TA1 and industrial high-purity Al were carried out, and the effects of a Ti_32.8Zr_30.2Cu₉Ni_5.3Be_22.7 amorphous interlayer on the microstructure and properties of the welded joints were investigated. This is the first application of this interlayer material in the field of Ti/Al dissimilar-metal welding. In order to better improve the interfacial reaction of the welded joints and effectively control the thickness of intermetallic compounds (IMCs), the electron beam was offset by 1 mm towards the Al side. The results indicate that the amorphous interlayer was beneficial for improving the performance of the welded joints, with the maximum tensile strength reaching 94.8 MPa, which was 97% of the strength of the Al base material (97.7 MPa). The thickness of the Ti-Al intermetallic compound (IMC) layer formed in the upper part of the welded joints was lower compared with the joints without an interlayer, and the IMC layer formed in the lower part of the welded joints was only 1–2 μm. Additionally, a large number of small-sized and dispersed Ti-Al and Al-Zr IMCs were generated on the Al side, which positively impacted the performance of the welded joints. Full article

This study investigates the insufficient surface hardness of medium-carbon 45 steel and the drawbacks associated with conventional surface modification techniques (e.g., cracking in laser cladding, weak bonding in thermal spraying, restricted thickness in chemical deposition). Series CeO₂-Ni/WC composite claddings (with CeO₂ content ranging from 0.5 to 2.0 wt %) were fabricated via vacuum cladding. The cladding with 0.5 wt % CeO₂ (NWC5) exhibited the lowest porosity (0.0673%) and finest grain size (12.06 nm) and demonstrated the highest microhardness (1042.74 HV0.2) and elastic modulus (269.06 GPa), respectively. The interfacial friction coefficient (0.343–0.444) was significantly reduced compared to the surface friction coefficient (0.562–0.617). Wear track analysis revealed that the width in the cladding layer-to-substrate transition zone (CTSZ) was 22.1–43.2% wider than that in the substrate-to-cladding layer transition zone (STCZ). This disparity is attributed to stress concentration induced by the abrupt hardness change across the CTSZ, promoting the formation of a three-tiered step structure (with a step height difference of 2.1–4.1 µm). In contrast, the progressive hardness series in the STCZ facilitated a smoother wear surface. The dominant wear mechanism was identified as a combination of abrasive and oxidative wear. This study provides a theoretical foundation for optimizing such high-reliability components. Full article

The purpose of this in silico study was to evaluate the main difference of the adhesion strength of direct and semi-direct composite resin restorations in dentin using micro-tensile testing (μTBS) and finite element analysis (FEA). This in silico study employed cohesive zone traction and shear laws to investigate interfacial damage in both restoration groups. Tridimensional finite element models of both restoration specimens were created. A 20 μm thick resin cement layer was created for the semi-direct case. The Clearfil SE Bond 2 adhesive system and the restorative material, Ceram X Spectra ST HV composite resin, were used on both restorations. The numerical bond strength of both restoration techniques was evaluated using two different analysis assumptions. In the first assumption, the numerical analysis procedure included only the non-linear behavior of dentin and the von Mises damage criterion, whereas cohesive zone models were included in the second analysis assumption. The influence of dentin-adhesive cohesive mechanical properties was studied using values reported in the literature, and a sensitivity study helped improve the correlation between experimental and numerical results. The mechanical properties of the composite cohesive zone were defined assuming that the interface strength of dentin and composite follows the values reported by the manufacturer of Spectra ST. Damage initiation and progression were analyzed, and strains and stresses of the cohesive zone models (CZM) were compared with the corresponding perfect bonded models. The experimental µTBS results for the direct restoration strategy showed an adhesive strength of 38.156 ± 10.750 MPa, while the CZM predicted a slightly higher value of 40.4 ± 10.8 MPa. For the indirect restoration strategy, the experimental adhesive strength was 25.449 ± 10.193 MPa, compared to a numerically predicted strength of 28.1 ± 9.3 MPa. Overall, the CZM tends to overestimate the adhesive strength relative to experimental values. The statistical analysis of dentin extension strains for direct (DR) and semi-direct (SR) group models reveals that the SR configuration yields higher strain levels. Hence, these results suggest that, assuming identical dentin properties across both restoration groups, the material configuration in the direct restoration offers better mechanical protection to the dentin. These findings highlight the critical role of incorporating damage mechanics to more accurately characterize stress distribution during tooth rehabilitation. Full article

A novel structure–functional-integrated particle featuring dual micromechanical interlocking property with resin matrix was constructed through surface modification of urchin-like serried hydroxyapatite (UHA) in this work, and the effect of this modification strategy on physicochemical and biological properties of dental resin composite was also investigated. A porous silica coating layer was anchored onto UHA surface via a simple template method in an oil−water biphase reaction system, and the coating time had a prominent effect on the coating thickness and morphology-structure of the particle. When these particles with different porous silica coating thickness were used as fillers for dental resin composite, results showed that UHA/PS5 (porous silica coating reaction time: 5 h) exhibited the optimal 3D urchin-like structure and a desirable porous silica coating thickness. Additionally, UHA/PS5 formed the best dual physical micromechanical interlocking structure when mixing with resin matrix, making the dental resin composites presented the desirable matrix/filler interfacial bonding, and the excellent physicochemical–biological properties, especially for flexural strength and water sorption-solubility. In vitro remineralization and cellular biological properties confirmed that the coating layer did not compromise their remineralization activity. The use of UHA/PSx provides a promising approach to develop strong, durable, and biocompatible DRCs. Full article

Metallic nanolaminates generally show ultra-high strength but low ductility due to their vulnerability to shear instability during deformation. Herein, we report the simultaneous enhancement in hardness (by 11.9%) and suppression of shear instability in a 10 nm Cu/Zr nanolaminate, achieved by introducing a nanoscale Cu₆₃Zr₃₇ amorphous interfacial layer (AIL) between the crystalline Cu and Zr layers via magnetron sputtering. The effect of AIL and its thickness (h) (h = 2, 5, and 10 nm) on the hardness and shear instability behavior was explored using nano- and micro-indentation tests. An abnormal increase in hardness occurs at h = 2 nm when h is decreased from 10 to 2 nm, deviating from the prediction of the rule of mixtures. This abnormal strengthening is attributed to thinner AIL, which induces an increased density of crystalline/amorphous interfaces, thereby generating a pronounced interface strengthening effect. The micro-indentation results show that shear banding was suppressed in the nanolaminate with AIL, as evidenced by fewer shear bands as compared to its homogeneous counterpart. This enhanced resistance to shear instability may originate from the crystalline/amorphous interface that provides more sites for dislocation nucleation, emission, and annihilation. Furthermore, two distinct shear banding modes were observed in the nanolaminate with AIL; i.e., a cutting-like shear banding emerged at h = 10 nm, whereas a kinking-like shear banding occurred at h = 2 nm. The potential mechanism of the AIL-thickness-dependent shear banding was analyzed based on the crack propagation model of the Griffith criterion. This study provides a comprehensive insight into the strengthening and tunable shear instability of super-nano metallic laminates by AIL. Full article

Covalent organic framework (COF) membranes are eminent candidates in filtration and separation applications due to their high porosity, ordered pore size, versatile molecular structure, inherent mechanical properties, and excellent stability. However, large-scale COF membranes suffer from several issues, including stacking and crystal defects, which negatively impact their rejection performance. In this study, a continuous thin film of porphyrinic-based COF (i.e., COF-TCPP (Fe)) with various thicknesses was fabricated on a PVDF support layer via a vacuum-assisted interfacial polymerization method. The composite membranes were then characterized, and their filtration and dye/salt separation performance were evaluated using a dead-end filtration cell. The results showed that the rejection efficiencies of Congo red and acid fuchsin for the optimal proposed membrane were 99.5% and 95.8%, respectively. In comparison, the corresponding values for the pristine membrane were 73.3% and 62.8%. The results also showed that with an increase in the COF loading concentration during synthesis, the membrane flux decreased, while the rejection efficiency increased. This study proposes a simple and effective method to mitigate the large-scale issues of COF-based membranes and to enhance the separation performance of existing polymeric membranes. Full article

To enhance the interfacial performance of Al/Mg bimetal, this study introduced a novel Mo coating and employed an ultrasonic field (UF) to regulate the interfacial microstructure. In the absence of both a Mo coating and ultrasonic treatment (referred to as the untreated specimen), the interfacial region was primarily composed of Al-Mg intermetallic compounds (Al-Mg IMCs), Al-Mg eutectic structures (ES), and Mg₂Si phases, with an average interfacial layer thickness of approximately 1623 μm. Upon application of the Mo coating, the formation of both Al-Mg phases and Mg₂Si phases was completely inhibited. The interfacial zone was predominantly characterized by the Mo solid solution (Mo SS) and oxide, with the average thickness significantly reduced to about 28 μm. Upon applying the UF to the Mo-coated specimen, the interfacial composition remained similar to that of the untreated specimen, except for Mo SS, with the interfacial thickness increasing to 561 μm. Shear strength tests indicated that the application of the Mo coating alone resulted in a decrease in bonding strength compared to the untreated specimen. However, subsequent ultrasonic treatment significantly improved the interfacial shear strength to 54.7 MPa, representing a 60.9% increase relative to the untreated specimen. This improvement is primarily attributed to the Mo coating and UF synergistically suppressing the formation of brittle Al-Mg IMCs and reducing oxide inclusions at the interface. Thus, the simultaneous application of Mo coatings and ultrasonic fields is required to enhance the properties of Al/Mg bimetals. Full article

Graphene/h-BN/Si heterostructures show considerable potential for future use in infrared detection and photovoltaic technologies due to their adjustable electrical behavior and well-matched interfacial structure. The near-lattice match between graphene and hexagonal boron nitride (h-BN) enables the deposition of low-defect-density graphene on h-BN surfaces. This study presents a thorough exploration of the low-frequency electrical noise behavior of graphene/h-BN/Si heterojunctions under both forward and reverse bias conditions at room temperature. Graphene nanolayers were directly grown on h-BN films using microwave plasma-enhanced CVD. The h-BN layers were formed by reactive high-power impulse magnetron sputtering (HIPIMS). Four h-BN thicknesses were examined: 1 nm, 3 nm, 5 nm, and 15 nm. A reference graphene/Si junction (without h-BN) prepared under identical synthesis conditions was also studied for comparison. Low-frequency noise analysis enabled the identification of dominant charge transport mechanisms in the different device structures. Our results demonstrate that grain boundaries act as dominant defects contributing to increased noise intensity under high forward bias. Statistical analysis of voltage noise spectral density across multiple samples, supported by Raman spectroscopy, reveals that hydrogen-related defects significantly contribute to 1/f noise in the linear region of the junction’s current–voltage characteristics. This study provides the first in-depth insight into the impact of h-BN interlayers on low-frequency noise in graphene/Si heterojunctions. Full article