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Search Results (954)

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Keywords = international migration

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21 pages, 5540 KB  
Article
Migration Architecture and Its Impact on the Rural Territory in Saraguro: Consequences of New Construction in the Quisquinchir Community
by Karina Monteros Cueva and Jéssica Andrea Ordoñez Cuenca
Buildings 2025, 15(20), 3649; https://doi.org/10.3390/buildings15203649 - 10 Oct 2025
Abstract
The indigenous community of Quisquinchir, in Saraguro (Loja, Ecuador), is facing a process of transformation of the rural Andean landscape associated with internal and external migration, as well as the influence of foreign architectural models. The new buildings symbolize, in the collective imagination, [...] Read more.
The indigenous community of Quisquinchir, in Saraguro (Loja, Ecuador), is facing a process of transformation of the rural Andean landscape associated with internal and external migration, as well as the influence of foreign architectural models. The new buildings symbolize, in the collective imagination, modernity and progress; however, they are alien to the natural environment characterized by the practice of agricultural and livestock activities. Although previous studies have described the loss of Andean vernacular architecture, its recent evolution in clear typologies has not been systematized. The objective of this study is to assess the current state of traditional dwellings and understand how migration reconfigures the landscape, collective memory, building traditions, and cultural identity of their inhabitants. Based on direct observation, photographic and stratigraphic analysis, and secondary sources, five typologies were identified: traditional one-story, traditional two-story, hybrid one-story, hybrid two-story, and eclectic. This classification indicates the replacement of earthen walls with cement blocks in 37% of the dwellings and of tile roofs with zinc roofs in 29%. However, 35% of the houses retain their traditional morphology and materials. These results and their classification are fundamental contributions to the design of local public policies that generate adequate interventions respectful of the environment. Full article
(This article belongs to the Section Architectural Design, Urban Science, and Real Estate)
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19 pages, 5463 KB  
Article
From TNM 8 to TNM 9: Stage Migration and Histology-Specific Patterns in Lung Cancer
by Amalia Constantinescu, Radu-Nicolae Căprariu, Emil-Robert Stoicescu, Roxana Iacob, Marius Mânzatu, Janet Camelia Drimus, Alessia-Stephania Roșian, Alexandre Ionescu, Cristian Oancea and Diana Manolescu
Cancers 2025, 17(20), 3290; https://doi.org/10.3390/cancers17203290 (registering DOI) - 10 Oct 2025
Abstract
Introduction: The 9th edition of the TNM classification for lung cancer implemented significant revisions, notably the subdivision of the N2 and M1c categories, to enhance anatomical precision and prognostic accuracy. Nonetheless, the actual effects of these modifications on stage distribution, histology-specific patterns, and [...] Read more.
Introduction: The 9th edition of the TNM classification for lung cancer implemented significant revisions, notably the subdivision of the N2 and M1c categories, to enhance anatomical precision and prognostic accuracy. Nonetheless, the actual effects of these modifications on stage distribution, histology-specific patterns, and clinical interpretation remain to be fully evaluated. Objectives: To compare lung cancer staging distributions between the 8th and 9th TNM editions, analyze patterns of stage migration, and evaluate histology-specific reclassification trends. Although TNM 9 applies the same descriptors across all histological subtypes, the magnitude of stage migration varies. In our cohort and in international datasets, adenocarcinoma demonstrated a higher likelihood of reclassification into advanced stages compared to other subtypes. Methods: A retrospective analysis was performed on a cohort of lung cancer patients staged according to the 8th and 9th editions of the TNM classification. Stage distribution alterations were analyzed by chi-squared tests, whereas McNemar’s test examined the directional shifts in upstaging and downstaging. Further investigations evaluated the correlation between histological subtype and stage reclassification. Results: A statistically significant redistribution of stages was noted (χ2 = 1013.03, df = 64, p < 0.0001), with a notable prevalence of upstaging (p = 0.0019). The most significant proportional increase was observed in stage IIIA, mostly attributable to the N2 subdivision (N2a vs. N2b). Adenocarcinoma was the predominant histological subtype at all stages and showed a greater tendency for reclassification into advanced stages, specifically IIIA and IIIB. Squamous cell carcinoma was predominantly observed in stages IIB and IIIA, whereas small cell and large cell carcinomas were concentrated in advanced stages. These histology-specific patterns correspond with international findings, including research confirming the prognostic relevance of N2 subdivision. Conclusions: The 9th edition of the TNM classification results in significant stage migration, particularly in adenocarcinoma cases, indicating the improved sensitivity of the updated criteria in identifying advanced nodal disease. These modifications significantly impact prognostic evaluation and global comparability of clinical cohorts, supporting the implementation of TNM 9 as a more anatomically and biologically relevant staging system. Full article
(This article belongs to the Section Methods and Technologies Development)
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20 pages, 1521 KB  
Article
Moving Down the Urban Hierarchy: Exploring Patterns of Internal Migration Towards Small Towns in Latvia
by Janis Krumins and Maris Berzins
Geographies 2025, 5(4), 54; https://doi.org/10.3390/geographies5040054 - 1 Oct 2025
Viewed by 233
Abstract
Europe has experienced a growing divergence in trends of population change across the urban hierarchy. A key driver of this divergence is internal migration, which underpins the efficient functioning of the economy by enhancing labor market flexibility and allowing people to choose the [...] Read more.
Europe has experienced a growing divergence in trends of population change across the urban hierarchy. A key driver of this divergence is internal migration, which underpins the efficient functioning of the economy by enhancing labor market flexibility and allowing people to choose the most desired locations. Internal migration in Latvia is of increasing importance, as the propensity to change residence within national borders has become the primary mechanism of demographic change, shaping population redistribution across regions and the urban hierarchy. We used Latvia as a case study, exemplified by the monocentric urban system with Riga City at its center, as well as a relatively dense network of small towns spread across all regions. Small towns in Latvia, although not characterized by high levels of internal migration, exhibit notable changes in their demographic and socioeconomic composition. Our analysis uses administrative data on registered migration for each year from 2011 to 2021 to characterize migration patterns, as well as data from the 2011 and 2021 census rounds on 1-year migration to analyze the composition of the migrant population. The results showed sociodemographic variations in the characteristics of individuals migrating to small towns. Understanding the temporal and spatial dynamics of internal migration patterns and compositional effects is vital for effective local and regional development policies to plan essential services and infrastructure. Full article
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12 pages, 252 KB  
Article
Governance Strategies in a Global Context from a Gender Perspective: Narratives of Migrant Women
by Teresa Terrón-Caro, Rocío Cárdenas-Rodríguez and Fabiola Ortega-de-Mora
Genealogy 2025, 9(4), 103; https://doi.org/10.3390/genealogy9040103 - 1 Oct 2025
Viewed by 237
Abstract
In recent decades, migratory processes have experienced growing feminization, with women accounting for about 50% of international migrations. However, they are not always recognized as social actors with the capacity for agency—that is, as subjects in decision-making, the formulation of proposals, and transformation [...] Read more.
In recent decades, migratory processes have experienced growing feminization, with women accounting for about 50% of international migrations. However, they are not always recognized as social actors with the capacity for agency—that is, as subjects in decision-making, the formulation of proposals, and transformation both in their lives and in those of the societies in which they participate. This article, from a critical and gender perspective, analyzes the narratives of migrant women interviewed in Spain within the framework of two research projects carried out during the period between 2021 and 2023. Through a qualitative analysis of their resistance strategies and demands, a series of comprehensive policy recommendations are proposed, which are aimed at providing theoretical and practical tools that would allow us to move towards more just and equitable societies. Full article
18 pages, 703 KB  
Article
Should I Stay or Should I Go? Mapping the Key Drivers of Skilled Migration Using Fuzzy Multi-Criteria Decision Methodology
by Ejder Ayçin and Esra Erarslan
Societies 2025, 15(10), 269; https://doi.org/10.3390/soc15100269 - 26 Sep 2025
Viewed by 409
Abstract
The emigration of highly skilled individuals has become a critical concern for many countries amid increasing global labor mobility. This study employs the Improved Fuzzy Step-Wise Weight Assessment Ratio Analysis (IF-SWARA) method within a fuzzy multi-criteria decision-making (FMCDM) framework to identify and prioritize [...] Read more.
The emigration of highly skilled individuals has become a critical concern for many countries amid increasing global labor mobility. This study employs the Improved Fuzzy Step-Wise Weight Assessment Ratio Analysis (IF-SWARA) method within a fuzzy multi-criteria decision-making (FMCDM) framework to identify and prioritize the key drivers of skilled migration. Drawing on opinions from sixteen Turkish emigrants currently residing abroad, the study captures firsthand perspectives on the structural factors influencing their migration decisions. The results indicate that the most influential factors are workplace conditions, living standards, and academic standards. These findings underscore the multifaceted nature of brain drain and highlight the necessity for comprehensive policy approaches that address both push and pull dynamics. By systematically ranking these determinants, the study contributes to the growing body of evidence-based research on international human capital flows. Full article
(This article belongs to the Special Issue International Migration and the Adaptation Process)
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24 pages, 5860 KB  
Review
Mapping the Rise in Machine Learning in Environmental Chemical Research: A Bibliometric Analysis
by Bojana Stanic and Nebojsa Andric
Toxics 2025, 13(10), 817; https://doi.org/10.3390/toxics13100817 - 26 Sep 2025
Viewed by 442
Abstract
Machine learning (ML) is reshaping how environmental chemicals are monitored and how their hazards are evaluated for human health. Here, we mapped this landscape by analyzing 3150 peer-reviewed articles (1985–2025) from the Web of Science Core Collection. Co-citation, co-occurrence, and temporal trend analyses [...] Read more.
Machine learning (ML) is reshaping how environmental chemicals are monitored and how their hazards are evaluated for human health. Here, we mapped this landscape by analyzing 3150 peer-reviewed articles (1985–2025) from the Web of Science Core Collection. Co-citation, co-occurrence, and temporal trend analyses in VOSviewer and R reveal an exponential publication surge from 2015, dominated by environmental science journals, with China and the United States leading in output. Eight thematic clusters emerged, centered on ML model development, water quality prediction, quantitative structure–activity applications, and per-/polyfluoroalkyl substances, with XGBoost and random forests as the most cited algorithms. A distinct risk assessment cluster indicates migration of these tools toward dose–response and regulatory applications, yet keyword frequencies show a 4:1 bias toward environmental endpoints over human health endpoints. Emerging topics include climate change, microplastics, and digital soil mapping, while lignin, arsenic, and phthalates appear as fast-growing but understudied chemicals. Our findings expose gaps in chemical coverage and health integration. We recommend expanding the substance portfolio, systematically coupling ML outputs with human health data, adopting explainable artificial intelligence workflows, and fostering international collaboration to translate ML advances into actionable chemical risk assessments. Full article
(This article belongs to the Section Novel Methods in Toxicology Research)
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15 pages, 1717 KB  
Article
Evaluation and Validation of an Accelerated Weathering Procedure to Characterise the Release of Bisphenol A from Polycarbonate Under Exposure to Simulated Environmental Conditions
by Olivia Frenzel, Tanja Westphalen, Katja Kaminski, Stephanie Kluge, Michael Bücker and Christian Piechotta
Appl. Sci. 2025, 15(19), 10361; https://doi.org/10.3390/app151910361 - 24 Sep 2025
Viewed by 293
Abstract
Bisphenol A (BPA) has been listed as a substance of very high concern (SVHC) due to its endocrine-disrupting properties according to REACH in 2017. European competent authorities have prepared a REACH restriction proposal to reduce BPA levels in the environment. The proposed limit [...] Read more.
Bisphenol A (BPA) has been listed as a substance of very high concern (SVHC) due to its endocrine-disrupting properties according to REACH in 2017. European competent authorities have prepared a REACH restriction proposal to reduce BPA levels in the environment. The proposed limit for the concentration of free BPA and other bisphenols in articles is 10 mg kg−1. If exceeded, migration testing can demonstrate that no more than 0.04 mg L−1 is released from the product or material over its lifetime. German authorities are drafting a new restriction proposal after the original was temporarily withdrawn. The residual and migration limits mentioned above were key requirements from the previous restriction proposal. Numerous national and international standards exist for assessing how environmental factors affect the physical and chemical properties of products and materials—such as notch impact strength and tensile strength—but these standards do not cover the release of pollutants. A standardised procedure that covers all aspects of artificial weathering and monitors the subsequent release of pollutants is necessary, especially in the context of the regulation of these substances. An accelerated weathering procedure was established for non-protected samples. This material was not intended for outdoor applications. The testing procedure applied a typical weathering scenario that represents Central European climate conditions. The procedure was validated and applied to samples under distinct quality assurance aspects. Released BPA is quantified via an organic isotope dilution LC-MS/MS method. In parallel, identical samples were weathered outdoors on a weathering rack. Haze and yellowness index are measured to compare outdoor and weathering chamber results. Full article
(This article belongs to the Section Environmental Sciences)
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13 pages, 295 KB  
Article
Barefoot Wandering: Hanshan’s Spiritual Hybridity and the Hehe Pluralism
by Yanfei Qu and John Zhao
Religions 2025, 16(10), 1223; https://doi.org/10.3390/rel16101223 - 24 Sep 2025
Viewed by 351
Abstract
This paper explores the concept of diasporic hybridity through Hanshan’s (Cold Mountain) life and poetry during the Tang dynasty (618–907). Departing from traditional diaspora models of forced migration, Hanshan’s voluntary exile from the Confucian-dominated capital to the spiritually diverse Tiantai Mountain reveals how [...] Read more.
This paper explores the concept of diasporic hybridity through Hanshan’s (Cold Mountain) life and poetry during the Tang dynasty (618–907). Departing from traditional diaspora models of forced migration, Hanshan’s voluntary exile from the Confucian-dominated capital to the spiritually diverse Tiantai Mountain reveals how internal dislocation can foster hybrid religious identities. Through a close reading of his poetry and spiritual journey, this study argues that Hanshan embodies the Chinese philosophy of Hehe (和合), which is a model of religious pluralism grounded in “harmony through difference.” By integrating Homi Bhabha’s “third space” theory and Arjun Appadurai’s “diaspora landscape,” the paper demonstrates how Hanshan’s engagement with Confucianism, Buddhism, and Daoism presents a dynamic framework for understanding interreligious dialog. Hanshan’s hybrid spiritual identity thus offers a transhistorical lens for reimagining religious pluralism in both historical and contemporary contexts. Full article
17 pages, 1530 KB  
Article
Aromatic and Medicinal Plant (AMP) Valorization via a Farmer-Centric Approach for the Sustainable Development of Climate-Challenged Areas Affected by Rural Exodus (Southeastern Tunisia)
by Taoufik Gammoudi, Houda Besser, Amel Chaieb, Fethi Abdelli, Afef Mahjoubi and Fernando Nardi
Sustainability 2025, 17(18), 8494; https://doi.org/10.3390/su17188494 - 22 Sep 2025
Viewed by 408
Abstract
The valorization of local plant cover, particularly through the integration of indigenous knowledge, is central to Tunisia’s economic development strategies. These approaches focus on diversifying agriculture by enhancing local natural and cultural heritage to strengthen community resilience amid environmental and socio-economic changes and [...] Read more.
The valorization of local plant cover, particularly through the integration of indigenous knowledge, is central to Tunisia’s economic development strategies. These approaches focus on diversifying agriculture by enhancing local natural and cultural heritage to strengthen community resilience amid environmental and socio-economic changes and to address rural exodus. This study examines the feasibility of AMP-based micro-projects in Matmata (southeastern Tunisia) by applying the Water–Energy–Food–Ecosystem (WEFE) nexus and participatory methods involving local stakeholders. Field surveys, literature reviews, and statistical analyses reveal growing youth interest in AMP ventures, driven by rising pharmaceutical and cosmetic demand. Economic viability is confirmed by internal rate of return (IRR) values of 32%, 28%, and 43%, all well above the 10% profitability threshold. Profitability index (PI) values indicate efficient investments, yielding returns of 2.64, 2.13, and 5.31 dinars per dinar invested. The initiatives also deliver socio-cultural and environmental benefits through WEFE-based resource management. Beyond profitability, the study identifies gaps and opportunities to enhance AMP biodiversity, resource management, and sustainable diversification in southern Tunisia. Further efforts are required to increase market value and ensure equitable benefit distribution. Government policies should focus on raising WEFE awareness, building capacity, and investing in climate-smart agriculture, especially in vulnerable, migration-prone regions, supported by reforms in financing, taxation, and spatial planning. Full article
(This article belongs to the Section Environmental Sustainability and Applications)
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24 pages, 3196 KB  
Article
Multiscale Geophysical Characterization of Leachate and Gas Plumes in a Tropical Landfill Using Electrical Resistivity Tomography for Environmental Analysis and Diagnosis
by Omar E. Trujillo-Romero, Gloria M. Restrepo and Jorge E. Corrales-Celedon
Environments 2025, 12(9), 337; https://doi.org/10.3390/environments12090337 - 21 Sep 2025
Viewed by 395
Abstract
Monitoring environmental risks in operational landfills that contain closed cells requires non-invasive techniques capable of accurately characterizing subsurface contaminant dynamics. Electrical Resistivity Tomography (ERT) was selected because it enables continuous imaging across capped cells without intrusive drilling, with high sensitivity to the strong [...] Read more.
Monitoring environmental risks in operational landfills that contain closed cells requires non-invasive techniques capable of accurately characterizing subsurface contaminant dynamics. Electrical Resistivity Tomography (ERT) was selected because it enables continuous imaging across capped cells without intrusive drilling, with high sensitivity to the strong conductivity/resistivity contrasts that differentiate leachate (very low resistivity) from landfill gas or dry waste (high resistivity). This study employed ERT to spatially characterize contaminant distribution in closed cells within a landfill system in the Caribbean region of Colombia. Fifteen geophysical survey lines were acquired using Wenner, Dipole–Dipole, and Gradient arrays and processed through 2D, 2.5D, and 3D inversion models. The results revealed extensive low-resistivity zones (<2.1 Ω·m) in the southeastern sector, interpreted as leachate accumulations, some reaching the surface. Conversely, high-resistivity anomalies (>154 Ω·m) were identified in the southwestern area, associated with potential biogas pockets. Although these high-resistivity volumes represent <1.1% of the total modeled volume, their location and depth may pose geoenvironmental risks due to internal pressure build-up and preferential migration pathways. Existing leachate and gas collection systems showed adequate performance, though targeted corrective actions are recommended. ERT proved to be a precise, scalable, and cost-effective method for mapping subsurface contamination, offering critical insights for post-closure landfill management in tropical settings. Full article
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28 pages, 312 KB  
Article
Coming to Turkey—Passing Through Turkey: Migration Routes and Spaces in the Cinema of Emigration
by Şölen Köseoğlu and Merve Kılıçbay
Arts 2025, 14(5), 113; https://doi.org/10.3390/arts14050113 - 19 Sep 2025
Viewed by 1005
Abstract
International migration is a dynamic phenomenon that shapes urban spaces in Turkey. This study focuses on 18 films that depict the experiences of migrants who see Turkey as a transit country or a temporary stop, offering insights into their journeys and perspectives. Using [...] Read more.
International migration is a dynamic phenomenon that shapes urban spaces in Turkey. This study focuses on 18 films that depict the experiences of migrants who see Turkey as a transit country or a temporary stop, offering insights into their journeys and perspectives. Using a qualitative analysis of cinematic narratives and spatial representations, the study highlights key locations, such as Istanbul, the Aegean coasts, and occasionally the Black Sea, where migrants often find themselves in waiting spaces, like motels, barns, or warehouses, facing uncertainty, violence, and discrimination. By examining these spatial representations and symbolic elements, the study explores how cinema reflects migration’s social and urban impacts, demonstrating its potential as a tool for understanding this complex process. Full article
(This article belongs to the Section Film and New Media)
12 pages, 1655 KB  
Article
Two-Dimensional Multilayered Ferroelectric with Polarization-Boosted Photocatalytic Hydrogen Evolution
by Yu Peng, Liangyao Li, Yilin Xu, Xing Wang and Yu Hou
Catalysts 2025, 15(9), 910; https://doi.org/10.3390/catal15090910 - 18 Sep 2025
Viewed by 455
Abstract
Ferroelectric materials have attracted great attention for photocatalytic hydrogen (H2) evolution due to their internal depolarization fields that promote carrier separation and directional migration. However, conventional inorganic ferroelectrics often suffer from wide band gaps and low conductivity, limiting their solar-to-hydrogen conversion [...] Read more.
Ferroelectric materials have attracted great attention for photocatalytic hydrogen (H2) evolution due to their internal depolarization fields that promote carrier separation and directional migration. However, conventional inorganic ferroelectrics often suffer from wide band gaps and low conductivity, limiting their solar-to-hydrogen conversion efficiency. Here, we report a two-dimensional (2D) multilayered perovskite ferroelectric, [butylammonium]2[ethylammonium]2Pb3I10 (BAPI), which integrates robust spontaneous polarization (Ps) and excellent semiconductor properties to enable efficient photocatalysis. Under simultaneous light and ultrasonic excitation, BAPI/Pt (1 wt%) achieves a H2 evolution rate of 1256 μmol g−1 h−1, which is twice that under light alone, due to dynamic polarization modulation that mitigates ionic screening and enhances internal electric fields. Notably, this enhancement vanishes when BAPI transitions to a centrosymmetric, nonpolar phase at 323 K, confirming the critical role of Ps. These findings offer a new pathway toward high-performance ferroelectric photocatalysts for solar hydrogen production. Full article
(This article belongs to the Section Photocatalysis)
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15 pages, 5370 KB  
Article
Experimental Study on Proppant Backflow and Fiber Sand Control in Vertical Fracture Based on the Visual Diversion Chamber Simulation
by Yixin Chen, Yu Sang, Jianchun Guo, Weihua Chen, Feng Feng, Botao Tang, Hongming Fang, Jinming Fan and Zhongjun Ma
Processes 2025, 13(9), 2983; https://doi.org/10.3390/pr13092983 - 18 Sep 2025
Viewed by 296
Abstract
Hydraulic fracturing is a critical technical means for enhancing production in gas fields, and post-fracturing flow-back constitutes a crucial phase of fracturing operations. Proppant backflow during the flow-back process significantly impacts both the effectiveness of stimulation and subsequent production. Particularly for tight gas [...] Read more.
Hydraulic fracturing is a critical technical means for enhancing production in gas fields, and post-fracturing flow-back constitutes a crucial phase of fracturing operations. Proppant backflow during the flow-back process significantly impacts both the effectiveness of stimulation and subsequent production. Particularly for tight gas reservoirs, achieving rapid post-fracturing flow-back while preventing proppant re-flux is essential. To date, domestic and international scholars have conducted extensive research on proppant backflow during flow-back operations, with laboratory experimental studies serving as a vital investigative approach. However, due to limitations in experimental apparatuses, further investigation is required regarding the migration mechanisms of proppants during flow-back, proppant backflow prevention techniques, and associated operational parameters. This paper developed a novel visualized flow chamber capable of simulating proppant migration in vertical fractures under closure stress conditions. Extensive proppant backflow experiments conducted using this device revealed that (1) proppant backflow initiates at weak structural zones near the two-phase interface boundaries; (2) proppant backflow occurs in three distinct stages, with varying fluid erosive capacities on proppant particles at each phase; (3) a multi-stage fiber injection sand control process was optimized; (4) at low proppant concentrations (<10 kg/m2), the fiber concentration should be 0.8%; at high proppant concentrations (>10 kg/m2), the fiber concentration should be 1.2%. The recommended fiber length is 6 mm. Full article
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23 pages, 6245 KB  
Article
Removal of Cu and Pb in Contaminated Loess by Electrokinetic Remediation Using Novel Hydrogel Electrodes Coupled with Focusing Position Adjustment and Exchange Electrode
by Chengbo Liu, Wenle Hu, Xiang Zhu, Shixu Zhang and Weijing Wang
Processes 2025, 13(9), 2915; https://doi.org/10.3390/pr13092915 - 12 Sep 2025
Viewed by 362
Abstract
Electrokinetic (EK) remediation is a promising approach for the removal of heavy metals from fine-grained soils; however, its efficiency is often hindered by electrode polarization, pH imbalance, and ion accumulation. In this study, we developed a novel hydrogel-based electrode (NH electrode), composed of [...] Read more.
Electrokinetic (EK) remediation is a promising approach for the removal of heavy metals from fine-grained soils; however, its efficiency is often hindered by electrode polarization, pH imbalance, and ion accumulation. In this study, we developed a novel hydrogel-based electrode (NH electrode), composed of sodium alginate and multilayer graphene oxide (GO), to enhance the electrokinetic removal of Cu2+ and Pb2+ from loess. The electrode was systematically characterized by atomic force microscopy (AFM), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS), confirming its structural integrity, electrochemical activity, and interfacial conductivity. The NH electrode exhibited a smooth layered graphene structure with abundant oxygen-containing functional groups (AFM), negligible electrochemical polarization (CV), and low internal resistance with high conductivity (EIS), enabling efficient ion transport and adsorption. Electrokinetic tests revealed that the NH electrode outperformed conventional graphene (Gr) and electrokinetic graphite (EKG) electrodes. Single regulation strategies, including focusing position adjustment and electrode exchange, improved local removal efficiency by mitigating ion accumulation in targeted regions. The combined regulation strategy, integrating both measures, achieved the most uniform Cu2+ and Pb2+ removal, significantly suppressing hydroxide precipitation in cathodic zones and enhancing ion migration in the mid-section. Compared with literature-reported systems under similar or even more favorable conditions, the NH electrode and combined regulation approach achieved superior performance, with Cu2+ and Pb2+ removal efficiencies reaching 47.25% and 16.93%, respectively. These findings demonstrate that coupling electrode material innovation with spatial–temporal pH/flow field regulation can overcome key bottlenecks in EK remediation of heavy-metal-contaminated loess. Full article
(This article belongs to the Special Issue Advances in Heavy Metal Contaminated Soil and Water Remediation)
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29 pages, 2031 KB  
Review
Perfluorinated and Polyfluoroalkyl Compounds in the Atmosphere: A Review
by Haoran Yang, Ying Liang, Shili Tian, Xingru Li and Yanju Liu
Atmosphere 2025, 16(9), 1070; https://doi.org/10.3390/atmos16091070 - 10 Sep 2025
Viewed by 797
Abstract
Perfluoroalkyl and polyfluoroalkyl substances (PFASs) are a class of synthetic organic compounds with extremely high chemical stability and environmental persistence that are widely used in the industrial sector and in consumer goods. Their strong C-F bonds make them difficult to degrade, meaning they [...] Read more.
Perfluoroalkyl and polyfluoroalkyl substances (PFASs) are a class of synthetic organic compounds with extremely high chemical stability and environmental persistence that are widely used in the industrial sector and in consumer goods. Their strong C-F bonds make them difficult to degrade, meaning they can migrate through the atmosphere and settle over long distances, posing long-term risks to the global ecological environment and human health. This article systematically reviews the classification, physicochemical properties, concentration levels, spatial distribution, migration and transformation behaviors, and health and ecological impacts of PFASs in the atmosphere, along with related analytical detection techniques and pollution control methods. Studies show that short-chain PFASs are more likely to migrate through the atmosphere due to their high water solubility and volatility, while long-chain PFASs tend to be adsorbed onto particulate matter and display stronger bioaccumulation. Although atmospheric research on PFASs lags behind that focused on their dynamics in water and soil, the existing data still reveal a difference in their distribution and regional pollution characteristics in the gas and particle phases. Toxicological studies have confirmed that PFAS exposure is associated with liver injury, immunosuppression, developmental toxicity, and cancer risk and can threaten ecological security through the food chain. Currently, governance technologies are confronted with the challenges of low efficiency and high cost. In the future, it will be necessary to combine multi-media models, new analytical techniques, and international collaboration to promote the development of source control and innovative governance strategies. Full article
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