Search Results (67)

Electronic transport through T-shaped double quantum dots (TDQDs) connected to normal metallic leads is studied theoretically by using a nonequilibrium Green’s function method. It is assumed that the Coulomb interaction exists only in the central QD (QD-1) sandwiched between the leads, and it is absent in the other reference QD (QD-2) side-coupled to QD-1. We also consider the impacts of Majorana bound states (MBSs), which are prepared at the opposite ends of a topological superconductor nanowire (hereafter called a Majorana nanowire) connected to QD-2, on the electrical current and differential conductance. Our results show that by the combined effects of the Coulomb interaction in QD-1 and the MBSs, a negative differential conductance (NDC) effect emerges near the zero-bias point, where MBSs play significant roles. Now, the electrical current decreases despite the increasing bias voltage. The NDC is prone to occur under conditions of low temperature, and both of the two QDs’ energy levels are resonant to the leads’ zero Fermi energy. Its magnitude, which is characterized by a peak-to-valley ratio, can be enhanced up to 3 by increasing the interdot coupling strength, and it depends on the dot-MBS hybridization strength nonlinearly. This prominent NDC combined with the previously found zero-bias anomaly (ZBA) of the differential conductance is useful in designing novel quantum electric devices, and it may also serve as an effective detection means for the existence of MBSs, which is still a challenge in solid-state physics. Full article

The search for keV-scale sterile neutrinos in tritium beta decay is made possible through the theoretically allowed small admixture of electron flavor in right-handed, singlet, massive neutrino states. A distinctive feature of keV-scale sterile-neutrino–induced threshold distortions in the tritium beta spectrum is the presence of quantized nuclear-recoil effects, as predicted for atomic tritium bound to two-dimension materials such as graphene. The sensitivities to the sterile neutrino mass and electron-flavor mixing are considered in the context of the PTOLEMY detector simulation with tritiated graphene substrates. The ability to scan the entire tritium energy spectrum with a narrow energy window, low backgrounds, and high-resolution differential energy measurements provides the opportunity to pinpoint the quantized nuclear-recoil effects. providing an additional tool for identifying the kinematics of the production of sterile neutrinos. Background suppression is achieved by transversely accelerating electrons into a high magnetic field, where semi-relativistic electron tagging can be performed with cyclotron resonance emission RF antennas followed by deceleration through the PTOLEMY filter into a high-resolution differential energy detector operating in a zero-magnetic-field region. The PTOLEMY-based approach to keV-scale searches for sterile neutrinos involves a novel precision apparatus utilizing two-dimensional materials to yield high-resolution, sub-eV mass determination for electron-flavor mixing fractions of $|U_{e4}{|}^2\simeq {10}^{-5}$ and smaller. Full article

Addressing the technological bottlenecks in the efficient utilization of clay-type Li deposits in China, this study systematically investigates Li occurrence states and develops clean extraction processes using the Jinyinshan clay-type Li deposit in southern Hubei as a case study. The research aims to provide technical guidance for subsequent geological exploration and development of such deposits. Analytical techniques, including AMICS, EPMA, and LA-ICP-MS, reveal that Li primarily occurs in structurally bound forms within cookeite (82.55% of total Li), illite (6.65%), and rectorite (5.20%), with mineral particle sizes concentrated in fine-grained fractions (<45 μm). Leveraging process mineralogical insights, two industrially adaptable blank roasting–acid leaching processes were innovatively developed. Process I employs a full flow of blank roasting–hydrochloric acid leaching–Li-Al separation–Ca/Mg removal–concentration for Li precipitation–three-stage counter-current washing. Optimizing roasting temperature (600 °C), hydrochloric acid concentration (18 wt%), and leaching parameters achieved a 92.37% Li leaching rate. Multi-step purification yielded lithium carbonate with >99% Li₂CO₃ purity and an overall Li recovery of 73.89%. Process II follows blank roasting–sulfuric acid leaching–Al removal via alum precipitation–Al/Fe removal–freeze crystallization for sodium sulfate removal–Ca/Mg removal–concentration for Li precipitation–three-stage counter-current washing. Parameter optimization and freezing impurity removal achieved an 89.11% Li leaching rate, producing lithium carbonate with >98.85% Li₂CO₃ content alongside by-products like crude sodium chloride and ammonium alum. Both processes enable resource utilization of Al-rich residues, with the hydrochloric acid-based method excelling in stability and the sulfuric acid-based approach offering superior by-product valorization potential. This low-energy, high-yield clean extraction system provides critical theoretical and technical foundations for scaling clay-type Li deposit utilization, advancing green Li extraction and industrial chain development. Full article

Spectral features of photoionization of various levels of C III are reported. These include characteristics of Rydberg and Seaton resonances, low and high excited levels, lifetimes, and total and partial cross sections. Calculations are performed in the relativistic Breit–Pauli R-matrix method with close-coupling approximation, including damping effects on the resonance structure associated with the core-excited states produced by the electron excitation of C IV and photoionization of C III. For bound channel contribution, the close-coupling wavefunction expansion for photoionization includes ground and 14 excited states of the target ion CIV and 105 states configurations of C III. Extensive sets of atomic data for bound fine-structure levels, resulting in 762 dipole-allowed transitions, radiative probabilities, and photoionization cross sections out of J^π = 0^± − 4^± fine-structure levels are obtained. The ground-level photoionization cross section smoothly decreases with increasing energy, showing a very narrow, strong Rydberg resonance converging to the CIV 1s²2p threshold. The work shows that prominent Seaton resonances for 2sns states with n ≥ 5, caused by photoexcitation of the core electron below the 2p threshold, visibly contribute to photoabsorption from excited states of C III. The present results provide highly accurate parameters of various model applications in plasma spectroscopy. Full article

Within the framework of the XHe hypothesis, the positive results of the DAMA/NaI and DAMA/LIBRA experiments on the direct search for dark matter particles can be explained by the annual modulation of the radiative capture of dark atoms into low-energy bound states with sodium nuclei. Since this effect is not observed in other underground WIMP (weakly interacting massive particle) search experiments, it is necessary to explain these results by investigating the possibility of the existence of low-energy bound states between dark atoms and the nuclei of matter. Numerical modeling is used to solve this problem, since the study of the XHe–nucleus system is a three-body problem and leaves no possibility of an analytical solution. To understand the key properties and patterns underlying the interaction of dark atoms with the nuclei of baryonic matter, we develop the quantum mechanical description of such an interaction. In the numerical quantum mechanical model presented, takes into account the effects of quantum physics, self-consistent electromagnetic interaction, and nuclear attraction. This approach allows us to obtain a numerical model of the interaction between the dark atom and the nucleus of matter and interpret the results of direct experiments on the underground search for dark matter, within the framework of the dark atom hypothesis. Thus, in this paper, for the first time, steps are taken towards a consistent quantum mechanical description of the interaction of dark atoms, with unshielded nuclear attraction, with the nuclei of atoms of matter. The total effective interaction potential of the OHe–Na system has therefore been restored, the shape of which allows for the preservation of the integrity and stability of the dark atom, which is an essential requirement for confirming the validity of the OHe hypothesis. Full article

This study employs DFT at the APFD/def2-TZVP level, with SMD solvation in THF, to investigate the catalytic activation of methane by [(κ³-CNC)Fe(N₂O)]²⁺ cation complexes. The catalytic mechanism encompasses three key steps: oxygen atom transfer (OAT), hydrogen atom abstraction (HAA), and oxygen radical rebound (ORR). The computational results identify OAT as the rate-determining step, with activation barriers of −10.2 kcal/mol and 5.0 kcal/mol for κ¹-O- and κ¹-N-bound intermediates in the gas and solvent phases, respectively. Methane activation proceeds via HAA, with energy barriers of 16.0–25.2 kcal/mol depending on the spin state and solvation, followed by ORR, which occurs efficiently with barriers as low as 6.4 kcal/mol. The triplet (S = 1) and quintet (S = 2) spin states exhibit critical roles in the catalytic pathway, with intersystem crossing facilitating optimal reactivity. Spin density analysis highlights the oxyl radical character of the Fe^IV=O intermediate as being essential for activating methane’s strong C–H bond. These findings underscore the catalytic potential of CNC-ligated iron complexes for methane functionalization and demonstrate their dual environmental benefits by utilizing methane and reducing nitrous oxide, a potent greenhouse gas. Full article

Quantum illumination (QI) is an entanglement-based protocol for improving LiDAR/radar detection of unresolved targets beyond what a classical LiDAR/radar of the same average transmitted energy can do. Originally proposed by Seth Lloyd as a discrete-variable quantum LiDAR, it was soon shown that his proposal offered no quantum advantage over its best classical competitor. Continuous-variable, specifically Gaussian-state, QI has been shown to offer a true quantum advantage, both in theory and in table-top experiments. Moreover, despite its considerable drawbacks, the microwave version of Gaussian-state QI continues to attract research attention. A recent QI study by Armanpreet Pannu, Amr Helmy, and Hesham El Gamal (PHE), however, has: (i) combined the entangled state from Lloyd’s QI with the channel models from Gaussian-state QI; (ii) proposed a new positive operator-valued measurement for that composite setup; and (iii) claimed that, unlike Gaussian-state QI, PHE QI achieves the Nair–Gu lower bound on QI target-detection error probability at all noise brightnesses. PHE’s analysis was asymptotic, i.e., it presumed infinite-dimensional entanglement. The current paper works out the finite-dimensional performance of PHE QI. It shows that there is a threshold value for the entangled-state dimensionality below which there is no quantum advantage, and above which the Nair–Gu bound is approached asymptotically. Moreover, with both systems operating with error-probability exponents 1 dB lower than the Nair–Gu bound, PHE QI requires enormously higher entangled-state dimensionality than does Gaussian-state QI to achieve useful error probabilities in both high-brightness (100 photons/mode) and moderate-brightness (1 photon/mode) noise. Furthermore, neither system has an appreciable quantum advantage in low-brightness (much less than 1 photon/mode) noise. Full article

We explore the equivalence between the low-energy dynamics of strained graphene and a quantum mechanical framework for the 2D Dirac equation in flat space with a deformed momentum operator. By considering some common forms of the anisotropic Fermi velocity tensor emerging from the elasticity theory, we associate such tensor forms with a deformation of the momentum operator. We first explore the bound states of charge carriers in a background uniform magnetic field in this framework and quantify the impact of strain in the energy spectrum. Then, we use a quadrature algebra formula as a mathematical tool to analyze the impact of the deformation attached to the momentum operator and identify physical consequences of such deformation in terms of energy modifications due to the applied strain. Full article

A communication network integrating multiple modes can effectively support the sustainable development of next-generation wireless communications. Integrated sensing, communication, and power transfer (ISCPT) represents an emerging technological paradigm that not only facilitates information transmission but also enables environmental sensing and wireless power transfer. To achieve optimal beamforming in transmission, it is crucial to satisfy multiple constraints, including quality of service (QoS), radar sensing accuracy, and power transfer efficiency, while ensuring fundamental system performance. The presence of multiple parametric constraints makes the problem a non-convex optimization challenge, underscoring the need for a solution that balances low computational complexity with high precision. Additionally, the accuracy of channel state information (CSI) is pivotal in determining the achievable rate, as imperfect or incomplete CSI can significantly degrade system performance and beamforming efficiency. Deep reinforcement learning (DRL), a machine learning technique where an agent learns by interacting with its environment, offers a promising approach that can dynamically optimize system performance through adaptive decision-making strategies. In this paper, we propose a DRL-based ISCPT framework, which effectively manages complex environmental states and continuously adjusts variables related to sensing, communication, and energy harvesting to enhance overall system efficiency and reliability. The achievable rate upper bound can be inferred through robust, learnable beamforming in the ISCPT system. Our results demonstrate that DRL-based algorithms significantly improve resource allocation, power management, and information transmission, particularly in dynamic and uncertain environments with imperfect CSI. Full article

We study the resonant processes of the excitation of weakly bound ${\mathrm{NeAr}}^{+}$ ions in collisions with the free electrons of Ne/Ar mixture plasma under conditions typical of the active media of gas lasers and plasma-based UV radiation sources. The transitions leading to the population of charge transfer electronic terms are considered. Using an original theoretical approach developed recently, we study the dependences of the cross-sections of several competing resonant processes on the incident electron energy and the gas temperature of the plasma. The role of the continuous states of internuclear motion is discussed. We highlight the specific features of the processes considered that stem from the low binding energy of ${\mathrm{NeAr}}^{+}$ ions and demonstrate that, in the weakly bound systems, the efficiencies of different charge transfer excitation channels differ greatly from those obtained for ions with moderate dissociation energies. Full article

A novel double-impurity doping process for silicon (Si) surfaces was developed, utilizing nanosecond-laser melting of an 11 nm thick gold (Au) top film and a Si wafer substrate in a laser plasma-activated liquid nitrogen (LN) environment. Scanning electron microscopy revealed a fluence- and exposure-independent surface micro-spike topography, while energy-dispersive X-ray spectroscopy identified minor Au (~0.05 at. %) and major N (~1–2 at. %) dopants localized within a 0.5 μm thick surface layer and the slight surface post-oxidation of the micro-relief (oxygen (O), ~1.5–2.5 at. %). X-ray photoelectron spectroscopy was used to identify the bound surface (SiN_x) and bulk doping chemical states of the introduced nitrogen (~10 at. %) and the metallic (<0.01 at. %) and cluster (<0.1 at. %) forms of the gold dopant, and it was used to evaluate their depth distributions, which were strongly affected by the competition between gold dopants due to their marginal local concentrations and the other more abundant dopants (N, O). In this study, 532 nm Raman microspectroscopy indicated a slight reduction in the crystalline order revealed in the second-order Si phonon band; the tensile stresses or nanoscale dimensions of the resolidified Si nano-crystallites envisioned by the main Si optical–phonon peak; a negligible a-Si abundance; and a low-wavenumber peak of the Si₃N₄ structure. In contrast, Fourier transform infrared (FT-IR) reflectance and transmittance studies exhibited only broad structureless absorption bands in the range of 600–5500 cm⁻¹ related to dopant absorption and light trapping in the surface micro-relief. The room-temperature electrical characteristics of the laser double-doped Si layer—a high carrier mobility of 1050 cm²/Vs and background carrier sheet concentration of ~2 × 10¹⁰ cm⁻² (bulk concentration ~10¹⁴–10¹⁵ cm⁻³)—are superior to previously reported parameters of similar nitrogen-implanted/annealed Si samples. This novel facile double-element laser-doping procedure paves the way to local maskless on-demand introductions of multiple intra-gap intermediate donor and acceptor bands in Si, providing related multi-wavelength IR photoconductivity for optoelectronic applications. Full article

We report the absorption and photoluminescence spectra of GaSe single crystals in the near-edge region. The temperatures explored the range from 17 to 300 K. Specifically, at a temperature of 17 K, the photoluminescence spectrum reveals an interesting phenomenon: the Wannier-Mott exciton separates into two states. These states are a triplet state with an energy of 2.103 eV and a singlet state with an energy of 2.109 eV. The energy difference between these two states is 6 meV. Furthermore, the bound exciton (BX) can be localized at an energy of 2.093 eV. It is worth noting that its phonon replicas (BX-nLO) can be clearly distinguished up to the fourth order. Interestingly, the energy gaps between these replicas exhibit a consistent spacing of 7 ± 0.5 meV. This intriguing finding suggests a high-quality crystalline structure as well as a strong coupling between the phonon and BX-nLO. Additionally, at low temperatures, both the ground state (n = 1) at 2.11 eV and the excited state (n = 2) at 2.127 eV of free excitons can be observed. Full article

4-(4-nitrophenyl)thiomorpholine, the title compound, has been used as a precursor for the corresponding 4-thiomorpholinoaniline, which is a useful building block in medicinal chemistry. The crystal and molecular structures of the title compound, however, have not been described thus far. We synthesized the title compound by means of a nucleophilic aromatic substitution reaction of 4-fluoronitrobenzene and thiomorpholine and structurally characterized it by X-ray crystallography, DFT calculations, and Hirshfeld surface analysis. In the crystal, the molecule exhibits an approximately C_S-symmetric structure, with the nitrogen-bound 4-nitrophenyl group in a quasi axial position on the six-membered thiomorpholine ring in a low-energy chair conformation. The solid-state structure of the title compound is markedly different from that of its morpholine analogue. This can be ascribed to the formation of centrosymmetric dimers through intermolecular C–H···O weak hydrogen bonds involving the methylene groups adjacent to the sulfur atom and face-to-face aromatic stacking. Full article

In this paper, we update the phase-space factors for all two-neutrino double electron capture processes. The Dirac–Hartree–Fock–Slater self-consistent method is employed to describe the bound states of captured electrons, enabling a more realistic treatment of atomic screening and more precise binding energies of the captured electrons compared to previous investigations. Additionally, we consider all s-wave electrons available for capture, expanding beyond the K and $L_1$ orbitals considered in prior studies. For light atoms, the increase associated with additional captures compensates for the decrease in decay rate caused by the more precise atomic screening. However, for medium and heavy atoms, an increase in the decay rate, up to 10% for the heaviest atoms, is observed due to the combination of these two effects. In the systematic analysis, we also include capture fractions for the first few dominant partial captures. Our precise model enables a close examination of low Q-value double electron capture in ¹⁵²Gd, ¹⁶⁴Er, and ²⁴²Cm, where partial $KK$ captures are energetically forbidden. Finally, with the updated phase-space values, we recalculate the effective nuclear matrix elements and compare their spread with those associated with $2\nu {\beta }^{-}{\beta }^{-}$ decay. Full article

We, the QUARTET Collaboration, propose an experiment to measure the nuclear charge radii of light elements with up to 20 times higher accuracy. These are essential both for understanding nuclear physics at low energies, and for experimental and theoretical applications in simple atomic systems. Such comparisons advance the understanding of bound-state quantum electrodynamics and are useful for searching for new physics beyond the Standard Model. The energy levels of muonic atoms are highly susceptible to nuclear structure, especially to the mean square charge radius. The radii of the lightest nuclei (with the atomic number, $Z=1,2$) have been determined with high accuracy using laser spectroscopy in muonic atoms, while those of medium mass and above were determined using X-ray spectroscopy with semiconductor detectors. In this communication, we present a new experiment, aiming to obtain precision measurements of the radii of light nuclei $3\le Z\le 10$ using single-photon energy measurements with cryogenic microcalorimeters; a quantum-sensing technology capable of high efficiency with outstanding resolution for low-energy X-rays. Full article