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Keywords = interlaminar shear test

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24 pages, 3537 KB  
Article
Macro–Mesoscale Equivalent Evaluation of Interlayer Shear Behavior in Asphalt Pavements with a Granular Base
by Fang Wang, Zhouqi Zhang, Chaoliang Fu and Zhiping Ma
Materials 2025, 18(17), 3935; https://doi.org/10.3390/ma18173935 - 22 Aug 2025
Viewed by 543
Abstract
To reduce reflective cracking in asphalt pavements, gravel base layers are commonly employed to disperse stress and delay structural damage. However, the loose nature of gravel bases results in complex interlayer contact conditions, typically involving interlocking between gravel particles in the base and [...] Read more.
To reduce reflective cracking in asphalt pavements, gravel base layers are commonly employed to disperse stress and delay structural damage. However, the loose nature of gravel bases results in complex interlayer contact conditions, typically involving interlocking between gravel particles in the base and aggregates in the asphalt surface course. In order to accurately simulate this interaction and to improve the interlayer shear performance, a mesoscale finite element model was developed and combined with macroscopic tests. Effects due to the type and amount of binder material, type of asphalt surface layer, and external loading on shear strength were systematically analyzed. The results indicate that SBS (Styrene–Butadiene–Styrene)-modified asphalt provides the highest interlayer strength, followed by SBR (Styrene–Butadiene Rubber)-modified emulsified asphalt and unmodified base bitumen. SBS (Styrene–Butadiene–Styrene)-modified asphalt achieves optimal interlaminar shear strength at a coating rate of 0.9 L/m2. Additionally, shear strength increases with applied load but decreases with increasing void ratio and the nominal maximum aggregate size of the surface course in the analyzed spectra. Based on simulation and experimental data, an equivalent macro–meso predictive model relating shear strength to key influencing factors was established. This model effectively bridges mesoscale mechanisms and practical engineering applications, providing theoretical support for the design and performance optimization of asphalt pavements with gravel bases. Full article
(This article belongs to the Section Construction and Building Materials)
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29 pages, 14203 KB  
Article
Inter Laminar Shear Strength of Flax-Glass Hybrid Polymer Composites for Automotive Frame: Numerical Modelling and Experimental Analysis
by Tegginamath Akshat, Michal Petru and Rajesh Kumar Mishra
Materials 2025, 18(16), 3852; https://doi.org/10.3390/ma18163852 - 17 Aug 2025
Viewed by 483
Abstract
This study deals with the mechanical performance in the case of hybrid polymer composites developed from sandwiched reinforcements using natural fibre and glass fibre-based fabrics. The composites developed by using different combinations and arrangements of the glass and flax fabrics were tested for [...] Read more.
This study deals with the mechanical performance in the case of hybrid polymer composites developed from sandwiched reinforcements using natural fibre and glass fibre-based fabrics. The composites developed by using different combinations and arrangements of the glass and flax fabrics were tested for the interlaminar shear strength (ILSS). Finite element analysis based on ANSYS was used to determine the ILSS for the hybrid composites. Further, experimental testing of the ILSS was carried out in order to validate the predicted performance. The comparison of simulated values with the tested values showed percentage error values ranging from 0.106% to 6.25%. The minor error between the tested and simulated values can be due to the presence of very small imperfections in the composite, like the presence of voids, which could potentially be introduced in the composite while manufacturing the samples. Microscopic analysis confirmed the fracture in between the layers and interfacial debonding between the fibre and the matrix. It was found that the flax fibre tends to break earlier as compared to the glass component, which has much better mechanical performance. The findings are important for understanding the performance of hybrid composites in real loading conditions in automotive frames and other similar applications. Full article
(This article belongs to the Special Issue Advances in Functional Polymers and Nanocomposites)
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16 pages, 2443 KB  
Article
Durability of Concrete Reinforced with GFRP Bars Under Varying Alkalinity and Temperature Conditions
by Ruan Carlos de Araújo Moura, Daniel Véras Ribeiro and Paulo Roberto Lopes Lima
Buildings 2025, 15(16), 2832; https://doi.org/10.3390/buildings15162832 - 9 Aug 2025
Viewed by 477
Abstract
The application of glass fiber reinforced polymer (GFRP) bars offers a promising solution for enhancing the durability of reinforced concrete structures, potentially reducing maintenance costs and associated socioeconomic impacts. However, concerns persist regarding the durability of GFRP bars in the highly alkaline environment [...] Read more.
The application of glass fiber reinforced polymer (GFRP) bars offers a promising solution for enhancing the durability of reinforced concrete structures, potentially reducing maintenance costs and associated socioeconomic impacts. However, concerns persist regarding the durability of GFRP bars in the highly alkaline environment of concrete, which can lead to physical, chemical, and mechanical degradation. This study evaluates the durability of GFRP bars composed of isophthalic polyester, vinyl ester, and epoxy matrices (6.0 mm diameter) under accelerated aging conditions. The bars were exposed to non-carbonated concrete (with and without silica fume) and carbonated concrete at temperatures of 23 °C, 40 °C, and 60 °C for durations of 500, 1000, and 3000 h. Interlaminar shear strength (ISS) was measured before and after aging. SEM and FTIR analyses confirmed degradation in the polymer matrix and fiber–matrix interface. Results indicated that silica fume significantly mitigated alkalinity effects, limiting ISS loss to 11.3%. Similarly, carbonation reduced the concrete’s pH, thereby decreasing ISS degradation to 10.7% after 3000 h. Among the tested materials, GFRP bars with vinyl ester matrix exhibited superior durability, followed by those with epoxy and polyester matrices. These findings emphasize the critical role of matrix selection and concrete mix design in improving GFRP durability. Full article
(This article belongs to the Special Issue Research on the Durability of Reinforced Concrete Structures)
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29 pages, 2673 KB  
Article
Process Parameters Optimization and Mechanical Properties of Additively Manufactured Ankle–Foot Orthoses Based on Polypropylene
by Sahar Swesi, Mohamed Yousfi, Nicolas Tardif and Abder Banoune
Polymers 2025, 17(14), 1921; https://doi.org/10.3390/polym17141921 - 11 Jul 2025
Viewed by 589
Abstract
Nowadays, Fused Filament Fabrication (FFF) 3D printing offers promising opportunities for the customized manufacturing of ankle–foot orthoses (AFOs) targeted towards rehabilitation purposes. Polypropylene (PP) represents an ideal candidate in orthotic applications due to its light weight and superior mechanical properties, offering an excellent [...] Read more.
Nowadays, Fused Filament Fabrication (FFF) 3D printing offers promising opportunities for the customized manufacturing of ankle–foot orthoses (AFOs) targeted towards rehabilitation purposes. Polypropylene (PP) represents an ideal candidate in orthotic applications due to its light weight and superior mechanical properties, offering an excellent balance between flexibility, chemical resistance, biocompatibility, and long-term durability. However, Additive Manufacturing (AM) of AFOs based on PP remains a major challenge due to its limited bed adhesion and high shrinkage, especially for making large parts such as AFOs. The primary innovation of the present study lies in the optimization of FFF 3D printing parameters for the fabrication of functional, patient-specific orthoses using PP, a material still underutilized in the AM of medical devices. Firstly, a thorough thermomechanical characterization was conducted, allowing the implementation of a (thermo-)elastic material model for the used PP filament. Thereafter, a Taguchi design of experiments (DOE) was established to study the influence of several printing parameters (extrusion temperature, printing speed, layer thickness, infill density, infill pattern, and part orientation) on the mechanical properties of 3D-printed specimens. Three-point bending tests were conducted to evaluate the strength and stiffness of the samples, while additional tensile tests were performed on the 3D-printed orthoses using a home-made innovative device to validate the optimal configurations. The results showed that the maximum flexural modulus of 3D-printed specimens was achieved when the printing speed was around 50 mm/s. The most significant parameter for mechanical performance and reduction in printing time was shown to be infill density, contributing 73.2% to maximum stress and 75.2% to Interlaminar Shear Strength (ILSS). Finally, the applicability of the finite element method (FEM) to simulate the FFF process-induced deflections, part distortion (warpage), and residual stresses in 3D-printed orthoses was investigated using a numerical simulation tool (Digimat-AM®). The combination of Taguchi DOE with Digimat-AM for polypropylene AFOs highlighted that the 90° orientation appeared to be the most suitable configuration, as it minimizes deformation and von Mises stress, ensuring improved quality and robustness of the printed orthoses. The findings from this study contribute by providing a reliable method for printing PP parts with improved mechanical performance, thereby opening new opportunities for its use in medical-grade additive manufacturing. Full article
(This article belongs to the Special Issue Latest Progress in the Additive Manufacturing of Polymeric Materials)
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20 pages, 14435 KB  
Article
Qualification of the Vitrimeric Matrices in Industrial-Scale Wet Filament Winding Processes for Type-4 Pressure Vessels
by Jonathan Alms, Anna Katharina Sambale, Jannick Fuchs, Niklas Lorenz, Nina von den Berg, Tobias Conen, Hakan Çelik, Rainer Dahlmann, Christian Hopmann and Markus Stommel
Polymers 2025, 17(9), 1146; https://doi.org/10.3390/polym17091146 - 23 Apr 2025
Cited by 1 | Viewed by 720
Abstract
The production of fibre-reinforced composites for use in applications such as type-4 pressure vessels for hydrogen storage is achieved through the use of a thermoset matrix. However, the recycling of thermosets presents a significant challenge due to the lack of established recycling methods. [...] Read more.
The production of fibre-reinforced composites for use in applications such as type-4 pressure vessels for hydrogen storage is achieved through the use of a thermoset matrix. However, the recycling of thermosets presents a significant challenge due to the lack of established recycling methods. Epoxy-based vitrimers show thermoset characteristics during the manufacturing and utilisation phases but exhibit thermoplastic behaviour at elevated temperatures of 190 °C. This study investigates the industrial-scale production of carbon fibre reinforced vitrimers via a wet filament winding, as exemplified by a type-4 pressure vessel demonstrator. Processing conditions of industrial processes have yet to be applied to vitrimers; therefore, two vitrimer formulations are compared to a conventional epoxy thermoset. The processability and resulting composite quality of wound composites using these materials as matrices are compared. The mechanical properties of the composites are compared using an interlaminar shear strength test, demonstrating that the vitrimeric matrices exhibit 19.8% (23 °C) and 49.2% (140 °C) improved interlaminar strength. Consequently, the epoxy-based vitrimers investigated in this study can be employed as a direct replacement for the thermoset matrix in industrial-scale applications, with the potential for recycling the composite. To increase composite qualities, the winding process must be adapted for vitrimers, since a pore free composite could not be achieved. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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14 pages, 3370 KB  
Article
Effect of UV Radiation Exposure and Simulated Particle Erosion Damage on the Mechanical Behavior of Carbon/Glass Hybrid Composites
by Marcello de Vasconcelos Porto Hermanny Tostes and José Roberto Moraes d’Almeida
Polymers 2025, 17(7), 861; https://doi.org/10.3390/polym17070861 - 24 Mar 2025
Viewed by 551
Abstract
The environments found in space research pose numerous challenges to the materials used in aerospace structures, such as high incidence of ultraviolet radiation (UV) and micrometeorite impacts. Therefore, this work analyzes the combined effects of exposure to UV radiation and damage caused by [...] Read more.
The environments found in space research pose numerous challenges to the materials used in aerospace structures, such as high incidence of ultraviolet radiation (UV) and micrometeorite impacts. Therefore, this work analyzes the combined effects of exposure to UV radiation and damage caused by sandblasting on the mechanical performance of a hybrid composite of epoxy matrix reinforced with carbon and glass fibers to simulate service conditions both in low Earth orbit (LEO) and in exoplanet environments. The blasting was carried out with silica particles with dimensions compatible with those found in the dust of the Martian atmosphere, and the damage produced by these particles has dimensions similar to those observed in several impact/wear events of structures exposed to LEO conditions. A qualitative analysis of the effect of UV radiation carried out by colorimetry showed a significant change in the color of the material, which became more greenish and yellowish. This color change is indicative of degradation processes in the polymer matrix. FT-IR analysis showed an increase in the carbonyl band with increasing aging time, which is consistent with the color change measured in the material. However, the interlaminar shear strength was not affected by UV radiation in the time used in this work. This behavior was attributed to the fact that UV radiation initially causes deterioration only on the surface of the material. From the results of the bending tests, both the three-point bending test and impulse excitation test, it was found that the effect of UV radiation on the elastic modulus of the composites was more important than the effect of blasting damage. It was also observed that initial UV exposure, prior to sandblasting, has a synergistic effect on the deterioration of flexural strength. Full article
(This article belongs to the Special Issue Mechanical Behavior of Polymer Composites)
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15 pages, 8576 KB  
Article
A Study on the Failure Behavior and Force Transmission of Composite Skin-Stringer Structures Under a Compressive Load
by Guoyang Zhao, Jian Shi, Wei Xu, Nan Sun, Jianjiang Zeng, Guang Yang, Kun Song and Jie Zheng
Materials 2025, 18(6), 1380; https://doi.org/10.3390/ma18061380 - 20 Mar 2025
Cited by 1 | Viewed by 500
Abstract
Carbon fiber-reinforced composite stringers, which support aircraft skins in resisting tensile, compressive, and shear loads, are widely used in aircraft structures. These composite structures play a crucial role in enhancing the performance and safety of the structural integration of aircrafts. To better understand [...] Read more.
Carbon fiber-reinforced composite stringers, which support aircraft skins in resisting tensile, compressive, and shear loads, are widely used in aircraft structures. These composite structures play a crucial role in enhancing the performance and safety of the structural integration of aircrafts. To better understand the load-bearing capacity of composite stringer structures, this study developed a novel model to study the complex failure and load transmission behavior of T800/3900S-2B fiber-reinforced composite skin-stringer structures under compressive loading. Compression strength tests were conducted on a composite stringer/skin structure, and a three-dimensional FEM was developed using Abaqus/Standard 2022. The model incorporated the modified 3D Hashin initiation criteria and Tserpes degradation law through a UMAT subroutine, which can effectively capture the in-plane ply failure and interlaminar damage. The results revealed a high degree of similarity between the load–displacement curves and failure modes (i.e., matrix compressive cracking, fiber compressive failure, and fiber–matrix shear-out failure) obtained from the simulations and those from the experiments. This study provides an efficient and accurate model to simulate the failure and load transfer of composite skin-stringer structures, offering significant advancements in understanding and predicting the behavior of these critical components. Full article
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11 pages, 1851 KB  
Article
The Influence of Two Spinning Processes of T800 Grade Carbon Fibers on the Mechanical Properties of Thermoplastic Composite Material
by Xu Cui, Xuefeng Sun, Weiguo Su, Shuo Wang and Han Guo
Coatings 2025, 15(1), 90; https://doi.org/10.3390/coatings15010090 - 15 Jan 2025
Viewed by 1424
Abstract
Two types of T800 grade carbon fibers, produced using distinct spinning processes, were utilized to fabricate thermoplastic prepregs via the hot melt method. These prepregs were subsequently employed to produce thermoplastic composites. A universal testing machine was used to assess the tensile, bending, [...] Read more.
Two types of T800 grade carbon fibers, produced using distinct spinning processes, were utilized to fabricate thermoplastic prepregs via the hot melt method. These prepregs were subsequently employed to produce thermoplastic composites. A universal testing machine was used to assess the tensile, bending, and interlaminar shear properties of the composites, evaluating the impact of the two different spinning processes on their mechanical characteristics. The experimental results indicate that the dry spray wet spinning carbon fiber (T800-DJWS) exhibits a smoother surface, more regular cross-section, and more uniform distribution compared to the wet spinning carbon fiber (T800-WS), enhancing the prepreg preparation via the hot melt method. The T800-DJWS/PAEK composite demonstrates a tensile strength that is 706 MPa higher than the T800-WS/PAEK composite, while the latter exhibits a bending modulus 31 GPa higher than the former. Full article
(This article belongs to the Special Issue Advances and Trends in Bio-Based Electrospun Nanofibers)
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18 pages, 8651 KB  
Article
Interlaminar Fracture Toughness Analysis for Reliability Improvement of Wind Turbine Blade Spar Elements Based on Pultruded Carbon Fiber-Reinforced Polymer Plate Manufacturing Method
by Hakgeun Kim, Yunjung Jang, Sejin Lee, Chanwoong Choi and Kiweon Kang
Materials 2025, 18(2), 357; https://doi.org/10.3390/ma18020357 - 14 Jan 2025
Viewed by 1078
Abstract
The key structural components of a wind turbine blade, such as the skin, spar cap, and shear web, are fabricated from fiber-reinforced composite materials. The spar, predominantly manufactured via resin infusion—a process of resin injection and curing in carbon fibers—is prone to initial [...] Read more.
The key structural components of a wind turbine blade, such as the skin, spar cap, and shear web, are fabricated from fiber-reinforced composite materials. The spar, predominantly manufactured via resin infusion—a process of resin injection and curing in carbon fibers—is prone to initial defects, such as pores, wrinkles, and delamination. This study suggests employing the pultrusion technique for spar production to consistently obtain a uniform cross-section and augment the reliability of both the manufacturing process and the design. In this context, this study introduces carbon fiber-reinforced polymer (CFRP/CFRP) and glass fiber-reinforced polymer (GFRP/CFRP) test specimens, which mimic the bonding structure of the spar cap, utilizing pultruded CFRP in accordance with ASTM standards to analyze the delamination traits of the spar. Delamination tests—covering Mode I (double cantilever beam), Mode II (end-notched flexure), and mixed mode (mixed-mode bending)—were performed to gauge displacement, load, and crack growth length. Through this crack growth mechanism, the interlaminar fracture toughness derived was examined, and the stiffness and strength changes compared to CFRP based on the existing prepreg manufacturing method were analyzed. In addition, the interlaminar fracture toughness for GFRP, which is a material in contact with the spar structure, was analyzed, and through this, it was confirmed that the crack behavior has less deviation compared to a single CFRP material depending on the stiffness difference between the materials when joining dissimilar materials. This means that the higher the elasticity of the high-stiffness material, the higher the initial crack resistance, but the crack growth behavior shows non-uniform characteristics thereafter. This comparison provides information for predicting interlaminar delamination damage within the interior and bonding area of the spar and skin and provides insight for securing the reliability of the design life. Full article
(This article belongs to the Section Advanced Composites)
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30 pages, 12568 KB  
Article
Numerical Modelling of Hybrid Polymer Composite Frame for Selected Construction Parts and Experimental Validation of Mechanical Properties
by Tegginamath Akshat, Michal Petru and Rajesh Kumar Mishra
Polymers 2025, 17(2), 168; https://doi.org/10.3390/polym17020168 - 11 Jan 2025
Cited by 1 | Viewed by 1323
Abstract
This article is a numerical and experimental study of the mechanical properties of different glass, flax and hybrid composites. By utilizing hybrid composites consisting of natural fibers, the aim is to eventually reduce the percentage usage of synthetic or man-made fibers in composites [...] Read more.
This article is a numerical and experimental study of the mechanical properties of different glass, flax and hybrid composites. By utilizing hybrid composites consisting of natural fibers, the aim is to eventually reduce the percentage usage of synthetic or man-made fibers in composites and obtain similar levels of mechanical properties that are offered by composites using synthetic fibers. This in turn would lead to greener composites being utilized. The advantage of which would be the presence of similar mechanical properties as those of composites made from synthetic fibers along with a reduction in the overall weight of components, leading to much more eco-friendly vehicles. Finite element simulations (FEM) of mechanical properties were performed using ANSYS. The FEM simulations and analysis were performed using standards as required. Subsequently, actual beams/frames with a defined geometry were fabricated for applications in automotive body construction. The tensile performance of such frames was also simulated using ANSYS-based models and was experimentally verified. A correlation with the results of the FEM simulations of mechanical properties was established. The maximum tensile strength of 415 MPa was found for sample 1: G-E (glass–epoxy composite) and the minimum strength of 146 MPa was found for sample 2: F-G-E (G-4) (flax–glass–epoxy composite). The trends were similar, as obtained by simulation using ANSYS. A comparison of the results showed the accuracy of the numerical simulation and experimental specimens with a maximum error of about 8.05%. The experimental study of the tensile properties of polymer matrix composites was supplemented with interlaminar shear strength, and a high accuracy was found. Further, the maximum interlaminar shear strength (ILSS) of 18.5 MPa was observed for sample 1: G-E and the minimum ILSS of 17.0 MPa was observed for sample 2: F-G-E (G-4). The internal fractures were analyzed using a computer tomography analyzer (CTAn). Sample 2: F-G-E (G-4) showed significant interlaminar cracking, while sample 1: G-E showed fiber failure through the cross section rather than interlaminar failure. The results indicate a practical solution of a polymer composite frame as a replacement for existing heavier components in a car, thus helping towards weight reduction and fuel efficiency. Full article
(This article belongs to the Section Polymer Physics and Theory)
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20 pages, 5025 KB  
Article
Toughened Vinyl Ester Resin Reinforced with Natural Flax Fabrics
by Bianca Dal Pont, Laura Aliotta, Elisa Tognarelli, Vito Gigante and Andrea Lazzeri
Appl. Sci. 2024, 14(22), 10459; https://doi.org/10.3390/app142210459 - 13 Nov 2024
Cited by 1 | Viewed by 2021
Abstract
Vinyl ester resins are widely used as thermoset matrix materials for laminated composites, particularly in naval and automotive applications, due to their strength, chemical resistance, and ease of processing. However, their brittleness limits their use, especially in cold conditions. This study investigates the [...] Read more.
Vinyl ester resins are widely used as thermoset matrix materials for laminated composites, particularly in naval and automotive applications, due to their strength, chemical resistance, and ease of processing. However, their brittleness limits their use, especially in cold conditions. This study investigates the toughness of core–shell rubber (CSR)-modified resins in composites with natural fibers. This research compares the properties of the neat resin matrix and the CSR-modified matrix. After optimizing the resin curing process with catalysts, various treatments were tested to analyze their mechanical and thermal properties. Using the vacuum bagging process, flax and glass fibers were used as reinforcements to assess the effects of matrix modifications. Flax fibers were chosen for their sustainability as a potential alternative to glass fibers. Mechanical testing was performed, comparing the performance of flax-based composites to those with glass fibers. Water absorption tests on flax composites followed the ISO 62 standard. Additionally, interlaminar shear strength and SEM micrography studies were conducted to examine the morphology and fiber–matrix adhesion, linking the microscopic structure to mechanical properties. Results indicate that while glass-reinforced composites have superior properties, flax composites offer a sustainable alternative, making them a promising choice for future applications. Full article
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15 pages, 6590 KB  
Article
Dynamic Mechanical Performance of Glass Microsphere-Loaded Carbon Fabric–Epoxy Composites Subjected to Accelerated UV Ageing
by Khubab Shaker, Anas Asim, Muhammad Ayub Asghar, Madeha Jabbar, Adeela Nasreen and Amna Siddique
J. Manuf. Mater. Process. 2024, 8(5), 224; https://doi.org/10.3390/jmmp8050224 - 3 Oct 2024
Cited by 3 | Viewed by 1456
Abstract
This study investigates the effects of incorporating glass microspheres (GMSs) as fillers in carbon fabric–epoxy composites (CFECs) on their degradation behavior under environmental conditions such as moisture and ultraviolet rays. The GMS-filled composites were subjected to accelerated ageing and evaluated using dynamic mechanical [...] Read more.
This study investigates the effects of incorporating glass microspheres (GMSs) as fillers in carbon fabric–epoxy composites (CFECs) on their degradation behavior under environmental conditions such as moisture and ultraviolet rays. The GMS-filled composites were subjected to accelerated ageing and evaluated using dynamic mechanical analysis (DMA), the Charpy impact test, and inter-laminar shear strength (ILSS) tests. The results indicate that the addition of GMS fillers significantly improves the stiffness and viscoelastic behavior of the composites. However, the impact strength of the composites decreases with the addition of GMS fillers and accelerated ageing. The ILSS results demonstrate that the addition of GMS fillers improved the interfacial bonding between the carbon–epoxy matrix and fillers. This study provides insights into the mechanical properties of GMS-filled carbon–epoxy composites. Full article
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15 pages, 9688 KB  
Article
Effect of Vibration Pretreatment–Microwave Curing Process Parameters on the Mechanical Performance of Resin-Based Composites
by Dechao Zhang, Lihua Zhan, Bolin Ma, Jinzhan Guo, Wentao Jin, Xin Hu, Shunming Yao and Guangming Dai
Polymers 2024, 16(17), 2518; https://doi.org/10.3390/polym16172518 - 4 Sep 2024
Cited by 3 | Viewed by 1413
Abstract
The vibration pretreatment–microwave curing process can achieve high-quality molding under low-pressure conditions and is widely used in the curing of resin-based composites. This study investigated the effects of the vibration pretreatment process parameters on the void content and the fiber weight fraction of [...] Read more.
The vibration pretreatment–microwave curing process can achieve high-quality molding under low-pressure conditions and is widely used in the curing of resin-based composites. This study investigated the effects of the vibration pretreatment process parameters on the void content and the fiber weight fraction of T700/TRE231; specifically, their influence on the interlaminar shear strength and impact strength of the composite. Initially, an orthogonal experimental design was employed with interlaminar shear strength as the optimization target, where vibration acceleration was determined as the primary factor and dwell time as the secondary factor. Concurrently, thermogravimetric analysis (TGA) was performed based on process parameters that corresponded to the extremum of interlaminar shear strength, revealing a 2.17% difference in fiber weight fraction among specimens with varying parameters, indicating a minimal effect of fiber weight fraction on mechanical properties. Optical digital microscope (ODM) analysis identified interlaminar large-size voids in specimens treated with vibration energy of 5 g and 15 g, while specimens subjected to a vibration energy of 10 g exhibited numerous small-sized voids within layers, suggesting that vibration acceleration influences void escape pathways. Finally, impact testing revealed the effect of the vibration pretreatment process parameters on the impact strength, implying a positive correlation between interlaminar shear strength and impact strength. Full article
(This article belongs to the Special Issue Advances in Functional Polymers and Composites)
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59 pages, 4658 KB  
Review
The Effect of Carbon Nanofibers on the Mechanical Performance of Epoxy-Based Composites: A Review
by Paulo Santos, Abílio P. Silva and Paulo N. B. Reis
Polymers 2024, 16(15), 2152; https://doi.org/10.3390/polym16152152 - 29 Jul 2024
Cited by 12 | Viewed by 3693
Abstract
This review is a fundamental tool for researchers and engineers involved in the design and optimization of fiber-reinforced composite materials. The aim is to provide a comprehensive analysis of the mechanical performance of composites with epoxy matrices reinforced with carbon nanofibers (CNFs). The [...] Read more.
This review is a fundamental tool for researchers and engineers involved in the design and optimization of fiber-reinforced composite materials. The aim is to provide a comprehensive analysis of the mechanical performance of composites with epoxy matrices reinforced with carbon nanofibers (CNFs). The review includes studies investigating the static mechanical response through three-point bending (3PB) tests, tensile tests, and viscoelastic behavior tests. In addition, the properties of the composites’ resistance to interlaminar shear strength (ILSS), mode I and mode II interlaminar fracture toughness (ILFT), and low-velocity impact (LVI) are analyzed. The incorporation of small amounts of CNFs, mostly between 0.25 and 1% by weight was shown to have a notable impact on the static and viscoelastic properties of the composites, leading to greater resistance to time-dependent deformation and better resistance to creep. ILSS and ILFT modes I and II of fiber-reinforced composites are critical parameters in assessing structural integrity through interfacial bonding and were positively affected by the introduction of CNFs. The response of composites to LVI demonstrates the potential of CNFs to increase impact strength by reducing the energy absorbed and the size of the damage introduced. Epoxy matrices reinforced with CNFs showed an average increase in stiffness of 15% and 20% for bending and tensile, respectively. The laminates, on the other hand, showed an increase in bending stiffness of 20% and 15% for tensile and modulus, respectively. In the case of ILSS and ILFT modes I and II, the addition of CNFs promoted average increases in the order of 50%, 100%, and 50%, respectively. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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16 pages, 5495 KB  
Article
Design, Manufacturing, and Evaluation of Race and Automotive Prototypal Components Fabricated with Modified Carbon Fibres and Resin
by Dionisis Semitekolos, Andreia Araújo, Raquel M. Santos, Chiara Pernechele, Francesco Panozzo, Luca Vescovi and Costas Charitidis
Polymers 2024, 16(14), 2062; https://doi.org/10.3390/polym16142062 - 19 Jul 2024
Cited by 2 | Viewed by 1508
Abstract
This study explores the enhancement of Carbon Fibre Reinforced Polymers (CFRPs) for automotive applications through the integration of modified carbon fibres (CF) and epoxy matrices. The research emphasizes the use of block copolymers (BCPs) and electropolymerisation techniques to improve mechanical properties and interfacial [...] Read more.
This study explores the enhancement of Carbon Fibre Reinforced Polymers (CFRPs) for automotive applications through the integration of modified carbon fibres (CF) and epoxy matrices. The research emphasizes the use of block copolymers (BCPs) and electropolymerisation techniques to improve mechanical properties and interfacial adhesion. Incorporating 2.5 wt.% D51N BCPs in the epoxy matrix led to a 64% increase in tensile strength and a 51.4% improvement in interlaminar fracture toughness. The electropolymerisation of CFs further enhanced interlaminar shear strength by 23.2%, reflecting a substantial enhancement in fibre–matrix interaction. A novel out-of-autoclave manufacturing process for an energy absorber prototype was developed, achieving significant reductions in production time and cost while maintaining performance. Compression tests demonstrated that the modified materials attained an energy absorption rate of 93.3 J/mm, comparable to traditional materials. These results suggest that the advanced materials and manufacturing processes presented in this study are promising for the development of lightweight, high-strength automotive components, meeting rigorous performance and safety standards. This research highlights the potential of these innovations to contribute significantly to the advancement of materials used in the automotive industry. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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